Conservation Of Artifacts Research Articles

Research on high-strength and rapid-hardening magnesium phosphate as a novel bonding material for limestone artifacts

Due to natural erosion and human interference, limestone artifacts often suffer from cracks and gradual detachment. There is a critical need for new bonding materials that possess excellent aging resistance and high compatibility with the artifact substrates. This study investigates the effects of varying proportions of citric acid (CA) and borax (B) as composite retarders on the fundamental properties of magnesium phosphate cement (MPC). Through the application of X-ray diffraction techniques and cold field emission scanning electron microscopy, this research elucidates the mechanisms by which the retarders affect MPC. It was found that a 5 % addition of CA and B significantly reduces the hydration temperature during the early stages of MPC setting, enhances the unconfined compressive strength (reaching 44.3 MPa at 28 days), and allows for controllable setting times (17 minutes). Additionally, the presence of CA was found to delay crystal growth, resulting in an increased quantity of the amorphous phase and higher density of MPC. The optimal MPC formulation was selected as a bonding and repair material for limestone artifacts. For comparative analysis, traditional glutinous rice lime mortar (GL) and commercially available epoxy resin (EP) were tested under wet-dry cycling and UV aging conditions. Results indicated that EP materials demonstrated significant aesthetic incompatibilities and progressive cracking and detachment as aging tests progressed. GL materials exhibited significantly lower bonding strength compared to EP and MPC. In contrast, MPC displayed excellent aging resistance, moderate bonding strength, and a Shore hardness value closely matching that of the limestone substrates. Therefore, high-strength, rapid-hardening MPC represents a valuable and forward-looking solution for the conservation of limestone artifacts.

A Review on Conservational Methodologies of Tangible Cultural Artifacts from Environmental Corrosion

Tangible cultural heritage are invaluable assets inherited from our ancestors, encompassing transformative skills, culture, tradition, knowledge and practice, passed down by generations to generation. It is sad to say that, these assets are at brink of deterioration, and vandalism from both pernicious natural forces and relentless time laps. There is an urgent need of preserving and carefully transferring these treasures to the future generations. The main objective of our study is to provide basic knowledge for the conservation of cultural artifacts. With this investigation, we lay stress on the significance of cultural artifacts, delve the factors influencing corrosion, talk about cleaning methods and stressing the use of inhibitor or protective coating to shield them from further decay. Our study emphasizes the urgent need of development of new methodologies and strategies to safeguard these assets from ruinous events. In addition, it also present ongoing efforts applied in transmission and preservation of these metallic artifacts in their original form.

Assessment of some air pollutants in the Sanctuary of the Beata Vergine dei Miracoli (Saronno, Italy) and first evaluation of a new axial passive sampler for nitrogen dioxide

In the present study the concentration of some air pollutants (nitrogen dioxide, sulphur dioxide, hydrogen sulphide, ammonia and BTEX, i.e. benzene, toluene, ethylbenzene and xylene) was monitored inside and outside the Sanctuary of the Beata Vergine dei Miracoli (Saronno, Italy) by passive air sampling (using radial samplers), during two sampling periods in 2022 (April 27-May 11 and May 11-May 25). Concurrently, particulate matter (PM10 and PM2.5) concentration was determined by using sensors based on laser scattering technology. Moreover, we took advantage of the location of this sanctuary (proximity to an air monitoring central unit) to evaluate the performance of a new axial-type sampler for nitrogen dioxide. Sulphur dioxide concentration was in the range 0.8–3.1 µg/m3, with outdoor values higher than indoor ones, whereas no detectable concentrations of hydrogen sulphide were found (<0.1 µg/m3). A different trend was observed for ammonia, where indoor concentrations were higher than outdoor ones (3.6–5.5 vs 2.7–3.1 µg/m3). Among BTEX, only for benzene statistical differences (p-value < 0.05) between the indoor and outdoor concentrations were found, suggesting additional indoor sources for this hydrocarbon. Toluene results as the most abundant among these hydrocarbons (1.7–2.3 µg/m3) in outdoor environments, whereas, in indoor environments, benzene has the higher concentration (6–9 µg/m3). The indoor concentrations of NO2 (15.4–22.2 µg/m3 for radial samplers and 48–60 µg/m3 for axial samplers) are not only much higher than the recommended limit values to guarantee proper conservation of artefacts (5 µg/m3), but also close to the values for human health preservation (40 µg/m3), suggesting the need of proper strategy to improve indoor air quality inside the Sanctuary. The preliminary results obtained for the new axial-type sampler for nitrogen dioxide are very encouraging, given the closeness of the obtained concentration data to those measured by monitoring central unit, even though further experiments will have to be carried out to validate this sampler.

Multimodal spectroscopic assessment of mechanical and chemical properties of ABS objects in cultural heritage preservation

The 1960s saw the emergence of plastic as an indispensable component in various fields, including art and design. Acrylonitrile-butadiene-styrene (ABS) is widely used by artists and designers for a range of applications including sculptures and decorative pieces. Consequently, the necessity to conserve ABS from deterioration is a crucial issue in the field of cultural heritage preservation. Many studies have highlighted the criticality of the stability of the polybutadiene component when exposed to light. We propose a new multimodal spectroscopic approach to assess the conservation status of plastic design objects. This non-destructive approach combines correlative Brillouin and Raman micro-spectroscopy (BRaMS), external reflection IR spectroscopy and portable NMR relaxometry. BRaMS is a novel non-destructive technique in the field of heritage conservation, allowing simultaneous monitoring of chemical and mechanical changes occurring at the sample surface. The present study focused on photochemically aged LEGO® bricks made of ABS and aimed to i) correlate chemical and mechanical changes induced by light exposure and ii) introduce a surface degradation index (SDI), measurable in situ by external reflection IR spectroscopy, to assess the state of conservation of plastic artefacts. Finally, non-invasive investigations were carried out on real design objects using the MObile LABoratory (MOLAB) platform.

Mechanical properties of wall soils for predicting damage to the substrate of Hiten wall paintings in the Horyu‐ji Temple main hall caused by humidity fluctuation: Measurements with mock‐up materials

AbstractSafe and efficient conservation of cultural artifacts requires preventing artifacts deterioration and energy‐saving environmental control. To achieve this, predicting deterioration caused by environmental conditions is necessary. Predicting the mechanical damage caused by humidity fluctuations necessitates knowledge of the mechanical properties of cultural artifacts materials. Although the mechanical properties of several artifacts have been extensively studied, no investigations have focused on the soils underlying wall paintings. This study aims to clarify some mechanical properties of the upper‐ and middle‐coat soils serving as the substrates for Hiten wall paintings at Horyu‐ji Temple. Mock‐up materials were prepared, and splitting tensile and uniaxial compressive tests were performed. Simultaneously, specimens with various equilibrium humidities were tested to clarify their humidity dependency. The tensile and compressive strengths, Young's modulus, proportional limit, and Poisson's ratio of the upper‐coat soil were 0.103–0.239 MPa, 1.16–2.55 MPa, 0.115–0.209 GPa, and 1.10–2.49 MPa, and 0.152, respectively. Moreover, the humidity‐induced strains for the upper‐ and middle‐coat soils were measured, and the moisture expansion coefficients were approximately 1240 and 2337 μST/−, respectively. The results of this study provide vital data for the conservation of the wall paintings and contribute to a deeper understanding of wall soil properties.

Copper Complexes in Verdigris Painting Mixtures: An Electron Paramagnetic Resonance Characterization

Abstract Copper complexes, also called “copper soaps” when referred to carboxylate compounds, have become a concern in the conservation of historical artefacts. These complexes are suspected to play a significant role in degradation processes such as darkening and cracking of painting layers. Here we propose the Continuous Wave Electron Paramagnetic Resonance spectroscopy (CW-EPR) as a tool for the identification of these species. EPR spectroscopy is a micro-invasive and non-destructive technique that is highly sensitive to paramagnetic species, including radicals, crystal defects, and transition metal ions, e.g., Cu(II) and Fe(III). We have selected the verdigris (copper acetate) pigment combined with many organic binders, e.g., egg tempera and gum Arabic, as mock-up systems because of the known degradation tendency of the copper-based pigment. We would like to demonstrate that a precise analysis of the experimental spectra assisted with the calculus of the main magnetic quantities could lead to a good characterization of the copper complexes (or “soaps”).

The conservation and utilization of museum relics based on internet of things and fuzzy control

With the development of Internet of Things and fuzzy control theory, there are new opportunities for the conservation and utilization of museum artifacts. The traditional way of heritage restoration lacks the overall harmony of heritage restoration, which leads to the stagnation of heritage restoration level. At the same time, traditional heritage conservation is also limited to manual management, which seriously hinders the development of the overall level of museums. Artifacts are of great commemorative and research value and are objects that have been handed down to mankind for thousands of years and have been subjected to the natural environment for a long time before being excavated. Heritage conservation requires not only restoring artifacts to the greatest extent possible, but also securing the environment in which they are displayed and stored to ensure that they can be preserved for as long as possible. But the following problems exist in the conservation of cultural relics (1) the lack of strict standards for the environment in which cultural relics are stored. (2) the professional competence of the staff is not strong. (3) The lack of a strict management system (4) heritage conservation technology is backward. To solve these problems our team constructed a fuzzy control method based on fuzzy control theory to assist in the restoration of cultural relics. The model constructed by fuzzy control theory solves this problem. The fuzzy control theory constructs a model for restoration of cultural relics, taking into account the overall harmony of the relics and the accuracy of the points, which is of great significance for the restoration of museum relics. At the same time through the Internet of Things technology to build a library heritage protection system, the main content of the system is (1) the use of Internet of Things technology to build a security protection system for cultural relics (2) the use of Internet of Things technology to detect the storage environment of cultural relics (3) the use of Internet of Things technology to optimize the management process of cultural relics (4) the use of Internet of Things technology to achieve real-time monitoring of the flow of information on cultural relics. And based on this, suggestions are made to (1) improve the museum heritage protection and utilization system (2) improve the infrastructure of museum heritage protection and build a good environment for heritage storage (3) improve the quality of heritage managers. The model constructed in the article has been tested in practice and is feasible, with certain practical and theoretical values.

A seismic risk assessment method for cultural artifacts based on the Law of Large Numbers

Earthquakes can cause significant damage to cultural artifacts, which often hold significant historical or cultural value. Seismic risk assessments can contribute to a more targeted approach by museum staff to the preventive conservation of cultural artifacts. The primary objective of this research is to suggest a new approach for assessing the seismic risk of cultural artifacts. This innovative method is founded on the Law of Large Numbers and aims to provide a more user-friendly way of evaluating the likelihood of potential seismic threat to cultural artifacts. The proposed method takes into account the statistical distribution of seismic ground motion and the seismic response characteristics of artifacts, and its accuracy and practicality are demonstrated by case studies. Compared with existing methods, the proposed method has the advantages of theoretical simplicity, low computational effort, and easier to be understood and mastered by museum staff. Furthermore, the impact of sample size on the assessment results was investigated. The findings demonstrate that the proposed method represents a valuable tool for cultural heritage risk decision-makers to evaluate the seismic risk of artifacts. By using this method, they can more effectively assess the potential damage caused by seismic effects and design suitable mitigation measures accordingly.

Archeological wood conservation with selected organosilicon compounds studied by XFM and nanoindentation

Waterlogged wood conservation is a complex and challenging task. Detailed knowledge about the interactions between the applied chemicals and wood is necessary to ensure the effective and safe conservation of wooden artifacts. The present research aims to determine the mechanism of dimensional stabilization of archeological wood by organosilicon compounds using the combination of synchrotron-based X-ray fluorescence microscopy (XFM) and nanoindentation. Archeological oak wood was treated with methyltrimethoxysilane, (3-mercaptopropyl)trimethoxysilane, or 1,3-bis-[(diethylamino)-3-(propoxy)propan-2-ol]-1,1,3,3-tetramethyldisiloxane, which in previous studies were found to be more effective than other organosilicons in stabilizing wood dimensions. The XFM and nanoindentation results showed that all three organosilicons infiltrated wood cell walls and enhanced their mechanical properties. The XFM also showed that part of the chemicals filled some void spaces like cell lumina. Based on the results obtained here and in our previous research, it is determined that the mechanism of archeological wood dimensional stabilization by organosilicon treatment is complex and likely involves both filling cell lumina and infiltration into cell walls where organosilicons interact with wood polymers.

B72 vs. Paraloid B67 Materials for Conservation of Wood Artifacts

Abstract The aim of the paper is a comparative testing of two Paraloid resins (B-72 and B-67), in order to determine which is the most efficient for the protection of wood artifacts. Healthy Spruce wood samples were cut (3cm ×3cm ×0.7cm) and covered by brushing with 3 layers of a Paraloid B 72 10% solution (solvent acetone: ethanol 1:1) and with a solution of Paraloid B 67 10% (solvent isopropanol) respectively. The samples further undergo rapid thermic aging and then, one set will undergo colorimetric testing in order to establish the degree of yellowing for each copolymer. Another set will undergo spectrometric FT-IR analysis in order to establish the degradation degree of the polymeric chains. The aim is also to compare the degree of water absorption for the wood samples treated with each of the two Paraloid resins. Also, the chromatic parameters and glossmetry values have been used as additional data in order to observe the degradation aspect of these samples.

Aïoli: A reality-based 3D annotation cloud platform for the collaborative documentation of cultural heritage artefacts

Archaeologists, architects, engineers, materials specialists, teachers, curators and restorers of cultural property, contribute to the daily knowledge and conservation of heritage artefacts. For many years, the development of digital technologies has produced important results in the collection, visualisation and indexing of digital resources. Whilst these advances have made it possible to introduce new tools that are making documentation practices evolve within the cultural heritage community, the management of multi-dimensional and multi-format data introduces new problems and challenges, in particular the development of relevant analysis and interpretation methods, the sharing and correlation of heterogeneous data among several actors and contexts, and the centralised archiving of documentation results for long-term preservation purposes. Despite their different approaches and tools for observation, description and analysis, the actors of cultural heritage documentation all have a common interest and central focus: the heritage object, the physical one, whether it is a site, a building, a sculpture, a painting, a work of art, or an archaeological fragment. This is the starting point for the development of “Aïoli”, a reality-based 3D annotation platform, which allows a multidisciplinary community to build semantically-enriched 3D descriptions of heritage artefacts from simple images and spatialised annotations coupled with additional resources. Resulting from more than 10 years of methodological and technological contributions concerning different steps of the workflow starting from reality-based 3D reconstruction to the analysis of cultural heritage data, this platform introduces an innovative framework for the comprehensive, large-scale collaborative documentation of cultural heritage by integrating state-of-the-art technological components within a cloud infrastructure accessible via web interfaces from PCs, tablets and smartphones online and onsite. This paper aims to provide a synthesis of the work done to build it, to describe its main features, and to discuss the limitations and opportunities it raises for cultural heritage studies.

Hybrid Materials Based on ZnO Nanoparticles and Organo-Modified Silica Coatings as Eco-Friendly Anticorrosive Protection for Metallic Historic Artifacts

Cultural heritage metallic artifacts are often subjected to environmental factors that promote degradation through corrosion processes. Anticorrosion protection is needed both for the long-term preservation of outdoor monuments and the short-term conservation of archaeological artifacts. In this work, functional nanocoatings based on ZnO nanoparticles (NPs) in a silica matrix are prepared as a replacement for a commercial Incralac lacquer. Facile sol–gel synthesis is employed for obtaining silica filmogenic materials, using tetraethoxysilane (TEOS) and 3-glycidyloxypropyl trimethoxysilane (GPTMS). Silica-based nanocomposite coatings, with and without ZnO NPs and benzotriazole (BTA) as anticorrosion agents, applied on copper coupons by brushing are characterized by using VIS and FTIR spectroscopy, SEM and AFM and compared to Incralac lacquer as reference materials. The optical and morphological properties of the proposed silica coatings are similar to the Incralac specimens. The protective effect against corrosion is investigated on the copper coupons as model metallic objects subjected to a corrosion test by using potentiodynamic polarization in a 3.5% NaCl solution at ambient temperature. The influence of the presence of BTA and ZnO NPs in both silica and Incralac coatings is studied, and the variations in the anticorrosive, morphological and optical properties with the concentration of ZnO NPs are evidenced. The presence of moderate concentrations of ZnO in both nanomaterials leads to changes in the color parameters slightly above the limit accepted in the field of cultural heritage (ΔE* 5.09 and 6.13), while a high ZnO concentration of 3% leads to higher values (ΔE* &gt; 10). Regarding the anticorrosive effect, the silica-based coatings with ZnO and BTA present similar efficiencies to that of the Incralac reference material (corrosion rates in the range of 0.044–0.067 mm/year for silica coatings compared to 0.055 mm/year for Incralac).

Preliminary study on the strength enhancement of Klucel E with cellulose nanofibrils (CNFs) for the conservation of wooden artifacts

Preliminary study on the strength enhancement of Klucel E with cellulose nanofibrils (CNFs) for the conservation of wooden artifacts

Toward a Non-Anthropocentric Italian Cinema

The 2015 film Lost and Beautiful, directed by Pietro Marcello, en­deavors in aesthetically compelling ways to decenter the human in the frame and engage viewers in what Gilles Deleuze and Felix Guattari term becoming animals. Part documentary film, part fairytale, this film tells the story in the nonhuman first person, of the life and journey of a water buffalo calf in the south of Italy and his relationship with the shepherd who saved him from pre­mature death, and later, with Pulcinella, a mythological figure from Neapol­itan folklore, who accompanies him in a journey north. Adopting ecocritical and posthuman perspective and providing elements of environmental cultural history, this article analyses the aesthetic and narrative strategies the film em­ploys to grant subjectivity to a nonhuman protagonist and, in turn, address the viewers. Advocating for the conservation of human artifacts while also posing the question of animal rights and agency, Lost and Beautiful powerfully gestures toward a non-anthropocentric cinema.

Sustainability by Design: Innovative Ways of Revolutionizing Production Practices for a Better Tomorrow

The incorporation of virtual design, augmented reality (AR), and immersive 3D modelling has resulted in a significant and extensive impact on several aspects of society and culture. The aforementioned technologies have not only brought about significant changes in various sectors such as education, entertainment, healthcare, and real estate, but they have also fundamentally transformed the way in which we engage in communication, interaction, and our overall perception of the surrounding world. Within the field of education, the utilisation of virtual design and immersive technology has expanded the possibilities for learning, presenting opportunities for interactive, experiential, and dynamic educational encounters. The use of various resources, such as 3D anatomy lectures and virtual historical excursions, has significantly augmented our capacity to comprehend intricate issues and facilitated a more captivating methodology towards education. The field of healthcare and medicine has experienced significant advancements as a result of these technologies, which have facilitated enhanced surgical planning, medical training, and therapeutic interventions. The field of telemedicine has seen a significant transformation with the integration of augmented reality (AR), resulting in enhanced accessibility and convenience of healthcare services, particularly in geographically isolated or underserved regions. The influence of these technologies has been extended to the preservation of cultural heritage, facilitating the digitization and conservation of heritage places and artefacts, so ensuring their accessibility for future generations to study and appreciate. The democratisation of creativity and empowerment has facilitated the artistic expression and utilisation of 3D models and augmented reality (AR) applications by individuals from various backgrounds. it is crucial to acknowledge ethical and societal concerns as we adopt these revolutionary technologies. The issues of privacy, addiction, misinformation, and the ethical utilisation of data are matters that necessitate continuous focus and resolution.

Biophysical Manipulation of the Extracellular Environment by Eurotium halophilicum.

Eurotium halophilicum is psychrotolerant, halophilic, and one of the most-extreme xerophiles in Earth's biosphere. We already know that this ascomycete grows close to 0 °C, at high NaCl, and-under some conditions-down to 0.651 water-activity. However, there is a paucity of information about how it achieves this extreme stress tolerance given the dynamic water regimes of the surface habitats on which it commonly occurs. Here, against the backdrop of global climate change, we investigated the biophysical interactions of E. halophilicum with its extracellular environment using samples taken from the surfaces of library books. The specific aims were to examine its morphology and extracellular environment (using scanning electron microscopy for visualisation and energy-dispersive X-ray spectrometry to identify chemical elements) and investigate interactions with water, ions, and minerals (including analyses of temperature and relative humidity conditions and determinations of salt deliquescence and water activity of extracellular brine). We observed crystals identified as eugsterite (Na4Ca(SO4)3·2H2O) and mirabilite (Na2SO4·10H2O) embedded within extracellular polymeric substances and provide evidence that E. halophilicum uses salt deliquescence to maintain conditions consistent with its water-activity window for growth. In addition, it utilizes a covering of hair-like microfilaments that likely absorb water and maintain a layer of humid air adjacent to the hyphae. We believe that, along with compatible solutes used for osmotic adjustment, these adaptations allow the fungus to maintain hydration in both space and time. We discuss these findings in relation to the conservation of books and other artifacts within the built environment, spoilage of foods and feeds, the ecology of E. halophilicum in natural habitats, and the current episode of climate change.

A Novel Protection Method for Carbonate Stone Artifacts with Gypsum Weathering Crusts

An innovative method using a methanol solution of barium hydroxide-urea as a protective agent was investigated for the conservation of stone artifacts with harmful gypsum weathering crusts. In this method, the methanol solution of barium hydroxide-urea and water were introduced into the gypsum crust in sequence by surface spraying. By doing so, the harmful gypsum crust is directly converted into a barium sulfate—calcium carbonate composite protective layer. The properties of the composite layer were characterized by SEM-EDX, XRD, ATR-FTIR, IC, water solubility, wetting angle, color difference, open porosity, capillary water absorption, and surface hardness. The results of the morphological and composition characterization (SEM-EDX, XRD, ATR-FTIR) indicate that the added urea can promote the carbonization reaction effectively. In addition, the methanol solution of barium hydroxide-urea can penetrate deep into the gypsum crust. The results of the physical properties characterization denote that the water stability of the specimens was significantly increased after the protection treatment; an approximate ten-fold stronger water resistance ability was achieved. Meanwhile, the intrinsic physical properties of gypsum crust, such as pore structure and original appearance, could basically be maintained. The presented conservative method has high facility and controllability and satisfying conservation effect, which means it has potential in the conservation of surface weathering carbonate stone artifacts.

Cultural-based digital archive approach to enrich student users’ curriculum interpretation and worldview

In the 21st century, digitalization is essential to optimize preservation and conservation of museum artifacts. Digital archives provide critical.extension value and relevant information resources that enrich users' cultural knowledge and connection through object analysis. This study explores the potential of HistoryPin, a free online application for cultural storytelling, to expand student users’ worldview concept and interaction with museum artifacts through a series of curated collections as a learning and engagement tool. &#x0D; A collaboration between Kent State University Museum and the School of Fashion’s Historic Textiles course in Spring 2022, this case study identified cultural artifacts including textiles, costumes, and related accessories to illustrate and support course topics. Artifacts representing a range of geographic areas were selected, digitized, and presented with images in different views, cultural and historical information, and linked data in the virtual tour setting of HistoryPin. Students from both online and in-person sections experienced a virtual exhibition of artifacts, which reinforced and extended class content for further interpretation and engagement. &#x0D; Advanced interactive technologies, such as comments, favorites, and thought/image sharing on different social media, from HistoryPin allowed students to reflect on various perspectives related to cultural objects. After each section of the course, researchers gathered student users’ interactive comments shared on HistoryPin. A content analysis approach of emergent themes revealed the impact and contributions of museum artifacts. Moreover, a targeted survey provided sub-analyses on the cultural-based digital archive approach which informed an overall assessment of the impact in enriching student users’ virtual museum experience.

Bayeux Tapestry: First use of early synthetic dyes for the restoration of a masterpiece

The earliest examples of the use of synthetic dyestuffs in the domain of art and conservation are still poorly documented. Here we show that the use of a database of reflectance spectra collected between 400 nm and 800 nm on pieces of dyed fabric attached in chemistry books printed at the beginning the 1870s and reference samples dyed with natural colourants, enables the non-invasive identification of the earliest artificial dyes present in these books. By applying this methodology on restored parts of the Bayeux Tapestry, it is possible to prove a major restoration of the textile artefact occurred between the years 1866 and 1872 and then to observe the very early acceptance of the use of artificial dyestuffs for the conservation of historical artefacts.

Gold Mine Wooden Artefacts: Multianalytical Investigations for the Selection of Appropriate Consolidation Treatments.

Environmental conditions present in mines generally are very favourable to decay; high temperature, high humidity, variable oxygen content, numerous metal-wood connections and the presence of a high content of inorganic compounds typical of mines have a significant impact on the biotic and abiotic degradation factors. The state of conservation of wooden artefacts from the Złoty Stok (Poland) gold mine was investigated using a multi-analytical approach. The aim was to select the conservation treatments that would stop decay and improve the conditions and dimensional stability of the wood. FT-IR and Py-GC/MS were used to assess the state of preservation of lignocellulosic material. ED-XRF and SEM-EDS were used to determine—and XRD to identify crystalline phases—salts and minerals in the wood structure or efflorescence on the surface. Highly degraded lignocellulosic material that had undergone depolymerisation and oxidation was found to be severely contaminated by iron-based mineral substances, mainly pyrite, and in some cases greigite and magnetite. The presence of inorganic salts made it difficult to choose the best consolidating material to reduce the level of decay and improve the dimensional stability of the wood.