Corner Charge Research Articles

Second‐Order Topological Insulator in Ferromagnetic Monolayer and Antiferromagnetic Bilayer CrSBr

Second‐order topological insulators (SOTIs) in 2D materials have attracted significant research interest. Recent theoretical predictions suggest that SOTIs can be achievable in 2D magnetic systems, especially within ferromagnetic (FM) materials. Yet, the quest for suitable 2D antiferromagnetic (AFM) materials capable of hosting magnetic SOTIs remains a challenge. Herein, utilizing first‐principles calculations and theoretical analysis, 2D CrSBr is proposed, including monolayer and bilayer forms, as a promising candidate for a magnetic high‐order topological insulator. The monolayer exhibits a FM ground state and features quantized fractional corner charge in its spin‐up channel in the absence of spin–orbital coupling (SOC), yielding fully spin‐polarized corner states. Intriguingly, the bilayer form adopts an AFM ground state while retaining the SOTI properties, with quantized corner charge in both spin channels. Remarkably, the SOTI properties in both monolayer and bilayer structures remain robust against the influence of SOC and symmetry‐breaking perturbations. The work not only identifies a tangible material for realizing 2D magnetic SOTIs, encompassing both FM and AFM phases, but also offers a path to explore the distinctive characteristics of SOTIs merged with magnetism.

General corner charge formulas in various tetrahedral and cubic space groups

General corner charge formulas in various tetrahedral and cubic space groups

Null Raychaudhuri: canonical structure and the dressing time

We initiate a study of gravity focusing on generic null hypersurfaces, non-perturbatively in the Newton coupling. We present an off-shell account of the extended phase space of the theory, which includes the expected spin-2 data as well as spin-0, spin-1 and arbitrary matter degrees of freedom. We construct the charges and the corresponding kinematic Poisson brackets, employing a Beltrami parameterization of the spin-2 modes. We explicitly show that the constraint algebra closes, the details of which depend on the non-perturbative mixing between spin-0 and spin-2 modes. Finally we show that the spin zero sector encodes a notion of a clock, called dressing time, which is dynamical and conjugate to the constraint.It is well-known that the null Raychaudhuri equation describes how the geometric data of a null hypersurface evolve in null time in response to gravitational radiation and external matter. Our analysis leads to three complementary viewpoints on this equation. First, it can be understood as a Carrollian stress tensor conservation equation. Second, we construct spin-0, spin-2 and matter stress tensors that act as generators of null time reparametrizations for each sector. This leads to the perspective that the null Raychaudhuri equation can be understood as imposing that the sum of CFT-like stress tensors vanishes. Third, we solve the Raychaudhuri constraint non-perturbatively. The solution relates the dressing time to the spin-2 and matter boost charge operators.Finally we establish that the corner charge corresponding to the boost operator in the dressing time frame is monotonic. These results show that the notion of an observer can be thought of as emerging from the gravitational degrees of freedom themselves. We briefly mention that the construction offers new insights into focusing conjectures.

Observation of a Higher-Order End Topological Insulator in a Real Projective Lattice.

The modern theory of quantized polarization has recently extended from 1D dipole moment to multipole moment, leading to the development from conventional topological insulators (TIs) to higher-order TIs, i.e., from the bulk polarization as primary topological index, to the fractional corner charge as secondary topological index. The authors here extend this development by theoretically discovering a higher-order end TI (HOETI) in a real projective lattice and experimentally verifying the prediction using topolectric circuits. A HOETI realizes a dipole-symmetry-protected phase in a higher-dimensional space (conventionally in one dimension), which manifests as 0D topologically protected end states and a fractional end charge. The discovered bulk-end correspondence reveals that the fractional end charge, which is proportional to the bulk topological invariant, can serve as a generic bulk probe of higher-order topology. The authors identify the HOETI experimentally by the presence of localized end states and a fractional end charge. The results demonstrate the existence of fractional charges in non-Euclidean manifolds and open new avenues for understanding the interplay between topological obstructions in real and momentum space.

Higher-order obstructed atomic insulator phase in pentagonal monolayer PdSe2

Abstract We investigate a pentagonal monolayer of palladium diselenide, a stable two-dimensional system, as a material realization of a crystalline phase with nontrivial topological electronic properties. We find that its electronic structure involves an atomic obstructed insulator related to higher-order topology, which is a consequence of the selenium-selenium bond dimerization along with inversion and time-reversal symmetry). By means of first-principles calculations and the analysis of symmetry indicators and topological invariants, we also characterize the electronic corner states associated with the atomic obstruction and compute the corresponding corner charge for a finite geometry, which is found to be not quantized but still inversion-protected. Applying tensile strain to the finite geometry we verify the robustness of the corner states and also achieve a strain-controlled variation of the corner charge magnitude.

Full-counting statistics of corner charge fluctuations

Full-counting statistics of corner charge fluctuations

Metal-organic framework as high-order topological insulator with protected corner modes

The capacity to design and manipulate the chemical characteristics of metal-organic frameworks (MOFs) presents a promising approach for developing functional materials, particularly with regard to their topological properties. Here, based on first-principles calculations, we predict Ni3(C6S6)2 as a two-dimensional (2D) higher-order topological insulator (HOTI) with protected corner modes, which is the first material example of such topological phase in MOFs reported so far. The non-trivial topology of the material is identified by two different classes of bulk topological invariants: the real Chen number induced by spacetime inversion symmetry, and the fractional corner charge induced by rotational symmetry. The presence of corner states can serve as a diagnostic of its nontrivial topology. Moreover, the HOTI natural is demonstrated to be robust against symmetry perturbations and spin-orbit coupling. Inspired by the topological properties of Ni3(C6S6)2, we can explore regulating organic ligands or metal atoms in metal-organic frameworks to realize other 2D HOTIs, thereby expanding the family of 2D HOTIs. Our findings not only broaden the understanding of physical properties of metal-organic materials, but also extend the study of high-order topological insulators to organic platforms.

Magnetic Second‐Order Topological Insulator: An Experimentally Feasible 2D CrSiTe3

Abstract2D second‐order topological insulators (SOTIs) have sparked significant interest, but currently, the proposed realistic 2D materials for SOTIs are limited to nonmagnetic systems. In this study, for the first time, a single layer of chalcogenide CrSiTe3—an experimentally realized transition metal trichalcogenide is proposed with a layer structure—as a 2D ferromagnetic (FM) SOTI. Based on first‐principles calculations, this study confirms that the CrSiTe3 monolayer exhibits a nontrivial gapped bulk state in the spin‐up channel and a trivial gapped bulk state in the spin‐down channel. Based on the higher‐order bulk–boundary correspondence, it demonstrates that the CrSiTe3 monolayer exhibits topologically protected corner states with a quantized fractional charge () in the spin‐up channel. Notably, unlike previous nonmagnetic examples, the topological corner states of the CrSiTe3 monolayer are spin‐polarized and pinned at the corners of the sample in real space. Furthermore, the CrSiTe3 monolayer retains SOTI features when the spin–orbit coupling (SOC) is considered, as evidenced by the corner charge and corner states distribution. Finally, by applying biaxial strain and hole doping, this study transforms the magnetic insulating bulk states into spin‐gapless semiconducting and half‐metallic bulk states, respectively. Importantly, the topological corner states persist in the spin‐up channel under these conditions.

Fractional mode charge in Cn-symmetric higher-order topological crystalline insulators

The measurement of topological insulators is usually achieved by measuring spectra, which is inadequate in higher-order topological insulators because the separation of bandgaps may be blurred, such as body boundaries and corner state hybridization, and the above measurement requires that the energy of the topological mode must be located in the bulk bandgap to be measured. Recent experiments have shown a strong relationship between the fractional mode charge and the location of the Wannier center in the crystal body. The fractional quantization of the corner charge originates from the filling anomaly, and the fractional mode charge can be calculated from experimental measurements of the local density of states to describe the topological state of the system, which has been demonstrated in optical systems. We have achieved a similar effect in acoustics by utilizing a coupled acoustic-cavity system featuring C3, C4, and C6 symmetries for simulation. Furthermore, we extended our study to 3D third-order topological crystalline insulators to validate the fractional-corner charge approach. The simulation and theoretical results demonstrate that the fractional mode charge can clearly identify the high-order topology, even without gap states.

Wannier topology and quadrupole moments for a generalized Benalcazar-Bernevig-Hughes model

We analyze a special separable and chiral-symmetric model with a quantized quadrupole moment, extending the Benalcazar-Bernevig-Hughes model [Science 357, 61 (2017)]. Using nested-Wilson loop formalism, we give an exact expression for Wannier centers, sector polarizations, and quadrupole moments. These are connected to the winding numbers of the constitutive one-dimensional chains. We prove that these winding numbers can characterize the model's Wannier topology as a $\mathbb{Z}\times\mathbb{Z}$ set. These results clearly show that the quantization of the quadrupole moment can arise without additional spatial symmetry (except for translation symmetry) for the bulk. By switching from the Wannier representation to the Bloch representation, we derive an alternative expression for the bulk quadrupole moment and obtain its exact value. Combining the bulk quadrupole and edge polarizations, we analytically calculate the corner charge in a large square system and make the bulk-boundary correspondence explicit in an edge-consistent gauge. Our work reveals the relationship between zero-energy states at the boundary, charge localization, and the bulk quadrupole of the extended model.

Many-body quadrupolar sum rule for higher-order topological insulators

The modern theory of polarization establishes the bulk-boundary correspondence for the bulk polarization. In this paper, we attempt to extend it to a sum rule of the bulk quadrupole moment by employing a many-body operator introduced in Kang et al. [B. Kang, K. Shiozaki, and G. Y. Cho, Phys. Rev. B 100, 245134 (2019)] and Wheeler et al. [W. A. Wheeler, L. K. Wagner, and T. L. Hughes, Phys. Rev. B 100, 245135 (2019)]. The sum rule that we propose consists of the alternating sum of four observables, which are the phase factors of the many-body operator in different boundary conditions. We demonstrate its validity through extensive numerical computations for various noninteracting tight-binding models. We also observe that individual terms in the sum rule correspond to the bulk quadrupole moment, the edge-localized polarizations, and the corner charge in the thermodynamic limit on some models.

Topological edge and corner states and fractional corner charges in blue phosphorene

We theoretically study emergent edge and corner states in monolayer blue phosphorus (blue phosphorene) using the first-principles calculation and tight-binding model. We show that the existence of the Wannier orbitals at every bond center yields edge states both in zigzag and armchair nanoribbons. The properties of the edge states can be well described by a simple effective Hamiltonian for uncoupled edge orbitals, where the structural relaxation near the boundary significantly affects the edge band structure. For corner states, we examine two types of corner structures consisting of zigzag and armchair edges, where we find that multiple corner states emerge in the bulk gap as a consequence of hybridization of edge and corner uncoupled orbitals. In the armchair corner, in particular, we demonstrate that corner states appear right at the Fermi energy, which leads to the emergence of fractional corner charge due to filling anomaly. Finally, we discuss the relationship between blue phosphorene and black phosphorene, and show that two systems share the equivalent Wannier orbital positions and similar edge/corner state properties even though their atomic structures are totally different.

Fractional hinge and corner charges in various crystal shapes with cubic symmetry

Higher-order topological insulators host gapless states on hinges or corners of three-dimensional crystals. Recent studies suggested that even topologically trivial insulators may exhibit fractionally quantized charges localized at hinges or corners. Although most of the previous studies focused on two-dimensional systems, in this work, we take the initial step toward the systematic understanding of hinge and corner charges in three-dimensional insulators. We consider five crystal shapes of vertex-transitive polyhedra with the cubic symmetry such as a cube, an octahedron, and a cuboctahedron. We derive real-space formulas for the hinge and corner charges in terms of the electric charges associated with bulk Wyckoff positions. We find that both the hinge and corner charges can be predicted from the bulk perspective only modulo certain fractions depending on the crystal shape, because the relaxation near boundaries of the crystal may affect the fractional parts. In particular, we show that a fractionally quantized charge $1/24$ mod $1/12$ in the unit of elementary charge can appear in a crystal with a shape of a truncated cube or a truncated octahedron. We also investigate momentum-space formulas for the hinge and corner charges. It turns out that the irreducible representations of filled bands at high-symmetry momenta are not sufficient to determine the corner charge. We introduce an additional Wilson-loop invariant to resolve this issue.

Spin-Polarized Fractional Corner Charges and Their Photonic Realization.

We demonstrate that a spin degree of freedom can introduce additional texture to higher order topological insulators (HOTIs), manifesting in novel topological invariants and phase transitions. Spin-polarized mid-gap corner states of various multiplicities are predicted for different HOTI phases, and novel bulk-boundary correspondence principles are defined based on bulk invariants such as total and spin corner charge. Those are shown to be robust to spin-flipping perturbations. Photonic realizations of spin-linked topological phases are demonstrated in engineered systems using pseudospin.

Fractional Corner Charge of Sodium Chloride

Recent developments in higher-order topological phases have elucidated on the relationship between nontrivial multipole moments in the bulk and the emergence of fractionally quantized charges at the boundary. Here, we put on the table a proposal of the three-dimensional octupole insulator with fractionally quantized corner charges $\pm e/8$: sodium chloride, commonly known as table salt. The fractional quantization of the corner charge is unaffected by the quantum fluctuation of the electric charge per ion, as we demonstrate explicitly with ab initio calculations. We further show that the electrostatic signature of the fractional charge is well-preserved even when the ideal crystal is sprinkled with defects, and provide a systematic analysis on how the corner charge contribution could be isolated from the electric-field corrections originating from realistic surface relaxation. Our results suggest that the observation of corner charges from quantized multipole moments in solids might be around the corner.

Exact higher-order bulk-boundary correspondence of corner-localized states

We demonstrate that the presence of a localized state at the corner of an insulating domain is not always a predictor of a certain non-trivial higher-order topological invariant, even though they appear to co-exist in the same Hamiltonian parameter space. Our analysis of $C^n$-symmetric crystalline insulators and their multi-layer stacks reveals that topological corner states are not necessarily correlated with other well-established higher-order boundary observables, such as fractional corner charge or filling anomaly. In a $C^3$-symmetric breathing Kagome lattice, for example, we show that the bulk polarization, which successfully predicts the fractional corner anomaly, fails to be the relevant topological invariant for zero-energy corner states; instead, these corner states can be exactly explained by the decoration of topological edges. Also, while the zero-energy corner states in $C^4$-symmetric topological crystalline insulators have long been conjectured to be the result of the bulk polarization at quarter-filling, we correct this misconception by introducing a proper bulk invariant at half-filling and establishing a precise bulk-corner correspondence. By refining several bulk-corner correspondences in two-dimensional topological crystalline insulators, our work motivates further development of rigorous theoretical grounds for associating the existence of corner states with higher-order topology of host materials.

Higher-order topological phases in tunable C3 symmetric photonic crystals

We demonstrate that multiple higher-order topological transitions can be triggered via the continuous change of the geometry in kagome photonic crystals composed of three dielectric rods. By tuning a single geometry parameter, the photonic corner and edge states emerge or disappear with higher-order topological transitions. Two distinct higher-order topological insulator phases and a normal insulator phase are revealed. Their topological indices are obtained from symmetry representations. A photonic analog of the fractional corner charge is introduced to distinguish the two higher-order topological insulator phases. Our predictions can be readily realized and verified in configurable dielectric photonic crystals.

Three-Dimensional Higher-Order Topological Insulator Protected by Cubic Symmetry

Recently discovered photonic higher-order topological insulators enable unprecedented flexibility in the robust localization of light in structures of different dimensionality. While the potential of the two-dimensional systems is currently under active investigation, only a few studies explore the physics of the three-dimensional higher-order topological insulators. Here we propose a three-dimensional structure with cubic symmetry exhibiting vanishing bulk polarization but nonzero corner charge and hosting a zero-dimensional corner state mediated by the long-range interactions. We trace the evolution of the corner state with the next-nearest-neighbor coupling strength and prove the topological origin of the corner mode calculating the associated topological invariants. Our results thus reveal the potential of long-range couplings for the formation of three-dimensional higher-order topological phases.

Multipolar topological field theories: Bridging higher order topological insulators and fractons

Two new recently proposed classes of topological phases, namely fractons and higher order topological insulators (HOTIs), share at least superficial similarities. The wide variety of proposals for these phases calls for a universal field theory description that captures their key characteristic physical phenomena. In this work, we construct topological multipolar response theories that capture the essential features of some classes of fractons and higher order topological insulators. Remarkably, we find that despite their distinct symmetry structure, some classes of fractons and HOTIs can be connected through their essentially identical topological response theories. More precisely, we propose a topological quadrupole response theory that describes both a 2D symmetry enriched fracton phase and a related bosonic quadrupolar HOTI with strong interactions. Such a topological quadrupole term encapsulates the protected corner charge modes and, for the HOTI, predicts an anomalous edge with fractional dipole moment. In 3D we propose a dipolar Chern-Simons theory with a quantized coefficient as a description of the response of both second order HOTIs harboring chiral hinge currents, and of a related fracton phase. This theory correctly predicts chiral currents on the hinges and anomalous dipole currents on the surfaces. We generalize these results to higher dimensions to reveal a family of multipolar Chern-Simons terms and related $\theta$-term actions that can be reached via dimensional reduction or extension from the Chern-Simons theories.

General corner charge formula in two-dimensional Cn -symmetric higher-order topological insulators

In this paper, we derive a general formula for the quantized fractional corner charge in two-dimensional ${C}_{n}$-symmetric higher-order topological insulators. We assume that the electronic states can be described by the Wannier functions and that the edges are charge neutral, but we do not assume vanishing bulk electric polarization. We expand the scope of the corner charge formula obtained in previous works by considering more general surface conditions, such as surfaces with higher Miller index and surfaces with surface reconstruction. Our theory is applicable even when the electronic states are largely modulated near system boundaries. It also applies to insulators with nonvanishing bulk polarization, and we find that in such cases the value of the corner charge depends on the surface termination even for the same bulk crystal with ${C}_{3}$ or ${C}_{4}$ symmetry, via a difference in the Wyckoff position of the center of the ${C}_{n}$-symmetric crystal.