Polycarbonate panels (PC panels) are state-of-the-art transparent insulating materials widely used in the construction industry due to their cavity structure, which provides exceptional thermal insulation and optimal optical performance. However, the inherent anisotropy of the three-dimensional cavity structure complicates radiative transfer and requires consideration of both azimuth and zenith angles in optical performance evaluation. This aspect has received limited attention in existing research. This study aims to accurately characterize the optical performance of PC panels through numerical simulations. A three-dimensional radiative transfer model based on the discrete ordinate radiation model is developed to solve the radiation transfer equation. The model's independency regarding mesh division, angular discretization, and accuracy is validated. The effects of incidence angle, geometric parameters, and optical properties of PC panels on optical performance are analyzed. The findings reveal a strong correlation between transmittance and absorption with variations in incident zenith and azimuth angles. The transmittance exhibits a consistent monotonic variation expressible as a rational bifunction. Notably, absorption peaks occur within specific solid angle ranges, with increased structural complexity resulting in heightened absorption and greater uncertainty. For conventional PC materials, maximum transmittance ranges from 46.9 % to 73 %, while maximum absorption ranges from 2.3 % to 13.5 %. Increasing absorption coefficients, refractive index, and surface scattering coefficients nonlinearly decrease transmittance while increasing absorption. Additionally, deviations in transmittance and absorption with azimuth angle amplify with an increase in non-horizontal structures. Sensitivity analysis indicates a significant influence of zenith angle on transmittance, and absorption coefficient predominantly affects absorption.
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