Continental Margin Research Articles

Predictive mapping of organic carbon stocks in surficial sediments of the Canadian continental margin

Abstract. Quantification and mapping of surficial seabed sediment organic carbon have wide-scale relevance for marine ecology, geology and environmental resource management, with carbon densities and accumulation rates being a major indicator of geological history, ecological function and ecosystem service provisioning, including the potential to contribute to nature-based climate change mitigation. While global analyses can appear to provide a definitive understanding of the spatial distribution of sediment carbon, regional maps may be constructed at finer resolutions and can utilise targeted data syntheses and refined spatial data products and therefore have the potential to improve these estimates. Here, we report a national systematic review of data on organic carbon content in seabed sediments across Canada and combine this with a synthesis and unification of the best available data on sediment composition, seafloor morphology, hydrology, chemistry and geographic settings within a machine learning mapping framework. Predictive quantitative maps of mud content, dry bulk density, organic carbon content and organic carbon density were produced along with cell-specific estimates of their uncertainty at 200 m resolution across 4 489 235 km2 of the Canadian continental margin (92.6 % of the seafloor area above 2500 m) (https://doi.org/10.5683/SP3/ICHVVA, Epstein et al., 2024). Fine-scale variation in carbon stocks was identified across the Canadian continental margin, particularly in the Pacific Ocean and Atlantic Ocean regions. Overall, we estimate the standing stock of organic carbon in the top 30 cm of surficial seabed sediments across the Canadian shelf and slope to be 10.9 Gt (7.0–16.0 Gt). Increased empirical sediment data collection and higher precision in spatial environmental data layers could significantly reduce uncertainty and increase accuracy in these products over time.

Mesozoic to Cenozoic tectonic evolution in the central Bohai Bay Basin, East China

The Mesozoic and Cenozoic tectonic evolutionary history of the East Asian continental margin has been the focus of many researchers because of the overprinting of multiple tectonic domains. Previous studies have suggested that the westward subduction of the Paleo-Pacific Plate and the Pacific Plate resulted in the deconstruction of the North China Craton and controlled the formation of the related basins on the continental margin of East Asia. However, controversy remains regarding the tectonic transition processes and mechanisms that occurred from the Mesozoic to the Cenozoic. Since the Mesozoic, the Bohai Bay Basin on the eastern margin of the North China Craton of East China has been influenced by multiple tectonic domains of the Paleo-Tethys, Paleo-Pacific, and Pacific oceans, and there are complete records of these tectonic transition processes. The Bozhong Depression is a subbasin in the Bohai Bay Basin, which is a crucial area for researching the tectonic evolution of the Bohai Bay Basin throughout the Mesozoic−Cenozoic and the regional tectonic evolution of the eastern continental margin of China. Based on 3-D seismic data, logging core data, and a balanced cross section in the Bozhong area, combined with data from the apatite fission-track inversion model, we reconstructed the tectonic evolutionary history of central Bohai Bay Basin and established a three-cycle and eight-stage tectonic model of the central Bohai Bay Basin during the Mesozoic−Cenozoic. The three cycles are the Indosinian, the Yanshinian, and the Himalayan. (1) The Indosinian was marked by two stages. During the early Indosinian, NW-trending thrust faults were formed due to the collision and northward subduction of the South China Block underneath the North China Block. In the late Indosinian, the tectonic stress in the central Bohai Bay Basin shifted from compression to extension. Consequently, the thrust faults reversed, leading to the deposition of Early−Middle Jurassic strata. (2) The Yanshanian cycle comprises three main phases. Early Yanshanian transpressional shearing led to the formation of a NE/NNE-trending, left-lateral strike-slip fault due to NWW-directed subduction of the Paleo-Pacific Plate. Middle Yanshanian transtensional shearing was driven by Paleo-Pacific Plate rollback and resulted in regional extension and the negative inversion of previous compressive faults. Late Yanshanian compression gave rise to the basin reversion, which resulted from an increased subduction speed of the Paleo-Pacific Plate and a transition from a high angle to a low angle. (3) The Himalayan cycle was marked by three phases. During the early Paleogene, the region was characterized mainly by extension, and NE-trending, right-lateral strike-slip normal faults began to form. This coincided with a decrease in the Pacific Plate’s subduction speed. In the late Paleogene, the subduction rate of the Pacific Plate increased, resulting in the change of the central Bohai Bay Basin from an extensional environment to one marked by regional differential compression. In the Neogene, regional thermal subsidence and depression sedimentation occurred, which were probably induced by the increasing subduction speed and rollback of the Pacific Plate. The Bozhong Depression has experienced multiple stages of tectonic evolution, which indicates the concurrent and superimposed effects and transition of multiple tectonic domains.

A primary evaporite weld revealed in the late Paleozoic Antigonish sub-basin of Nova Scotia

The Antigonish sub-basin lies within the late Paleozoic Maritimes Basin of Atlantic Canada. Late Devonian to early Carboniferous basin development resulted in a basin-and-range topography, within which the clastic Horton Group was deposited in grabens and half-grabens. The overlying Visean Windsor Group contains substantial evaporite units; later basin development was accompanied by expulsion of these evaporites. In the Antigonish sub-basin a significant stratigraphic omission surface initially described as a thrust was subsequently reinterpreted as the extensional Ainslie Detachment. This surface can be examined in drill-core, where the halite-bearing interval is reduced to 3.8 m of halite-cemented breccia of sedimentary rock fragments. The halite cement is sub-horizontally foliated and lineated. At Lakevale an outcrop section of the Windsor Group is reduced in thickness to tens of metres. Above a basal limestone unit containing pseudomorphs of gypsum, most of the Windsor Group is represented by sedimentary-clast breccias which resemble those seen in core, but with the halite removed by solution in the near-surface environment. The stratigraphic record within the sub-basin implies that expulsion of lower Windsor salt was initially toward the edges of the basin where rising diapirs blocked the deposition of Middle Windsor group, but in the basin centre a second salt unit was deposited. Subsequently, during contractional inversion of basin-bounding faults, the middle Windsor salt was expelled into diapirs near the centre of the basin. The Ainslie Detachment is reinterpreted as a primary salt weld: a boundary between units formerly above and below expelled lower Windsor evaporites. The resulting stratigraphic omissions and structures match those seen above expelled evaporite layers on continental margins.

Geohazard features of the Tyrrhenian Calabria

ABSTRACT This paper accompanies the Maps of Geohazard features of the Cilento and the Calabro-Tyrrhenian continental margin in the southern Tyrrhenian Sea (Italy). The main geohazard-related features were derived from extensive seafloor mapping through the collection of high-resolution multibeam data acquired during several oceanographic cruises. They encompass many fluids seepage features, fault scarps, landslides scars, gullies, channels, and canyons. Hazards related to coastal landslides and shelf-indenting canyons are very high in these sectors (especially in southern Calabria) due to active seismicity coupled with rapid uplift, high sedimentation rates and narrow or totally absent continental shelf, thus promoting a direct connection between steep slopes and coastal areas. In this setting, mass-wasting features can directly impact coastal or submarine infrastructures or indirectly create local tsunami waves, as observed in historical times. Moreover, this physiographic setting of the margin facilitates the transfer of marine litter toward deep-sea areas.

Basal erosion during the initiation of continental deep subduction in the North Qaidam ultrahigh-pressure metamorphic belt (NW China): Constraints from geochemistry and geochronology on eclogites and gneisses in the Chachahe unit

Subduction erosion is thought to be a common process in active continental margins that removes upper-plate material and transfers it to the subduction channel. The North Qaidam ultrahigh-pressure metamorphic belt of NW China was formed by subduction of the Qaidam Block beneath the Quanji Block in the early Paleozoic. In this study, we found gneisses and eclogites in the Chachahe unit of the North Qaidam ultrahigh-pressure metamorphic belt that recorded 2.39−2.28 Ga magmatism and 1.93−1.87 Ga amphibolite-facies metamorphism prior to the early Paleozoic (452−439 Ma) eclogite-facies metamorphism. The Paleoproterozoic tectono-thermal history recorded by these gneisses and eclogites is distinct from that of the Qaidam Block but similar to that of the Quanji Block. The rock assemblages, field occurrences, geochemical characteristics, and zircon Lu-Hf isotopic compositions of these rocks closely resemble those of gneisses and enclosed mafic enclaves in the Delingha Complex in the basement of the Quanji Block and the mafic dikes intruded within it. This evidence clearly illustrates that the protoliths of gneisses and eclogites in the Chachahe unit were from the basement of the upper Quanji Block rather than the subducted Qaidam Block. Further considering the spatial location of the Chachahe unit, as well as similarities in early Paleozoic metamorphic ages, peak metamorphic conditions, and clockwise P-T paths between rocks in the Chachahe unit and those that originated from the Qaidam Block, we propose that the bottom basement of the Quanji Block was scraped off by basal erosion during the initiation of continental subduction, transported to mantle depth, and then exhumed with other slices from the subducted slab.

The Quaternary sedimentary history and dynamics of the deep-water margin off the Hudson Strait ice stream

Sites of ice-stream discharge to the continental slope build trough-mouth fans from glacigenic debris flows (GDFs), subglacial meltwater flows, and suspended sediment. Thus, past ice configurations may be interpreted from the sedimentological record. This study links the records in cores, high-resolution seismic profiles, and multibeam swath bathymetry of Hatton Slope and Fan to the changing glaciological history in Hudson Strait, one of the largest ice streams of the late Pleistocene Laurentide Ice Sheet. 14C-AMS dates, X-ray fluorescence geochemical profiles, and oxygen isotopes in sixteen cores document sediment supply during the last glacial cycle, and earlier history is interpreted from seismic data. The Frobisher Bay slope sector has a long record of GDF deposits from severe glacial periods between MIS 6 and 22, with little impact of meltwater discharge. Mass-transport events and aggrading gravel-floored valleys dominate the northern Hatton slope sector. The central slope sector shows the greatest shelf break progradation by till deposition, with kilometre-spaced gullies heading at 700–730 mbsl from the last major grounding of the ice-stream on the upper slope during Heinrich event 3 (H3). The gullies pass downslope into ∼5 km wide valleys, which have been sites of sediment bypass since widespread meltwater flow in MIS 6 and show little aggradation since MIS 16. Intervening >50 m high ridges show alternating levee accretion and erosion by shallow mass-transport events. Downslope on Hatton Fan, GDFs are common and fill wide erosional channels that lead to the sandy braid plain of the central Labrador Sea. The channels of the southern sector and Saglek Slope have channeled turbidity currents down the NAMOC, and stratified contourite deposits accumulated on the fan. Over the MIS 1–3 period widely represented by cores, ice was grounded in Hatton Basin and on the upper slope to 700 m water depth only immediately prior to H3. Older and younger H events had a floating ice-shelf in Hatton Basin, and sedimentation was dominated by the retreat of that ice shelf to Resolution Island. Distal cores show no systematic difference between the H1–top H3 interval and the base H3–H5 interval. Given the supply of carbonate detritus of consistent composition back to at least H5, any MIS 3 deglaciation of Hudson Bay would require improbably high growth rates of ice sheets in the centre of the continent.

Discovery of the first hydrothermal field along the 500-km-long Knipovich Ridge offshore Svalbard (the Jøtul field)

Oceanic spreading centers north of Iceland are characterized by ultraslow spreading rates, and related hydrothermal activity has been detected in the water column and at the seafloor along nearly all ridge segments. An exception is the 500-km-long Knipovich Ridge, from where, until now, no hydrothermal vents were known. Here we report the investigation of the first hydrothermal vent field of the Knipovich Ridge, which was discovered in July 2022 during expedition MSM109. The newly discovered hydrothermal field, named Jøtul hydrothermal field, is associated with the eastern bounding fault of the rift valley rather than with an axial volcanic ridge. Guided by physico-chemical anomalies in the water column, ROV investigations on the seafloor showed a wide variety of fluid escape sites, inactive and active mounds with abundant hydrothermal precipitates, and chemosynthetic organisms. Fluids with temperatures between 8 and 316 °C as well as precipitates were sampled at four vent sites. High methane, carbon dioxide, and ammonium concentrations, as well as high 87Sr/86Sr isotope ratios of the vent fluids indicate strong interaction between magma and sediments from the Svalbard continental margin. Such interactions are important for carbon mobilization at the seafloor and the carbon cycle in the ocean.

Correlation between acoustic velocity and physical parameters of sea floor sediments: a case study of the northern South China Sea

As the interface between seawater and the seabed, superficial sediments on the seabed are an important part of the marine acoustic field environment and are indispensable for marine resource investigations. Studying sediments several meters to hundreds of meters below the seafloor is highly valuable and important. This study processes and analyses the water depth, topography and bottom data and obtains the shallow bottom profile and topographic map of the northern continental slope of the South China Sea (SCS). The study analyzes the influence of physical parameter (including density, porosity, and grain size) on the acoustic velocity in sediments. Single-parameter and dual-parameter models are established to further examine this influence. The results show that porosity and density have greater influences on the acoustic velocity of sediments than does grain size. Finally, the acoustic properties of several typical stations with water depths are tested to analyze the variations in the acoustic properties of the shallow sediments in the northern SCS. The results show that the influence of each parameter on the prediction of the acoustic velocity of the sediment is in the following order: porosity>density>grain size. This study analyses and reveals the reason why the seafloor sediments in the local area cause the acoustic properties to change greatly. It may be caused by changes in the sediment type, lithology along with the depth. And the other reason is the development of interlayer in the land slope of the northern SCS.

The evolution of crystal‐poor rhyolite in the middle Okinawa Trough and its implications for the state of magma chamber

The crystal‐poor rhyolitic pumice is the product of extreme magma differentiation and is characterized by highly vesicular, honeycomb‐like structure. However, little is known about the evolutionary history and the time of volatile saturation of the pumice‐forming melt. A crystal‐poor rhyolitic pumice (TVG7‐1) has been collected from the Yoron Hole hydrothermal field in the middle Okinawa Trough, a young continental margin back‐arc basin in the western Pacific. This study conducted a detailed analysis on the texture and in situ chemical composition of plagioclase, orthopyroxene and Fe‐Ti oxides to reveal the evolution process, storage state and eruption triggers of eruptible silicic melt. Texture and zoning of specific minerals and mineral populations suggest a magmatic evolution history of open system. Additionally, the hollow reentrant texture, as well as results from plagioclase‐liquid hygrometers, confirm a water‐rich melt pocket. The exsolution of volatiles (H2O, etc.), in this melt pocket, will contribute to local oxidation conditions, which may have been recorded by the concordant behaviour of FeO and An in plagioclase. Then, the overpressure caused by volatile exsolution would destabilize the magma chamber, which will eventually be broken by magma mixing/recharge, and lead to violent melt evacuation. Consequently, crystal size distribution (CSD) provides a new perspective on understanding the kinetic effect of magma mixing/recharge in the Okinawa Trough, especially on the mineral populations. Our study reveals the petrogenesis of crystal‐poor rhyolite within the framework of the mush model, refines the magma evolution history and demonstrates that pumice magma reaches volatile saturation before the eruption.

The role of ice-sheet dynamics in the Miocene-Pliocene depositional systems of the Ross Sea, Antarctica

The dynamics of the Antarctic ice sheet (AIS) have profound implications for the evolution of the Antarctic continental margin, global ocean currents, and climate changes. Marine sediments from the Antarctic continental margins recorded the history of the advance and retreat of the AIS. In this study, we present an integrated analysis of the sedimentary characteristics of the Early Miocene to Late Miocene of the Ross Sea by using 2D seismic reflection data and cores from International Ocean Discovery Program (IODP) Expedition 374 Sites U1521, U1522, and U1524. The characteristics of the seismic facies and sediments show that the expansion and grounding of the ice sheets across the continental shelf significantly influenced the depositional processes, leading to increased glacial erosion, the formation of prograding wedges, mass transport deposits (MTDs), and mixed (turbidite-contourite) depositional systems since the Early Miocene. The seaward migration of the continental shelf edge and the steepening of the continental slope were mainly influenced by the glaciation of extreme expansion of the AIS. Marked increases in the prograding wedge and MTD are associated with extensive sediment reworking and deposition at the grounding zones and along the continental slope as a result of ice sheet expansion. The development of the mixed (turbidite-contourite) depositional systems was the result of extensive sediment reworking and deposition by gravity flows and bottom currents on the continental slope and the rise. This research provides new insights into the complexity of the ice sheet and the sensibility of marginal sediments in responding to the past climate changes in Antarctica.

New insights into the origin and depositional setting of the Haerdaban Pb[sbnd]Zn deposit, Chinese western Tianshan: Evidence from geology, chert geochemistry, and detrital zircon U[sbnd]Pb geochronology

The Haerdaban PbZn deposit (with an ore reserve of 10.93 Mt. at 1.0–25.65 % Zn and 0.7–12.29 % Pb) is hosted in weakly metamorphosed clastic‑carbonate rocks from the Proterozoic Haerdaban Group. It represents a significant addition of the sediment-hosted PbZn deposits in the Yili block, Chinese western Tianshan. Currently, there are ongoing debates regarding its genesis, with a particular focus on the crucial metallogenic mechanism (syngenetic sedimentary exhalation or epigenetic reworking) responsible for the primary sulfide mineralization. Mineralization at Haerdaban primarily occurs as banded to stratiform ore layers or lenses conformably sandwiched in their host rocks. Vein and stockwork ores occur locally below the stratiform ore layers. A syn-sedimentary fault trending SN was identified based on abrupt lateral changes in lithofacies and thickness of the stratigraphic units. The ore mineralogy is dominated by sphalerite, galena, quartz, and dolomite, with a small amount of pyrite, barite, and organic matter. Detrital zircon LA-ICP-MS UPb dating of the Haerdaban siltstones obtained a maximum depositional age of about 604 Ma. Their geochemical composition similar to the passive continental margin signatures, with rare earth element (REE) patterns enriched in LREE and negative Eu anomalies (Eu/Eu* = 0.50–1.14). Stratiform beds of chert that host disseminated ores have relatively high contents of hydrothermal components (e.g., Ba, Zn), with apparent positive Eu anomalies (Eu/Eu* = 7.38–49.34) and negligible negative Ce anomalies (Ce/Ce* = 0.85–0.98). They are thus interpreted to be hydrothermal sedimentary rocks (exhalites) deposited in a suboxic-anoxic environment proximal to the hydrothermal vents. Integrated geological and geochemical evidence indicates that the Haerdaban PbZn deposit is a typical vent-proximal sedimentary exhalative (SEDEX) deposit formed in a Neoproterozoic Sinian (Ediacaran) passive continental margin rift basin. Post-depositional metamorphism and deformation in the Paleozoic may have caused partial remobilization of primary ores but did not significantly alter the morphology of the orebodies. Furthermore, establishing a genetic model for the Haerdaban deposit has important implications for the exploration of similar deposits preserved in the equivalent stratigraphy within the Chinese western Tianshan region.

The Shelf‐To‐Basin Transport of Iron From the Northern U.S. West Coast to the Pacific Ocean

AbstractRelease of iron (Fe) from continental shelves is a major source of this limiting nutrient for phytoplankton in the open ocean, including productive Eastern Boundary Upwelling Systems. The mechanisms governing the transport and fate of Fe along continental margins remain poorly understood, reflecting interaction of physical and biogeochemical processes that are crudely represented by global ocean biogeochemical models. Here, we use a submesoscale‐permitting physical‐biogeochemical model to investigate processes governing the delivery of shelf‐derived Fe to the open ocean along the northern U.S. West Coast. We find that a significant fraction (∼20%) of the Fe released by sediments on the shelf is transported offshore, fertilizing the broader Northeast Pacific Ocean. This transport is governed by two main pathways that reflect interaction between the wind‐driven ocean circulation and Fe release by low‐oxygen sediments: the first in the surface boundary layer during upwelling events; the second in the bottom boundary layer, associated with pervasive interactions of the poleward California Undercurrent with bottom topography. In the water column interior, transient and standing eddies strengthen offshore transport, counteracting the onshore pull of the mean upwelling circulation. Several hot‐spots of intense Fe delivery to the open ocean are maintained by standing meanders in the mean current and enhanced by transient eddies and seasonal oxygen depletion. Our results highlight the importance of fine‐scale dynamics for the transport of Fe and shelf‐derived elements from continental margins to the open ocean, and the need to improve representation of these processes in biogeochemical models used for climate studies.

Testing alternative tectonic models for the Permian-Pleistocene tectonic development of the Kyrenia Range, N Cyprus: Implications for E Mediterranean Tethyan palaeogeography

Three published alternative tectonic models of the Permian-Pleistocene development of the Kyrenia Range, N Cyprus are tested, supported by new field, geochemical and micropalaeontological evidence: 1. The Kyrenia Range represents the northern continental margin of the S Neotethys, close to its present relative position. The range initiated as a Permian-Cretaceous rift/passive margin, switching to a N-facing active margin during Late Cretaceous-Neogene; 2. The Range was located along the N African continental margin until the Neogene when northward subduction transferred it to the southern margin of the Eurasian plate; 3. The Range is a far-travelled allochthon that was emplaced to near its present position, probably during the Eocene.In the light of regional comparisons, especially with southern Turkey, the combined evidence mainly supports tectonic model 1. Sedimentary and palaeontological data show that the restored stratigraphy of the Kyrenia Range indicates Late Permian initial rifting and Early-Middle Triassic advanced rifting, followed by Jurassic-Early Cretaceous passive margin subsidence. Small exposures of ophiolite-related melange located between the Mesozoic carbonate platform and the overlying latest Cretaceous-Palaeogene deep-water volcanic-sedimentary succession include evidence of HP/LT metamorphism, pointing to Late Cretaceous subduction. MORB/boninites, diabase-gabbro and extensive harzburgitic serpentinite originated as a SSZ ophiolite, together with a possible high-grade metamorphic sole (garnet amphibolite) and an accretionary prism (E-MORB/OIB; metachert). Microfossil evidence indicates exhumation of the melange and the underlying platform prior to Late Maastrichtian. A mass-transport complex formed within a compression-related foredeep during the Middle Eocene. Associated southward thrusting and folding culminated in emergence and subaerial erosion, generating a major unconformity, that was followed by subaerial and then marine deltaic deposits (Late Eocene-Oligocene). Following major Late Miocene southward thrusting, uplift of the Kyrenia Range took place during the Pleistocene, related to collision of the leading edge of the North African plate (Eratosthenes Seamount) with the Eurasian (Anatolian) plate.

Recycled lower oceanic crust signal in early Jurassic A1-type granites, South China: Implications for flat-slab subduction and mantle heterogeneity in the continental back-arc region

Flat-slab subduction is a distinctive phenomenon that leads to the development of a wide orogenic zone (≥ 800 km) along former continental margins, triggering extensive intraplate magmatism and deformation. However, occurrences of flat-slab subduction on ancient convergent margins are exceptionally rare, possibly owing to multiple episodes of structural destruction and/or poor preservation. Furthermore, the impact of flat-slab subduction on mantle heterogeneity remains ambiguous. In this study, we present comprehensive whole-rock geochemical analyses as well as in-situ zircon UPb dating and HfO isotopic data for Early Jurassic A-type granites from the Pitou and Shibixia plutons in the interior of the South China Block to investigate the potential influence of flat-slab subduction on intraplate magmatism. The Pitou granites exhibit characteristics consistent with those of A2-type granite, displaying zircon εHf(t) values ranging from −4.9 to +0.3 and elevated δ18O values of 6.2–7.6‰. These features suggest that the granites formed through the differentiation of a basaltic parental magma, which underwent varying degrees of crustal contamination. In contrast, the Shibixia granites show A1-type geochemical features and were derived from basaltic parental magma without significant crustal contamination. The zircons in these granites exhibit positive εHf(t) values ranging from +6.6 to +10.6 and anomalously low δ18O values of 3.3–4.0‰, suggesting the involvement of recycled altered lower oceanic crust components in their mantle source. This provides strong evidence for the occurrence of flat-slab subduction beneath the interior of the South China Block during the early Mesozoic, which was located at least 800 km away from the trench. Combined with the presence of post-delamination ocean island-like intraplate magmatic rocks in the South China interior, it is suggested that the flat-slab delamination at approximately 190 Ma facilitated late Mesozoic intraplate OIB-like magmatism. This process, associated with flat-slab subduction, is expected to exert a significant impact on mantle isotopic heterogeneity within continental back-arc regions.

Facies analysis for the Neoarchean Itchen and Sherpa formations of the Winter Lake greenstone belt, Slave craton, Northwest Territories, Canada

There are numerous Neoarchean metasedimentary rock packages in the Slave craton, and they serve as important archives of tectonic processes. Little is documented on the Neoarchean sedimentary packages of the Winter Lake greenstone belt of the central Slave craton, however, and their interpretation can aid in the understanding of the final stages of Slave craton amalgamation. This project investigates the depositional environments and tectonic settings of the Itchen Formation and Sherpa Formation of the Winter Lake greenstone belt. Our study provides constraints for reconstructing the Neoarchean evolution of the central Slave craton through bedrock mapping and facies analysis. The Itchen Formation consists of submature mudstone, siltstone, and sandstone, with preserved graded bedding, planar bedding, and flame structures. Unconformably overlying the Itchen Formation is the Sherpa Formation, which is dominated by polymictic conglomerates and coarse-grained sandstones with preserved cross-bedding, imbricated clasts, and scour surfaces. The Itchen Formation is interpreted to have been deposited in a convergent basin (i.e., retro-arc foreland basin), where two facies associations outline turbidite and suspension sedimentation consistent with submarine fan deposition on a continental slope and a basin floor environment. By contrast, the Sherpa Formation has three facies associations representing dominantly alluvial–fluvial environments in terrestrial–marine–lacustrine settings deposited in pull-apart basins resulting from transtensional forces associated with the Beniah fault zone.

Provenance signature and tectono–sedimentary setting of the Permian Shihezi Formation (Ordos Basin, China): Insights from geochemistry and detrital zircon U–Pb dating

During the depositional period of the Permian Shihezi Formation, the southern margin of the Ordos Basin was a key location for studying the tectonic movement of the North China Craton (NCC) and South China Blocks. The sedimentary environment was the first period of complete transition from marine to continental. However, the distribution of sediments controlled by a multi–provenance supply and the response of deposition to tectonics remain ambiguous, and the restoration of paleogeography remains in the qualitative stage, restricting the study of larger-scale tectono–sedimentary patterns. Based on field profiles and core observations, the paleocurrent direction, lithic fragments, heavy mineral assemblages, rare earth element distribution patterns, 11 detrital zircon U–Pb age datasets, and discrimination diagram of major and trace elements, the provenance signature and tectono–sedimentary setting were revealed. The results indicated that there are three main provenances in the southern margin of the Ordos Basin: North Qilian and western and eastern sections of the North Qinling Orogenic Belt. The tectonic setting of the North Qilian was a continental island arc, and the North Qinling was transformed from a passive to an active continental margin. Owing to the continued intense tectonic activities of the North Qilian, a braided river delta with a large sedimentary range developed in the west, and it was mixed with detrital sediments from the western section of the North Qinling with weak tectonic activity in the central. Affected by the uplift of the southern North China Craton, the sedimentary environment in the eastern range was unstable, and the thickness distribution of sandy sediments in the braided river delta was uneven. Refinement of provenance and deposition has important implications for the study of basin–mountain coupling relationships and paleogeographic reconstruction in the southern Ordos Basin and provides a basis for the study of collision evolution of the North and South China Blocks in the Permian.

Deep-water first occurrences of Ediacara biota prior to the Shuram carbon isotope excursion in the Wernecke Mountains, Yukon, Canada.

Ediacara-type macrofossils appear as early as ~575 Ma in deep-water facies of the Drook Formation of the Avalon Peninsula, Newfoundland, and the Nadaleen Formation of Yukon and Northwest Territories, Canada. Our ability to assess whether a deep-water origination of the Ediacara biota is a genuine reflection of evolutionary succession, an artifact of an incomplete stratigraphic record, or a bathymetrically controlled biotope is limited by a lack of geochronological constraints and detailed shelf-to-slope transects of Ediacaran continental margins. The Ediacaran Rackla Group of the Wernecke Mountains, NW Canada, represents an ideal shelf-to-slope depositional system to understand the spatiotemporal and environmental context of Ediacara-type organisms' stratigraphic occurrence. New sedimentological and paleontological data presented herein from the Wernecke Mountains establish a stratigraphic framework relating shelfal strata in the Goz/Corn Creek area to lower slope deposits in the Nadaleen River area. We report new discoveries of numerous Aspidella hold-fast discs, indicative of frondose Ediacara organisms, from deep-water slope deposits of the Nadaleen Formation stratigraphically below the Shuram carbon isotope excursion (CIE) in the Nadaleen River area. Such fossils are notably absent in coeval shallow-water strata in the Goz/Corn Creek region despite appropriate facies for potential preservation. The presence of pre-Shuram CIE Ediacara-type fossils occurring only in deep-water facies within a basin that has equivalent well-preserved shallow-water facies provides the first stratigraphic paleobiological support for a deep-water origination of the Ediacara biota. In contrast, new occurrences of Ediacara-type fossils (including juvenile fronds, Beltanelliformis, Aspidella, annulated tubes, and multiple ichnotaxa) are found above the Shuram CIE in both deep- and shallow-water deposits of the Blueflower Formation. Given existing age constraints on the Shuram CIE, it appears that Ediacaran organisms may have originated in the deeper ocean and lived there for up to ~15 million years before migrating into shelfal environments in the terminal Ediacaran. This indicates unique ecophysiological constraints likely shaped the initial habitat preference and later environmental expansion of the Ediacara biota.

Zircon and Whole-Rock Trace Element Indicators of Magmatic Hydration State and Oxidation State Discriminate Copper Ore-Forming from Barren Arc Magmas

Abstract To meet surging requirements of copper for the green energy revolution, minable resources subequal to all copper production in history must be found in the next two decades. We show that trace elements in zircon and whole-rock samples that are diagnostic of unusually high-pressure magmatic differentiation and high hydration state and oxidation state of their parent silicate melt are effective for discriminating copper sulfide-ore-productive arc magmas from infertile arc magmas. Tests on our database of 5,777 zircons from 80 igneous complexes, including 2,220 zircons from ore-generative intrusions in 37 major porphyry and high-sulfidation epithermal Cu(-Au-Mo) deposits worldwide, demonstrate that our magmatic copper fertility discriminants apparently perform equally well in intraoceanic arcs, continental margin arcs, and continental collision orogens of Ordovician to Quaternary age. That performance consistency means that the tectono-magmatic controls on development of magmatic-hydrothermal copper ore-forming fertility are essentially the same in all those plate-convergence settings. The ratio Ce/√(U × Ti) in zircon is a quantitative indicator of the relative oxygen fugacity of the silicate melt and its sulfur-carrying capacity. The ratio of the europium anomaly to ytterbium in granitoid melts and zircon is an uncalibrated but empirically useful indicator of the melt’s hydration state and ability to provide chloride-complexed metals to exsolving hydrothermal fluids. Plots of (EuN/Eu*)/YbN vs. Ce/√(U × Ti) in zircon are remarkably effective for discriminating igneous complexes, arc segments, and time intervals within them that can generate and are likely to host magmatic-hydrothermal Cu(-Au-Mo) ore deposits. Arrays of cognate zircons on such plots have slopes that vary with pressure-dependent chlorinity of exsolving fluid and its efficacy in scavenging CuCl from the melt. Our zircon indicators of Cu metallogenic fertility are applicable to detrital as well as in situ zircons and can assist with ore discovery in watersheds upstream from a sediment sampling site. We formulated a composite zircon copper fertility index (ZCFI) that can be applied to each microbeam spot analysis—ZCFI = 104 (EuN/EuN*)/YbN + 5 Ce/√(Ui × Ti)—and substantially decreases the number of zircon analyses needed for reliable prospectivity assessment in a detrital grain population, thereby making this watershed-scale exploration tool cost-competitive with other methods of geochemical exploration.

LITHO- AND CHRONOSTRATIGRAPHY OF THE UPPER QUATERNARY SEDIMENTS FROM THE PIEDRA BUENA TERRACE, PATAGONIAN CONTINENTAL MARGIN (SW ATLANTIC)

This paper presents a detailed description of the lithostratigraphy of mostly contouritic deposits from the Piedra Buena Terrace (PBT), collected at water depth of 2 – 2.5 km. It is based unpon a multi-proxy investigation of five gravity cores, including visual description and scanning, grain size distributions, microfossils and sand fraction study, supported by the analysis of high-resolution sub-bottom profiles. Two older seismic units were identified in addition to those previously described in the area . The defined lithostratigraphic units were correlated to the upper seismic units, while the age of the younger units was confirmed using AMS-14C dating. In terms of the sedimentary facies, the dark quartz-glauconitic sands, which seem to be a fingerprint of the Piedra Buena Terrace, were investigated by applying the X-ray diffraction and performing grain SEM-SE images. The sandy facies correspond to sea-level low-stands during cold glacials (MIS 2 and MIS 4), when glauconite and terrigenous material were transported from the emerged shelf down and along the Patagonian continental slope by vigorous bottom currents. The latter is confirmed by an occurrence of parts of bi-gradational sequences reported from the grain-size distributions in lithostratigraphic units 2 and 4. Units 1 and 3, represented by mostly hemipelagic calcareous ooze, were formed during warm high sea-level stages (MIS 1 and 3). Unlike Unit 1, Unit 3 also demonstrates clear contourite features, similar to Units 2 and 4. They include common bioturbation, occurrence of mottles, lenses, irregular thin layers of sand, erosional boundaries and hiatuses between and within the units, good sorting of fine sands, and microfossil reworking. Together with our previous data from canyons on the Perito Moreno Terrace and the Ameghino segment , supported by available publications from the PBT and Mar del Plata areas, this study demonstrates that the Patagonian Continental Margin could be used as a natural laboratory to investigate and better understand contourite systems.

Mineralized structures from the Alhué mining district, Chile: Using fluid inclusions and textures

The Alhué mining district (AMD) of the Coastal Range in Central Chile is situated approximately 70 km southwest of the city of Santiago and hosted in stratified Jurassic and Early Cretaceous sequences which are common in central Chile. More than 79 faults and veins are recognized in the AMD hosted in andesites and tuffs with clear structural control showing two distinct trends. Precious‐metal mineralization locally extends over strike lengths of up to 1000 m along these structures with grades averaging at 5 ppm gold and 23 ppm of silver. In this study, a University of Chile – YAMANA GOLD joint research project was created to better understand this particular deposit and explore the origin of gold anomalies found in the district using drill core, mine, and surface samples. Wide internal variations in homogenization temperature and electrolytes were observed at all scales: on the district scale, in mineralized structures intersected in drill core, and in hand specimens. This variability may reflect the diversity of ore-forming conditions in the mining district in addition to the different processes (including fault motion over time) and geochemical components within the district. Textural analyses and fluid inclusion assemblages (FIA) provide evidence for boiling and flashing mechanisms at several localities. Raman spectroscopy and LA-ICP-MS techniques allowed a better characterization of the fluid composition and mineral paragenesis. The presence of gold (∼3.8 ppm) and silver (∼1424 ppm) in both vapor-rich only FIAs (i.e. that contain 99 % vapor) hosted in quartz and liquid-rich FIA hosted in sphalerite implies that gold was transported as sulfide and chloride complexes. The AMD shows a transition from a high temperature environment (sometimes containing calc-silicate minerals) to a low temperature (epithermal) system. This mineralization depended on the type of vein system which tend to be mineralized in strike slip faults e.g. Maqui and Lorena structures. The consequence of flashing documented at dilational jogs, structural intersections and fault bends was likely an important outcome leading to the precipitation of metals at the AMD.Coexisting liquid-rich and vapor-rich fluid inclusions contained in a FIA were observed at the deepest levels in the Chilco vein and the proportion of samples showing boiling increases with depth, indicating that additional precious metal resources may be present below current exploration depths. In summary, our new results reveal that gold, silver and base metal veins found at the AMD in Chile are unique hydrothermal polymetallic ore deposits that are structurally controlled and related to an orogenic environment. A general model for the AMD is one where high temperature fluids from deep crustal mafic magmatic systems, probably as products of a devolatilization and far-from-equilibrium conditions, reach subsurface conditions along faults and are mineralized along these faults. Because having a truly unique ore deposit in the geologic record is very unlikely, the AMD forms an important case study that helps understand structurally controlled ore deposits. Thus our work can form a model for future exploration in the AMD and provide insight into exploration in other sites in Chile and along continental margin settings worldwide, in both poorly characterized known deposits and at greenfield sites.