In this research study, fuel blends of pine oil and waste cooking oil biodiesel (P/WCO) were examined for combustion analysis, engine performance, and emission characteristics tests. Improved combustion and engine performance were achieved using a toroidal re-entrant combustion chamber (TCC) and hydrogen supply as a dual fuel. The combustion behavior of fuel blends and hydrogen fuel was examined by varying the engine load at a constant speed. The results revealed that significant reduction in the specific fuel consumption for rich pine oil. Thus, a slightly lesser energy share from the fuel blends and a higher energy share from the hydrogen fuel was required for the engine to maintain the same brake power. Lower viscosity, higher flash point, and presence of oxygen in the pine oil enhance the combustion rate and brake thermal efficiency. Furthermore, hydrogen induction in the engine improves the flame velocity. A lesser crevice volume in the TCC can trap the unburnt fuel which can further increase the combustion efficiency. Thus, rich pine oil with the support of hydrogen induction in TCC causes advanced ignition, improved combustion, and more heat release during the combustion. The investigation results revealed that hydrogen induction increases the heat release rate and peak pressure by 7.4% and 2.67%, respectively. Similarly, the maximum of 24.55% increase in BTE and 18.22% reduction in BSFC was observed due to a constant 10 lpm hydrogen induction. Furthermore, hydrogen fuel significantly reduces the emissions such as CO, HC, CO2, and smoke. However, more NOx was generated due to more heat release rate during combustion. Thus, pine oil and waste cooking oil biodiesel blends with the support of hydrogen induction in TCC improve the engine performance and mitigate the toxic pollutants and can be a suitable alternative to diesel fuel.