Core Expansion Research Articles

Ion motion in strongly magnetized cluster laser plasma

Abstract This paper investigates the interaction of high intensity, circularly polarized, short laser pulses with heavy cluster plasma through analytical modelling and numerical simulations. The optimal parameters were found for the generation of several GigaGs, quasi-stationary magnetic field by using the upgraded analytical model and detailed 3D PIC simulations. It was confirmed that a field of such strength slows down the thermal expansion of the cluster core in the direction transverse to the laser beam axis, which can be used in nuclear physics. The generated inward shocks produce ion core compression, which is relevant to nuclear fusion. The electrostatic interaction between the rotating laser field, electrons and ions leads to ion spiral density distribution in the cluster’s transversal plane, which is absent in a cluster irradiated by linearly polarized pulses with the same parameters.

Axial compressive behavior of circular RC stub columns jacketed by UHPC and UHPFRC

This study investigated the axial compressive behavior of circular reinforced concrete (RC) stub columns jacketed by ultra-high performance concrete (UHPC) and ultra-high performance fiber reinforced concrete (UHPFRC). Eighteen composite columns were tested under compressive loadings on the entire section and only the RC section, while three control RC columns were tested under axial compression. Loading on the entire section exhibited a higher maximum compressive load and better expansion restraint than loading on the RC section. Adding 1 % and 2 % steel fibers by volume significantly increased the maximum compressive load and ductility index. However, the difference between 1 % and 2 % fiber content was not substantial. Maximum compressive load when loading on the entire section surpassed that when loading on the RC section, increasing by 75.6 %, 76.18 %, and 76.78 % for 0 %, 1 %, and 2 % steel fiber volume, respectively. Loading on the RC section led to faster cracking and failure, resulting in more tensile stress and lateral strain in the UHPC and UHPFRC jackets. Conversely, loading on the entire section maintained the expansion restraint even after reaching the maximum load. Columns with higher steel fiber volume demonstrated a greater enhancement in strength and ductility. Furthermore, a finite element model (FEM) using ABAQUS software was built to identify the experiments. Material models for UHPC, UHPFRC, and NSC core were proposed. The comparison between FEM and the test results shows that the FEM can predict accurately the behavior of tested columns. Based on developed FEM, a parametric study with the change of two variables, including the thickness and the compressive strength of the UHPC and UHPFRC layers, was conducted. The increase in the thickness of the UHPC or UHPFRC layer led to a remarkable increase in the maximum compressive load and ductility, indicating the importance of the thickness of the UHPC and UHPFRC jackets in restraining the expansion of the RC core. However, increasing the compressive strength of UHPC and UHPFRC had minimal impact on the maximum compressive load and ductility. Derived from these findings, UHPC and UHPFRC can be considered alternative material to provide lateral confinement to RC columns in addition to the traditional materials, indicating the potential application in strengthening or repairing damaged RC columns

Core Expansion and Spiral Breakup in Oscillatory Recovering Media

Core Expansion and Spiral Breakup in Oscillatory Recovering Media

Rapid repair of RC columns with post-tensioned external clamps

A recent technique for repair of damaged reinforced concrete (RC) columns is reviewed. The technique involves the application of external post-tensioned clamps. The clamps are composed of steel angles and high-strength steel rods. The pairs of angles are placed on the corners of the cross-section, and they are connected with steel rods to each other. To evaluate the effectiveness of the repair technique, four large-scale RC columns with insufficient transverse reinforcement were subjected to lateral displacement reversals and constant axial load. The tests were conducted in two phases: initial testing of columns with none to light transverse reinforcement, followed by the application of clamps on the damaged columns and further testing. The study focused on the efficacy of the clamps to a) restore the lateral-carrying capacity of damaged RC columns, and b) increase drift capacity. Variations in lateral expansion of the column core and their plausible correlations with damage and ‘repairability’ are examined. Within the conditions investigated, two key requirements are proposed for safe column repair: 1) the concrete in damaged columns with cross-sectional expansion exceeding 1% should be replaced or repaired before clamps are applied as a repair measure, and 2) clamps should be proportioned to resist 100% of the maximum plausible shear demand even though perceptible contributions to shear resistance attributable to the concrete were observed in columns repaired before excessive expansion occurred. In columns with crisscrossing inclined cracks leading to lateral cross-sectional expansion of up to 1%, clamps were observed to provide effective shear resistance comparable to what conventional transverse reinforcement can provide.

Controlling sonic rectangular jet with nozzle trailing edge modification

Sonic rectangular jet emanating from a convergent nozzle of aspect ratio 2 with modified trailing edge in the form of triangular extension on its widest side is investigated experimentally at different nozzle pressure ratios corresponding to underexpanded states of sonic jet. To assess the impact of trailing edge modification on jet mixing, the sonic rectangular jet from aspect ratio two plain convergent nozzle (without trailing edge modification) is also studied. The centerline pressure decay results at nozzle pressure ratios 2, 3, 4 and 5 confirm the superiority of modified jet (jet from trailing edge modified nozzle) over plain jet from the mixing point of view. At all the pressure ratios, the modified jet possessed shorter core and weaker shock and expansion waves compared to plain jet, which is an outcome of faster mixing of modified jet with ambient fluid. The enhanced mixing caused the modified jet to decay faster than the plain jet. An appreciable core length reduction of about 32% is noticed at pressure ratio of 5. The modified jet experienced increased spread along major axis than along minor axis owing to the restriction offered by the triangular extension on jet spread along minor axis. Thus, the axis switching was absent in modified jet compared to plain jet switching axes at all pressure ratios. The shadowgraph images confirmed the presence of weaker waves in the modified jet. Also, the images confirmed the absence of Mach disk in the modified jet at pressure ratio of 5 compared to plain jet.

Environmentally friendly and temperature resistant water-based drilling fluids with highly inhibitory synthetic nanocellulose polymers for deep sea drilling

The ocean is rich in sustainable hydrocarbon. The process of extracting these resources poses challenges such as coexistence of low temperature and high temperature, high pressure of deepwater and unpredictable shale formations. A kind of ionic crosslinking polymer consisting of N, N-dimethylacrylamide (DMA), 2-acrylamido-2-methylpropane sulfonic acid (AMPS), and Cellulose Nanofibers (CNF) (PADC), was synthesized to address these challenges. Cellulose was first oxidized to nanocellulose (CNF) through 2,2,6,6-tetramethylpiperidinyl-1-oxide (TEMPO) oxidation. Subsequently, the ionic crosslinking polymer, consisting of DMA, AMPS, and CNF, was synthesized using ionic crosslinking polymerization. The surface characteristics and morphology were characterized by transmission electron microscopy (TEM), nanoparticle size analysis, and zeta potential analysis. The structural composition was analyzed by Fourier Transform Infrared Spectroscopy (FT-IR). The shale inhibition mechanism was investigated through contact angle and pressure transmission experiments. The results indicated that the average length of PADC is approximately 1450 nm, with an average diameter of less than 100 nm and contains sulfonic acid groups. The shale contact angle increased from 16.75° to 82°, indicating that PADC increased the hydrophobicity of the shale by 390%. Pressure transfer experiments show that PADC can reduce shale permeability by 37%, which means PADC has good hydration inhibition performance. In addition, a drilling fluid system suitable for deep sea drilling was proposed. The drilling fluid system exhibits good rheological properties at 160 °C and 0 °C. The fluid loss after hot rolling at 160 °C is less than 12 mL. The linear expansion of shale core after 16 h is only 0.7%, and the rolling recovery rate at 160 °C is as high as 99.48%. Luminescent bacteria EC50 is 2.0 × 105 mg/L, which means it is non-toxic and environmentally friendly. And drilling fluid conforms to the power law flow model. Therefore, the drilling fluids proposed in this paper can meet the requirements of deep sea drilling in terms of rheological properties and filtration loss properties at 0–160 °C, and can seal shale pores and inhibit shale hydration through the ionic cross-linking PADC. This research offers insights into the utilization of cellulose in well drilling processes and provides references for designing deep sea drilling fluids.

Local core expanding-based label diffusion and local deep embedding for fast community detection algorithm in social networks

Community detection is a key task in social network analysis, as it reveals the underlying structure and function of the network. Various global and local techniques exist for uncovering community structures in social networks wherein diffusion-based algorithms are proposed as novel methods for local community detection, particularly suited for large-scale networks. The efficacy of diffusion processes and initial detection is paramount in the successful identification of community structures within social networks. This effectiveness hinges significantly on the meticulous selection of the label diffuser core, which serves as the foundation for propagating labels through the network, and the precise labeling of boundary nodes. Addressing the constraints of current community detection algorithms, notably their time complexity and efficiency, this paper proposes a novel local community detection algorithm that combines core expansion with label diffusion, and deep embedding techniques. In the proposed method, a new centrality measure is introduced for appropriate core selection to facilitate precise label diffusion in the initial phase. Subsequently, a deep embedding technique is employed for updating labels of boundary and core nodes using the GraphSage embedding method. Finally, a rapid merging step is executed to amalgamate initially proximate communities into finalized community structures in large-scale social networks. We evaluate our algorithm on 14 real-world and 4 synthetic networks and show that it outperforms existing methods in terms of NMI, F-measure, ARI, and modularity. According to numerical results, the proposed method shows approximately 1.04 %, 1.03 %, and 1.12 % improvement in F-measure, NMI, and ARI measures respectively, compared to the second-best method, LBLD, in the networks with ground-truth. In addition, our method is able to accurately identify communities in large-scale networks such as Orkut, YouTube, and LiveJournal, where it ranks among the top-performing methods. Our approach exhibits the best performance in terms of ARI compared to other algorithms under comparison.

Regulating interaction with surface ligands on Au25 nanoclusters by multivariate metal–organic framework hosts for boosting catalysis

ABSTRACT While atomically precise metal nanoclusters (NCs) with unique structures and reactivity are very promising in catalysis, the spatial resistance caused by the surface ligands and structural instability poses significant challenges. In this work, Au25(Cys)18 NCs are encapsulated in multivariate metal–organic frameworks (MOFs) to afford Au25@M-MOF-74 (M = Zn, Ni, Co, Mg). By the MOF confinement, the Au25 NCs showcase highly enhanced activity and stability in the intramolecular cascade reaction of 2-nitrobenzonitrile. Notably, the interaction between the metal nodes in M-MOF-74 and Au25(Cys)18 is able to suppress the free vibration of the surface ligands on the Au25 NCs and thereby improve the accessibility of Au sites; meanwhile, the stronger interactions lead to higher electron density and core expansion within Au25(Cys)18. As a result, the activity exhibits the trend of Au25@Ni-MOF-74 > Au25@Co-MOF-74 > Au25@Zn-MOF-74 > Au25@Mg-MOF-74, highlighting the crucial roles of microenvironment modulation around the Au25 NCs by interaction between the surface ligands and MOF hosts.

Axial compressive behavior of low-alkalinity seawater sea-sand concrete column reinforced with hydrophobic longitudinal SFCBs and FRP hoops

To address corrosion problem of steel bars and shortage of freshwater and river sand in marine and offshore structures, a novel hydrophobic-modified longitudinal steel-FRP composite bars (SFCB) and FRP hoops reinforced low-alkalinity seawater sea-sand concrete (SWSSC) is developed. However, axial compressive behavior of hybrid SFCB and FRP reinforced columns is not clear and the applicability of existing design methods is low. Here, nine hybrid reinforced columns have been designed and tested. Typical failure modes of columns and axial compressive behavior of constituent materials (i.e., hydrophobic reinforcements and low-alkalinity SWSSC) are investigated. It is found that the synergistic confining effect formed by hybrid reinforcement are significant. The mesh confinement formed by densely distributed FRP hoops and longitudinal SFCBs improves the local buckling behavior, and effectively constrains the lateral expansion of concrete core, resulting in improved compressive strength and ductility of column. The compressive contribution of single longitudinal SFCB to ultimate load capacity of column can be enhanced effectively, up to 36.3 %, by increasing steel content of SFCB. Based on this, a prediction model of hybrid reinforced columns is proposed, which can accurately evaluate the ultimate load capacity. This work provides valuable experimental observations and load capacity model for hybrid reinforced column, which promote its design and application in marine engineering.

Startup and Multiphysics Analysis of a Compact kW-Class Thermal Spectrum Microreactor

Self-regulating compact nuclear microreactor concepts are being developed for use in space and at terrestrial remote sites. The current emphasis is on the development of high-assay low-enriched uranium–fueled reactors that rely on metal hydrides to achieve size, specific weight, and power parity with the legacy highly enriched uranium systems. In the case of terrestrial applications, metal hydride–moderated systems can also improve economic feasibility. The neutronic design of metal hydride–moderated high-temperature reactor cores is complicated by the need to optimize and synchronize delayed spatial and temporal reactivity feedback from outer reflectors. Zebra is a thermal spectrum proof-of-principle core designed for demonstrating the reactor dynamics of hydride-moderated spectrum reactors, which is studied in this work. The reactor, including the fuel, yttrium hydride moderator, heat pipes, central control rod, structural supports, and the beryllium reflector, weighs ~425 kg. The design shares several features common with nuclear criticality test geometries routinely used in National Criticality Experiments Research Center (NCERC) experiments such that a prototype of the reactor can be readily assembled and tested. Additional features, such as heat pipes and hydrogen barrier clads, were added to minimize the potential for large thermal gradients that in turn could induce hydrogen loss or structural deformation during extended periods of operation at ~1000 K. In this work, normal and off-normal state performance of the Zebra rector core was analyzed using MCNP and Abaqus-based Reactor Multiphysics (MARM) software. Up-to-date nuclear, thermal, and mechanical performance data were used to characterize the performance of the yttrium hydride moderator. Steady-state analyses established that at a postulated power between 20 and 50 kW(thermal), the reactor core is nearly isothermal irrespective of quality of conduction coupling between heat pipes and fuel plates. Additionally, heat pipe failure modes, including simultaneous failure of all heat pipes in a quadrant of a reactor, were examined to bound the maximum credible temperature spike in the reactor core for extreme off-normal operating conditions. Finally, we detail the startup design challenges for the hydride-moderated thermal core, and analyze load-following cases to achieve “self-regulation” using the Dynamic Analysis of Reactor Transients module of MARM. The reactor is self-regulating with a reactivity temperature coefficient of ~−1 pcm/K at the operating point based solely on nuclear cross-section feedback. It can be further strengthened using additional spectral shift neutron absorbers and incorporating design features that enhance core expansion. This work captures that hydride-moderated systems are feasible for various self-regulating applications once systematic checks are verified in order to achieve a well-engineered core design.

The Church Museums’ Evolution of the Idea and Methods of Missionary Work in China: A Study of Tsinanfu Institute

The Church Museums’ Evolution of the Idea and Methods of Missionary Work in China: A Study of Tsinanfu Institute

The spatial‐temporal evolution of urban development patterns in Chinese cities: Dynamics and interpretations

AbstractThis paper examines the spatial‐temporal evolution of urban spatial structure across 269 Chinese prefectural cities from 2002 to 2019. Our analysis identifies a consistent trend toward a more polycentric configuration in the 25 Chinese mega‐cities during this period, primarily due to population growth and a supportive policy environment. However, the evolutionary pathways of small‐ and medium‐sized cities unfolded in a rather complex and diverse manner, with some becoming more polycentric while the majority adhering to a monocentric trajectory. In these cases, population growth is usually associated with a more monocentric pattern, characterized by rapid expansion of the urban core, while polycentric development is primarily attributed to specific spatial policies that support the emergence of subcenters. We conclude that polycentric development, while potentially suitable for mega‐cities to alleviate diseconomies of scale, may be less appropriate for small‐ and medium‐sized cities as it may constrain growth associated with agglomeration economies. We suggest that the development and implementation of regional spatial policy should be considerate of local historical paths and contextual factors. Finally, we propose a stylized framework to more accurately reflect the diverse and complex nature of urban spatial structure evolution in Chinese prefectural cities.

Diastereoselective Synthesis of Dihydrobenzofuran Spirooxindoles and Their Transformation into Benzofuroquinolinones by Ring Expansion of Oxindole Core.

A mild and efficient approach for the diastereoselective synthesis of dihydrobenzofuran spirooxindoles using 3-chlorooxindoles and imines is presented. This process involves a formal [4 + 1] annulation, yielding the product with excellent diastereoselectivity. Furthermore, a novel method for constructing benzofuroquinolinone scaffolds through the ring expansion of oxindoles has been established. This method involves a lactam ring expansion to the quinolinone skeleton. Besides, a one-pot procedure for creating benzofuroquinolinone scaffolds from 3-chlorooxindoles and imines is also provided.

Enhanced Optic Nerve Expansion and Altered Ultrastructure of Elastic Fibers Induced by Lysyl Oxidase Inhibition in a Mouse Model of Marfan Syndrome

Two major constituents of exfoliation material (XFM), fibrillin- 1 and lysyl oxidase-like 1 (encoded by FBN1 and LOXL1) are implicated in exfoliation glaucoma (XFG), yet their individual contributions to ocular phenotype are minor. To test the hypothesis that a combination of FBN1 mutation and LOXL1 deficiency exacerbates ocular phenotypes, pan-LOX inhibitor, β-aminopropionitrile (BAPN) was used to treat adult wild-type (wt) and Fbn1C1041G/+ mice for 8 weeks and their eyes were examined. Although intraocular pressure was not changed and XFM not detected in the eyes, BAPN treatment worsened optic nerve and axon expansion in Fbn1C1041G/+ mice, an early sign of axonal damage in rodent models of glaucoma. Disruption of elastic fibers was only detected in Fbn1C1041G/+ mice, which increased with BAPN treatment, revealed by histological and immunohistochemical staining of the optic nerve pia mater. Transmission electron microscopy showed that Fbn1C1041G/+ mice had fewer microfibrils, smaller elastin cores and lower density of elastic fibers as compared to wt mice in control groups. BAPN treatment led to elastin core expansion in both wt and Fbn1C1041G/+ mice, but an increase in the density of elastic fiber was confined to Fbn1C1041G/+ mice. LOX inhibition had a stronger effect on optic nerve and elastic fiber parameters in the context of Fbn1 mutation, indicating Marfan mouse model with LOX inhibition warrants further investigation for XFG pathogenesis.

Tetrylene-Functionalized Si7-Siliconoids.

The core expansion of metallic or metalloid clusters by the addition of further homo- or heteronuclear vertices is pivotal to the nucleation and growth of particles. The exohedral grafting of a low-valent functionality followed by endohedral incorporation have been identified as key steps. Following previous work on the Si6 series, we now report the synthesis and full characterization of the amidinatotetrylene-functionalized seven-vertex siliconoids Si7R5[E(NtBu)2CPh] (E = Si, Ge, Sn). In the case of the silylene derivative, the solid-state structure was determined by single crystal X-ray diffraction.

Controlled cluster expansion at a Zintl cluster surface

AbstractReaction of the tris‐hypersilyl nonagermanide Zintl cluster salt, K[Ge9(Hyp)3] (Hyp=Si(SiMe3)3) with [Rh(η2,η2‐L)Cl]2 (L=1,5‐cyclooctadiene, COD; norbornadiene, NBD) afforded eleven‐ and twelve‐vertex homo‐multimetallic clusters by cluster core expansion. Using a stepwise procedure, starting from the Zintl cluster [Rh(COD){Ge9(Hyp)3}] and [Ir(COD)Cl]2, this methodology was expanded for the synthesis of eleven‐vertex hetero‐multimetallic clusters. A mechanism for the formation of these first examples of closo eleven‐vertex Zintl clusters is proposed, informed by density functional theory calculations.

Controlled cluster expansion at a Zintl cluster surface.

Reaction of the tris-hypersilyl nonagermanide Zintl cluster salt, K[Ge9 (Hyp)3 ] (Hyp=Si(SiMe3 )3 ) with [Rh(η2 ,η2 -L)Cl]2 (L=1,5-cyclooctadiene, COD; norbornadiene, NBD) afforded eleven- and twelve-vertex homo-multimetallic clusters by cluster core expansion. Using a stepwise procedure, starting from the Zintl cluster [Rh(COD){Ge9 (Hyp)3 }] and [Ir(COD)Cl]2 , this methodology was expanded for the synthesis of eleven-vertex hetero-multimetallic clusters. A mechanism for the formation of these first examples of closo eleven-vertex Zintl clusters is proposed, informed by density functional theory calculations.

Macrophage-specific deletion of MIC26 (APOO) mitigates advanced atherosclerosis by increasing efferocytosis

Background and aimsRecent studies have suggested that MIC26 (apolipoprotein O, APOO), a novel mitochondrial inner membrane protein, is involved in inflammation. Thus, the role of macrophage MIC26 in acute inflammation and chronic inflammatory disease atherosclerosis was investigated. MethodsMacrophage-specific MIC26 knockout mice (MIC26LysM) were generated by crossing Apooflox/flox and LysMcre+/- mice. An endotoxemia mouse model was generated to explore the effects of macrophage MIC26 deficiency on acute inflammation, while an atherosclerosis mouse model was constructed by crossing MIC26LysM mice with Apoe−/− mice and challenged with a Western diet. Atherosclerotic plaques, primary macrophage function, and mitochondrial structure and function were analyzed. ResultsMIC26 knockout did not affect the median survival time and post-injection serum interleukin 1β concentrations in mice with endotoxemia. Mice with MIC26 deficiency in an Apoe−/− background had smaller atherosclerotic lesions and necrotic core than the control group. In vitro studies found that the loss of MIC26 did not affect macrophage polarization, apoptosis, or lipid handling capacity, but increased efferocytosis (the ability to clear apoptotic cells). An in situ efferocytosis assay of plaques also showed that the ratio of macrophage-associated apoptotic cells to free apoptotic cells was higher in the MIC26-deficient group than in the control group, indicating increased efferocytosis. In addition, an in vivo thymus efferocytosis assay indicated that MIC26 deletion promoted efferocytosis. Mechanistically, the loss of MIC26 resulted in an abnormal mitochondrial inner membrane structure, increased mitochondrial fission, and decreased mitochondrial membrane potential. Loss of MIC26 reduced mitochondria optic atrophy type 1 (OPA1) protein, and OPA1 silencing in macrophages promoted efferocytosis. Overexpression of OPA1 abolished the increase in efferocytosis produced by MIC26 deficiency. ConclusionsMacrophage MIC26 deletion alleviated advanced atherosclerosis and necrotic core expansion by promoting efferocytosis. This mechanism may be related to the increased mitochondrial fission caused by reduced mitochondrial OPA1.

Steady-state multi-physics coupling analysis of heat pipe cooled reactor core

The employment of heat pipe reactors is gaining significant traction due to their exceptional advantages in terms of mobility, safety, and applicability across a wide range of scenarios, including strategic defense locations, remote communities, and situations of power shortage. Importantly, most of the heat pipe reactors are designed as solid-state reactors, which avoids the challenges associated with two-phase flow problems that commonly arise from coolant transformation and makes it possible to analyze the reactor through the integration of multiple physical field coupling. In this paper, we conduct a 3D neutronic-thermal-mechanical coupled performance analysis of a heat pipe reactor operating under steady-state conditions. This analysis employs a combination of the Monte Carlo code and finite element analysis software, facilitating in-depth insights into the behavior of reactor. Coupling calculation results show that under normal operation, the maximum temperature and thermal expansion of core is 1338.94 K and 2.53 mm. In the steady-state coupling process, the influence of temperature parameters on neutronic calculation is mainly reflected in keff and its power level, the maximum temperature drops from 1347.26 K to 1338.94 K, but it has little influence on power distribution. By coupling calculations, the maximum stress of the reactor is reduced by 5.78 MPa. The research results will support the subsequent development of multi-physics coupled transient analysis code for heat pipe reactors.

Uniform Li-ion diffusion and robust solid electrolyte interface construction for kilogram-scale Si@ZIF powder as the anode in Li-ion batteries

The zeolitic imidazolate framework (ZIF) is characterized by a highly ordered structure, large cavities, and thermal/chemical stabilities and has been widely researched for energy storage. In this study, using commercial Si powder with a diameter of 50–200 nm at a kilogram scale, Si@ZIF core-shell particles with dispersed ZIF-8 rhombic dodecahedrons were fabricated by a one-pot method and achieved excellent electrochemical performance. With the specific pore diameter and ordered network formed by membered rings, experimental results demonstrated that the ZIF-8 shell realized a uniform and accelerated Li+ diffusion route, alleviated volumetric expansion of the Si core, and constructed a LiF-concentrated robust solid electrolyte interface film with less unnecessary consumption of electrolyte and Li+. Density functional theory calculations verified the higher adsorption energy for Li-solvated clusters and the de-solvation effect on the surface of ZIF-8, which can increase Li+ concentration along the one-dimensional channels of 4-membered ring with a diameter similar to that of Li+ for high-speed and uniform Li+ intercalation. Furthermore, the large and elastic rhombic dodecahedrons formed by pure ZIF-8 buffered the volume change and maintained the integrity of the Si electrode during cycling. As a result, the Si@8Z anode achieved a reversible capacity of 818.5 mAh g−1 after 650 cycles at 1 A g−1 with a high initial coulombic efficiency of 88.2 % and outstanding rater performance even at 8 A g−1. Nevertheless, the capacity of the Si anode decreased to 0 mAh g−1 after 200 cycles. The present work clarifies the effect of ZIF on the performance of Si anodes and provides a simple method to modify commercial Si powder.