Conversion Of Organic Waste Research Articles

Characteristics and biological mechanism of protein degradation by the black solider fly (Hermetia illucens L.) larvae gut strain Bacillus subtilis S4

The black solider fly larvae (BSFL) can efficiently convert nitrogen in organic waste into insect protein. Bacillus subtilis S4, an efficient protein-degrading bacterium from the BSFL gut, was isolated and identified to explore the mechanism of nutrient metabolism underlying BSFL nitrogen utilization. Results showed that B. subtilis S4 could effectively increase larval biomass in a bean stem bioconversion system. In vitro high-performance liquid chromatography analysis showed that B. subtilis S4 completely degraded casein into Val, Ile, Phe, Leu, Tyr, Lys, Gly, and Met. Various protease genes with secretion expression ability were annotated in B. subtilis S4. They included peptidoglycan DL - endopeptidase, aminopeptidase, extracellular metalloprotease, peptidoglycan endopeptidase, and peptidase M15. Therefore, the BSFL intestinal microbe B. subtilis S4 could effectively degrade protein and promote larval biomass accumulation, which could provide novel insights into the combined conversion of organic waste into proteins by microbes and insects.

Insect Production: A Circular Economy Strategy in Iceland

In this review, the multifaceted issue of food security is addressed, emphasizing the need for innovative and culturally appropriate solutions. Exploring insect livestock farming emerges as a potential remedy, offering a pathway to alleviate food insecurity and promote food sovereignty, particularly when integrated with social acceptability. Stakeholder engagement on both production and consumption fronts, coupled with sustained support, is vital for successful implementation. The expanding landscape of commercial insect farming in the West prompts questions about its broader scalability and equitable deployment, especially for vulnerable populations. Existing research gaps underscore the need for a coordinated effort across international, national, and legal frameworks to effectively integrate insect farming into existing agricultural systems. In this review, we have delved into the industrial-scale production processes of mealworms and black soldier flies (BSFs), known for their high protein content and organic waste conversion, covering small and industrial cultivation methods, offering insights into mealworm production life cycles, innovative rearing systems, and harvesting techniques. This review concludes with climate-specific recommendations for insect facilities, stressing the importance of sustainable practices, continuous research and development, effective market strategies and economic feasibilities in Iceland. In the context of escalating demand for sustainable protein sources, industrial-scale insect production emerges as a pivotal player in addressing global food security challenges.

A concentric 3D-printed centrifuge rotor to study the effects of hypergravity on small organisms at three different but concurrent radial accelerations

For life to reach space, it must first escape Earth's gravity—hence exposure to hypergravity during launch, and interplanetary acceleration and deceleration. Long-term colonisation of space requires the establishment of sustainable, in situ, food production systems. Earthworms may be involved as a regolith/soil ameliorant, a source of protein, and for organic waste conversion. Earthworms, however, have hydrostatic skeletons that may be susceptible to hypergravity exposure. We investigated whether earthworms (Eisenia andrei) would survive prolonged centrifugal hypergravity using a table-top centrifuge. Our intention was to concurrently test three different hypergravity treatments (plus a 1 G control). Our concentric rotor concept, with appropriate design adaptations, allows concurrent testing of three different gravity treatments on small- and microorganisms, cell cultures, plants, microcosm, and chemical/biochemical reactions for extended periods of hours to months. Our concentric concept therefore is easily adaptable and may facilitate other terrestrial-based research on chemical, molecular, and organismal levels.•We designed a 3D-printed centrifuge rotor with three concentric rings, each ring with four separate 125 mL compartments.•This design was tested with an 8-day pilot run with four young worms per container at 1.7 G, 2.5 G, and 3.1 G, with a 1 G control.•All worms at all treatments gained body mass, the mean increases of which were almost indistinguishable between treatments, illustrating the utility of the design.

Biochars from waste as an additive material in anaerobic co-digestion: Characterization and application in batch and semi-continuous systems

The conversion of organic waste into energy through anaerobic digestion (AD) is a profitable and environmentally friendly strategy. Enhancing the process is crucial for optimizing and maximizing biogas and methane production. To achieve this, various strategies can be employed, such as anaerobic co-digestion (co-AD) and the use of biochar. Biochar aids in process stability, provides buffering capacity, mitigates inhibitory toxins, immobilizes microorganisms, facilitates microbial colonization, and accelerates electron transfer between microorganisms. This study aimed to produce biochar from different wastes and pyrolysis temperatures and to investigate its use as an additive material in the co-AD of fruit and vegetable waste (FVW) and laying chicken manure (LCM) in batch and semi-continuous systems. Thermogravimetric analysis (TGA) and differential scanning calorimetry were performed to determine the pyrolysis temperature for biochar production, defining temperatures of 450 and 550 °C. A biochemical methane potential (BMP) test was conducted in 120 mL reactors (working volume) with the addition of 10 g/L of biochar from FVW, LCM, and wood pruning waste (WPW). WPW450 biochar showed the highest fixed carbon content, rough surface, and deep porous structure, factors that contributed to a 28 % increase in methane production compared to the control. Semi-continuous tests were conducted in 50 L reactors (working volume) using a reduced dosage (1 g/L) of WPW450 biochar, providing process stability and better biogas quality, resulting in a 31 % increase in methane production. The reduction in biochar dosage did not negatively impact the semi-continuous system, which showed a 74 % higher methane yield compared to the batch system. The results of this study highlight the importance of biochar addition to increase methane production in the co-AD of FVW and LCM at different scales, as well as the study of different biomasses and temperatures for biochar production.

Sustainable organic waste valorisation: A zero-waste approach

The annual increase in global organic waste generation emphasises the need to develop a sustainable management platform to address environmental concerns. This study aims to explore sustainable treatments for the conversion of organic waste into energy in pursuit of zero-waste. The organic waste generated from the animal feed industry (referred to as WF) was used for the model compound in this study. 8.5 wt% of lipids were extracted from the WF, which contained unidentified impurities. Acid-catalysed transesterification yielded less than 80 wt% biodiesel might be due to the reversible reaction. In contrast, non-catalytic transesterification resulted in a significantly higher biodiesel yield (95.6 wt%), suggesting that this method was more effective at converting impure lipids into biodiesel compared to acid-catalysed transesterification. These results indicate the potential advantages of the non-catalytic approach, particularly when dealing with impure lipid sources. To minimise the generation of waste in the process, the WF residue produced after lipid extraction was converted into combustible gas (syngas) through pyrolysis. CO2 was used as a reactive medium in pyrolysis. In one-stage pyrolysis, the gas yield under CO2 was comparable to that under N2, indicating that CO2 did not react effectively with the volatiles derived from the WF residue. Enhanced CO2 reactivity was achieved via catalytic pyrolysis using a nickel-impregnated catalyst. Consequently, the combustible gas yield under CO2 was much higher than that under N2. This approach might contribute to maximising the efficiency of converting organic waste into renewable energy while simultaneously consuming CO2 during pyrolysis, thereby enhancing the sustainability of this approach.

TEKNOLOGI TEPAT GUNA DENGAN MEMANFAATAN SAMPAH ORGANIK MENJADI ECOENZYME DI SDN TEMUGIRING

Adiwiyata schools have environmentally sound waste programmes, organic waste processing being one of them. Not only is it beneficial for the adiwiyata school programme, but it can also be used as ecoenzyme (student learning media). The purpose of this ecoenzyme processing activity is to provide a comprehensive solution to the community's organic waste management programme, which is then converted into ecoenzyme. This programme is expected to be useful for students, especially for those who can apply it at home. This activity was carried out in a participatory manner, involving the school, guardians, and students of SDN Temugiring. This activity began with initial observations related to the identification of various problems, then continued with the conversion of organic waste into ecoezyme. It can be concluded that this activity provides results for students in terms of learning and processing organic waste from fruit peels into multipurpose liquid (ecoenzyme). This programme is also expected to be useful for students, especially for use at home.

Research Trends in the Recovery of By-Products from Organic Waste Treated by Anaerobic Digestion: A 30-Year Bibliometric Analysis

The prevailing extractive economic model is unsustainable due to the finite nature of resources, thereby necessitating the development of alternative models and policies. The anaerobic digestion (AD) process is key to achieving this objective, as it facilitates the conversion of organic waste into biogas and nutrient-rich digestate. This approach is aligned with the principles of a circular economy and contributes to a reduction in carbon emissions. This study aims to conduct a comprehensive bibliometric analysis of the literature published over the past three decades (1993–2023). The analysis will be based on data drawn from the Scopus database and then analysed using the VOSviewer software, which allows for the interconnection of the revised bibliography through a series of selected keywords. The results demonstrated the existence of four clusters: (i) the beneficial valorisation of waste; (ii) volatile fatty acids and biohydrogen as added value by-products resulting from AD; (iii) lignocellulosic substrates and their by-products; and iv) the main products of AD, biogas and digestate. The bibliometric analysis demonstrates a growing interest in AD within the biorefinery concept in recent years, showcasing its potential for effective waste management and integration into the production chain through the principles of the circular economy.

Impact of Black Soldier Fly Larval Frass on Growth and Yield of Cluster Bean (Cyamopsis tetragonoloba L.)

Hermetia illucens L., commonly known as the Black Soldier Fly (BSF), has garnered global attention for its role in insect farming due to its efficient conversion of organic waste into nutrient-rich larval biomass, with frass as a primary byproduct. This study aimed to explore the potential of BSF larval frass (BSFF) as an organic fertilizer for agricultural production, especially evaluating its performance compared to vermicompost on cluster bean growth and yield under field conditions during rabi season at Rajendranagar, Hyderabad. Using a completely randomized block design with eight treatments, various growth parameters such as plant height, number of branches plant-1 and dry matter production, along with yield attributes including number of clusters plant-1, number of pods cluster-1, number of pods plant-1, pod weight (g), pod yield plant-1 and yield (t ha-1) were assessed. Significant differences were observed among treatments, the highest growth and yield parameters were recorded in application of 25 % N through BSF frass + 75 % RDN (T5) and it was on par with 25 % N through vermicompost + 75 % RDN (T6), 50 % N through BSF frass + 50 % RDN (T7), 50 % N through vermicompost + 50 % RDN (T8) and RDF (T2) compared to 100 % N through BSF frass (T3), 100 % N through vermicompost (T4) and control (T1).These treatments resulted in yield increase of 35.7 % (T5), 24.7 % (T6), 23.4 % (T7), 22 %(T8) and 24.36 % (T2) respectively, compared to the control. These findings indicated that BSF larval frass holds promise as a sustainable alternative to vermicompost for enhancing cluster bean production, offering potential benefits for agricultural sustainability and organic waste management.

Biomethane and Green Hydrogen Production Potential from Municipal Solid Waste in Cape Coast, Ghana.

Biomethane and hydrogen are promising elements in the transition towards sustainable energy, due to their capacity to mitigate greenhouse gas emissions. In Ghana, efforts to promote sustainable waste valorization for energy production are underway; however, organic waste conversion into biomethane and hydrogen still needs to be expanded. This study aims to evaluate the potential of producing biomethane and hydrogen from the municipal solid waste in Cape Coast, and their injection into the national gas grid. The upgrading biogas obtained from anaerobic digestion of food/organic wastes was used to generate biomethane. The modified Buswell Equation and data from literature were used to estimate the amount of biomethane and hydrogen. The environmental impact was assessed using the CO2 equivalent emissions. The findings reveal that Cape Coast generated approximately 6,400 tons of food waste in 2021, with a projection to 11,000 tons by 2050. Biomethane and hydrogen quantities was estimated at 3,700,000 m³ and 784,000 kg in 2021, respectively. Their projection reaches to 6,600,000 m³ and 1,400,000 kg by 2050. Converting waste into biomethane and hydrogen is an eco-friendly method of their management and use for renewable energy in Ghana. Strategies can be integrated into Ghana national energy policies to encourage waste-to-energy projects.

Comprehensive compositional analysis of liquid organic product prepared by industrialized hydrothermal cracking of biomass waste and its potential application as fertilizer

Hydrothermal cracking involves the conversion of organic waste into efficient fertilizer through hydrolysis at temperatures ranging from 180 to 220 °C and pressures of 1.5 to 2.45 MPa, which offers significant advantages in shortening the production cycle, enhancing efficiency, and decomposing antibiotics. As a result, it holds immense practical value for promoting organic fertilizer manufacturing processes globally. The products derived from hydrothermal cracking can be categorized into solid and liquid components. Extensive research has focused on the composition and use of solids, while studies on liquids have mainly examined basic characteristics. The study aimed to comprehensively analyze the components in liquid products prepared through hydrothermal cracking and evaluate their suitability as liquid fertilizers. Specifically, we employed rigorous analytical techniques to accurately identify and quantify medium and trace elements, organic acids, amino acids, and plant growth regulators. Furthermore, we carried out a planting experiment to assess the yield and soil changes following the application of liquid products in maize cultivation. The experimental data revealed that the liquid product contained abundant medium and trace elements, along with 6.22 g/L free amino acids and 9.22 g/L organic acids. It is noteworthy that this liquid product contained 1.22 × 105 pg/mL ABA, 6.26 × 103 pg/mL IAA, 1.07 × 102 pg/mL IBA, and 3.60 × 10−2 pg/mL GA3. The utilization of this liquid product has the potential to enhance the disease resistance of maize crops and promote the accumulation of nitrate nitrogen in the soil. By understanding the composition of liquid products via hydrothermal cracking, valuable insights can be gained into their potential benefits for agricultural and ecological applications.

Unlocking the potential of biogas systems for energy production and climate solutions in rural communities

On-site conversion of organic waste into biogas to satisfy consumer energy demand has the potential to realize energy equality and mitigate climate change reliably. However, existing methods ignore either real-time full supply or methane escape when supply and demand are mismatched. Here, we show an improved design of community biogas production and distribution system to overcome these and achieve full co-benefits in developing economies. We take five existing systems as empirical examples. Mechanisms of synergistic adjusting out-of-step biogas flow rates on both the plant-side and user-side are defined to obtain consumption-to-production ratios of close to 1, such that biogas demand of rural inhabitants can be met. Furthermore, carbon mitigation and its viability under universal prevailing climates are illustrated. Coupled with manure management optimization, Chinese national deployment of the proposed system would contribute a 3.77% reduction towards meeting its global 1.5 °C target. Additionally, fulfilling others’ energy demands has considerable decarbonization potential.

Predictive analysis of methane-enhanced conversion of organic waste into sustainable fuel: A machine learning approach

Currently, methane-assisted biomass-to-fuel (M-BtF) processes are being introduced, which are of considerable importance due to the production of an environmentally friendly fuel. Due to the lower price, natural gas can address a stronger potential compared to hydrogen and nitrogen under pyrolysis and bio-oil upgrading processes. Based on this, it seems vital to evaluate such a clean fuel production process from the standpoints of the life cycle analysis (LCA) and techno-economic assessment to exhibit the economic feasibility and environmental superiority. This article aims to utilize machine learning (ML) to predict the yield of organic solid waste, evaluate its economic feasibility, and investigate the environmental sustainability of the valorization of a methane-assisted organic solid waste process. The study employs an artificial neural network (ANN) model with a semi-automatic tuning procedure to forecast the yield of bio-oil, based on biomass characterization. This approach eliminates the need for pilot plant trials for new types of biomass to determine process yields before industrial scale-up. The ANN model demonstrated a high prediction accuracy, achieving an R2 (coefficient of determination) value higher than 0.82. The simulation results, derived from the ML predictions, were then employed in the techno-economic analysis and LCA, where they were compared with other commercial processes for economic viability and environmental impact assessments. The minimum selling price for the renewable diesel was calculated as 3.45 US$/gallon, which is notably competitive, being around 26 % lower than the average minimum selling price observed in relevant publications. Based on Monte Carlo simulation, the plant's internal rate of return (IRR) remained above 50 % across various discount rates, suggesting a highly profitable investment. From LCA results, the proposed method was found to emit ∼ 67 % less greenhouse gases (GHG) compared to standard commercial processes. Overall, the study showcases how the integration of machine learning into process simulation can lead to both economically and environmentally beneficial outcomes, particularly in the context of renewable energy production.

Biomass and organic waste conversion for sustainable bioenergy: A comprehensive bibliometric analysis of current research trends and future directions

The rising demand for renewable energy sources has fueled interest in converting biomass and organic waste into sustainable bioenergy. This study employs a bibliometric analysis (2013-2023) of publications to assess trends, advancements, and future prospects in this field. The analysis explores seven key research indicators, including publication trends, leading contributors, keyword analysis, and highly cited papers. We begin with a comprehensive overview of biomass as a renewable energy source and various waste-to-energy technologies. Employing Scopus and Web of Science databases alongside Biblioshiny and VOSviewer for analysis, the study investigates publication patterns, citation networks, and keyword usage. This systematic approach unveils significant trends in research focus and identifies prominent research actors (countries and institutions). Our findings reveal a significant increase in yearly publications, reflecting the growing global focus on biomass and organic waste conversion. Leading contributors include China, the United States, India, and Germany. Analysis of keywords identifies commonly used terms like "biofuels," "pyrolysis," and "lignocellulosic biomass." The study concludes by proposing future research directions, emphasizing advanced conversion technologies, integration of renewable energy sources, and innovative modelling techniques.

Konversi Limbah Organik Menjadi Sumber Cahaya Berkelanjutan: Pendekatan Teknologi untuk Lampu Hemat Energi

In an effort to reduce environmental impact and utilize renewable resources, this research explores the conversion of organic waste into a sustainable light source through a technological approach for energy-saving lamps. The organic waste processing method is carried out by utilizing a fermentation process and special material synthesis to produce environmentally friendly light components. This study includes characterization of the converted components as well as performance tests of the resulting lamps, including energy efficiency, light quality and service life. The results show great potential in converting organic waste into a reliable and energy-efficient light source, and offer an innovative solution to address the organic waste problem while promoting energy sustainability.

High-throughput screening of non-conventional yeasts for conversion of organic waste to microbial oils via carboxylate platform

Converting waste into high-value products promotes sustainability by reducing waste and creating new revenue streams. This study investigates the potential of diverse yeasts for microbial oil production by utilizing short-chain fatty acids (SCFAs) that can be produced from organic waste and focuses on identifying strains with the best SCFA utilisation, tolerance and lipid production. A collection of 1434 yeast strains was cultivated with SCFAs as the sole carbon source. Eleven strains emerged as candidates with promising growth rates and high lipid accumulation. Subsequent fermentation experiments in liquid SCFA-rich media, which focused on optimizing lipid accumulation by adjusting the carbon to nitrogen (C/N) ratio, showed an increase in lipid content at a C/N ratio of 200:1, but with a concurrent reduction in biomass. Two strains were characterized by their superior ability to produce lipids compared to the reference strain Yarrowia lipolytica CECT124: Y. lipolytica EXF-17398 and Pichia manshurica EXF-7849. Characterization of these two strains indicated that they exhibit a biotechnologically relevant balance between maximizing lipid yield and maintaining growth at high SCFA concentrations. These results emphasize the potential of using SCFAs as a sustainable feedstock for oleochemical production, offering a dual benefit of waste valorisation and microbial oil production.

Pemanfaatan Limbah Organik Menjadi Pupuk oleh Pendeta di Lingkungan Gereja: Strategi Pemberdayaan Ekonomi dan Pelestarian Lingkungan

This research aims to analyze strategies for economic empowerment and environmental preservation through the use of organic waste by a pastor in a church environment. This case study focuses on Ibu Ismawati, a widowed priestess with two children, one of whom is studying at college and the other is in high school. Mrs. Ismawati uses her pig manure to produce compost, which is used in small-scale farming on the land behind her house. This agriculture includes corn, chilies, beans, and rice. This research uses a qualitative approach with observation and in-depth interviews to collect data. The research results show that the conversion of organic waste into compost not only helps meet the daily needs of Mrs. Ismawati's family but also supports environmental preservation through waste reduction and increased soil fertility. Additionally, this activity provides a concrete example of how church communities can implement sustainable agricultural practices to improve the economic welfare of their members.

Composting of Agro-Phyto wastes: An Overview on Process, factors and Applications for Sustainability of Environment and Agriculture

Composting is a naturally occurring process that turns organic waste materials like leaves, food scraps, and other organic wastes into a valuable manure that can improve the fertility and structure of the soil by introducing beneficial organisms, humus, and important plant nutrients. By breakdown, this process transforms the organic substance into inorganic and organic components. In recent years, composting received more attention due to pollution concerns. Loss of resources due to the continuous increase in wastes leads to environmental risks. The process of composting is of three types, i.e., aerobic, anaerobic and vermicomposting. Anaerobic composting occurs when there is no oxygen present, whereas aerobic composting occurs when oxygen is present. Vermicomposting is the breakdown of organic wastes by earthworms. The main purpose of composting is to stabilize waste used for land filling and mass reduction of solid waste. Its aim is to recycle the organic wastes to a natural product, i.e., manure. This study reviews the information on the conversion of organic wastes into a compost to reduce the environmental pollution. The use of central composting after separating organic and non-organic waste at source is one of the most innovative strategies especially in the fast-growing cities for the sustainability of environment.

Quinones-enhanced humification in food waste composting: A novel strategy for hazard mitigation and nitrogen retention

The harmless and high-value conversion of organic waste are the core problems to be solved by composting technology. This study introduced an innovative method of promoting targeted humification and nitrogen retention in composting by adding p-benzoquinone (PBQ), the composting without any additives was set as control group (CK). The results indicated that the addition of exogenous quinones led to a 30.1% increase in humic acid (HA) content during the heating and thermophilic phases of composting. Spectroscopic analyses confirmed that exogenous quinones form the core skeleton structure of amino-quinones in HA through composting biochemical reactions. This accelerated the transformation of quinones into recalcitrant HA in the early stages of composting, and reduced CO2 and NH3 by 8% and 78%, respectively. Redundancy analysis (RDA) revealed that the decrease in carbon and nitrogen losses primarily correlated with quinones enhancing HA formation and greater nitrogen incorporation into HA (P < 0.05). Furthermore, the compost treated with quinones demonstrated a decrease in phytotoxicity and earthworm mortality, alongside a significant increase in the relative abundance of actinobacteria, which are associated with the humification process. This research establishes and proposes that co-composting with quinones-containing waste is an effective approach for the sustainable recycling of hazardous solid waste.

Continuous wet air oxidation of aqueous phase from hydrothermal liquefaction of sewage sludge

The conversion of organic waste into advanced fuels through hydrothermal liquefaction (HTL) is a promising route. However, for the commercialisation of HTL technology, treatment and valorisation of the generated aqueous by-product are required for its economic viability. This study investigates subcritical non-catalytic continuous wet air oxidation (WAO) for the treatment of the aqueous phase from hydrothermal liquefaction (HTL-AP) of sewage sludge. A custom-made tubular reactor was used at temperatures and residence times similar to the HTL process (300–350 °C; 6–50 min), with excess air equivalent to 1.5–2 times the oxygen demand. The WAO process removed up to 95.3 % of the chemical oxygen demand and 91.8 % of the total organic carbon, generating volatile fatty acids, mainly acetic acid, as intermediary compounds from the oxidation reactions, and CO2 and H2O from the pollutant’s complete degradation. The process effectively eliminated almost all of the organonitrogen compounds, generating NH4+, which reached values of up to 97 % of the total nitrogen. Comprehensive molecular characterization performed by FT−Orbitrap MS analysis revealed that the main basic organonitrogen compounds in HTL-AP are distributed in the O1N1, N2, O1N2, N1 classes. For neutral to acidic organonitrogen species, O3N1 is the most representative chemical class. The energy consumption for heating the WAO reactor was up to 40 % lower using HTL-AP compared to blanks experiments. Despite good process water clean-up, autothermal operation was not achieved, and improvements in the reactor design are suggested.

A novel high-entropy spinel ferrites (CoNiCuZnMg)Fe2O4 catalyst for H2 production via steam reforming of derived volatiles from polypropylene and waste cooking oil

Municipal organic waste conversion to high-value products is a vital carbon–neutral way to simultaneously tackle the energy crisis and environmental contamination. This study aims to develop and evaluate a novel high-entropy spinel ferrites (Co0.2Ni0.2Cu0.2Zn0.2Mg0.2)Fe2O4 catalyst (HEO) toward H2 production from co-pyrolysis volatiles of polypropylene (PP) and waste cooking oil (WCO) in an integrated two-stage reactor system. In the 1st stage of medium temperature reforming, the optimal 3:7 PP/WCO blend mass ratio facilitated H2 production. Under a catalytic reforming at high temperature of 750 °C in the 2nd stage, the HEO catalyst demonstrated remarkable efficiency, yielding 58.43 mmol·g−1 of H2 with a composition of 65.17 %, a notable 22.3 times higher than that without HEO. The catalyst exhibited a prolonged service life of 540 min without compromising H2 selectivity, maintaining a high yield of 510.2 mmol·gcat.−1·s−1. The exceptional performance of HEO arises from the synergistic effects of multiple elements, augments oxygen vacancy, enhances reducibility, and promotes structural stability in the high-entropy system, which causes the strong C–C breaking ability and the excellent C–H breaking abilities of Fe, Ni, Co, Cu, and Zn species. The analysis of tar, gaseous products, and deactivated HEO catalyst characterization results provides a comprehensive understanding of the co-pyrolysis route and volatiles catalytic reforming process. This study developed a high-entropy ferrite catalyst that not only achieves efficient and stable H2 production but also lays the foundation for a new high-entropy catalyst design concept, fostering the development of efficient reforming catalysts for H2 production.