Conductivity Probe Research Articles

Uncertainty study of two-phase flow distribution characteristics measurement based on bubble trajectory tracking method

Bubbles undergo complex motions such as nonlinear trajectories in two-phase flow, where the position, velocity magnitude, and direction of bubble centers continuously change as they evolve under the influence of forces. The complexity of bubble trajectory increases the difficulty in measuring the flow field distribution characteristics, which has been understudied in the previous. The bubble trajectory tracking model based on the Monte Carlo method is constructed to study the uncertainty of two-phase flow distribution characteristics measurement by the conductivity probe. The Monte Carlo method is adopted to randomly generate the bubble velocity at the initial moment and the bubble force characteristics are embedded to simulate the three-dimensional motion of the bubble. The influence of various factors on the distribution of effective bubble numbers and velocity relative error at the local point is quantitatively analyzed. It is found that the lateral spacing of the sensors has the greatest influence on the measurement results of small-sized bubbles, the accuracy is greatly reduced when the space is larger than the radius of the measured bubbles. Moreover, the measurement accuracy of the probe for medium-sized bubbles is high, and the effect of bubble lateral velocity and aspect ratio on the effective bubble ratio and velocity relative error is negligible. In addition, the maximum measurement range of the probe at local points is investigated which is found to be 4 mm in the lateral direction and 2 mm in the longitudinal direction. Finally, uniformly distributed bubbles are generated in a 20 mm × 10 mm transverse plane and the distribution of the effective bubble ratio of the probe is found to be consistent at different measurement points, which verifies the reliability of the probe measurement.

Neural network based two-phase flow classification in a vertical narrow rectangular channel

Flow Regimes in a vertical narrow rectangular channel of cross-section 20×1cm2 are investigated up-to wispy annular flow using a dense test matrix and double sensor conductivity probe at section mid point. The data from the probe is used to calculate void fraction, velocity of interfaces, and chord length of various flow structures. A five unit self organizing neural network is used to identify various flow regimes by using single point geometrical data of flow structures. Six separate flow regimes are found to exist. A new flow regime is identified and is called rolling-wispy flow. A discussion on boiling crisis is given regarding this flow regime. The resultant flow regime map is compared with various existing maps.

Automated membrane characterization: In-situ monitoring of the permeate and retentate solutions using a 3D printed permeate probe device

Self-driving laboratories and automated experiments can accelerate the design workflow and decrease errors associated with experiments that characterize membrane transport properties. Within this study, we use 3D printing to design a custom stirred cell that incorporates inline conductivity probes in the retentate and permeate streams. The probes provide a complete trajectory of the salt concentrations as they evolve over the course of an experiment. Here, automated diafiltration experiments are used to characterize the performance of commercial NF90 and NF270 polyamide membranes over a predetermined range of KCl concentrations from 1 to 100 mM. The measurements obtained by the inline conductivity probes are validated using offline post-experiment analyses. Compared to traditional filtration experiments, the probes decrease the amount of time required for an experimentalist to characterize membrane materials by more than 50× and increase the amount of information generated by 100×. Device design principles to address the physical constraints associated with making conductivity measurements in confined volumes are proposed. Overall, the device developed within this study provides a foundation to establish high-throughput, automated membrane characterization techniques.

Miniaturized device to measure urease activity in the soil interstitial fluid using wenner method

This paper presents a microdevice developed to measure the electrical conductivity of a liquid or a saturated porous medium using Wenner method. It is developed in the context of biocementation as soil improvement technique, which is used in Civil Engineering applications to produce calcium carbonate through bacterial or enzymatic activity, replacing the use of other binder materials such as cement or resins, and therefore reducing carbon footprint. The microdevice was used to measure urease activity in the soil interstitial fluid, to investigate if bacterial activity could be affected by the presence of the particles and tortuosity from pore geometry. Such analysis is important to understand biocementation mechanism inside the soil and helps to improve the design of such treatment solutions. The device is basically a squared reservoir printed in polypropylene using a 3D printing machine, incorporating stainless steel electrodes in its base. The electrical resistivity was computed adopting Wenner method, by connecting 4 PCB electrodes to a signal generator and an oscilloscope for measuring the voltage when a AC current of 1 mA was applied. Both square and sinusoidal waves with 5 kHz frequency were selected among other frequencies. The measurements were adjusted during the calibration of the microdevice, done using standard salt solutions with known electrical conductivity measured using an electrical conductivity probe. For the bacterial activity measurements, the bacterial and urea solutions were added to a uniform-graded size quarzitic sand (average diameter 0.3 mm) placed inside the microdevice and covering completely the electrodes. Bacterial activity was not affected by the presence of the sand, which confirms that this treatment is effective for this type of soils.

Non-destructive electroluminescence inspection for LED epitaxial wafers based on soft single-contact operation

Non-destructive and accurate inspection of gallium nitride light-emitting diode (GaN-LED) epitaxial wafers is important to GaN-LED technology. However, the conventional electroluminescence inspection, the photoluminescence inspection, and the automated optical inspection cannot fulfill the complex technical requirements. In this work, an inspection method and an operation system based on soft single-contact operation, namely, single-contact electroluminescence (SC-EL) inspection, are proposed. The key component of the SC-EL inspection system is a soft conductive probe with an optical fiber inside, and an AC voltage (70V pp , 100 kHz) is applied between the probe and the ITO electrode under the LED epitaxial wafer. The proposed SC-EL inspection can measure both the electrical and optical parameters of the LED epitaxial wafer at the same time, while not causing mechanical damage to the LED epitaxial wafer. Moreover, it is demonstrated that the SC-EL inspection has a higher electroluminescence wavelength accuracy than photoluminescence inspection. The results show that the non-uniformity of SC-EL inspection is 444.64%, which is much lower than that of photoluminescence inspection. In addition, the obtained electrical parameters from SC-EL can reflect the reverse leakage current (I s ) level of the LED epitaxial wafer. The proposed SC-EL inspection can ensure high inspection accuracy without causing damage to the LED epitaxial wafer, which holds promising application in LED technology.

Study on the internal waves induced by a submerged body moving in a continuously stratified fluid

This paper studies the characteristics of internal waves induced by the motion of a submerged body through a combination of experimental and numerical methods. First, by deploying an array of conductivity probes in an experiment, the temporal evolution of the internal wave at the plane of the conductivity probe array is obtained and compared with numerical simulation results based on the Navier–Stokes equations, thereby validating the accuracy of the Computational Fluid Dynamics (CFD) model. Subsequently, utilizing CFD calculations, further exploration is conducted on the spatiotemporal distribution characteristics of the internal wave, encompassing its generation and evolution, velocity field distribution, wake angle, and wave profile features. Finally, the variation of the internal wave with the Froude number (Fr) is investigated, revealing that it varies apparently with Fr, including the wave component, wave mode, wake length, wake angle, wave amplitude, and so on. It is found that when Fr is large, the internal wave converges toward the centerline behind the body, until forming a line. The wave magnitude changes with Fr in four stages, i.e., increasing with Fr from zero in the first stage, reaching a peak and decreasing thereafter in the second stage, then changing little in the third stage, and finally increasing approximately linearly in the fourth stage.

Design of a first-of-A-kind instrumented advanced test reactor irradiation Capsule experiment for In situ thermal conductivity measurements of metallic fuel

Metallic fuel undergoes dramatic microstructural changes early in life due to fission gas swelling until ∼2–3 at% burnup which affects the conductivity of the material, however the evolution of metallic fuel thermal conductivity during this early phase burnup has never been successfully measured in situ. The Irradiated Material Properties Accelerated Characterization Test (IMPACT) experiment will be the first in a series of experiments to irradiate advanced nuclear metallic fuel specimens with novel embedded thermal conductivity probes in ATR. In the current work the IMPACT experiment final design and supporting analysis is reported in detail. Results are evaluated for various reactor operational conditions to meet the functional requirements of the experiment. The first iteration of this IMPACT experiment will provide data regarding thermal properties evolution in uranium-zirconium (U10Zr) fuel, but this experiment vehicle is envisioned for future advanced fuels and structural materials irradiations in ATR.

Phase distribution characteristics in 5 × 5 bowing rod bundles

During operation of the nuclear power plant, fuel rods tend to bend. In order to accurately predict the thermal-hydraulic phenomena in the rod bundles with bowing rod, the profile of local parameters in two-phase flow is greatly important. In this study, experiments were conducted in 5 × 5 rod bundle channel with a bowing rod. Four different bow deformation ratios (0%, 50%, 80% and 100%) were adopted for the bowing rod. Measurements were performed using a four-sensor conductivity probe to assess local parameters in two-phase flow, including interfacial area concentration (IAC), bubble chord length, void fraction and bubble velocity. The results indicate that, after passing through the bowing section, the void fraction changes from a wall-peak distribution to a core-peak distribution. The distribution of the local parameters at L/D = 78.6 and L/D = 102.1 are almost identical, suggesting that the dissipation length of the bowing section is greater than 23.5 (102.1–78.6) L/D. The void fraction reaches highest in the center of the subchannel with a bowing rod and increases with an increase in bow deformation ratio. In the bowing rod bundle channel, both of the void fraction and bubble chord length increase with the increase of gas velocity, especially in the region of the inner subchannel. Finally, based on the measured local parameters such as bubble velocity and void fraction, a new distribution parameter model in the subchannel with a rod bow deformation ratio of 80% was proposed.

A machine-learning-aided data recovery approach for predicting multi-material thermal behaviors in advanced test reactor capsules

Instrumented experiments conducted at test reactors are essential to the deployment of new advanced reactor systems. Designing new experiments and generating data on specific reactor conditions require significant investments in terms of both time and cost. Finite element analysis software can be used to create high-fidelity models of experiment environments in order to support the actual experiments, but computation time remains a concern in terms of applying outcomes to real-time usage of data (e.g., a digital twin [DT]). The present research proposes a machine-learning (ML) aided approach to making temperature and displacement predictions based on the thickness of the outer gas gap on the experimental capsule used for in-pile demonstration of a novel new thermal conductivity probe in the Advanced Test Reactor (ATR). This capsule consisted of U10Zr fuel, a rodlet, sodium, and inner and outer capsules. Gas gaps existed between the fuel and the rodlet, and between the inner and the outer capsule. The learning data pertained to an experimental capsule's radial distributions of temperature and displacement, as obtained based on Abaqus and the physical features. For the first step of ML sequence, the temperature was predicted using three positional parameters. Next, the displacement was predicted using seven additional parameters. Each physical feature was normalized in order to be both nondimensional and standardized. The temperature and displacement predictions showed good agreement with the simulation results in all cases involving interpolation and extrapolation. Furthermore, data similarity enhancement increased the similarity between the training and the target data, thereby increasing the predictive accuracy of the ML models. In certain extrapolation cases involving limited original ML model accuracy, data similarity enhancement and data recovery was able to somewhat improve this accuracy.

Local characteristics of bubbly flow in rods assembly 3 × 3

This study focuses on the experimental investigation of local characteristics of upward bubble flow in a 3 × 3 square rod bundle assembly. The experiments were conducted at Reynolds numbers ranging from 4000 to 11000 and gas void fractions up to 10%. The distribution of the gas phase around the central rod of the assembly was measured using a frontal conductivity probe, while the wall shear stress on the central rod was obtained through the electrodiffusion method. It is shown that the gas phase distribution does not exhibit the symmetry characteristic of the assembly cross-section. Furthermore, as the distance from the spacer grid increases, a reconfiguration of void fraction profiles is observed. This explains the non-monotonic dependence of wall shear stress and wall shear stress fluctuations on the distance to the spacer grid.

Experimental study of internal solitary wave evolution beneath an ice keel model

Internal solitary waves (ISWs) propagating in polar seas are affected by the sea ice at upper boundary of seas and thus exhibit complex evolution characteristics. Herein, spatiotemporal changes in the wave element, flow field, and energy of ISWs beneath an ice keel model were investigated to examine the evolution of ISWs. For this purpose, laboratory experiments were conducted using dye-tracing labeling, conductivity probes, Schlieren technology, and particle image velocimetry. The results show that ice keel causes an increase in the thickness of the pycnocline and even the occurrence of breaking and internal surging of ISW. Additionally, the waveform becomes narrower or wider at different positions, and wave amplitude and speed decrease, with a maximum reduction 30%–40%. Furthermore, the ice keel strengthens the shear of the ISW-induced flow field, generating vortices and mixing. The energy of ISWs undergoes internal conversion majorly at the front slope of the ice keel, while energy dissipation occurs largely at the back slope, with dissipation rates as high as 60%.

Online monitoring of continuous aqueous two-phase flotation (ATPF) for the development of an autonomous control strategy

Aqueous two-phase flotation (ATPF) is a separation technique for isolating biological products such as enzymes from crude complex biosuspensions. The continuous operation mode of ATPF allows high throughput while maintaining a high separation efficiency. In this work, a laboratory plant for continuous ATPF with integrated online measurement technology is presented and ATPF experiments with the model enzyme phospholipase A2 are performed. Three electrical conductivity probes allow real time and spatially resolved characterization of phase mixing in the flotation tank caused by rising bubbles. UV/Vis spectroscopy is used to measure the enzyme concentration online at the top phase outlet. The equilibrium concentrations in the top and bottom phase are linearly dependent on the feed concentration, revealing a constant partition coefficient. The experimental results of this work provide the basis for the development of an autonomous feedback controller for the continuous ATPF process.

Stratified water columns: homogenization and interface evolution

Stratified water columns are often found in lakes and oceans. Stratifications result from differences in density due to salt concentration, temperature, solid content and oxygenation. The stability of stratifications affects bioactivity, sedimentation, contaminant transport and environmental remediation. This study investigates the evolution of 6 stratified water columns created by differences in salinity, suspended minerals and the presence of a bottom heat source. We use acoustic wave reflection, photography, and both electrical conductivity and temperature profiles to track changes in stratification. Results show that multiple concurrent processes emerge across layers in otherwise quiescent water bodies. Dissimilar chemo-thermo conditions give rise to chemical and thermal diffusion, convection, and double-diffusion convection. When stratification involves suspended particles, interlayer processes include diffusiophoresis, flocculation/aggregation, sedimentation, osmosis, and chemo-consolidation; in this case, the specific surface and surface charge of suspended particles, and the salt concentration in contiguous layers determine aggregation-sedimentation-consolidation patterns. The interlayer transition zone acts as a high-pass filter that preferentially reflects low-frequency long-wavelength P-waves; invasive thermal and electrical conductivity probes provide complementary information and may identify stratification even when it is undetected by acoustic signals.

Strong Covalent Coupling in Vertically Layered SnSe2/PTAA Heterojunctions Enabled High Performance Inorganic-Organic Hybrid Photodetectors.

Controllable large-scale integration of two-dimensional (2D) materials with organic semiconductors and the realization of strong coupling between them still remain challenging. Herein, we demonstrate a wafer-scale, vertically layered SnSe2/PTAA heterojunction array with high light-trapping ability via a low-temperature molecular beam epitaxy method and a facile spin-coating process. Conductive probe atomic force microscopy (CP-AFM) measurements reveal strong rectification and photoresponse behavior in the individual SnSe2 nanosheet/PTAA heterojunction. Theoretical analysis demonstrates that vertically layered SnSe2/PTAA heterojunctions exhibit stronger C-Se covalent coupling than that of the conventional tiled type, which could facilitate more efficient charge transfer. Benefiting from these advantages, the SnSe2/PTAA heterojunction photodetectors with an optimized PTAA concentration show high performance, including a responsivity of 41.02 A/W, an external quantum efficiency of 1.31 × 104%, and high uniformity. The proposed approach for constructing large-scale 2D inorganic-organic heterostructures represents an effective route to fabricate high-performance broadband photodetectors for integrated optoelectronic systems.

Landau Theory of Altermagnetism.

We formulate a Landau theory for altermagnets, a class of collinear compensated magnets with spin-split bands. Starting from the nonrelativistic limit, this Landau theory goes beyond a conventional analysis by including spin-space symmetries, providing a simple framework for understanding the key features of this family of materials. We find a set of multipolar secondary order parameters connecting existing ideas about the spin symmetries of these systems, their order parameters, and the effect of nonzero spin-orbit coupling. We account for several features of canonical altermagnets such as RuO_{2}, MnTe, and CuF_{2} that go beyond symmetry alone, relating the order parameter to key observables such as magnetization, anomalous Hall conductivity, and magnetoelastic and magneto-optical probes. Finally, we comment on generalizations of our framework to a wider family of exotic magnetic systems derived from the zero spin-orbit coupled limit.

Nanoscale mapping of relativistic photocarrier transports in epitaxial graphene surface and edge states

We report the direct mapping of photo-transport properties of relativistic carriers generated on terrace-surface and terrace-edge structures of epitaxial graphene grown on silicon carbide. In this method, a conductive probe made a direct contact with epitaxial graphene and scanned the surface, allowing us to map the topography, current, and noise of graphene with nanoscale resolutions via a scanning noise microscopy. The maps were further analyzed by a two-dimensional network model to obtain the sheet-conductance (S□) and noise-source density (neff) distributions of epitaxial graphene. The topography image showed the formation of terraces, which could be attributed to the different decomposition rate of silicon atoms during the graphene growth. The terraces of graphene exhibited uniform S□, being separated by one-dimensional terrace-edges. Interestingly, terrace-edges exhibited a rather large neff with a power-law relationship of S□ ∝ neff−0.5, indicating a typical hopping conduction. However, in terrace-surfaces, sheet-conductance was nearly independent on neff, which was attributed to the relativistic nature of charge carriers unaffected by charge-trapping potential. Notably, under illumination, we observed the relativistic behavior of photocarriers in overall graphene terraces, presumably because photocarriers were generated through charge-transfer complexes formation at epitaxial graphene/substrate interface without the participation of noise-sources. Interestingly, we observed nearly homogeneous photoconductance and neff, which could be possibly due to the merger of one-dimensional edge-states into two-dimensional surface-states. The mapping of photoconductance and photo-traps provides valuable insights into the generation of relativistic photocarriers in epitaxial graphene.

An experimental investigation of void fraction characteristics of flow boiling in a 5×5 rod bundle channel

Flow boiling in the rod bundle channel is an important phenomenon in nuclear reactors. The local inhomogeneous void fraction distribution in the flow channel will affect the flow and heat transfer in two phase flow. A 5 × 5 rod bundle test section is designed and utilized in the experiments and a conductivity probe is utilized to measure the local void fraction of two phase flow. A remote-control stepping driving assembly is designed to drive the void probe. The local void fraction characteristics at the outlet of a 5 × 5 rod bundle channel during subcooled boiling and saturated boiling are experimentally studied when the system pressure is 2∼3 MPa. The outlet subcooling ranges from 0 °C to 18 °C. The mass flux is 2000 kg/m2s and the heat flux ranges from 186.3 kW/m2 to 320.8 kW/m2.The effects of thermal parameters on local phase interfacial parameters in subcooled boiling and saturated boiling are obtained. The research results are important for revealing the two phase flow mechanisms in rod bundle channels.

Groundwater Protection Assessment using Frequency Domain Electromagnetic Method and Direct Current Electrical Resistivity Method in Papalanto South-West Nigeria

The aim of this work is to assess the extent of protection of the subsurface hydrogeological structures. Fieldworks were performed integrated geophysical techniques namely Frequency Domain Electromagnetic Method (FDEM) using Geonics-EM-34 to determine the vertical and lateral variations of subsurface conductivity probing depths of 20m, 40m and 60m, while subsurface profiles were obtained using Direct Current Resistivity (DCRE) with AGI Super-sting Earth Resistivity meter; current electrode spacing (AB) ranging from 1 to maximum of 100m and the potential electrodes (MN) were consequently changed from 0.25m to 5m respectively. 1141.92 mmho/m was recorded as the highest true conductivity value for the Horizontal Dipole in the second layer (Profile EMPAP5) while the highest true conductivity value for the Vertical Dipole in the first layer was 134.31 mmho/m (Profile EMPAP1). Four principal geoelectric layers inferred from the VES data where the Topsoil is partly lateritic and alluvium, Sandy Clay/Clay/Silt, Sand/Clay/Shale, and Limestone/Sandstone. Resistivity values for these layers vary from 9.78 to 1428, 1.46 to 1057, 1.46 to 451, and 15 to 10,000 Ω m with corresponding thickness of 0.5m to1.43m, 1.29m to 13m, 2.8m to 84.4m and infinity, respectively. The higher resistivity values at the surface and extremes of both edges were indication of little or no presence of leachates or contaminant plume accumulation in other area. Also, there was a noticeable general decrease of resistivity values of formation rock with depth in these investigated areas; this is an indication that the plumes must have infiltrated rapidly into the subsurface through the massive presence of weathered rock materials of average lateral distances of 15m to 167m of considerable depth and thickness of about 24.9m. The degree of leachate contamination range from 0.0007264 mho to 0.668 mho with the highest value in VESPAP2 followed by VESPAP13 and VESPAP19 while VESPAP22 exhibited the lowest conductance.

ПОЛУЧЕНИЕ И ИССЛЕДОВАНИЕ ПОЛИМЕРНЫХ НАНОЧАСТИЦ

Currently, there is an increasing interest in the study of polymers in a nanodisperse state. Since polymer materials, as a rule, are heterogeneous systems with a sufficiently variable surface, a correct assessment of their chemical structure, physical properties and morphology is of great scientific and practical importance. Polymer nanoparticles (PNPs) have been successfully studied for a long time as nanoscale colloidal particles obtained from polymers. Research on HDPE is most intensively conducted in the field of nanomedicine, and the possible application of HDPE in the field of optoelectronics, photonics, gadgets, sensors, sensors, and new nanocomposites is of great interest to researchers. An independent task is to compare the properties of the HDPE with the properties of a bulk polymer, including the features of its supramolecular structure. Previous studies of the supramolecular structure of PDFs have suggested that charge transfer in the polymer during resistive switching occurs along the grids of intergranular boundaries. This paper presents the results of an experimental study of polymer nanoparticles on different substrates by atomic force microscopy. The main metrological parameters of polymer nanoparticles were determined, the results were compared with the available data on the supramolecular structure of polymer films. The possibility of using atomic force microscopy techniques to visualize polymer nanoparticles on dif- ferent substrates has been demonstrated. Using the AFM method with a conductive probe, it was found that in some cases, during the aggregation of nanoparticles on a metal substrate, charge transfer is realized along separate nanometer-sized sections. The conducting channels in the current image have the form of separate points with a height corresponding to the locally flowing current. It was found that the arrangement of the observed channels correlates well with the model of conductivity along the grain boundaries of the supramolecular structure of the polymer. The issues of interpretation of current images of polymer nanoparticles and the physical model of charge transfer in polymer nanostructures are discussed. The work was carried out with the support of the Mirror Labora- tories project of the National Research University Higher School of Economics and an intra-university grant from the Bashkir State Pedagogical University named after M. Akmulla.

Shape reconstruction of axisymmetric Taylor bubbles using conductivity probes through a scheme of combined experiment and theory.

A simple measurement scheme is proposed to reconstruct the geometry of an axisymmetric void propagating through a conducting liquid using a pair of parallel wire conductivity probes. An experimental study allows for obtaining the time variation of the resistance of the film surrounding the void. Analytical modeling and numerical simulation has been adopted to correlate the resistance between the wire electrodes and the film thickness. Finally, the shape of the void can be estimated by combining the predicted resistance-film thickness relationship and the measured time variation of resistance. For validation, this scheme has been used to reconstruct the shape of a rising Taylor bubble. There is a fair match between the reconstructed shape of the bubble and its photographic image. The probable errors in the measurement scheme have been discussed and assessed mathematically.