Conventional Refrigeration Research Articles

Optimization and Thermodynamic Analysis of CO2 Refrigeration Cycle for Energy Efficiency and Environmental Control

Supermarket applications are significant contributors to greenhouse gas emissions, necessitating efforts to reduce carbon footprints in the food retail sector. Carbon dioxide (R744) is recognized as a viable long-term refrigerant choice due to its favorable properties, including low Global Warming Potential, non-toxicity, non-flammability, affordability, and widespread availability. However, enhancing the energy efficiency of pure CO2 systems in basic architecture units, particularly in warm regions like India, remains a challenge. To address this, modern refrigeration systems must prioritize low energy consumption and high coefficient of performance (COP) while meeting environmental standards. This study investigates different operating conditions to determine the optimal parameter range for maximizing COP and improving the efficiency of conventional CO2 refrigeration configurations. It examines both subcritical and transcritical refrigeration cycles under varying parameters, emphasizing the importance of understanding COP’s relationship with factors such as subcooling, superheating, ambient temperature, and evaporator temperature. The study advises against superheating in CO2 systems but highlights the substantial COP increase with higher degrees of subcooling, leading to enhanced system performance. Additionally, it provides a comprehensive theoretical comparison between advanced pure CO2 supermarket applications and commonly used hydrofluorocarbons-based systems, offering insights into energy efficiency and environmental impacts for informed decision-making in the industry.

Low corrosive dual desiccant air conditioning: Antimicrobial activity, performance characteristics, and economic valuation with traditional VCRS

Liquid desiccant dehumidification systems (LDDS) serve as an energy-efficient alternative to conventional vapor compression refrigeration (VCR) systems, providing enhanced control over both temperature and humidity levels. However, the broader implementation of LDDS is limited due to the corrosive effects of the liquid desiccants on metal components. In response, this study introduces an economical blend of potassium formate (HCOOK) and magnesium chloride (MgCl2) designed to minimize corrosion while maintaining energy efficiency and performance. Selection of mixture ratio and solution concentration and determination of thermo-physical properties were conducted by initial lab-scale tests. Significant bactericidal effects against E. coli and S. Aureus were observed. The feasibility and effectiveness of the developed solution were experimentally tested by a comparative investigation in a large-scale solar-integrated liquid desiccant dehumidification system against standard HCOOK (63.5 wt%). The cyclic performance of the novel desiccant solution was examined under varying operational conditions for tropical climates. Results demonstrated that the corrosion levels of the new mixture are comparable to those observed with a standard 63.5 wt% HCOOK solution, while the dehumidification efficiency showed significant improvements, with moisture removal and effectiveness enhanced by 8.7–14.3 % and 5.8–15.2 %, respectively. Significant regeneration occurred between 45 °C and 55 °C. Regeneration efficiency improved by a maximum of 12.5 % relative to the standard HCOOK solution. Notably, the deployment of a solar-assisted regeneration system led to energy cost reductions by 22.8 % compared to traditional VCR systems, achieving a return on investment within 1.8 years.

Research on the performance of ultra-low temperature cascade refrigeration system based on low GWP refrigerants

The EU Security Council and Parliament have tentatively agreed to ban fluorinated gases with a global warming potential (GWP) higher than 150 in split air conditioners and heat pumps from 2027. This will further motivate the refrigeration industry to accelerate the search for refrigerants with low GWP and zero ozone depletion potential (ODP). At present, research into low GWP refrigerants for cascade systems is limited, focusing mainly on single refrigerant substitutes without comprehensive comparisons and lax GWP restrictions. In this study, the cascade refrigeration cycle (CRS) system is established to meet the demand of −100 to −50 °C. The GWP of the refrigerants is strictly controlled below 150, and a comprehensive screening of the four generations of refrigerants is carried out to identify refrigerant pairs that meet environmental and refrigeration requirements. The relationship between the high-temperature cycle (HTC) evaporation temperature and the optimal coefficient of performance (COP) is determined, and the effects of the low-temperature cycle (LTC) evaporation temperature Te concerning with mass flow rate, discharge temperature of compressor, compressor power consumption, exergy destruction, and exergy efficiency are analyzed in detail. The thermodynamically superior refrigerant pairs are identified by comparison with several conventional refrigerant pairs. The results show that when Te > −67 °C, R170/R600a is preferred, and when Te ≤ −67 °C, R170/R1270 is preferred. In the temperature range of −100 ∼ −50 °C, R170/R1270 is the better refrigerant pair, which can improve the performance by 6.39–13.11 % than traditional refrigerant pairs. Finally, the exergy destruction analysis of CRS components is carried out, which provides a reference for refrigerant selection and system optimization of CRS in the field of ULT.

Energy, exergy, environmental, and enviroeconomic (4E) analysis of cascade vapor compression refrigeration systems using nanorefrigerants

The refrigerants used in traditional vapor compression refrigeration systems are harmful to the ozone layer and contribute to global warming. The demand for refrigeration is increasing because of global warming. In this study, for the first time, an energy, exergy, environmental, and enviroeconomic (4E) analysis was performed using different refrigerants and nanoparticles to reduce the energy required in low-temperature vapor compression cascade refrigeration systems and to determine more environmentally friendly nanorefrigerants. The R290 refrigerant was used for the Low-Temperature Circuit (LTC), while the High-Temperature Circuit (HTC) used RE170, R1234yf, R600, R600a, and R450A refrigerants. The nanoparticles used in the analysis were Al2O3, CNT, CuO, TiO2, ZnO, and SiO2. The R600 nanorefrigerant performed the best, whereas the R1234yf nanorefrigerant performed the worst. The results indicate that the CuO nanoparticles provided the highest performance. In addition, the results showed that the R290+R600-CuO nanorefrigerant emitted 11 % less CO2 than the pure R290+R600 refrigerant. The nanorefrigerants provide a more environmentally sustainable option because of their high efficiency and lower energy consumption than conventional refrigerants.

Performances Study of Eco-friendly Binary Azeotropic Mixtures Used as Working Fluid in Three Refrigeration Cycles

According to the European (F-gas) regulation, all refrigerants with a global warming potential (GWP) above 150 will be out by 2030. Searching for alternative refrigerants that are environmentally friendly has become an urgent challenge for the refrigeration and air-conditioning sector. Based on their environmental advantages and good thermo-physical properties, azeotropic mixtures have recently gained special interest as substitutes for conventional refrigerants. This study aims to compare the performance of three eco-friendly azeotropic mixtures with the common refrigerant R134a in three refrigeration cycles: the basic cycle (BC), the ejector-expansion refrigeration cycle, and the ejector sub-cooled cycle. The mixtures under study are R1234ze+R600a, R1234yf+R600a, and R1234yf+R290. These mixtures have global warming potential (GWP) of 5.668, 3.8688, and 3.2865 respectively, whereas R134a has a GWP of 1430. To reach this objective a numerical program was developed using MATLAB software to evaluate the coefficient of performance (COP), and the cooling capacity of the three refrigeration cycles using the studied eco-friendly mixtures and were compared with those of the commonly used R134a refrigerant. The entrainment ratio was also compared for the two ejector cycles using these refrigerants. The simulation was realized for condensing temperatures (Tc) selected between 30 and 55°C and evaporation temperatures (Te) ranging between -10 and 10°C. The results have shown that the eco-friendly azeotropic mixture R1234yf+R290 (GWP=3.51) has the best performances compared to the two other mixtures and they are close to those of R134a. On the other hand, the ejector expansion refrigeration cycle has exhibited a high coefficient of performance compared to the basic cycle and ejector sub-cooled cycle, and a high entrainment ratio compared to the ejector sub-cooled cycle for all used refrigerants. However, the ejector sub-cooled cycle gave a better cooling capacity than the other cycles. According to the obtained results, the azeotropic mixture R1234yf+R290 apart from its excellent environmental properties yields better performances in most of cases, this confirms that it could be a suitable substitute for conventional working fluid R134a which has a great global warming potential.

Large and reversible elastocaloric effect induced by low stress in a Ga-doped Ni-Mn-Ti alloy

The Solid-state cooling based on caloric effects is considered a potential alternative to conventional refrigeration technology, which uses ozone-depleting gases. Several shape memory alloys have attracted attention for solid-state cooling since they present a high reversibility of the caloric effect, which depends mainly on thermal hysteresis and sensitivity to the applied field. In the present work, a study substitution of Mn by Ga in the Ni50Mn34Ti16 alloy led to diminished thermal hysteresis in the martensitic transformation by 6 K. The elastocaloric effect, thermal and microstructure properties of a polycrystalline Ni50Mn32Ti16Ga2 alloy have been characterized. The elastocaloric effect was obtained indirectly from the length change as a function of temperature at constant stress. An isothermal entropy change (ΔSISO) of 23.0 J kg−1 K−1 during heating and 22.0 J kg−1 K−1 during cooling was observed for applied stress of 160 MPa. In addition, the ΔSISO is reversible for a temperature span between 287 and 319 K, reaching a maximum of 20.5 J kg−1 K−1 at 299 K. The thermal hysteresis changed slightly while the applied stress increased up to 160 MPa since the sensitivity of the martensitic transformation temperatures to stress was 0.150 K M/MPa during cooling and 0.160 K/MPa during heating. The X-ray diffraction analysis revealed a mixture of B2-type cubic austenite, 5 M modulated martensite, and a second intermetallic phase identified as Ni3Ti. All these results were obtained around room temperature.

A point of view of the elastocaloric effect associated with 7M and 5M modulated martensite in Ni–Mn–Ga alloys

Solid-state refrigeration has emerged as the most promising alternative to conventional refrigeration technology. However, for this technology to be applicable, the caloric effects produced in the alloys must be highly reversible. In this context, we compare the elastocaloric effect of two Ni–Mn–Ga alloys with different types of modulated martensite. The elastocaloric effect, quantified as the isothermal entropy change (ΔSela), was investigated in Ni50Mn28Ga22 and Ni50Mn30Ga20 alloys with 5M and 7M modulated martensite, respectively. Maximum ΔSela values obtained were 1.91 J kg−1 K−1 during cooling and 1.83 J kg−1 K−1 during heating in martensite 5M and 0.19 J kg−1 K−1 during cooling and 0.26 J kg−1 K−1 during heating in martensite 7M, for a constant applied stress of 10 MPa. However, although the 7M modulated martensite exhibited a lower ΔSela, its reversibility was higher. Therefore, our results could be useful for selecting a good material to be used in solid-state refrigeration.

Device Model for a Solid‐State Barocaloric Refrigerator

Solid‐state refrigeration represents a promising alternative to vapor compression cooling systems. Solid‐state devices based on magnetocaloric, electrocaloric, and elastocaloric effects have demonstrated the ability to achieve high‐efficiency, reliable, and environment‐friendly refrigeration. Cooling devices based on the barocaloric (BC) effect—entropy change due to applied hydrostatic pressure, however, has not yet been realized despite the significant promise shown in material‐level studies. As a step toward demonstrating a practical cooling system, this work presents a thermodynamic and heat transfer model for a BC refrigerator The model simulates transient thermal transport within the solid refrigerant and heat exchange with hot and cold thermal reservoirs during reversed Brayton refrigeration cycle operation. The model is used to evaluate the specific cooling power (SCP) and coefficient of performance (COP) of the device comprising nitrile butadiene rubber (NBR) as a representative BC refrigerant. Experimentally validated BC properties of NBR are used to quantify the contribution of different operating parameters including cycle frequency, applied pressure, operating temperatures, and heat transfer coefficient. The results show that a BC refrigerator operating with a temperature span of 2.4 K and 0.1 GPa applied pressure can achieve an SCP of 0.024 W g−1 at 10 mHz cycle frequency and a COP as high as 5.5 at 1 mHz cycle frequency—exceeding that of conventional vapor compression refrigerators. In addition, to identify key refrigerant properties, the effect of bulk modulus, thermal expansion coefficient, heat capacity, and thermal conductivity on device performance are quantified. The results highlight the trade‐off between different material properties to maximize the BC response, while minimizing mechanical work and improving thermal transport. This work demonstrates the promise of solid‐state cooling devices based on soft BC materials and provides a framework to quantify its performance at the device‐level.

Energy and exergy analysis of a two-stage cascade vapor compression refrigeration system with modified system configuration

This study proposes a modification to the two-stage cascade vapor compression refrigeration system by adding internal heat exchangers that function as subcoolers and desuperheater. The influence of each internal heat exchanger proposed on the exergy destruction rate, exergy efficiency, compressor power consumption, ECOP, and COP of the system was investigated. Additionally, various refrigerant combinations were considered as working fluids to evaluate which combination is the most suitable for the proposed system. Mathematical models based on the principles of thermodynamics were established in Engineering Equation Solver (EES), a software used for energy and exergy analysis. The results reveal that the addition of specific internal heat exchangers causes either an increase or decrease in overall system performance, depending on the type of refrigerant combination used. Consequently, there exists an optimal system configuration for each refrigerant combination. Compared with the conventional two-stage cascade refrigeration system, the optimal system configurations in the present study exhibited higher overall system performance. A maximum increase in exergy efficiency, ECOP, and COP of 7.31 %, 9.8 %, and 7.3 %, respectively, can be observed with the refrigerant combination R450A/R404A. Additionally, the results of the exergy analysis identify that the HTC compressor, condenser, LTC compressor, and cascade condenser are the primary contributors to the exergy destruction rate within the system.

Proposals for Next-Generation Eco-Friendly Non-Flammable Refrigerants for a −100 °C Semiconductor Etching Chiller Based on 4E (Energy, Exergy, Environmental, and Exergoeconomic) Analysis

Recent advancements in cryogenic etching, characterized by high aspect ratios and etching rates, address the growing demand for enhanced performance and reduced power consumption in electronics. To precisely maintain the temperature under high loads, the cascade mixed-refrigerant cycle (CMRC) is predominantly used. However, most refrigerants currently used in semiconductor cryogenic etching have high global warming potential (GWP). This study introduces a −100 °C chiller using a mixed refrigerant (MR) with a GWP of 150 or less, aiming to comply with stricter environmental standards and contribute to environmental preservation. The optimal configuration for the CMRC was determined based on a previously established methodology for selecting the best MR configuration. Comprehensive analyses—energy, exergy, environmental, and exergoeconomic—were conducted on the data obtained using Matlab simulations to evaluate the feasibility of replacing conventional refrigerants. The results reveal that using eco-friendly MRs increases the coefficient of performance by 52%, enabling a reduction in compressor size due to significantly decreased discharge volumes. The exergy analysis indicated a 16.41% improvement in efficiency and a substantial decrease in exergy destruction. The environmental analysis demonstrated that eco-friendly MRs could reduce carbon emissions by 60%. Economically, the evaporator and condenser accounted for over 70% of the total exergy costs in all cases, with a 52.44% reduction in exergy costs when using eco-friendly MRs. This study highlights the potential for eco-friendly refrigerants to be integrated into semiconductor cryogenic etching processes, responding effectively to environmental regulations in the cryogenic sector.

Experimental study of an absorption-based refrigeration driven by ocean thermal energy

Establishing an island-based cold chain is essential for ensuring food storage, vaccine preservation, and fish freezing on islands, which is indispensable for the sustainable development of island communities. The compression-absorption refrigeration system that uses ocean-thermal-energy is ideal for cold storage on islands as it efficiently utilizes local renewable energy sources and can meet refrigeration needs below 0 °C. Therefore, a refrigeration prototype has been constructed and thoroughly experimentally investigated to obtain refrigeration characterization under variations of refrigeration demand and environmental conditions. The system's energy-saving potential is evaluated by conducting comparisons with conventional refrigeration techniques. The results indicate that refrigeration temperature plays a crucial role in determining refrigeration capacity, with an increase of approximately 8.2 % observed for every 1 °C rise in refrigeration temperature. Lower cold-seawater temperatures or higher warm-seawater temperatures do not have a significant effect on the refrigeration capacity, but contribute to a reduction in compressor power due to increased thermally-driven compression force. Consequently, for every 1 °C change, the refrigeration capacity per unit compressor power increases by approximately 4 %. Additionally, the refrigeration capacity of the system is three times greater than that of a vapor-compression-refrigeration-system. The findings provide theoretical and experimental guidelines for the design and operation of refrigeration using ocean-thermal-energy.

Optimizing cascade refrigeration systems with low GWP refrigerants for Low-Temperature Applications: A thermodynamic analysis

This study offers a comprehensive thermodynamic analysis of a cascade refrigeration system conducted for low-temperature applications, focusing on the use of low-GWP and zero-ODP refrigerants to improve efficiency and sustainability. The target of this study is to explore the performance of the system using a combination of refrigerants: low-temperature cycle refrigerants such as R744, while high-temperature cycle refrigerants such as R717, R1234yf, R1234ze(E), R1336mzz(E), and R1336mzz(Z), respectively. The ECS model incorporating in REFPROP 10.0a tool was utilized to extract the data through coding for analysis. The assessment of this system involves the examination of various parameters such as its coefficient of performance, total compressor workload, total exergy, and exergy efficiency across various operational conditions. The results are compared with and without superheated and subcooled conditions to understand the impact of these parameters on the system performance. The system with R744 in the low-temperature cycle and R717, R1234yf, R1234ze(E), R1336mzz(E), and R1336mzz(Z) in the high-temperature cycle provides a higher COP and lower total compressor work compared to the conventional cascade refrigeration system. In optimal CRS, the R744-R717 pair attains the highest COP of 2.05 at the lowest possible compressor work from 9.53 to 4.87 kW than other refrigerants pair while evaporator temperature shifting from −55 °C to −20 °C. The exergy efficiency of R744/R717 is found at 26.47 % at an evaporator temperature of −55 °C, but it extends to a peak of 51.73 % at −20 °C. The study also shows that the superheating and sub-cooling of the refrigerants have a significant impact on the performance of the cascade refrigeration system. Superheating and sub-cooling at 10 °C, improves the COP of the system by reducing the compressor work and increasing the heat transfer efficiency. The research offers valuable insights into the system’s thermodynamic performance when employing low GWP refrigerants in low-temperature applications. These findings have the potential to guide the design and optimization of cascade refrigeration systems over the range of low-temperature applications.

Establishing universality in entropy change and critical behavior for magnetocaloric effect in Si-substituted Mn50Ni40Sn10 inverse Heusler alloy

Magnetic refrigeration working based on the magnetocaloric effect can be the perfect replacement of the conventional gas compression-based refrigeration technology and reduces its harmful effects on the environment. The boundary between a first-order and a second-order phase transition would be where the perfect magnetocaloric material would be found. Therefore, establishing the sequence of phase transitions clearly is essential for the characterization of other phase change materials and for applied magnetocaloric research. A quantitative fingerprint of second-order thermomagnetic phase transitions is reported here in Si-substituted high content Mn-based inverse Heusler alloy systems, which are found to be crystallized in cubic structures. The second-order nature of the phase transition has been confirmed from the Arrott plot analysis and a correlation between magnetocaloric effect and local exponent is established. Using the Arrott plot, the critical exponents are evaluated employing different techniques such as modified Arrott plot, Kouvel–Fisher method, and critical isotherm. Their values are found to be in great agreement with each other and follow the mean-field model signifying the presence of long-range ordering in the materials. The high value of isothermal magnetic entropy change and the reversibility justifies the suitability of the reported materials in the practical application as magnetic refrigerants.

Effect of magnetic field treatment on the softening of green chilies (Capsicum annuum L.) during storage

In this study, effects of magnetic field treatment on the softening of green chilies during storage (0–30 d at 10 °C) were investigated, and the cell wall polysaccharide content, modifying enzyme activities, water distribution, and cell wall structure were determined. After 30 d of storage, the weight loss of the green chilies in conventional refrigeration (CR) group reached 35.40 %, whereas it was 20.96 % and 29.85 % in the static (SMF; 4 mT) and alternating magnetic field (AMF; 4 mT, 1 Hz) groups, respectively. Furthermore, magnetic field treatment maintained low levels of water-soluble pectin (WSP) and high levels of chelate-soluble pectin (CSP) and sodium carbonate-soluble pectin (NSP) in the green chilies. The degree of methylation (DE) values of WSP and NSP in the pre-treated samples were 0.37 and 0.18, respectively. Conversely, at the end of storage, the DE values of WSP and NSP in the CR, SMF, and AMF groups decreased to 0.12 and 0.05, 0.25 and 0.11, and 0.18 and 0.07, respectively, suggesting that magnetic field treatment had a negative influence on the demethylation of pectin. Magnetic field treatment also decreased the activities of pectin methyl esterase, polygalacturonase, and β-galactosidase in the green chilies, maintaining them at a low level. The magnetic field treatment resulted in a higher free water content in green chilies compared to the CR, exceeding the CR group’s content by 1.79 % and reaching 88.18 % at the terminal storage. Scanning electron microscopy results revealed that magnetic field treatment maintained the structural integrity of the cell wall in the green chilies. The results of this study confirmed the applicability of magnetic field treatment in maintaining the firmness and reducing the weight loss of the green chilies, thus prolonging their shelf life.

Unsteady-state entropy generation analysis of the counter-flow dew-point evaporative coolers

The surging demand for air conditioning, especially in hot climates, underscores the urgency of strategies aimed at curbing fossil fuel reliance and fostering energy saving strategy. Despite the longstanding utility and advantages of the conventional mechanical vapor compression refrigeration system, sustainability hurdles persist owing to its pronounced electricity demand. While evaporative cooling, harnessing water evaporation, emerges as a more efficient alternative, its efficacy is contingent upon environmental conditions. Addressing this, dew-point evaporative cooling (DPEC) presents an innovative direction, showcasing superior efficiency by directing supply air into a wet channel. This study delves into the thermodynamic losses within a counter-flow configured DPEC system, employing a transient entropy generation model rooted in the second law of thermodynamics to provide a comprehensive analysis of DPEC’s performance. Key findings that emerged from this study reveal that (1) the transient entropy generation is intricately distributed across different layers of the dew point evaporative cooling (DPEC) system, including dry air, wet air, the channel plate, and the water film; (2) Parametric analyses highlight the significant impact of factors on entropy generation, inlet air temperature has a minimal effect on system efficiency, but higher temperatures increase thermal losses. Excessive humidity limits evaporative potential, while low humidity significantly increases entropy generation. The system performs optimally at a working ratio of 0.3 and lower air velocities (within the inlet air velocity range of 0.6 to 2.2 m/s). Channel length has little impact, while the system is more sensitive to channel height, with a height of 2.5–3.5 mm being conducive to better performance. Experimental validation demonstrates the model’s accuracy in predicting system performance. The research contributes to a deeper understanding of DPEC systems, offering insights for achieving optimal operating conditions and enhancing overall efficiency in the pursuit of sustainable development.

Coupling lactic acid fermentation of food waste at various concentrations as storage strategy with dark fermentation for biohydrogen production

Lactic acid fermentation (LAF) has recently been considered a promising strategy to store food waste (FW) prior to dark fermentation (DF), as it can stabilize organic matter with no negative impact on biohydrogen potential (BHP). However, concentrations can affect LAF and its subsequent impact on BHP is not known. This novel study evaluates the impact of storing FW by LAF at 1%, 5%, 10%, 15% and 20% total solids (TS), at 35 °C and 23 °C, subsequently converted to biohydrogen through DF. Storing FW in LAF at 5%, 10%, 15% and 20% TS has no impact on its BHP (88 ± 23 mL/gVS). Storing at 1% TS increases variability of metabolic pathways, with replicates undergoing butyric fermentation instead of LAF, resulting in 33 mL/gVS and 13 mL/gVS of BHP, compared to the total average of all conditions at 84 ± 25 mL/gVS. Microbial analysis shows Lactobacillus sp. and Weissella sp. as the main genera selected during storage. The concentrations affect the relative abundance of various remaining genera, such as Burkholderia-Paraburkholderia sp. at 20% TS and Lactococcus sp. at 1% TS. Except at low TS, LAF is a robust storage strategy of FW prior to DF, preserving its BHP without the need for conventional refrigeration.

Design of Mixed-Metal MOF-74-MgNi for Water Adsorption-Driven Solar Thermal Energy Storage and Heat Transformation Applications.

Adsorption solar thermal energy storage and heat transformation are ecologically benign and energy-efficient technologies. Efficient adsorbents are the key to this technology. In this paper, two metal ions, Mg2+ and Ni2+, were introduced into the metal-organic framework MOF-74. The synthesis conditions were adjusted to obtain MOF-74 with a high water adsorption capacity and stability. The results show that MOF-74-MgNi-2 has the maximum water adsorption capacity. At a low moisture pressure P/P0 = 0.1, its water adsorption capacity is 0.44 g/g, 0.12 g/g, and 0.10 g/g greater than that of MOF-74-Mg and MOF-74-Ni, respectively. Its saturated water adsorption capacity at P/P0 = 0.9 is as high as 0.62 g/g, which is 1.3 times that of MOF-74-Ni and 1.1 times that of MOF-74-Mg, respectively. Its superior water adsorption capacity is explained by the combination of experiment and molecular simulation, which takes into account the pore structure and electrostatic potential energy distribution. Its thermal breakdown temperature is greater than 250 °C. Its water adsorption capacity decreases by only 9.0% in the 10th cycle. Under conventional refrigeration conditions, its refrigeration coefficient and working capacity are 0.75 and 0.43 cm3/cm3, respectively, which are greater than those of the majority of the regularly used adsorbents. In addition, it satisfies the primary technological goals of adsorption-based thermal batteries with a heat storage capacity of up to 1394 kJ/kg. The mixed-metal method is shown to be useful in the design of high-performance MOF-74 for solar thermal energy storage and heat transformation.

Refrigerant charge estimation method based on data-physic hybrid-driven model for the fault diagnosis of transcritical CO2 heat pump system

The transcritical CO2 heat pump system is a promising and excellent heating scheme. However, the operating pressure of the transcritical CO2 heat pump system is high, and refrigerant leakage is a frequent problem. It is worth noting that the operating principle of CO2 heat pump systems is unique. Thus, conventional refrigerant charge estimation methods for subcritical systems cannot be directly applied to transcritical systems. In this study, a novel refrigerant charge estimation method for the transcritical CO2 heat pump system is proposed. Based on the heat and mass transfer characteristics of the transcritical system, the grey box model constrained by physical laws is constructed. Based on the machine learning algorithm, the correction model of the grey box model is built. The hybrid model combines the advantages of the high generalization ability of the physic-driven model and the nonlinear fitting ability of the data-driven model. The results show that the novel estimation method can accurately predict the refrigerant charge, enabling fault diagnosis of refrigerant leakage. The data-driven correction model can improve the prediction accuracy of the grey box model. The Mean Relative Error of the hybrid-driven model can be controlled within 5 %.

How to cool a warming world? – The potential of photovoltaic green cooling with natural refrigerants in sunbelt countries

The study investigates the economic feasibility of photovoltaic-powered air-conditioning (AC) systems in thirteen different sunbelt countries. Two different technical solutions have been analysed: (i) hybrid (partially PV powered, grid-connected) and (ii) off-grid (fully PV powered, no grid connection). These two solutions have been studied for three different locations in each country, namely minimum, average and maximum annual global solar irradiation on the horizontal. Lastly, each solution and location has been examined for application in the residential and commercial sector. All solar-based air-conditioning scenarios use high efficiency AC appliances with R290 as refrigerant (Global Warming Potential – GWP of 1) and have been compared against a base-case scenario using AC units with moderate efficiency AC appliances with conventional R410a refrigerant (GWP of 2088) and 100 % grid electricity supply. The scope of the study is to identify the economic potential of solar PV cooling technologies. Levelized Cost of Electricity (LCOE) and Net Present Value (NPV) have been calculated for each scenario as part of the comparative analysis. It was found that hybrid photovoltaic-based air-conditioning for a residential house has a financial advantage over grid-based air-conditioning in eleven out of thirteen countries investigated. Exceptions are Ghana and Vietnam. Off-grid photovoltaic-based air-conditioning for residential houses is only economically feasible in five out of thirteen countries, namely Costa Rica, Iran, Grenada, Philippines and Thailand. Hybrid photovoltaic-based air-conditioning for a small commercial building has a financial advantage over grid-based air-conditioning in ten of thirteen countries, except in Colombia, Ghana and Iran. Off-grid photovoltaic-based air-conditioning for a small commercial building is only feasible in China, Grenada, Kenya and Philippines.

A DFT+U and Monte Carlo study of Gd2Zr2O7 pyrochlore

Pyrochlore oxides, specifically Gd2Zr2O7, have been a subject of interest due to their unique structural, physical, and magnetic properties. These properties make pyrochlore oxides potential candidates for various technological applications, including magnetocaloric refrigeration. Magnetocaloric refrigeration is a promising alternative to conventional refrigeration methods, as it is more energy-efficient and environmentally friendly. By studying the magnetocaloric effect of pyrochlore oxides like Gd2Zr2O7, researchers can gain a deeper understanding of the underlying mechanisms and potential applications of these materials in magnetocaloric refrigeration systems. By employing advanced computational methods such as Monte Carlo simulations and first-principles calculations based on the full-potential linearized augmented plane wave (FP-LAPW) a technique is employed to examine the magnetic structure, researchers can investigate the magnetocaloric effect of pyrochlore oxides with high accuracy and precision. This information has the potential to aid in the advancement of more effective magnetocaloric systems materials and ultimately lead to the design and optimization of advanced magnetocaloric refrigeration systems.