Based on liquid cooling and phase change material (PCM), a fin-enhanced composite thermal management system suitable for high power and extended cycle operations of lithium-ion battery module at high ambient temperature is proposed in this work. The coupling effect between the protruding fin structure and PCM thickness, as well as the addition of expanded graphite to the PCM, are investigated to optimize hybrid cooling arrangement. The results show that synergistic optimization of the protruding fin structure and PCM arrangement can enhance heat diffusion from the batteries to the cooling water, improve PCM utilization, and ensure sufficient latent heat. And then, the expanded graphite-modified PCM can make heat absorption and phase transition more uniform, and battery temperatures can be further decreased by up to 7.45 °C with 16 wt% expanded graphite. Clearly, the coupling optimization improves the cooling performance and applicability of conventional thermal management systems, while the temperature difference and maximum temperature in the optimized system have been regulated to within 4.30 °C and 46.78 °C under 40 °C environment and 5C discharge, respectively. Moreover, the cyclic charging and discharging strategies are designed and matched, and using the matching strategy with a fixed charge or discharge rate of 1C provides lower temperatures and better temperature uniformity, which can always control the temperatures below 47.22 °C and temperature difference below 4.69 °C. The optimized system with cycle strategy matching ensures the repeatability of battery operation and provides cooling solutions for different application scenarios.
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