Particle Content Research Articles

Master actions and helicity decomposition for spin-4 models in [formula omitted]

The present work introduces a master action which interpolates between four self-dual models, SD(i), describing massive spin-4 particles in D=2+1 dimensions. These models are designated by i=1,2,3 and 4, representing the order in derivatives. Our results show that the four descriptions are quantum equivalents by comparing their correlation functions, up to contact terms. This is an original result since that a proof of quantum equivalence among these models have not been demonstrated in the literature. Besides, a geometrical approach is demonstrated to be a useful tool in order to describe the third and fourth order in derivatives models. On the other hand, the construction of the master action relies on the introduction of mixing terms, which must be free of particle content. Here, we demonstrate how the helicity decomposition method can be used in order to verify the absence of particle content of such terms, ensuring the proper usability of the master action technique. This kind of result can be very useful in situations where we do not have access to the higher spin-projection basis which would allow the analysis to be handle by explicitly calculating the propagator and subsequently analyzing its poles.

Understanding dilution effects on particle-containing pesticide droplets deposition on rice leaf via developing CFD-VOF-DPM model.

Pesticide dilution is one of the essential aspects of plant protection. However, the effect of dilution on the deposition characteristics of pesticide droplets containing particulate additives on crop leaf surfaces remains unclear and warrants further research. Herein, a validated computational fluid dynamics (CFD)-volume of fluid (VOF)-discrete phase model (DPM) numerical model was developed to analyze the influence of particle content on the deposition behavior of droplets on the leaf surface comparatively, taking into account the particle content of different diluted thifluzamide solutions. Additionally, the study aimed to analyze further the kinetic behavior of pesticide droplets landing on rice leaves across different dilution conditions. Pesticide droplets diluted 100-fold had a lower retraction rate during spreading than particle-free droplets, so the solution is more easily deposited in the leaves. Moreover, the low dilution (high concentration) increased the critical adhesion rate between droplets and rice leaves, inhibiting the bouncing of droplets on the leaf surface, thus promoting their effective deposition on the surface. In addition, low dilution (high concentration) is not conducive to spreading droplets when the impact velocity is high, and it also results in a large amount of pesticide use. The actual application process can be through understanding the dilution factor of the configured pesticide solution, and reasonable adjustment of the nozzle pressure can effectively improve the utilization rate of pesticides and reduce the pollution brought by pesticides to the environment. These results provide an essential reference for studying pesticide droplet deposition characteristics, including rice plant protection and spraying technology. © 2024 Society of Chemical Industry.

Thermal decomposition kinetics and aging lifetime prediction of waste rubbers in porous elastic road surface

The waste rubbers used as partly aggregates in porous elastic road surface (PERS) mixture are more easily to be attacked by the heat and oxygen during the service process. This study aims to investigate the thermal decomposition kinetics of waste rubbers in PERS and propose a method to predict the lifetime of waste rubbers. Firstly, the PERS mixtures containing unaged and aged waste rubbers were prepared with void ratio of 25 % and rubber particle content of 25 %. Then, from the water residual results, it can be seen that the residual stability and freezing-thawing splitting strength ratio of PERS mixtures containing waste rubbers being aged for 7 days significantly decreased to 65 % and 59 % compared with that of the unaged PERS mixture, which cannot be used as pavement. The thermal decomposition kinetics of waste rubbers fixed with the first-order reaction, which was related with the road performance of PERS mixtures by the mass loss rate of 17 % after being aged for 7 days. Based on that, the lifetime prediction equation of waste rubbers was established. It is expected that this work provides a new strategy for predicting the lifetime of waster rubbers in PERS pavement during the service process.

DIC-Based Hydration Absorption Detection and Displacement Field Evolution of Outcrop Porous Sandstone

In order to study the hydration absorption behaviors and characteristics of sandstone in Mogao Grottoes in China, the pressure-less hydration absorption experiment on the outcrop porous sandstone of Mogao Grottoes was carried out by using the self-developed real-time monitoring experimental system. The hydration absorption was measured and the curve of hydration absorption with time was drawn. At the same time, the digital image correlation method (DIC) was used to measure the full-field deformation, and the speckle pattern of the sample was analyzed using Match ID, and the displacement field and strain field of the sandstone sample at different hydration absorption moments were computed. Moreover, the sparse area and dense area of sandstone are used as regions of interest (ROI) for DIC analysis. According to the test results, it is concluded that the hydration absorption of sandstone increases rapidly in the initial stage, and gradually tends to be stable with the change of time. This corresponds well with the deformation characteristics of sandstone analyzed using DIC. In the initial stage, the deformation of sandstone increases rapidly. With the change in time, the deformation of sandstone samples gradually slows down. When the hydration adsorption reaches saturation, the sandstone continues to deform for a period of time before stopping hydration absorption. The results of the mercury injection test and the XRD test show that the porosity of the sparse area is larger than that of the dense area and the particle content of the dense area is lower. When the sandstone is saturated with water, the liquid is immersed in the pores between the solid particles, which makes the sparse area more prone to stress concentration, and the deformation in the sparse area is larger. Therefore, when analyzing the hydration absorption deformation of sandstone, the porosity should be considered.

Analytical assessment of hetero-/homogeneous combustion of magnesium particle: Fully explicit formulas for flame characteristics

In this study, by proposing a comprehensive multi-step model, the combustion of magnesium particles in O2-He, O2-Ar, and O2-N2 is scrutinized. In the current model, both the heterogeneous and homogeneous combustions are considered and the process is divided into four stages solid, liquid, and gas combustion and melting. Moreover, the diffusions of oxygen and unreacted magnesium to droplet and infinity together with surface exothermic reaction are considered. The governing equations are analytically solved and then, the formulas are extracted for combustion time and temperature, flame standoff distance, and evaporation rate as the functions of particle diameter, ambient temperature and pressure, oxygen mass fraction, type of inert gas, and Lewis numbers. For 120 µm particle and oxygen content of 0.05, time contributions of homogeneous and heterogeneous combustions are 85.8% and 14.2%, respectively. The burning time has drastic changes at ambient pressures below l atm, so that the burning time variations relative to the pressure in the environments less than 1 atm and greater than it are equal to 1200–1550 and 70–90 ms/atm, respectively. When the oxygen mass fraction is less than 0.29, combustion in helium-oxygen ends earlier than that in O2-Ar and O2-N2, but for the mass fraction greater than 0.35, it has the longest burning time.

Enzyme-induced Carbonate Precipitation (EICP) Combined with Lignin to Improve the Unconfined Compression Strength (USC) of Shanghai Clay

In order to improve the mechanical properties of high moisture content and low strength of clay particles in Shanghai, the effects of different lignin content on the unconfined compressive strength of EICP-lignin-cured clay were studied by using the method of lignin combined with EICP technology to strengthen the clay by lignin combined with EICP technology. The experimental results showed that EICP-lignin could enhance the unconfined compressive strength of Shanghai clay. With the increase of lignin content, the unconfined compressive strength of clay first increased and then decreased, and there was an optimal content value. The optimal lignin content is 8%.

Experimental Study on the Effect of Fine-Grained Soil Content on the Freezing Strength of Aeolian Sand-Cement Interface

In cold regions, understanding the freezing strength of the interface between soil and structure is crucial for designing frost-resistant foundations. To investigate how the content of cement powder in aeolian sand affects this strength, we conducted direct shear tests under various conditions such as different fine-grained soil content, normal stress, and initial moisture content of the soil. By analyzing parameters like soil properties, and volume of ice content, and using the Mohr-Coulomb strength theory to define interface strength, we aimed to indirectly measure the cementation strength of the interface. Our findings revealed that as the particle content increased, the interface stress-strain curves became noticeably stiffer. We also observed a positive linear relationship between freezing strength and silt content, while the initial moisture content of the soil did not significantly impact the strengthening effect of fine-grained soil on freezing strength. Moreover, we discovered that as the powder content increased, the force binding the ice to the interface decreased, while the friction angle at the interface increased. However, the cohesion force at the interface remained relatively unchanged. Overall, our analysis suggests that the increase in freezing strength due to fine-grained soil content is primarily due to the heightened friction between aeolian sand and the interface.

Review on Mercury Control during Co-Firing Coal and Biomass under O2/CO2 Atmosphere

Combining biomass co-firing with oxy-fuel combustion is a promising Bioenergy with Carbon Capture and Storage (BECCS) technology. It has the potential to achieve a large-scale reduction in carbon emissions from traditional power plants, making it a powerful tool for addressing global climate change. However, mercury in the fuel can be released into the flue gas during combustion, posing a significant threat to the environment and human health. More importantly, mercury can also cause the fracture of metal equipment via amalgamation, which is a major risk for the system. Therefore, compared to conventional coal-fired power plants, the requirements for the mercury concentration in BECCS systems are much stricter. This article reviews the latest progress in mercury control under oxy-fuel biomass co-firing conditions, clarifies the impact of biomass co-firing on mercury species transformation, reveals the influence mechanisms of various flue gas components on elemental mercury oxidation under oxy-fuel combustion conditions, evaluates the advantages and disadvantages of various mercury removal methods, and finally provides an outlook for mercury control in BECCS systems. Research shows that after biomass co-firing, the concentrations of chlorine and alkali metals in the flue gas increase, which is beneficial for homogeneous and heterogeneous mercury oxidation. The changes in the particulate matter content could affect the transformation of gaseous mercury to particulate mercury. The high concentrations of CO2 and H2O in oxy-fuel flue gas inhibit mercury oxidation, while the effects of NOx and SO2 are dual-sided. Higher concentrations of fly ash in oxy-fuel flue gas are conducive to the removal of Hg0. Additionally, under oxy-fuel conditions, CO2 and metal ions such as Fe2+ can inhibit the re-emission of mercury in WFGD systems. The development of efficient adsorbents and catalysts is the key to achieving deep mercury removal. Fully utilizing the advantages of chlorine, alkali metals, and CO2 in oxy-fuel biomass co-firing flue gas will be the future focus of deep mercury removal from BECCS systems.

NiCrBSi/WC Composite Claddings Processed on AISI 316L Steel Alloy by the Direct Laser Deposition Process: Studies on Dry Sliding Wear Behavior and Wear Mechanism Maps

Abstract This study presented the wear behavior of the NiCrBSi/WC composite claddings processed on an AISI 316L steel alloy substrate by laser cladding approach. The scanning electron microscope (SEM) morphology of the claddings has shown excellent substrate–cladding interface bonding, good WC particulate distribution, and no noticeable cracks and voids. The electron dispersion spectroscope (EDS) spectra have confirmed the presence of respective NiCrBSi alloy matrix and WC elements. The XRD spectra have identified various phases and compounds such as gamma-Ni, FeNi3, Ni3B, Cr23C6, Ni3Si, and W2C commonly in all the processed composite claddings. The microhardness of the claddings was measured between 791 and 1086 HV0.2 for increasing the reinforcement WC particulate percentage from 15 wt% to 60 wt%. It is about 470% surface hardness enhancement with the processed composite claddings compared with the substrate alloy. The reinforcement of WC from 15 wt% to 60 wt% with the composite claddings resulted in wear resistance enhancement from 21.85% to 60.64% and the coefficient of friction from 56.87% to 77.92% against the substrate. The wear-rate maps and their respective cladding's worn surface morphology have described the wear mechanisms typically as adhesive, abrasive, oxidation, and delamination. The wear mechanisms are mainly influenced by the WC particulate percentage. The increased WC particulate content has increased the dominance of the abrasive wear mechanism while reducing the window of the adhesive wear mechanism. The windows of various wear mechanisms and their ranges, such as adhesive 0.0033 to 0.028, abrasion 0.010 to 0.067, oxidation 0.012 to 0.093, and delamination 0.015 to 0.120 mm3/m, for NiCrBSi/WC composite claddings comprehensibly represented the wear behavior for the varied conditions of dry sliding wear parameters.

Coal gangue in asphalt pavement: A review of applications and performance influence

The comprehensive utilization of coal gangue is low, and this causes serious environment problems and security risks. The physical and chemical properties of coal gangue were analyzed in this paper, and the estimated value of different chemical components of coal gangue was counted. The physical properties of coal gangue aggregate were analyzed, and performance and its influencing factors of base course mixture with coal gangue aggregate were studied. The influence of coal gangue powder and coal gangue aggregate on performance of asphalt mortar and asphalt mixture was analyzed, and possible influencing factors and function mechanism were discussed. The results showed that heavy metal elements of coal gangue applied into asphalt pavement is not seeped out. The crushing value, water absorption and flat elongated particles content of coal gangue aggregate are generally high, but the compressive strength of base course with coal gangue aggregate is verified to meet the strength requirement. The performance, volume stability and durability of base course with coal gangue aggregate are closely related to aggregate gradation, the type and dosage of cementations materials and aggregate. The high temperature performance, temperature susceptibility and viscosity of asphalt mortar are improved by the addition of different coal gangue powder, and improvement effect of activated coal gangue powder on asphalt mortar performance is better. The low temperature performance and adhesion property of asphalt mortar with chemical activated coal gangue powder are improved. The physical reaction between asphalt and different coal gangue powder is only taken place. The temperature stability of asphalt mixture with coal gangue coarse aggregate has achieved the specification requirement. The water stability and low temperature fracture performance of asphalt mixture with fine aggregate replaced by coal gangue are improved. However, the high temperature performance of above mixture is lower than conventional hot mix asphalt mixture. The research results will provide reference for coal gangue applied into asphalt pavement.

Effect of SiC particle content on the mechanical behavior and deformation mechanism of SiCp/Al composite under high-frequency dynamic loading

SiCp/Al composites exhibit excellent structural properties but suffer from inherent brittleness, which has brought rigorous challenges on the materials processing. Ultrasonic-vibration-assisted approach offers a promising solution to improve the processability. However, the underlying mechanisms of mechanical response and defect suppression under ultrasonic action have been rarely studied for SiCp/Al composites, hindering the development of high-efficiency processing. This work aims to investigate the mechanical behavior and microstructural evolution in this class of composites with varying SiC volume fractions up to 45% under high-frequency dynamic load induced by ultrasonic vibration. The results showed that the deformation stress of SiCp/Al composites under ultrasonic compression was significantly reduced to only about 1/10 of that under conventional quasi-static loading. Moreover, as the SiC fractions increasing, this ultrasonic softening effect of SiCp/Al became more pronounced. The plastic limit of SiCp/Al with 45% SiC fraction nearly doubled under ultrasonic compression without any macroscopic cracks. The subsequent nanoindentation tests revealed a transition in work-hardening behavior of SiCp/Al with different SiC fractions under ultrasonic loading. Microstructure characterization was conducted to analyze the grain refinement, recrystallization, and deformation textures within the deformed areas, revealing the deformation mechanism of SiCp/Al under different loading mode. TEM observations confirmed the distribution of dislocations in Al matrix and dense stacking faults in SiC particles after ultrasonic compression, indicating that the plastic behaviors were enhanced in both Al matrix and SiC phase under the high-frequency cyclic stress. This research revealed the distinct deformation mechanisms of SiCp/Al composites under high-frequency dynamic loading, exhibiting extremely low deformation stress accompanied with significantly enhanced plasticity. The results provide theoretical insights for the high-efficiency processing and rapid property regulation of particle-reinforced-composites based on ultrasonic-vibration-assisted technologies.

Joining SiC ceramics with ZrSi2–SiC filler at low temperatures

AbstractZrSi2–SiC powder was employed as the joining material to join SiC ceramics in this study. The effects of SiC particle (SiCp) content and joining temperature on the phase composition, microstructure, and shear strength of SiC joints were studied and reported for the first time. Research results showed that introduction of SiCp into the interlayer improved the mechanical performance of the joint. When 10 wt.% SiCp was introduced into the interlayer, the optimal shear strength measured of the joint was 116.7 ± 6.7 MPa under the joining condition of 1500°C for 10 min. With the joining temperature increased, the shear strength of the joint gradually increases. When the joint was performed at 1600°C for 10 min, an ultra‐high temperature phase of ZrC was detected in the interlayer, and the shear strength of the joint was 168.1 ± 12.6 MPa. The SiC joint with high mechanical strength might have the potential for application in the field of nuclear industry.

Evaluation of dental pulp stem cells response to flowable nano-hybrid dental composites: A comparative analysis.

Flowable resin composites (FRC) are tooth-colored restorative materials that contain a lower filler particle content, and lower viscosity than their bulk counterparts, making them useful for specific clinical applications. Yet, their chemical makeup may impact the cellular population of the tooth pulp. This in-vitro study assessed the cytocompatibility and odontogenic differentiation capacity of dental pulp stem cells (DPSCs) in response to two recent FRC material extracts. Extracts of the FRC Aura easyflow (AEF) and Polofil NHT Flow (PNF) were applied to DPSCs isolated from extracted human teeth. Cell viability of DPSCs was assessed using MTT assay on days 1, 3 and 7. Cell migration was assessed using the wound healing assay. DPSCs' capacity for osteo/odontogenic differentiation was assessed by measuring the degree of mineralization by Alizarin Red S staining, alkaline phosphatase enzyme (ALP) activity, and monitoring the expression of osteoprotegerin (OPG), RUNX Family Transcription Factor 2 (RUNX2), and the odontogenic marker dentin sialophosphoprotein (DSPP) by RT-PCR. Monomer release from the FRC was also assessed by High-performance liquid chromatography analysis (HPLC). DPSCs exposed to PNF extracts showed significantly higher cell viability, faster wound closure, and superior odontogenic differentiation. This was apparent through Alizarin Red staining of calcified nodules, elevated alkaline phosphatase activity, and increased expression of osteo/odontogenic markers. Moreover, HPLC analysis revealed a higher release of TEDGMA, UDMA, and BISGMA from AEF. PNF showed better cytocompatibility and enhancement of odontogenic differentiation than AEF.

A fermionic portal to a non-abelian dark sector

We introduce a new class of renormalizable models for dark matter with a minimal particle content, consisting of a dark SU(2)D gauge sector connected to the standard model through a vector-like fermion mediator, not requiring a Higgs portal, in which a massive vector boson is the dark matter candidate. These models are labeled fermion portal vector dark matter (FPVDM). Multiple realizations are possible, depending on the properties of the vector-like partner and scalar potential. One example is discussed in detail. Fermion portal vector dark matter models have a large number of applications in collider and non-collider experiments, with their phenomenology depending on the mediator sector.

AI-Driven Spectral Decomposition: Predicting the Most Probable Protein Compositions from Surface Enhanced Raman Spectroscopy Spectra of Amino Acids.

Surface-enhanced Raman spectroscopy (SERS) is a powerful tool for elucidating the molecular makeup of materials. It possesses the unique characteristics of single-molecule sensitivity and extremely high specificity. However, the true potential of SERS, particularly in capturing the biochemical content of particles, remains underexplored. In this study, we harnessed transformer neural networks to interpret SERS spectra, aiming to discern the amino acid profiles within proteins. By training the network on the SERS profiles of 20 amino acids of human proteins, we explore the feasibility of predicting the predominant proteins within the µL-scale detection volume of SERS. Our results highlight a consistent alignment between the model's predictions and the protein's known amino acid compositions, deepening our understanding of the inherent information contained within SERS spectra. For instance, the model achieved low root mean square error (RMSE) scores and minimal deviation in the prediction of amino acid compositions for proteins such as Bovine Serum Albumin (BSA), ACE2 protein, and CD63 antigen. This novel methodology offers a robust avenue not only for protein analytics but also sets a precedent for the broader realm of spectral analyses across diverse material categories. It represents a solid step forward to establishing SERS-based proteomics.

Simulation and parameter determination of the net sorption of phenanthrene by sediment particles

The distribution of polycyclic aromatic hydrocarbons (PAHs) in the ocean is affected by the sorption-desorption process of sediment particles. This process is determined by the concentration of PAHs in seawater, water temperature, and organic matter content of sediment particles. Quantitative relationships between the net sorption rates (=the difference of sorption and desorption rates) and these factors have not been established yet and used in PAH transport models. In this study, phenanthrene was chosen as the representative of PAHs. Three groups of experimental data were collected to address the dependence of the net sorption processes on the initial concentration, water temperature, and organic carbon content representing organic matter content. One-site and two-compartment mass-transfer models were tested to represent the experimental data using various parameters. The results showed that the two-compartment mass-transfer model performed better than the one-site mass-transfer model. The parameters of the two-compartment mass-transfer model include the sorption rate coefficients kafand kas (L g−1 min−1), and the desorption rate coefficients kdf and kds (min−1). The parameters at different temperatures and organic carbon contents were obtained by numerical simulations. Linear relationships were obtained between the parameters and water temperature, as well as organic carbon content. kaf, kas and kdf decreased linearly, while kds increased linearly with temperature. kaf, kas and kdf increased linearly, while kds decreased linearly with organic carbon content. The r2 values between the simulation results based on the relationships and the experimental results reached 0.96–0.99, which supports the application of the model to simulate sorption-desorption processes at different water temperatures and organic carbon contents in a realistic ocean.

Influence of cutting speed and particulate content on polycrystalline diamond tool wear in machining AA7075/TiB2 in situ aluminum matrix composites

Aluminum alloy AA7075 was reinforced with in-situ synthesized TiB2 particles (0–12 wt%) to prepare aluminum matrix composites (AMCs) by casting. The cast composite bars were machined using polycrystalline diamond (PCD) tool inserts. The influence of cutting speed and TiB2 particle content on the tool wear was quantified. The rake face, flank face, and machined surface morphologies were studied using a field emission scanning electron microscope (FESEM). Energy dispersive X-ray analysis (EDS) was carried out on the rake face across a defined line. The increase in cutting speed and TiB2 particle content increased the tool wear. The highest cutting conditions accelerated tool wear and caused chipping. The mechanisms responsible for tool wear were identified as adhesion, abrasion, chipping and diffusion. The state of the tool wear was directly reflected on the machined surface in the form of deposited material and feed mark ridges.

Phase Evolution Behavior during the Reduction Process of Medium‐Silica Fluxed Pellets

To enhance the proportion of domestically manufactured Chinese pellets in the furnace, it is crucial to investigate the impact of calcium flux on the metallurgical characteristics of pellets and analyze the phase evolution behavior during the reduction process of medium‐silica fluxed pellets. This study examines the metallurgical properties of medium‐silica acid pellets and low‐basicity medium‐silica fluxed pellets produced in China. The results indicate that incorporating a small amount of calcium flux significantly enhances reducibility index (RI), reduces reduction swelling index, and lowers reductive degradation index (RDI+3.15 mm) for fluxed pellets. At a basicity level of 0.6, RI for medium‐silica fluxed pellets reaches 66.86%, while RDI−0.5 mm increases to 1.62% with increasing basicity levels. As pellet basicity increases, charge pressure drop (APmax) decreases, CaO content in silicate liquid phase within slag phase increases, and softening–melting zone widens, consequently leading to reduced solid‐phase particle content within pellets and increased fluidity within slag phase.

Unveiling the temperature-dependent mechanisms of viscoelasticity of sand-enhanced epoxy

The viscoelastic behavior of epoxy is critical for its engineering performance and applications. This work focuses on the improvement of its viscoelastic performance by using natural sand particles as fillers. Experiments are carried out to investigate the static and dynamic viscoelastic properties of epoxy with various sand particles content. Static mechanical tests demonstrated an increase in the elastic modulus, albeit at the cost of reduced strength at higher sand content due to stress concentrations. Dynamic tests indicated substantially improved storage modulus and damping of epoxy after being filled with the sand particles. Moreover, the glass transition temperature of the epoxy shows a substantial rise upon the addition of sand particles, signifying an augmentation in its heat resistance. Static viscoelastic characterization revealed an elevation in both room and high-temperature relaxation moduli upon incorporating sand. By applying time-temperature superposition principles, long-term relaxation curves are obtained, which can provide a reference for engineering design. These viscoelastic investigations offer insights into the underpinning mechanisms governing the performance of sand-reinforced epoxy. This enables the rational design of sand particle reinforced epoxy for customized durability, heat resistance, and vibration damping.

Size Control and Antioxidant Properties of Sulfur-Rich Polymer Colloids from Interfacial Polymerization.

High sulfur content polymeric materials, known for their intriguing properties such as high refractive indices and high electrochemical capacities, have garnered significant interest in recent years for their applications in optics, antifouling surfaces, triboelectrics, and electrochemistry. Despite the high interest, most high sulfur-content polymers reported to date are either bulk materials or thin films, and there is a general lack of research into sulfur-rich polymer colloids. Water-dispersed, sulfur-rich particles are anticipated to broaden the range of applications for sulfur-containing materials. In this study, the preparation and size control parameters are presented of an aqueous dispersion of sulfur-rich polymers with the sulfur content of dispersed particles exceeding 75wt%. Employing polymeric stabilizers with varying hydrophilic-lipophilic balance (HLB), along with changing the rank of inorganic polysulfides, allow for the control of particle size in the range of 360nm - 1.8µm. The sulfur-rich colloid demonstrates antioxidant properties in water, demonstrating the potential for the use of sulfur-rich polymeric materials readily removable, heterogeneous radical scavengers.