<p>Distance learning lacks person-to-person interaction, which makes learning less interesting. While peer interaction can gain the support, assistance, and discussion of peer empathy, which can effectively motivate learning. This study proposes a remote peer live learning strategy, which allows learners to conduct peer learning anytime and anywhere via the Internet and uses peer-to-peer video methods to conduct peer-to-peer live teaching. Explores the influence of adding peer factors on their learning effectiveness and learning motivation. The findings of this study are as follows: (1) The learners who use peer live teaching strategy, regardless of whether they are high or low achievement, can effectively improve their learning effectiveness, learning motivation and reduce their cognition compared with those who use general distance teaching. (2) Students who utilized the peer-to-peer live teaching platform exhibited notably higher levels of technology acceptance compared to their counterparts enrolled in the conventional distance learning system.</p> <p>&nbsp;</p>