The reentry trajectory planning problem of hypersonic vehicles is generally a continuous and nonconvex optimization problem. The solution efficiency and convergence properties of the planning algorithm become an essential point when considering the practical application scenarios. In this paper, an augmented-Lagrange-based improved sequential convex programming algorithm is proposed to solve it and achieve superior solutions with higher accuracy and efficiency. Firstly, the mapped Chebyshev pseudo-spectral method is utilized to convert the continuous optimal control problem into a highly approximately discretized one. In this framework, the discretization technique is employed to discretize the states and control variables at the time interval, which leads to the improvement of ill-conditioned differential matrix and better approximation properties of the variables. Moreover, by introducing slack variables, automatically updated penalty parameters and Lagrange multipliers during the convexification processing, the original nonconvex problem is transformed into an augmented-Lagrange-function-formed relaxed convex one. Then, the arrived convex subproblem can be solved iteratively by the matured interior-point method until the predetermined precision is satisfied. Based on this transformation, it can effectively alleviate the numerical difficulty and improve the convergence property of the proposed improved sequential convex programming algorithm. Finally, Rigorous theoretical analysis is conducted to prove that the solution sequence generated by the proposed algorithm could converge to an approximate global solution of the original problem. Numerical simulations are also presented, and it is demonstrated that the solution time of the proposed algorithm is more than 95% less than that of the traditional nonlinear programming methods without losing the merits of high precision.