Expressway slopes within the boundary of expressway construction land have the potential to be transformed from conventional land use to valuable utilization through the installation of photovoltaic (PV) systems. Considering the continuous increase in expressway mileage, the PV potential could be enormous; therefore, a method to quantify such potential is urgently needed. This study proposes a potential assessment method for expressway slope photovoltaics. First, the suitable locations of expressway slopes for installing PV systems are identified on the basis of publicly available digital maps, combined with the principles of PV site selection and geographic information systems. Then, the PVsyst model is used to simulate the power generation efficiency and power output of the PV systems and to evaluate their PV potential, contribution, and economic benefits. The implementation of the proposed method in Fujian Province, China, indicates that the installed capacity of PV systems could reach 16.3 GW, with an annual power output of 17,940 GWh, contributing to the peak shaving of power grids and regional energy supply. The reductions in CO2, SOx, and NOx emissions are 16.65 Mt, 8970 t, and 3947 t per year, respectively. Considering carbon trading, the payback period is shortened to 11.7 years, with the return on investment of 65.38 % and the net present value of 52.6 billion RMB over a 25-year operational period. Additionally, this project could create 19.88 % of jobs in the energy sector in Fujian Province, providing 27,861 jobs during the construction phase and 18,248 jobs during the operation and maintenance phase. Thus, this project is economically viable and generates positive energy, environmental, and social benefits, contributing to the promotion of local energy transition and sustainable development.
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