Wavelength Control Research Articles

Intramolecular Photochemical C−H Insertions of α‐Diazocarbonyl Compounds

AbstractIntramolecular photochemical C−H insertion reactions of α‐diazocarbonyl compounds are powerful synthetic transformations leading to carbon‐carbon bond formation. While there are limitations in the scope of C−H bonds amenable to C−H insertion under photochemical conditions relative to metal catalysed C−H insertions, the benefits of conducting these synthetically powerful transformations in a metal‐free approach offers “green” advantages. Recent advances in technology have revolutionised the potential for use of photochemical transformations in synthesis, including the wavelength control enabled by LEDs and the benefits associated with continuous flow processing which overcome many of the traditional challenges associated with synthetic photochemistry including scale‐up. The potential for telescoping the synthesis of α‐diazocarbonyl compounds and downstream photochemical reactions is clear. This review summarises the development of intramolecular photochemical C−H insertions and highlights the benefits of recent technological advances.

An 8-channel narrow linewidth multi-wavelength laser hybrid integrated by photonic wire bonding structures for DWDM systems

An 8-channel monolithically integrated narrow linewidth multi-wavelength laser array (NL-MLA) combined with the commercial 8 × 1 planar lightwave circuit (PLC) coupler by the photonic wire bonding (PWB) technique is demonstrated in this paper. A distributed feedback (DFB) laser with the high-reflection and anti-reflection coatings (HR-AR) and the tapered asymmetric corrugation-pitch-modulated (TACPM) grating structure is proposed. The TACPM grating is achieved by the reconstruction equivalent chirp (REC) technique, which is low-cost and of high wavelength accuracy. According to the numerical simulation results, under the unavoidable impact of the facet phase of the HR end, the TACPM DFB laser suppresses the longitudinal spatial hole burning (LSHB) effect significantly, while having better single-mode performance and control of wavelength compared with the conventional HR-AR DFB laser. An 8-channel HR-AR TACPM DFB NL-MLA is fabricated with the 0.8 nm wavelength spacing design. The hybrid integration between the 8-channel NL-MLA and the PLC chip is achieved using the PWB technique. Both good single-mode performance and accurate wavelength interval of 0.8 nm can be obtained when all channels work simultaneously. The laser linewidth is below 273.8 kHz with good uniformity, and the relative intensity noise is under −159.6 dB/Hz for each channel.

GaSb-Si3N4 hybrid lasers with precise wavelength control and narrow spectral linewidth based on low-kappa Bragg gratings

GaSb-Si3N4 hybrid lasers with precise wavelength control and narrow spectral linewidth based on low-kappa Bragg gratings

Wearable quantum dots organic light-emitting diodes patch for high-power near infra-red photomedicene with real-time wavelength control

Wearable photomedical application fields, such as photobiomodulation (PBM), and photoplethysmography (PPG) sensors using organic light-emitting diodes (OLEDs), are promising and attractive due to their flexibility, surface light emission, and ability to apply to various free-form (attachable or implantable) healthcare platforms. However, to maximize the impact on wearable photomedical applications, their spectrum needs to be freely tunable in real-time, and expanded into the near-infrared (NIR) wavelengths which are difficult to achieve in conventional electroluminescent OLED. In this study, we introduce the wavelength selective quantum dots high-power parallel-stacked OLED (QD-OLED) patch. Several NIR QD-OLEDs with 630, 700, and 730 nm peak wavlength were optimized by the high-power (> 100 mW·cm−2 at 6.3 V) parallel-stacked blue OLED with a 465 nm emission peak.The NIR QD-OLED patch platform with multi-functional blue reflective NIR-enhanced (> 60 %) encapsulation film (6 x 10−6 g·m−2·day−1), capable of real-time wavelength control, achieved a high-output NIR power density (>23.28 mW·cm−2). Using this NIR QD-OLED patch, PPG bio-signals were successfully measured. Additionally, this NIR QD-OLED demonstrated that it can increase the proliferation of dermal papilla cells by up to 131 % through NIR wavelength control, thereby optimizing the hair growth effect.

Precise Control of the Emission Wavelength on Perovskite Quantum Dots by Crystal Lattice Shrinkage/Expansion of the A Site Mixture

Precise Control of the Emission Wavelength on Perovskite Quantum Dots by Crystal Lattice Shrinkage/Expansion of the <i>A</i> Site Mixture

Emission Wavelength Control Based on Coupling of Surface Plasmon and Microcavity Mode in Organic Light-Emitting Diodes with Metal/Dielectric/Metal Anodes

Emission Wavelength Control Based on Coupling of Surface Plasmon and Microcavity Mode in Organic Light-Emitting Diodes with Metal/Dielectric/Metal Anodes

Simultaneous measurement of 13C-,18O-, and 17O- isotopes of CO2 using a compact mid-infrared hollow waveguide gas sensor

A compact gas sensor has been developed for the first time employing a quantum cascade laser (QCL) with a central wavelength of 4.32 μm, combined with direct absorption spectroscopy technology and a hollow waveguide. The sensor could measure the concentrations of four isotopic molecules (16O12C16O, 18O12C16O, 16O13C16O, and 17O12C16O) in CO2 gas simultaneously, thereby obtaining the relative isotope ratios of δ13C, δ18O, and δ17O. By adjusting the incident light path, the anomalous absorption peaks in the system have been effectively suppressed, and a compact feedback function generator has been integrated to ensure control of the laser output wavelength to eliminate the loss of measurement precision caused by wavelength fluctuations. Under the two conditions of free-running and wavelength-controlled, a standard CO2 sample with a concentration of 5 % was measured continuously. The results showed that under wavelength-controlled conditions, the precision of the four isotopic molecule concentration measurements was improved by a minimum of 1.8 times, and the measurement precision could be further improved after filtering. According to the Allan variance analysis, the detection precision for δ13C, δ18O, and δ17O were 0.7 ‰, 0.62 ‰, and 1.58 ‰, respectively, at the optimal integration time of 98 seconds. This study has the potential for respiratory diagnosis to detect simultaneously the values of δ13C, δ18O, and δ17O in exhaled samples.

Bicolor Tuning and Hyper-Reflective Color Switching Based on Two Stacked Cholesteric Liquid Crystal Cells with Asymmetric Electrothermal Optical Responses.

We propose a double-cell cholesteric liquid crystal (CLC) device composed of a left-handed (LH) CLC cell with a pair of sheet electrodes and a right-handed (RH) CLC cell with a tri-electrode configuration characterized by a sheet electrode on the top and an interdigitated electrode on the bottom substrates. Bi-reflected color tuning and hyper-reflective color switching are revealed from this cell stack via the electrothermal control of the central wavelengths of the LH- and RH-bandgaps by voltage-induced pseudo-dielectric heating. The two CLCs are thermally sensitive and exhibit overlapped bandgaps in the field-off state with nearly identical temperature dependence, resulting in a hyper-reflective color at 720 nm at 23.4 °C and 380 nm at 29.8 °C. Upon the application of 4 Vrms at 2 MHz across the stacked device to induce pseudo-dielectric heating, two reflective colors can be resolved due to asymmetrical temperature elevations. Accordingly, the difference in wavelength between the two colors increases with increasing voltage through a series cell connection, while maintaining approximately constant via a parallel connection. This study provides a feasible pathway to developing a multifunctional device with electrothermally tunable bi-reflected and hyper-reflective states based on two conventional cell geometries, which is promising for lasers and color-related display applications.

Stable and wavelength-tunable multiwavelength laser for high-rate measurement device independent quantum key distribution

Measurement device independent quantum key distribution (MDI QKD) has attracted growing attention for its immunity to attacks at the measurement unit, but its unique structure limits the secret key rate. Utilizing the wavelength division multiplexing (WDM) technique and reducing error rates are effective strategies for enhancing the secret key rate. Reducing error rates often requires active feedback control of wavelengths using precise external references. However, for a multiwavelength laser, employing multiple references to stabilize each wavelength output places stringent demands on these references and significantly increases system complexity. Here, we demonstrate a stable, wavelength-tunable multiwavelength laser with an output wavelength ranging from 1270 to 1610 nm. Through precise temperature control and stable drive current, we passively lock the laser wavelength, achieving remarkable wavelength stability. This significantly reduce the error rate, leading to an almost doubling of the secret key rate compared to previous experiments. Furthermore, the exceptional wavelength stability offered by our multiwavelength laser, combined with the WDM technique, has further boosted the secret key rate of MDI QKD. With a wide wavelength tuning range of 5.1 nm, our multiwavelength laser facilitates flexible operation across multiple dense wavelength division multiplexing channels. Coupled with high wavelength stability and multiple wavelength outputs simultaneously, this laser offers a promising solution for a high-rate MDI QKD system.

Large‐Scale Bottom‐Up Fabricated 3D Nonlinear Photonic Crystals

Nonlinear optical effects are used to generate coherent light at wavelengths difficult to reach with lasers. Materials periodically poled or nanostructured in the nonlinear susceptibility in three spatial directions are called 3D nonlinear photonic crystals (NPhCs). They enable enhanced nonlinear optical conversion efficiencies, emission control, and simultaneous generation of nonlinear wavelengths. The chemical inertness of efficient second‐order nonlinear materials () prohibits their nanofabrication until 2018. The current methods are restricted to top‐down laser‐based techniques limiting the periodicity along the z‐axis to . The first bottom‐up fabricated 3D NPhC is demonstrated in sol–gel‐derived barium titanate by soft‐nanoimprint lithography: a woodpile with eight layers and periodicities of (‐plane) and (z‐plane). The surface areas exceed , which is two orders of magnitude larger than the state‐of‐the‐art. This study is expected to initiate bottom‐up fabrication of 3D NPhCs with a supremely strong and versatile nonlinear response.

Omnidirectional color wavelength tuning of stretchable chiral liquid crystal elastomers

Wavelength-tunable structural colors using stimuli-responsive materials, such as chiral liquid crystals (CLCs), have attracted increasing attention owing to their high functionality in various tunable photonic applications. Ideally, on-demand omnidirectional wavelength control is highly desirable from the perspective of wavelength-tuning freedom. However, despite numerous previous research efforts on tunable CLC structural colors, only mono-directional wavelength tuning toward shorter wavelengths has been employed in most studies to date. In this study, we report the ideally desired omnidirectional wavelength control toward longer and shorter wavelengths with significantly improved tunability over a broadband wavelength range. By using areal expanding and contractive strain control of dielectric elastomer actuators (DEAs) with chiral liquid crystal elastomers (CLCEs), simultaneous and omnidirectional structural color-tuning control was achieved. This breakthrough in omnidirectional wavelength control enhances the achievable tuning freedom and versatility, making it applicable to a broad range of high-functional photonic applications.

Multiplexed manipulation of orbital angular momentum and wavelength in metasurfaces based on arbitrary complex-amplitude control

Due to its unbounded and orthogonal modes, the orbital angular momentum (OAM) is regarded as a key optical degree of freedom (DoF) for future information processing with ultra-high capacity and speed. Although the manipulation of OAM based on metasurfaces has brought about great achievements in various fields, such manipulation currently remains at single-DoF level, which means the multiplexed manipulation of OAM with other optical DoFs is still lacking, greatly hampering the application of OAM beams and advancement of metasurfaces. In order to overcome this challenge, we propose the idea of multiplexed coherent pixel (MCP) for metasurfaces. This approach enables the manipulation of arbitrary complex-amplitude under incident lights of both plane and OAM waves, on the basis of which we have realized the multiplexed DoF control of OAM and wavelength. As a result, the MCP method expands the types of incident lights which can be simultaneously responded by metasurfaces, enriches the information processing capability of metasurfaces, and creates applications of information encryption and OAM demultiplexer. Our findings not only provide means for the design of high-security and high-capacity metasurfaces, but also raise the control and application level of OAM, offering great potential for multifunctional nanophotonic devices in the future.

Controlling Fluorescence Wavelength in the Synthesis of TGA-Capped CdTe Quantum Dots

Quantum dots (QDs) are semiconductor materials, with a size range between 1–10 nm, showcasing unique size-dependent physical and chemical properties. Such properties have potentiated their use in areas like medical imaging and biosensing. Herein, we present an open-air approach for synthesis of QDs, reducing the need for controllable atmospheric conditions. Furthermore, we present a predictive mathematical model for maximum emission wavelength (λmax) control. Through a straightforward microwave-based aqueous synthesis of TGA-CdTe QDs, we investigated the influence of time, temperature, and Te:Cd and TGA:Cd molar ratios on λmax, using a chemometric experimental design approach. CdTe-QDs were characterized by UV-Vis and fluorescence spectroscopies. Additionally, Fourier-Transform Infrared spectroscopy, X-ray photoelectron spectroscopy, Transmission Electron Microscopy, and Energy Dispersive X-ray were conducted. Stable QDs with fluorescence ranging from green to red (527.6 nm to 629.2 nm) were obtained. A statistical analysis of the results revealed that time and temperature were the most significant factors influencing λmax. After fine-tuning the variables, a mathematical model with 97.7% of prediction accurately forecasted experimental conditions for synthesizing TGA-CdTe QDs at predefined λmax. Stability tests demonstrated that the QDs retained their optical characteristics for over a month at 4 °C, facilitating diverse applications.

Quickly tunable ultra-narrow filter via a metal film waveguide.

The development of fast, efficient, and cost-effective tunable optical filters is a tireless pursuit of the goal in the field of optical signal processing and communications. However, the traditional filters have been limited by their complex structures, slow tuning speed, and high cost. To address this challenge, we present a tunable ultra-narrow bandpass filter, which is fabricated by a metal layer cladded in a high-parallelism and high-precision piezoelectric ceramic for an interlayer. Experimental results show a remarkable full width at half maximum of 51 pm and a fast response time of 800 ns. In addition, by cascading double filters, the wavelength of the output light has been fine-tuned from a Vernier effect. Moreover, we realize a tunable filter to select and output several ultra-narrow single peaks with 56% efficiency in the 2 nm range. Furthermore, it offers a wide tunable range, exceptional narrowband filtering performance, and fast piezoelectric response times. Hence, it is particularly well suited to applications requiring precise wavelength selection and control, opening new possibilities in the field of tunable optical filters.

In Situ Center Wavelength Control of AlInN/GaN Distributed Bragg Reflectors with In Situ Reflectivity Spectra Measurements

An in situ control of a center wavelength in a 40‐pair AlInN/GaN distributed Bragg reflector (DBR) for GaN‐based vertical‐cavity surface‐emitting lasers (VCSELs) with an in situ reflectivity spectra measurement is proposed and developed. A procedure of the in situ control consists of the following three steps: 1) to grow an initial 5‐pair DBR; 2) to obtain the center wavelength value just after the initial DBR growth by the in situ reflectivity spectra measurement; and 3) to adjust growth times as a result of the obtained center wavelength value and continue the remaining 35‐pair DBR. It is experimentally demonstrated that the in situ control of the center wavelength in the 40‐pair DBRs with the ±2% thickness deviations in the initial 5‐pair DBR results in reductions of the deviation down to ±0.3%. The in situ DBR center wavelength control is a key technique for highly reproducible GaN‐based VCSELs.

Impact of Hybrid Plasmonic and Temperature in Random Laser Tuning

This research explores the interaction between silver films and dispersed silver nanowires (Ag NWs) in the context of generating random laser emission. To achieve random lasing, we use a mixture of Rhoda mine B (RhB) dye and a polyvinyl alcohol (PVA) matrix as the gain medium. The combination of silver components plays a crucial role in trapping and controlling light. The surface characteristics of the film, including its roughness and the interplay between localized and extended surface plasmons significantly affect the performance of the random laser (RL). The laser’s threshold is closely linked to the thickness of the film, which is influenced by its surface roughness. Additionally, variations in film thickness lead to wavelength modulation, ranging from 597 nm to 606 nm, primarily due to the reabsorption of RhB. Moreover, this research demonstrates the intriguing capability to tune emission wavelengths in response to temperature changes, promising precise wavelength control for plasmonic devices and potential applications.

Vortex random lasing with tunable wavelength and orbital angular momentum

Random lasing with special structured light field has broad application prospects in various fields. However, the complex spatial modes of random lasing increase the difficulty of light field regulation and limit its practical application. Here, a vortex random lasing with dynamically tunable wavelength and orbital angular momentum is proposed based on the microfluidic channel. Different color random lasers are integrated into the same microfluidic channel for coarse control of the emission wavelengths from 462 to 685 nm by dynamically controlling the liquid flow. A special-shape cavity with a variable size of a gain region is further constructed to finely manipulate the emission wavelengths. Moreover, the vortex random lasing with tunable orbital angular momentum mode from −50 to 50 is realized. The results provide an outstanding strategy for generating the partially coherent vortex beams and may promote the practical applications of random lasers in the fields of sensing, imaging, and communication.

Photoswitchable luminescent lanthanide complexes controlled and interrogated by four orthogonal wavelengths of light.

Optical information storage requires careful control of excitation and emission wavelengths in a reversible and orthogonal manner to enable efficient reading, writing, and erasing of information. Photochromic systems, in which a photoswitch is typcially coupled to an emissive organic fluorophore, have much promise in this regard. However, these suffer from considerable spectral overlap between the switch and fluorophore, such that their emissive and photoswitchable properties are not orthogonal. Here, we overcome this limitation by coupling visible/NIR emissive lanthanide complexes with molecular photoswitches, enabling reversible and orthogonal photoswitching with visible light. Crucially, photoswitching does not lead to sensitised emission from the lanthanide, while excitation of the lanthanide does not induce photoswitching, enabling the state of the system to be probed without perturbation of the switch. This opens up the possibility of developing multi-colour read-write methods for information storage using emissive photoswitches.

Brewster mirror ultrafast optical parametric oscillator with high precision wavelength tuning.

We demonstrate a synchronously-pumped optical parametric oscillator (OPO) with a cavity formed from high refractive index inverted prisms, also known as Brewster mirrors. Exploiting a single total internal reflection, this is the simplest device capable of deviating a laser beam by 180∘. The OPO produced a chirped signal output tunable from 1060-1570nm with a maximum power of 114 mW. We investigate the geometric properties of ideal and imperfect Brewster mirror prisms and find the latter can provide ∼1000 × finer control of the signal wavelength when compared to cavity length tuning.

Spectral control in the liquid crystal tunable filters

A liquid crystal is used as an electro-optical device with the advantages of low voltage driving, low power consumption, and thin flatness by utilizing its refractive index anisotropy (birefringence). In this research, a liquid crystal tunable filter (LCTF) with control of a main peak wavelength λ 0 and a full-width Δλ at half maximum is developed. The device contains two stacking liquid crystal layers with different wavelength dependences of birefringence Δn with their optical axes perpendicular to each other and controlling the light wavenumbers in a complementary manner (S-ECB).