Constant Current Method Research Articles

Electrodeposited zinc cobalt bimetallic phosphate as a bifunctional catalyst for hydrogen evolution and urea oxidation

The theoretical potential of the urea oxidation reaction (UOR) is a mere 0.37 V(vs.RHE), significantly lower than the 1.23 V (vs. RHE) of the oxygen evolution reaction (OER). Thus, substituting the OER with the UOR can effectively reduce the voltage required for electrolysis. Transition metal phosphates (TM-Pi), with their unique physical properties, can partly replace precious metal catalysts and hold great application potential. However, further modification is necessary to enhance their catalytic activity and stability. Therefore, this study prepared a coral-like cluster Co/Zn-Pi@NF (Pi represents phosphate) catalyst, which was grown in situ on nickel foam (NF) using the constant current electrodeposition method. The catalyst exhibited superior catalytic performance in 1 M KOH, with the required overpotentials for the hydrogen evolution reaction (HER) and OER reaching 10 mA·cm−2 being 36.6 mV and 343.4 mV, respectively. In 1 M KOH containing 0.5 M urea, the urea oxidation potential was only 1.4 V, which remained stable for 60 hours. The Co/Zn-Pi@NF nanoparticles were used as the anode and cathode for water-urea electrolysis, and the electrolysis voltage was 1.43 V at a current density of 10 mA·cm−2, which was 290 mV lower than that of electrolyzed water. This study demonstrates that zinc-cobalt bimetallic phosphate can be used as a dual-function electrocatalyst for hydrogen evolution and urea oxidation.

Sensor Fusion-Based Pulsed Controller for Low Power Solar-Charged Batteries with Experimental Tests: NiMH Battery as a Case Study

Solar energy is considered the major source of clean and ubiquitous renewable energy available on various scales in electric grids. In addition, solar energy is harnessed in various electronic devices to charge the batteries and power electronic equipment. Due to its ubiquitous nature, the corresponding market for solar-charged small-scale batteries is growing fast. The most important part to make the technology feasible is a portable battery charger and the associated controllers to automate battery charging. The charger should consider the case of charging to be convenient for the user and minimize battery degradation. However, the issue of slow charging and premature battery life loss plagues current industry standards or innovative battery technologies. In this paper, a new pulse charging technique is proposed that obviates battery deterioration and minimizes the overall charging loss. The solar-powered battery charger is prototyped and executed as a practical, versatile, and compact photovoltaic charge controller at cut rates. With the aid of sensor fusion, the charge controller is disconnected and reconnects the battery during battery overcharging and deep discharging conditions using sensors with relays. The laboratory model is tested using a less expensive PV panel, battery, and digital signal processor (DSP) controller. The charging behavior of the solar-powered PWM charge controller is studied compared with that of the constant voltage–constant current (CV–CC) method. The proposed method is pertinent for minimizing energy issues in impoverished places at a reasonable price.

A Constant Current Output Method for Low-Voltage and High-Current DWPT Systems Based on Inverse Coupled Current Doubler Rectifier

A Constant Current Output Method for Low-Voltage and High-Current DWPT Systems Based on Inverse Coupled Current Doubler Rectifier

Electrodeposition of NiCo on stainless steel substrate using deep eutectic solvent for efficient hydrogen evolution and methanol oxidation reactions

The electrodeposition of NiCo on a stainless-steel substrate using Deep eutectic solvent (DES) was carried out using constant current methods. A 1:2 mol ratio of ChCl (Choline chloride) and crystalline urea was used to prepare DES. The XRD analysis of the fabricated NiCo@SS showed a highly crystalline nature, and the SEM image revealed the fabricated electrode surface morphology. The composition and oxidation state of the deposited material were confirmed by EDAX and XPS techniques. The prepared electrodes were subjected to LSV and CV studies with 1 M KOH using a three-electrode system to analyse its catalytic ability in the Hydrogen evolution reaction (HER) and methanol oxidation reaction (MOR). Among all the deposited electrocatalysts, NiCo@SS demonstrated the highest catalytic activity and excellent stability for the hydrogen evolution reaction (HER), achieving an overpotential of 257 mV at a current density of 100 mA/cm2. Additionally, NiCo@SS exhibited a remarkable current density of 240 mA at a potential of 0.8 V towards the MOR. The synthesized NiCo@SS possessed excellent low overpotential, low charge transfer resistance, high current density, and large surface area. The explored catalyst of NiCo@SS was examined with different concentrations of methanol using the CV technique. Finally, the stability of NiCo@SS, as examined by chronoamperometry and LSV with 3000 cycles, revealed it to be a robust, stable catalyst towards HER and OER.

The mechanism of enhanced electrocatalytic water splitting on S-doped NiFe2O4/Ni–Fe alloy@copper foams

The development of bifunctional catalysts with subtle structures, high efficiencies, and good durabilities for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is crucial for overall water splitting. In this work, a multicomponent S-doped NiFe2O4/Ni–Fe micro nano flower electrocatalyst was synthesized rapidly on foam copper using a simple one-step constant current electrodeposition method. The introduction of S leads to the transformation of the microsphere structure of the Ni–Fe alloy into a cauliflower-like morphology and induces changes in the surface electronic structure, significantly enhancing the catalytic performance for the HER and OER. The S-NiFe2O4/Ni–Fe alloy/CF showed low overpotentials of 220 and 66 mV at 10 mA cm−2 in 1.0 M KOH for the OER and HER, respectively. High durability OER and HER performances were demonstrated through 60 h of chronopotentiometry and 6000 CV cycles test. Excellent overall water splitting electrocatalytic activity was observed in the S-NiFe2O4/Ni–Fe alloy/CF‖S-NiFe2O4/Ni–Fe alloy/CF two-electrode system. In particular, active-phase NiOOH, a highly active substance for OER, can be controllably formed in the reaction process owing to the nanoflower structure of multi-layer sulfur which slows down the dissolution of NiFe2O4/Ni–Fe alloy. These results suggest that this composite structure is a promising bifunctional electrocatalyst.

Preparation and capacitance performance of NiCo layered double hydroxide by multi-step constant current electrodeposition method

In comparison with single-step electrodeposition, multi-step electrodeposition for electrode preparation is more effective in releasing internal stresses, utilizing the highly efficient deposition time at the beginning of the electrodeposition, improving deposition efficiency, and producing adhesive-free high-performance electrodes with controllable mass. In this paper, NiCo layered double hydroxide (NiCo-LDH) with similar mass was successfully deposited by a two-electrode constant-current electrodeposition method using nickel foam as the substrate through different electrodeposition steps. A comparative study was conducted on the effects of NiCo-LDH deposition steps on the morphology, total deposition time, and electrochemical performance of NiCo-LDH samples. The results show that the mass of NiCo-LDH grown on foam nickel is similar when the number of deposition steps is from 1 to 6 at 12–13 mg, the coating of foam nickel substrate became more uniform. The total deposition time has decreased from 2550 s for 1-step deposition to 1542 s for 6-step deposition, reducing the occupation time of the electrodeposition equipment. As the number of deposition layers increases, the specific capacitance of NiCo-LDH shows a trend of first increasing and then stabilizing. The high mass specific capacitance of NiCo-LDH electrode material deposited in 6 steps is 953 F g−1 at a current density of 3 mA cm−2. The assembled asymmetric supercapacitor device achieved an energy density of 0.309 mWh cm−2 at a power density of 4.25 mW cm−2, and a capacitance retention rate of 94% after 10,000 cycles at a current density of 40 mA cm−2. This indicates that the NiCo-LDH material prepared by multi-step electrodeposition method has good capacitance performance, providing a simple and time-saving method for manufacturing large-scale multi-step electrodeposition of adhesive-free supercapacitor electrodes.

Electrode Blending Simulations Using the Mechanistic Degradation Modes Modeling Approach

Blended electrodes are becoming increasingly more popular in lithium-ion batteries, yet most modeling approaches are still lacking the ability to separate the blend components. This is problematic because the different components are unlikely to degrade at the same pace. This work investigated a new approach towards the simulation of blended electrodes by replicating the complex current distributions within the electrodes using a paralleling model rather than the traditional constant-current method. In addition, a blending model was used to generate three publicly available datasets with more than 260,000 unique degradations for three exemplary blended cells. These datasets allowed us to showcase the necessity of considering all active components of the blend separately for diagnosis and prognosis.

Experimental study on the upward annular two-phase flow of nitrogen and ethanol aqueous solutions with different concentrations

Vertical upward annular flow experiments of nitrogen gas and ethanol aqueous solutions with volume fractions of 30 %, 60 %, and 95 % under 0.2 MPa were conducted. The characteristics of the liquid film including base, average, and maximum film thickness and height, velocity, and frequency of disturbance waves were obtained and studied based on the constant electric current method in a 5 mm inner diameter polycarbonate tube. The flow behavior was observed using a high-speed camera simultaneously. It is found that a large number of bubbles in the liquid film is critical to these characteristics. A connection between ethanol concentration and bubbles in the liquid film is found and interpreted by considering bubble stability which arises from the dynamic rise in surface tension. Our experimental investigation suggests that the effect of bubbles in the liquid film on the flow characteristics is not negligible in such annular flows under high liquid flow rates and bubble stability should be considered for annular flows employing solutions consisting of two or more components with large differences in surface tension.

Flexible bidirectional pulse charging regulation achieving long-life lithium-ion batteries

Typical application scenarios, such as vehicle to grid (V2G) and frequency regulation, have imposed significant long-life demands on lithium-ion batteries. Herein, we propose an advanced battery life-extension method employing bidirectional pulse charging (BPC) strategy. Unlike traditional constant current charging methods, BPC strategy not only achieves comparable charging speeds but also facilitates V2G frequency regulation simultaneously. It significantly enhances battery cycle ampere-hour throughput and demonstrates remarkable life extension capabilities. For this interesting conclusion, adopting model identification and postmortem characterization to reveal the life regulation mechanism of BPC: it mitigates battery capacity loss attributed to loss of lithium-ion inventory (LLI) in graphite anodes by intermittently regulating the overall battery voltage and anode potential using a negative charging current. Then, from the perspective of internal side reaction, the life extension mechanism is further revealed as inhibition of solid electrolyte interphase (SEI) and lithium dendrite growth by regulating voltage with a bidirectional pulse current, and a semi-empirical life degradation model combining SEI and lithium dendrite growth is developed for BPC scenarios health management, the model parameters are identified by genetic algorithm with the life simulation exhibiting an accuracy exceeding 99%. This finding indicates that under typical rate conditions, adaptable BPC strategies can extend the service life of LFP battery by approximately 123%. Consequently, the developed advanced BPC strategy offers innovative perspectives and insights for the development of long-life battery applications in the future.

Microscale Structure Additive Manufacturing Control Method Using Localized Electrochemical Deposition

Micro‐nano scale 3D printing is attracting attention as an alternative manufacturing method for a variety of applications in electronic information, biomedical, and sensing devices. Localized electrochemical deposition (LECD) based on nanopipettes is naturally superior and economical for the manufacturing of high‐freedom, impurity‐free metal conductors. However, flexible printing sacrifices roughness and straightness. Therefore, the present study initially establishes a simulation model for LECD and subsequently analyzes the key factors that influence the quality and stability of the deposited structure. Furthermore, an effective solution is proposed to enhance the surface quality. Second, a constant deposition current control method based on fuzzy proportional–intergral–derivaite (PID) is proposed to effectively suppress the fluctuation and improve the stability and quality of the deposited structure. Finally, compared with the open‐loop control method, the proposed constant current control method can reduce the radial fluctuation of the copper pillar structure by 87%, and effectively improve the surface quality of the structure. The proposed method provides a new idea to carry out LCED‐based 3D printing with high resolution at the micro‐nano scale.

The role of lateral hypothalamic nucleus in mediating locomotive behaviors in pigeons (Columba livia)

The lateral hypothalamic nucleus (LHy) is located in the dorsolateral hypothalamus of birds, and it is essential to many life processes. However, limited information is available about the role of LHy in mediating locomotive behaviors. In this work, we investigated the structure and function of LHy in pigeons (Columba livia) by Nissl staining, immunohistochemical (IHC) staining, insituhybridization (ISH) staining and constant current stimulation methods. The results showed that LHy appears crescent in shape, and three-dimensional coordinate value range of LHy is: A: 5.0–8.0 mm, L: 0.7–1.2 mm, D: 9.5–10.3 mm. The dopaminergic neurons in LHy were distributed in small amount and concentrated manner, while the glutamatergic neurons were distributed in a large number and uniform manner. The distribution of the above two neurons at each coronal level showed a significant positive correlation (R2 = 0.7516, P < 0.001). Our work demonstrated that LHy mainly mediates forward movement (P < 0.01) and ipsilateral lateral movement (P < 0.001), and these movements were significantly effected by electrical stimulation intensity. Our results showed that LHy can mediate the generation of directional behavior and this will provide technical support for the study of locomotor behavior regulation in birds.

Realization of a composite ferroelectric characterization test system using a modified constant current method and a modified virtual ground method.

A composite ferroelectric characterization test system constructed using a modified constant current method (CCM) and a modified virtual ground method (VGM) has been successfully designed and implemented. By sending instructions to the microcontroller through software, the system's test mode can be easily changed by arranging the switching status of six switching elements. When validating the system, a dual-channel precision source/measure unit B2912B was used to verify this design. There is also parasitic capacitance that cannot be ignored in this commercial machine. This parasitic capacitance affects the appearance of the entire hysteresis curve. However, the parasitic capacitance values also differ in various test current ranges. In addition, to confirm the data credibility of this composite ferroelectric test system, Keysight B1530A and Radiant Premier II were used to conduct cross-verification between different systems. The results obtained between different systems show good consistency. Furthermore, reproducible and recoverable imprint phenomena were found in this composite system during interactive validation using VGM and CCM methods. After designing different voltage profiles for verification, it was found that the root cause of this imprint phenomenon was the difference between the final polarization state of the previous test and the pre-initialized polarization state. This imprint phenomenon exists in traditional Pb(Zr, Ti)O3(PZT) ferroelectric capacitors and Hf0.5Zr0.5O2-based ferroelectric capacitors. Fortunately, this imprint phenomenon is reversible. Moreover, this imprint phenomenon disappears through the design of the time-varying voltage profile on the ferroelectric capacitor of the CCM method.

The fatigue crack growth behavior of hydrogenated 9Cr‐1Mo steel: An experimental and numerical study

AbstractThis research investigates the fatigue crack evolution in P91 steel through experiments and extended finite element method (XFEM) simulation for as‐received and hydrogenated conditions. Hydrogen pre‐charging is performed using a constant current electrochemical method in 1 M sulfuric acid solution. The study compares the experimental fatigue crack growth rate (FCGR) of hydrogenated and as‐received conditions and employs an XFEM simulation to replicate FCGR. The results of the experiments reveal an increased FCGR in hydrogenated specimens. Fracture surface analysis confirms the co‐occurrence of the “hydrogen‐enhanced localized plasticity” (HELP) and “hydrogen‐enhanced decohesion” (HEDE) mechanism (HELP+HEDE, HEDE&gt;HELP). The simulation results closely align with the experimental findings, validating the model's accuracy. Consequently, these findings are the basis for proposing a damage tolerance approach‐based numerical algorithm. This algorithm allows the prediction of component integrity by considering a known crack length. Furthermore, fracture toughness (KIQ) was experimentally evaluated to enhance the understanding of the material's mechanical properties.

Synthesis of Porous Carbon Nanomaterials from Vietnamese Coal: Fabrication and Energy Storage Investigations

The choice of precursor and simple synthesis techniques have decisive roles in the viable production and commercialization of carbon products. The intense demand for developing high-purity carbon nanomaterials through inexpensive techniques has promoted the usage of fossil derivatives as a feasible source of carbon. In this study, Vietnamese-coal-derived porous carbon (PC) was used to fabricate coal-derived porous carbon nanomaterials (CDPCs) using the modified Hummers method. The resulting porous carbon nanomaterials achieved a nanoscale structure with an average pore size ranging from 3 to 10 nm. The findings indicate that CDPC exhibits well-developed micropores and mesopores. The presence of macropores and mesopores not only facilitates the complete immersion of the material in the electrolyte but also effectively shortens the ion diffusion pathways. CDPC boasts a high carbon content, constituting 80.88% by weight. Electrochemical impedance spectroscopy (EIS) Nyquist plot of electrodes made from CDPC showed good conductivity value with low charge-transfer resistance. This electrode worked well and stably with capacitance retention of 74.7% after 1000 cycles. The CDPC specific capacitance reached 236 F/g under a current density of 0.1 A using the constant current discharge method and then decreased as the current density increased. Based on the results of the electrochemical properties of the materials, the energy storage capacity of the CDPC material was good and stable. This investigation presents an eco-friendly methodology for the judicious utilization of coal in energy storage applications, specifically as electrodes for supercapacitors and anodes for Li-ion batteries.

A ballistic model for subthreshold current and threshold voltage of the dual-material-gate nanosheet MOSFET

— A ballistic model for subthreshold current of the dual-material-gate (DMG) nanosheet (NS) MOSFET is developed based on the Landauer approach, three-dimensional scaling equation, and the continuity of subthreshold current at the interface between the control gate and screen gate in the channel, The work function difference between the screen gate and control gate can be converted into the new interface-quasi-fermi-potential (IQFP) at the junction between different gate regions. Through the IQFP, the ballistic subthreshold current for DMG NS MOSFET is successfully developed. With the determined subthreshold current, the ballistic threshold voltage can also be achieved by the constant current method. Under the low and high drain voltage corresponding to their IQFPs, the subthreshold behavior is mainly governed by the contact potential and thermal voltage, respectively. Furthermore, Ohm's law regarding ballistic resistance for the DMG NS MOSFET can still be valid in the subthreshold conduction.

Implementation of battery storage system in a solar PV-based EV charging station

Commercial production of solar-powered battery charging stations for electric vehicles has recently started largely as a result of the growing popularity of electric vehicle (EV) technology as well as the falling cost of photovoltaic (PV) systems. The rise in popularity of EVs may be attributed to both the progression of technology and rising awareness of environmental issues. In this work, a 400V DC bus voltage-based EV charging station is designed which is powered by both a PV system and a utility grid. Also, battery energy storage units are used to overcome the unpredictable behavior of the environment. An Energy management algorithm (EMA) has been presented to balance the power flow among PV, EVs, BESS, grid, and residential load. A sharing coefficient-based power sharing is done between the grid and battery to reduce the stress from the battery units. Then, a multi-step constant current charging method is used to charge the EVs in the charging station to maintain the proper state of charge (SOC) of EV batteries. During this study, different operating conditions are considered according to available PV power and load to validate the power management scheme in the EV charging station. The model is run using MATLAB simulation and opal-RT simulation. The obtained results have been demonstrated with an explanation and system performance verification.

A Communication-Free Fast Constant Current and Voltage Control Method for Dynamic Wireless Power Transfer System

A Communication-Free Fast Constant Current and Voltage Control Method for Dynamic Wireless Power Transfer System

A Review on Fast Charging Methodologies of Electric Vehicles

The Li-Ion battery is charged using a constant voltage, constant current charging method. The solution, photovoltaic energy, is making its appearance in the EV charging infrastructure. By altering the transformer ratio, the inverter's voltage gain can be adjusted. Instantaneous thermal gradients are altered by fast charging. The grid and electricity quality may be impacted by EV charging.The goal of this study is to create a comprehensive, current overview of fast charging techniques for battery-electric vehicles (BEVs). The foundational ideas of single battery cell charging as well as existing and upcoming charging standards are covered in this paper. Globally, battery-powered electric vehicles are becoming more and more common. Numerous causes, such as the need to lessen noise and air pollution and our reliance on fossil fuels, are driving this trend. The primary disadvantage of modern electric vehicles is their short range and the length of time needed to charge their batteries. Through research and development, great strides have been achieved recently to use pulse charging, as opposed to continuous current and/or voltage delivery, to shorten the charging period of the batteries in electric vehicles. The portion that needs to be concentrated on estimating the electrical properties of the vehicle's battery is crucial for learning about the potential driving range.

High-performance CF/MXene/β-PbO2 materials as anodes for asymmetric supercapacitors

MXene has excellent capacitive properties as a two-dimensional material, but its cycling stability is poor. β-PbO2 is one of the common crystalline forms of lead dioxide, and it has excellent electrochemical properties and cyclic stability and has potential as a capacitor electrode material. However, the capacitive performance of β-PbO2 as a capacitor electrode material is not ideal. Therefore, CF/MXene/β-PbO2 (CMP) composites were prepared in this study by combining β-PbO2 with CF/MXene (CM) using a constant current electrodeposition method, and their electrochemical energy storage properties were investigated. The ordered structure of interwoven CF is used to fix MXene, which has metallic properties and large layer spacing, as the matrix material. This utilization enables faster ion transport and electron storage. The electrochemical advantages of β-PbO2 and CM can be unified by the synergistic effect of the composites, which results in a high specific capacity (399.42 F g−1) of the CMP electrode at 0.2 A g−1. In addition, the CM//CMP asymmetric supercapacitor constructed in 1 M Na2SO4 solution has a wide potential window of 2.0 V and a high specific capacitance of 193.8C g−1, and the capacity remains 54.3% of the initial value after 5000 cycles at a charge/discharge rate of 40 mA g−1. This work provides important research ideas and clues for the application of β-PbO2 composite electrode materials in supercapacitors.

Fast Charging Station for Electric Vehicles Based on DC Microgrid

Increasing numbers of electric vehicles (EVs) have led to an increased power demand from the grid. The fast-charging station requires very high power for charging the EVs in a short time (30mins). The rapid high-power (80-240kW) demand results in voltage instability in the power grid. It is important to reduce the impact on the grid due to fast charging of EVs. The effect on the grid due to EVs fast charging is included in this paper. The grid instability is visible during the fast-charging period of the battery. As a solution, a renewable energy source integrated DC microgrid using a multi-step constant current fast charging method is proposed to reduce the effect on the grid. Additionally, the proposed system provides solar PV and/or vehicle to grid power transfer during the no charging/the peak demand period of the grid. The simulation and analysis of the proposed system using the coulomb counting based state of charge estimation method is implemented to show the grid impact and reduction using DC microgrid. A hardware prototype is developed to validate the proposed fast charging method and also to reduce grid impact during the fast-charging operation.