Chemographic constraints from high-pressure mafic rocks of the INTRODUCTION Nevado–Filabride Complex (Betic–Rif mountain belts, SE Spain) The relevance of singular equilibria has been largely and from worldwide high-pressure terrains have been used to unravel recognized in chemical systems of interest for the Earth phase relationships between amphibole, garnet, clinopyroxene, and Sciences. After the early experiments of Konovalov on albite in the system Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O azeotropic or congruent transformations, Ricci (1951) (NCFMASH) at quartz-, paragonite-, clinozoisiteand waterexhaustively discussed the fundamentals of singularities. saturated conditions. Extensive analysis of element partitioning Two types of singularities were recognized: the first, between amphibole and clinopyroxene suggests that the Fe–Mg called type m and most relevant, is associated with azeopartition coefficient is low at low-temperature and high-pressure tropic points, and the second, called type k, is related to conditions (‘high-temperature’ blueschists–low-temperature eclogites) the intersection of solvi with compositional loops, as and a progressive increase is achieved by an increase in temperature, occurs in the alkali feldspar system at low pressures or by a decrease in pressure, or by a decrease in the sodium content (Morse, 1970). Examples and discussion of both type m of the clinopyroxene. Mass-balance analysis of paragonite eclogites and type k singular points in igneous systems have been and amphibolites suggests that at least two singular reactions are given by Morse (1980, e.g. see chapters 16 and 18). The possible in NCFMASH: clinopyroxene+ paragonite+ quartz= widespread occurrence of singularities in igneous systems amphibole + albite + clinozoisite + water (garnet-absent), and is obviously related to the extremely large compositional amphibole+ clinozoisite= garnet+ clinopyroxene+ paragonite range of silicate liquids. The well-known concept of + quartz + water (albite-absent). Albite-absent singular equithe ‘thermal barrier’ or ‘thermal divide’ implies the librium is relevant for the blueschist–eclogite transition, whereas occurrence of singular equilibria, and their importance garnet-absent equilibrium may control the eclogite to amphibolite in the petrogenesis of granites [e.g. modelled in the binary transition. A complex arrangement of divariant reactions, singular system kalsilite–silica (Lindsley, 1966)] or basalts [e.g. in reactions and conjugate non-degenerate reactions arises in topologies the binary system forsterite–silica or in the ternary system at the blueschist–eclogite–amphibolite transitions. Schreinemakers’ forsterite–silica–diopside or forsterite–silica–anorthite analysis in P–T diagrams, and mixed-variable T–XM′–XC′ and (Presnall et al., 1979)] has been widely discussed. P–XM′–XC′ diagrams suggest that complex pressure–temperature In contrast, the significance and implications of singular paths are not mandatory if a recurrent appearance and disappearance point nets at subsolidus conditions have been largely of similar phase assemblages is observed in paragonite-bearing mafic undervalued. Although Korzhinskii (1963) analysed azeorocks. The P–T location of the singular curve net is discussed in tropic transformations in subsolidus open systems, only the context of Nevado–Filabride Complex mafic rocks. recently have applications to metamorphic assemblages