The performance of shotcrete used in underground tunnel construction is often compromised by the challenging service environment, causing severe deterioration and structural integrity concerns. Developing high-quality accelerating agents can be a viable approach to mitigate this effect. This study formulates alkali-free fluorine-free (AF-I); alkali-free fluorine-containing (AF-II); and low-alkaline (AC) liquid accelerators and explores their impacts on sulfate resistance and calcium leaching behavior of shotcrete, utilizing semi-immersion and short-term tank water testing protocols on a time-resolved basis. Microstructural analysis of eroded shotcrete was conducted employing XRD, TGA and SEM to reveal underlying mechanisms. Additionally, ionic analyses of simulated leaching systems, including groundwater and 5 % sodium sulfate solution were performed using ICP-OES to monitor calcium activity and assess leaching behaviors. Results indicate that shotcrete accelerated with AF-II exhibits the strongest resistance, whereas shotcrete with AC suffers the severest deterioration. The primary deterioration mechanism of shotcrete with AC was majorly due to high ettringite and gypsum corrosion, whereas AF-I and AF-II induces little ettringite corrosion. In terms of leaching behavior, AF-II demonstrates superior calcium leaching mitigation, with leachability indices in groundwater and sodium sulfate solution measuring 0.06 and 0.19, and 0.02 and 0.16 higher values, respectively, compared to AF-I and AC. Findings of this study provide valuable insights into the application and performance of shotcrete in sulfate-prone environments, aiming to mitigate potential deterioration through optimal accelerator selection.
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