Understanding the spatial and temporal dynamics of air pollutants is crucial for effective urban air pollution management. This study focuses on the temporal dynamics of air quality monitoring stations (AQMSs) and the association among air pollutants, particularly PM2.5, in Tehran, Iran. Using time series clustering and the Copula model, we analyzed data from 2019 to 2022. We found that the levels and dynamics of O3 and SO2 were similar across most AQMSs and unrelated to geographical positions. CO levels and dynamics were consistent among urban and border AQMSs, with higher concentrations in urban stations. NO2 levels and dynamics varied significantly among northern AQMSs with no relationship geographical positions. PM10 levels and dynamics had a relationship with geographical positions, with western clusters having the highest and northern clusters the lowest concentrations. The dynamics of PM2.5 showed significant relationship among AQMSs in the eastern, southern, and western regions, but not in the north. We also observed that PM10 and O3 levels were higher in warm seasons, whereas CO, SO2, NO2, and PM2.5 levels were higher in cold seasons. Most pollutants, except O3, peaked during traffic hours. Notably, the significant increase in PM2.5 since spring 2021 was primarily due to PM10. Policymakers should focus on these spatial and temporal variations to improve urban air quality and public health outcomes through targeted interventions.