Spray pyrolysis is an excellent method to realize high value utilizing industrial waste bischofite. Interacting droplet evaporation characteristics under the combined influence of ambient pressure, temperature, and decomposition reactions are a prerequisite for constructing spray pyrolysis devices. Therefore, this work established a comprehensive heat and mass transfer model during the multi-component droplet evaporation incorporating decomposition reaction. It also delved into the interplay between temperature and pressure, elucidating their combined influence on the decomposition process during evaporation. The results suggest that raising either temperature or pressure alone can speed up the decomposition process; raising both will more successfully increase the rate of decomposition conversion. In addition, a set of non-dimensionless parameters, mth/ml (mass transfer contribution rate) and Qth/Qd (heat transfer contribution rate), are proposed to characterize the contribution of the decomposition reaction to the evaporation process. Under the actual spray pyrolysis conditions, the mass transfer contribution rate, mth/ml, which is varied in a range of 2 %–70 %, indicating the important role of decomposition reaction during the mass transfer process. The maximum value of the heat transfer contribution rate Qth/Qd is less than 10 %, indicating the dominant role of evaporation in the heat transfer process. Based on the analysis, a theoretical direction for modeling may be provided.
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