Greenschist-facies Conditions Research Articles

Deformation Pattern of Well-Preserved High-Pressure Rocks (SE Syros, Cyclades)

New, detailed geological/structural mapping and field-based structural analysis were carried out to investigate the deformation pattern of well-preserved high-pressure rocks of the Blueschist Unit exposed in SE Syros (Cyclades, Greece). Geological mapping revealed the occurrence of extensive alternations between different rock groups, as well as interfingering patterns in map-scale that are possibly the result of folding. The earlier ductile deformation phase recognized in the mapped area is associated with the development of a penetrative foliation, which was formed at eclogite/blueschist-facies conditions under peak metamorphism. The subsequent main deformation phase occurred under blueschist facies conditions synchronous with the early stages of exhumation of the high-pressure rocks. This phase is mainly associated with the formation of WNW-trending folds and a pervasive axial planar foliation linked with ESE-directed shearing. The main deformation ceased under blueschist-facies conditions, and exhumation of the rocks to greenschist-facies conditions took place under very weak and localized deformation. Greenschist retrogression observed in the southwestern part of the mapped area seems to be controlled by fluids, rather than by intense deformation and formation of major syn-greenschist shear zones.

Tonian Continental Arc Magmatism of the Porongos Complex, Dom Feliciano Belt, Southern Brazil

This study provides new information on the deformation, metamorphism, and tectonic setting of the metavolcanic rocks of the southern portion of the Porongos Complex, southern Brazil. The structural analysis enabled the identification of three deformational phases, formed under ductile to semi-ductile conditions. D1 progressed through deformation partitioning, comprising closed to isoclinal folds and an axial plane foliation. Then, simple shear prevailed, resulting in isoclinal folds, sigma-type porphyroclasts, foliation transposition, and mylonitic rocks. D2 comprises open to gentle folds and an axial plane cleavage. The formation of shear bands is ascribed to the semi-ductile D3. The mineral assemblage represented by phengite + chlorite + clinozoisite-epidote + actinolite + albite + quartz associated with the temperatures obtained through the chlorite geothermometer (316°C) indicates greenschist facies conditions. The protoliths of these metavolcanic rocks are geochemically discriminated as calc-alkaline, dacite-to-rhyodacite, with peraluminous compositions. The bulk trace element compositions show enrichment in large-ion lithophile elements and light rare-earth elements and depletion in heavy rare-earth elements. Also, negative Nb, P, Ti, and Ta anomalies are observed in the multielement diagram. All these geochemical features are typical of rocks formed in continental magmatic arcs. Geochemical comparison with other pre-collisional Tonian orthometamorphic rocks from the Dom Feliciano Belt demonstrates strong similarities, which corroborates the prior interpretation of a continental arc setting for the origin of these Tonian rocks.

Extrusion tectonism of Indochina reassessed: constraints from 40Ar/39Ar geochronology from the Day Nui Con Voi metamorphic massif, Vietnam

The extrusion tectonic model for the southeastern margin of the Himalayan orogeny links the crustal shear activity along the Red River Shear Zone (RRSZ) to the opening of the South China Sea (SCS). The Day Nui Con Voi (DNCV) metamorphic massif in northern Vietnam strikes NW-SE, is bounded by the RRSZ to the south and continues along the strike where it meets the SCS. The DNCV is thus a critical area to document thermotectonic history in order to advance our understanding of the tectonic evolution of Indochina extrusion and its relationship to the opening of the SCS. Our new 40Ar/39Ar data combined with microstructural and petrological analyses constrained the timing of the left-lateral shearing of the RRSZ and revealed the thermal evolution of the DNCV metamorphic massif. Three ductile deformation events were observed. D1 formed NNW-SSE striking upright folds under granulite to upper amphibolite facies conditions. D2 was a horizontal to sub-horizontal folding event that occurred at amphibolite facies conditions. D3 was a doming event that formed NW-SE striking up-right folds bounded by left-lateral shearing mylonite belts along the two limbs. The S/C fabrics were defined by muscovite fish, quartz + albite + K-feldspar aggregates, and muscovite folia. The D3 doming event exhumed the DNCV metamorphic massif from amphibolite facies conditions to the lower greenschist facies conditions. The 40Ar/39Ar ages obtained from amphibole (∼26 Ma), phlogopite (∼25 Ma), muscovites (∼24-23 Ma), biotite (∼25-23 Ma), and K-feldspars (∼25-22 Ma) from different structural domains of the DNCV metamorphic massif indicated a rapid exhumation ∼26–22 Ma. We interpreted this as the time period for the D3 event, with the onset of left-lateral shearing occurring around 24 Ma based on ages obtained from syn-kinematic muscovites. This age was much younger than the initiation of sea-floor spreading of the SCS (since 32 Ma) but coincided with the age for the ridge jump event in the SCS. Based on these new data, we proposed that extrusion tectonism cannot be the cause for the initial opening of the SCS. Rather, the extrusion of the Indochina block was temporally correlative with the southward ridge jump event of the already opened SCS.

Gabbroids of the Bazhenov gabbro-hyperbasite massif (Middle Urals): Material composition and age

Research subject. Saussurite-amphibole rocks (metagabbroids) of the Bazhenov gabbro-hyperbasite massif (eastern sector of the Middle Urals).Materials and methods. The material composition of metagabbroids and their mineralogy were studied in the analytical laboratories of the Institute of Geological Geology, Ural Branch, Russian Academy of Sciences (Ekaterinburg), Urals State Mining University (Ekaterinburg), Institute of Mineralogy, Ural Branch, Russian Academy of Sciences (Miass), Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences (Moscow), and Moscow State University (Moscow). Isotope analyzes of zircon were performed on a SHRIMP-II ion microanalyzer at the Center for Isotope Research of VSEGEI (St.Petersburg).Results. The metagabbroids under study feature the following mineral composition: clinozoisite (zoisite, epidote), magnesian hornblende (pargasite, tremolite), albite, clinochlore, and dolomite. According to petro-geochemistry data, saussurite-amphibole rocks were formed after gabbronorites and olivine gabbro-norites, belonging to the alpine-type formation of gabbro-hyperbasite complexes. U-Pb dating showed the ancient age of zircons from metagabbroids, most of the analyzes are grouped below the concordia line, forming a discordia line, the upper intersection of which with the concordia corresponds to the age of 1992 Ma. Two points on the diagram located below the concordia line, although not falling on the continuation of the discordia line, apparently reflect the influence of intermediate stages of metamorphism, and two points with concordant ages of 256 and 251 Ma record the time of the last tectono-thermal episode.Conclusions. The formation of saussurite-amphibole rocks took place under the conditions of greenschist facies. In local areas of the massif, metamorphism reached the zeolite facies with signs of hydrothermal reworking. The primary gabbroids of the Bazhenov massif were most likely formed under the conditions of a suprasubduction basin. The age of zircons of about 2 Ga obtained by the U-Pb method indicates that the crystallization of the studied zircons occurred in the mantle rocks. It is not yet possible to unambiguously explain the presence of grains of these zircons in the metagabbroids of the Bazhenov massif; several possible explanations have been proposed. Zircons with the youngest age (256 and 251 Ma) were most likely formed as a result of metamorphic transformations under thermal influence from the nearby Aduy granite-leucogranite complex.

Monazite and xenotime petrochronologic constraints on four Proterozoic tectonic episodes and ca. 1705 Ma age of the Uncompahgre Formation, southwestern Colorado, USA

Abstract The Proterozoic tectonic evolution of the southwestern USA remains incompletely understood due to limited constraints on the timing and conditions of the tectono-metamorphic phases and depositional age of metasedimentary successions. We integrated multi-scale compositional mapping, petrologic modeling, and in situ geochronology to constrain pressure-temperature-time paths from samples of Paleoproterozoic basement gneisses and overlying quartzites in southwestern Colorado, USA. Basement gneiss from the western Needle Mountains records metamorphic conditions of 600 °C at 0.75 GPa at 1764 ± 9 Ma and ~575 °C at 1741 ± 10 Ma. Gneiss sampled from drill core near Pagosa Springs, Colorado, records conditions of 700 °C at 1748 ± 9 Ma, 800 °C at 1.1 GPa at 1650 ± 40 Ma, 540 °C at 1570 ± 36 Ma, and 440 °C at 1424 ± 12 Ma. The Uncompahgre Formation was deposited at ca. 1705 Ma, as constrained by detrital monazite (1707 ± 8 Ma) and xenotime (1692 ± 40, 1725 ± 50 Ma), metamorphic xenotime (1650 ± 10 Ma), and published 40Ar/39Ar and detrital zircon data. Compositions of ca. 1705 Ma detrital monazite and xenotime are consistent with derivation from a garnet-bearing source in the Yavapai orogenic hinterland. The Vallecito Conglomerate and Uncompahgre Formation record macroscopic folding and greenschist-facies metamorphism at 1650 ± 10 Ma and temperatures of 270 °C to >570 °C at 1470–1400 Ma. Laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) zircon geochronology yielded dates of 1775 ± 18 Ma from the Twilight Gneiss and 1696 ± 7 Ma from the Bakers Bridge Granite, supporting previous isotope dilution–thermal ionization mass spectrometry (ID-TIMS) dates. The Eolus Granite yielded a date of 1463 ± 6 Ma, which is older than previous 1.44–1.43 Ga ID-TIMS dates. The newly dated granite of Cataract Gulch is 1421 ± 12 Ma. In situ analysis of detrital and meta-morphic monazite and xenotime, igneous zircon, and quantitative thermobarometry, integrated with previously published constraints, indicate multiple tectonic episodes after the emplacement of 1800–1760 Ma arc-related rocks. The region experienced greenschist- to amphibolite-facies metamorphism (M1) from 1760 Ma to 1740 Ma, which was followed by the intrusion of granites at 1730–1695 Ma and deposition of the Uncompahgre Formation at ca. 1705 Ma, contemporaneous with the Yavapai orogeny. Metamorphism at 1680–1600 Ma was characterized by greenschist-facies conditions near Ouray, Colorado, and granulite-facies conditions near Pagosa Springs (M2) during the Mazatzal orogeny. From 1470 Ma to 1400 Ma, greenschist- to amphibolite-facies metamorphism (M3) and largely granitic plutonism occurred during the protracted Picuris orogeny. These results demonstrate the power of monazite and xenotime analyses to constrain depositional ages, provenance, and pressure-temperature-time (P-T-t) paths to resolve the compound orogenic history that is characteristic of most mountain belts.

Drowned in granite - retrieving the tectono-metamorphic history of the Janub metamorphic complex, the northernmost part of the Arabian-Nubian Shield

The Janub Metamorphic Complex (JMC) in southern Jordan provides new correlative data constraining the transition from compressional to extensional tectonics in the northern Arabian-Nubian Shield. This constraint comes from the identification of extensional mylonitic shear zones affecting both the JMC and some intruding granitoids. The JMC comprises metamorphosed andesitic-dacitic-rhyolitic flows and pyroclastics, meta-volcanogenic sediments, and hornfels. Volcanism ceased by 618 ± 5 Ma. The volcanosedimentary sequence formed in an intra-arc basin in a mature island arc and was then buried and regionally metamorphosed at lower greenschist facies conditions in the waning accretionary phase between 618 and 615 Ma. This is based on the age of crosscutting plutons of the Rumman Suite, which triggered local high-T/low-P metamorphism at ∼ 615 Ma. Rumman granitoids and JMC rocks were deformed by narrow gently-dipping mylonitic shear zones, interpreted as extensional, that ceased operating by 605 Ma, the age of crosscutting undeformed dikes and plutons of the Yutum Suite. At 596 Ma, a late granite intruded the JMC and thermally metamorphosed some of the meta-sediments. This granite was deformed in a Najd-related brittle shear zone at ∼ 590 Ma as recorded by 40Ar/39Ar geochronology. The JMC can be correlated with the higher-grade Abu-Barqa Metamorphic Complex (ABMC), despite tectonics relations being obscured by younger intrusive rocks. The main metamorphic phase in the ABMC occurred at a depth of 18 km at ∼ 620–615 Ma, followed by gradual uplift and high-T metamorphism at 615–610 Ma and exhumation to the surface at ∼605 Ma. Extensional shearing in the JMC and exhumation of the ABMC probably developed in a core-complex like setting triggered by orogenic collapse. Ductile shearing related to collapse ceased before 605 Ma. The 590 Ma brittle shear zone is the first dated Najd-related structure from the basement of Jordan. The central setting of our data allows correlation of metamorphic complexes in Sinai and Saudi Arabia and is consistent with the final assembly of Gondwana, initiation of orogenic collapse, and transition to extensional tectonics occurring at ∼ 620–610 Ma in the northern Arabian-Nubian Shield.

The Maira-Sampeyre and Val Grana Allochthons (south Western Alps): review and new data on the tectonometamorphic evolution of the Briançonnais distal margin

Here we describe the structure, the high-pressure, low-temperature (HP-LT) metamorphism and tectonic evolution of the Briançonnais distal margin units from the south Western Alps. The studied area extends southwest of the Dora-Maira (U)HP basement units and east-southeast of the classical Briançonnais nappes. A new structural map accompanied by geological profiles shows the thrusting of the oceanic nappes (Monviso and Queyras units) onto the distal Briançonnais units (D1 and D2 late Eocene deformation phases) under blueschist-facies conditions. Subsequent deformation during the Early Oligocene (D3 deformation phase) took place under greenschist-facies conditions and was associated with back-folding and -thrusting in the units overlying the Dora-Maira massif and with exhumation related to normal reactivation of former thrusts within the latter massif. Two large cover units, detached from their former distal Briançonnais basement, are redefined as the Maira-Sampeyre and Val Grana Allochthons (shortly: Maira-Grana Allochthons = MGA) including, (i) the Val Maira-Sampeyre unit involving Lower and Middle Triassic formations, seemingly detached from the Dora-Maira units during the subduction process, and (ii) the Val Grana unit with Middle-Upper Triassic and Early-Middle Jurassic formations, which was probably detached from the Maira-Sampeyre unit and correlates with the “Prepiemonte units” known from the Ligurian Alps to the Swiss Prealps. Three major shear zones involving tectonic mélanges of oceanic and continental rocks at the base of the Val Grana, Maira-Sampeyre and Dronero units testify to an early phase of exhumation within the subduction channel in front of the Adria plate. We present a new metamorphic map based on published and new petrological data, including new thermometric data obtained by Raman spectroscopy of carbonaceous material (RSCM). The TRSCM values range from ~ 400 °C to > 500 °C, going from the most external Val Grana unit and overlying Queyras schists to the uppermost Dora-Maira unit. During the Late Triassic, the width of the Briançonnais s.l. domain can be restored at ~ 100 km, whereas it reached ~ 150 km after the Jurassic rifting. A significant, second rifting event affected the Briançonnais domain during the Late Cretaceous-Paleocene, forming the Longet-Alpet chaotic breccias, which deserve further investigations.

Tectonic setting, fluid inclusion and gold mineralization of the southwest Poli region (northern Cameroon Domain)

This paper documents original petrographic and structural data on metamorphic and magmatic rocks as well as the occurrence of gold mineralization in the Dourou Tchaga area (SW Poli) in the northwestern Cameroon domain. The study area is dominated by high-grade gneisses derived from a volcanic-sedimentary series alternating with orthogneiss and magmatic rocks. Four main deformation stages were distinguish comprising the early D1 and D2 deformations showing ductile behavior under amphibolite to granulite facies, followed by retrogression into greenschist facies. D3 and D4 are characterized by ductile-brittle and late brittle structures. Gold mineralization is hosted in laminated quartz veins in steeply dipping, ENE–WSW-trending, sinistral shear zone developed during D3. Host rocks are high-grade metamorphic paragneiss and orthogneiss. Ore minerals include native gold, galena, sphalerite, pyrite and chalcopyrite; wall rock alteration assemblage includes stable pyrite, magnetite and hematite. This assemblage together with specific quartz microstructures indicate gold mineralization at lower greenschist facies conditions. Gold is disseminated in quartz veins and wall rock alteration zones, where it occurs as free grains but also as inclusions in pyrite and sphalerite. Two types of fluid inclusions are distinguished: aqueous-carbonic CO2–H2O and aqueous (H2O), both with low to moderate (2.0–13.9 wt% NaCleq) salinity and variable CO2 content of 13–23 mole% for the aqueous-carbonic fluid inclusions. Fluid inclusions data and alteration assemblage provide evidence that gold precipitation in quartz veins occurred in response to an increase in fO2 caused by fluid pressure fluctuations in the shear zone. Gold mineralization in the northern Cameroon domain was formed during post-collisional stage and retrograde exhumation of the terrane in the greenschist facies toward the end of the Panafrican Orogeny.

An evolutionary model and classification scheme for nephrite jade based on veining, fabric development, and the role of dissolution–precipitation

Although nephrite jade has been collected and treasured since the Stone Age, we lack a clear understanding of how it forms during deformation and metasomatism in shear zones. Using microstructural analysis of samples from Taiwan, California, and New Zealand, we propose a conceptual model for the evolution of nephrite jade that distinguishes four nephrite types based on mode of formation and textural characteristics: (1) primary (type 1a) or folded (type 1b) vein nephrite, (2) crenulated nephrite (type 2), (3) foliated semi-nephrite (type 3), and (4) nodular or domainal nephrite (type 4). We interpret the texture of our analysed samples to represent snapshots of a progressive textural evolution similar to that experienced by other deformed and fine-grained metamorphic rocks that develop under fluid-present, greenschist-facies conditions. Our observations suggest that types 2 and 3 nephrite can evolve from vein nephrite (type 1) by the development of crenulated and foliated metamorphic fabrics, during which the most important deformation process is dissolution–precipitation. However, development of metamorphic fabrics can be interrupted by transient brittle deformation, leading to the formation of type 4 nephrite that is characterised by nodular or angular clasts of nephrite in a nephritic matrix.

Features of Geological Structure and Mineragenic Specialization of Sheikhdzheyli-Zengiboba of the Sultan-Uvais Ridge Area

The productive mineralization of the Sheikhdzheili-Zengiboba area is associated with metamorphogenic transformations of the rocks of the Urusai, Karauzyak, Kuyanchik, Sheikhdzheili suites, metamorphosed under conditions of green schist facies. The mineralized zones of the site are confined to narrow faults in the tectonic zones of the northeast and northwest directions. The main form of manifestation of gold-bearing mineralization is small steeply dipping veins, lenses, nests, non-extended systems of conformal and secant quartz veinlets containing dissemination of pyrite, arsenopyrite, chalcopyrite and pyrrhotite, which are represented by gold-arsenopyrite-pyrite, gold-arsenopyrite-chalcopyrite-pyrite natural type of ores.

Eburnean/Trans-Amazonian orogeny in the Nyong complex of southwestern Cameroon: Meta-basite geochemistry and metamorphic petrology

New and published geochemical, petrologic, and geo-thermobarometric data of meta-basites were combined to constrain the geodynamic evolution of the Paleoproterozoic Nyong complex (NyC) in southwestern Cameroon, a part of the Central African tectonic belt. Their geochemical signatures, including (La/Yb)N = 0.53–56.26, slightly positive Eu anomalies (0.21–1.04), abundance of Pb and U, negative Nb–Ta anomalies, and REE depletion, suggest various degrees of partial melting of mostly spinel-bearing mantle sources. In addition, the meta-basite protoliths can be classified as IAB-, E-MORB-, N-MORB-, and exceptionally OIB-compositional types with minor crustal contamination. Petrologically, the meta-basites are characterized by coronitic textures, marked by microblasts and porphyroblasts of garnet surrounded by plagioclase or by both plagioclase and clinopyroxene, indicating metamorphic recrystallization under decompression. Our new geo-thermobarometric data outline various segments of an overall clockwise pressure‒temperature path. In the different meta-basite samples, the pressure peak at eclogite-facies conditions (∼625 °C, 11.7 kbar) was followed by nearly isobaric heating to amphibolite-facies conditions (600–690 °C, 11.5 kbar) or decompression and heating to amphibolite- (∼740 °C, 10.8 kbar) and granulite-facies (∼800 °C, 10.0 kbar) conditions. The retrograde path evolved from granulite- (850–750 °C, 11.3–7.6 kbar) and amphibolite- (790–550 °C; 12.4–3.0 kbar) to epidote-amphibolite- (∼600‒490 °C, 8.0–7.6 kbar) and greenschist-facies (∼400 °C, 4.2 kbar) conditions. Combining the new with published, in general high to middle temperature-middle pressure data from various rock types, with published high temperature-high pressure data from eclogites highlights distinct burial-exhumation paths for the NyC rocks: these paths document a clockwise pressure-temperature evolution, typical for a collisional setting associated with the Rhyacian-Orosirian Eburnean/Trans-Amazonian orogeny in Cameroon. The eclogite data outline a deep burial–isothermal decompression evolution, typical for a subduction setting predating the collisional setting.

U-Pb zircon-titanite-apatite age constraints on basin development and basin inversion in the Kiruna mining district, Sweden

To constrain the tectonothermal evolution of the type locality for iron oxide-apatite deposits, we have obtained U-Pb zircon, titanite, and apatite age data for the Kiruna mining district in northernmost Sweden. The results indicate that the host basin initiated in an overall extensional regime as indicated by the deposition of alluvial conglomerates and greywackes. A volcanic intercalation in a conglomerate unit approximately 1 km northwest of the Luossavaara iron oxide-apatite deposit yields a U-Pb zircon concordia age of 1887 ± 3 Ma representing the timing of the earliest Orosirian volcanism in the central Kiruna mining district coinciding with the onset of basin development. In-situ analysis of titanite sitting on hydrothermally altered fracture planes within a cataclastic fault damage zone (c. 270 m from the fault core system associated with the Luossavaara iron oxide-apatite deposit) yields complex U-Pb data. Applying a strict discordance filter yields seven analyses (<1.5 % relative discordance which included six common Pb-corrected analyses and one analysis where no significant common Pb was detected) that yield a 207Pb/206Pb weighted average age of 1889 ± 26 Ma that we interpret as the most probable minimum age of fault initiation. The overlap in age of the host volcanic rock and the fault implies that during basin development, contemporaneous volcanism and syn-volcanic faults may have played an important role during iron ore emplacement. A U-Pb lower intercept age of apatite from the Nukutus iron oxide-apatite deposit provides a first indication that the area was subsequently buried and metamorphosed under upper greenschist-facies conditions and later tectonically exhumed and cooled below the apatite closure temperature at 1805 ± 26 Ma. Further temporal constraints on exhumation and basin inversion is given by syn-tectonic titanite along a brittle-ductile reverse shear zone to the east of the study area that shows limited presence of significant common Pb and is part of a sodic-calcic + Fe + Cl hydrothermal alteration assemblage. Titanite grains that show a well-developed zonation yield a U-Pb concordia age of 1812 ± 3 Ma, which we interpret as the onset of basin inversion. Titanite grains from the same sample that show less pronounced zonation yield a U-Pb concordia age of 1802 ± 8 Ma, tentatively indicating that the tectonothermal activity lasted up to c. 20 m.y.

Using Th-U-Pb geochronology to extract crystallization ages of Paleozoic metamorphic monazite contaminated by initial Pb

Geochronology of Th-rich minerals is advantageous as it allows use of three isotopic systems (i.e., 206Pb/238U, 207Pb/235U, and 208Pb/232Th) for accurate data assessment. The 208Pb/232Th system is especially advantageous in cases where the dated mineral includes an initial Pb component, as 208Pb/232Th is the least sensitive to the effects of initial Pb amongst the three systems. This benefit is demonstrated with monazite from a white mica schist of the Tsäkkok Lens, Scandinavian Caledonides, where three distinct generations of Paleozoic monazite (MnzI, Mnz-II, Mnz-III) are recognized and dated using laser ablation inductively coupled mass spectrometry. The generations are interpreted to represent monazite crystallization in high-pressure conditions (MnzI), followed by lower-pressure monazite growth (Mnz-II), and likely dissolution-reprecipitation of the pre-existing monazite (Mnz-III). The results are compared in Tera-Wasserburg, Wetherill, and Th-U-Pb concordia space for each monazite generation. In both Tera-Wasserburg and Wetherill space, the data are all discordant and indicate an initial Pb component in the monazite. The trend and magnitude of discordance due to initial Pb in Mnz-I and Mnz-II is generally controlled by UO2 content of the monazite, with higher UO2 equating to greater radiogenic Pb and a dampening of the initial Pb effect, which is most prominent in the 207Pb/235U system. For the same generations, initial Pb discordance of 206Pb/238U versus 208Pb/232Th is less apparent due to the insensitivity of 208Pb/232Th. Mnz-III does not follow the initial Pb trends, likely due to disturbance of the chemical and isotopic systems during recrystallization. Additional discordance in Mnz-I and Mnz-II, which is not related to initial Pb, is recognized and increases with actinide content. The additional discordance may be due to Pb-mobilization in Mnz-I and Mnz-II domains and is revealed when utilizing the 208Pb/232Th system due to its insensitivity to initial Pb effects. Consequently, relying only on the UPb systems can lead to significant initial Pb overcorrections in Tera-Wasserburg or Wetherill concordia space and to calculations of erroneously young concordia dates. The Th-U-Pb concordia method, incorporating all three systems, does not require an initial Pb correction and, therefore, can account for the additional discordance. The Th-U-Pb concordia dates are interpretated as accurate crystallization ages for Mnz-I (484.7 ± 1.1 Ma, MSWD: 1.4) and Mnz-II (474.7 ± 1.2 Ma, MSWD: 1.9). The timing for Mnz-III formation is not well-resolved as it formed via result of dissolution-reprecipitation of the pre-existing monazite, likely under lower amphibolite- to greenschist-facies conditions.

Element mobility as a proxy for delineating shear zone boundaries in orogenic belts: A case study of Iwaraja shear zone, southwestern Nigeria

Shear zones are localised regions of intense deformation and are important archives of element mobility history during crustal deformation. The boundary is determined by examining shear deformation fabrics in affected rocks. However, the "mixture" of relicts of undeformed rocks coupled with newly formed shear fabrics affect the determination of the internal boundaries of the shear zone and its boundary with the unsheared protolith, which in turn limits the evaluation of the shear zone's width. A new approach involving element mobility across the shear zone is proposed as a proxy to address this problem and corroborate existing methods. The petrographic and geochemical analyses of granitic gneiss across the Iwaraja shear zone and its adjacent rock were carried out. The element mobility patterns and volume of chemical changes were evaluated using isocon and Cartesian element-distance plots to interpret the chemical changes in the granitic gneiss across the shear zone. The result indicates a very high enrichment of TiO2, Fe2O3, MnO, MgO, P2O5, and REEs with relatively similar mobility patterns and a high depletion of Na2O, Rb, and Th in the shear zone. Al2O3 is not significantly mobilized but the mobility pattern of K2O is erratic. Based on the chemical changes in the granitic gneiss, the ductile shear zone is a CaO–MgO–Fe2O3-REE-enriched and Na2O–Rb–Th-depleted system. Under greenschist facies condition, the chemical mobility of TiO2, MnO, P2O5, Th, Rb, Zn, Ba, Zr, Th, Hf, and REEs is sensitive to the changes in the deformation intensity between the strongly- and weakly-deformed zones whereas REE [Lu, Yb, Gd, Eu, Ho, Tb] is useful to determine the boundary between the weakly-deformed zone and the unsheared rock. These index minerals are useful in other similar ductile shear zones in any orogenic belt. Based on the element mobility patterns, the width of the affected granite gneiss in the shear zone is ~680 m.

Shearing and fluid evolution of the Porto Nacional orogenic gold district, western Brazil: microstructural, fluid inclusion, and C-O isotopic evidence

The Porto Nacional Gold District, in the northern Tocantins Province, Brazil, is one of the few crustal-scale shear systems that contain both hypozonal and mesozonal orogenic gold deposits. It is situated within a Paleoproterozoic terrane, hosted by the crustal-scale Neoproterozoic Transbrasiliano-Kandi Shear System. The Cachimbo Shear Zone (CSZ) hypozonal deposits are hosted by phyllonites characterized by staurolite, garnet, and median to high-crystallinity graphite, consistent with amphibolite facies conditions. The mesozonal deposits, hosted in the Mutum Shear Zone (MSZ) and the Conceição Shear Zone (CoSZ), show a paragenesis that reflects greenschist-facies conditions. All zones host quartz fault-fill veins and adjacent extensional quartz-carbonate veinlet swarms. Two mineralizing stages are recognized. Stage 1 occurs in old quartz porphyroclasts in the fault-fill veins of the CSZ and MSZ deposits, and comprises pyrite, Type-2 graphite, gold, and other sulphides. In the CSZ stage 1, pressure-temperature data derived from mineral thermometry, quartz microstructure, and fluid inclusion isochores are compatible with a ductile deformation regime (433° to 580 °C and 3.5 to 6.3 kb), equivalent to 16 to 24 km depths under lithostatic conditions. Conditions for MSZ stage 1 are 350° to 415 °C and 2.0 to 3.1 kb, where the calculated depth (9 to 12 km) suggests the MSZ developed at shallower levels in the crust than the CSZ. In both shear zones the ore fluids are represented by H2O-CO2 fluid inclusions that are CH4-bearing and low salinity (0.3 to 6 wt% NaCl), and have low ƒO2. Reactivation along the shear zones caused folding and boudinaging of the extensional veinlets and recrystallization by subgrain rotation in the vein quartz, suggesting temperatures of ~ 400 °C. Ore stage 2 (gold-galena) occurs in vug-fill quartz in the veins and in extensional veinlets of the MSZ and CoSZ. It is estimated to have formed at lower temperatures (340° and 390℃) and pressures (1.8 to 4.5 kb) than ore stage 1, at depths of 6 to 18 km. The fluids were H2O-CO2 rich, with salinities of 3 to 8 wt% NaCl. The high and fluctuating pressures, above lithostatic conditions, suggest supralithostatic conditions. The wide fluid pressure variation is consistent with the fault-valve model for both ore stages. Later, higher salinity aqueous fluids (up to 15 wt% NaCl) with no CO2 or CH4 circulated at 300℃ and at 1.0 to 1.7 kb, which is more compatible with hydrostatic conditions at depths of 4 to 7 km. The stable isotopic composition of the fluids (δ18OH2O = 2 to 12‰, δ13CCO2 = −4 to −8‰) and the local geological constraints indicate that the mineralizing fluids were metamorphic. The P-T characteristics of the system, which indicate a decrease in T and P from the CSZ to the MSZ and CoSZ suggests that the PNSZ developed concurrently in the greenschist-amphibolite window. The further development of footprints for the hypozonal-mesozonal orogenic gold deposits of the PNGD could help identify new target areas for exploration in Brazil and elsewhere in this Neoproterozoic crustal-scale shear system.

Retrograde carbon sequestration in orogenic complexes: A case study from the Chinese southwestern Tianshan

The interaction between ascending carbonic fluids and rocks at shallow depths in orogenic systems plays a crucial role in carbon distribution and fluxes regulation. Here we present field, microstructural, petrological and geochemical results of carbonic fluid–rock interactions affecting exhumed mafic eclogites from the Chinese southwestern Tianshan ultrahigh-pressure (UHP) metamorphic belt. The mafic eclogites recorded two successive, superimposed, metamorphic–metasomatic stages: graphite precipitation along fractures and veins at eclogite facies (Stage#1) and pervasive rock carbonation (i.e., silicate dissolution and carbonate precipitation) at retrograde amphibolite to greenschist facies (Stage#2). This work focuses on Stage#2 carbonation, which consists of the transformation of Stage#1 graphite-bearing eclogites by carbonate + paragonite (± zoisite) + quartz. Carbon and oxygen isotopic data and Deep Earth Water (DEW) thermodynamic modeling suggest an external metasedimentary source for the Stage#2 carbonation. This deep carbon sequestration event can be referred to retrograde, greenschist-facies conditions at about 10 kbar and 450 °C, and redox conditions equal or more oxidized than the quartz–fayalite–magnetite (QFM) buffer. Modeling results also show that the saturation of carbonic fluid with respect to graphite can boost retrograde carbonation processes. Our findings provide new insights into the reactivity of metastable, exhumed metamafic rocks with ascending carbonic fluids in orogenic systems. We conclude that retrograde, fluid-mediated rock carbonation can significantly impact on carbon fluxes from active collisional belts.

Feldspar microboudinage paleopiezometer and its applications to estimating differential stress magnitudes in the continental middle crust (examples from west Yunnan, China)

Feldspar, which is the most abundant crustal mineral, exhibits brittle behavior while quartz and mica deform plastically by dislocation creep, under the greenschist-facies conditions (300–450 °C). Pull-apart microboudinage, which formed by repeated cycles of tensile fractures, is a common microstructure observed in feldspar porphyroclasts embedded in the ductile matrix of quartz in granitic mylonites from the Red River, Chongshan and Gaoligong shear zones (Yunnan, China). These crustal-scale shear zones, which lie in the southeastern margin of the Tibet Plateau, have played a critical role in the southeastward lateral extrusion of the Indochina composite block in response to the Indo-Asian continental collision. Here we developed a feldspar microboudinage paleopiezometer. In each feldspar porphyroclast, the differential stresses estimated from microboudins progressively increases with sequential fracturing, depicting an evolution during exhumation of the mylonite upwards the brittle-ductile transition. The results from the feldspar microboudinage piezometer and the quartz recrystallized grain-size piezometer are largely consistent within the range of uncertainties. The microboudinage piezometer, combined with results of finite strain measurements, deformation temperature estimates, and thermochronological data, can yield the valuable information about rheological properties of naturally deformed rocks. It can also be directly used or adapted to a wide range of geological problems, for example, fractured pebbles in an unlithified matrix, chromite pods in serpentinized mantle rocks, and strong boudins in a soft material at any scale.

Blueschist mylonitic zones accommodating syn-subduction exhumation of deeply buried continental crust: the example of the Rocca Canavese Thrust Sheets Unit (Sesia\u2013Lanzo Zone, Italian Western Alps)

The Rocca Canavese Thrust Sheets Unit (RCTU) is a subduction-related mélange that represents the eastern-most complex of the Sesia–Lanzo Zone (SLZ), bounded by the Periadriatic (Canavese) Lineament that separates the Alpine subduction complex from the Southalpine domain. The RCTU is limited to the south by the Lanzo Massif (LM) and to the east by the Eclogitic Micaschists Complex (EMC). Particularly the tectonic contact area of the RCTU, adjacent to the neighbouring SLZ and the LM is characterised by a 100–200-m-thick mylonitic to ultra-mylonitic zone (MZ) that was active under blueschist-to greenschist-facies conditions. Despite the dominant mylonitic structure, some rocks (garnet-bearing gneiss, garnet-free gneiss and orthogneiss) still preserve pre-mylonitic parageneses in meter-sized domains. The scarcity of superposed structures and the small size of relicts impose a detailed microstructural analysis supported by chemical investigation to reconstruct the tectono-metamorphic history of the MZ. Therefore, we integrated the classical meso- and microstructural analysis approach with a novel quantitative technique based on the Quantitative X-Ray Map Analyzer (Q-XRMA), used to classify rock-forming minerals starting from an array of X-ray elemental maps, both at whole thin section and micro-domain scale, as well as to calibrate the maps for pixel-based chemical analysis and end-member component maps, relevant for a more robust conventional geothermobarometer application as well for calculating reliable PT pseudosections. Pre-Alpine relicts are garnet and white mica porphyroclasts in the garnet-bearing gneiss and biotite and K-feldspar porphyroclasts in garnet-free gneiss and orthogneiss, respectively, providing no PT constraints. The Alpine evolution of the MZ rocks, has been subdivided in three deformation and metamorphic stages. The first Alpine structural and metamorphic equilibration stage (D1 event) occurred at a pressure of ca. 1.25–1.4 GPa and at a temperature of ca. 420–510 °C, i.e. under blueschist-facies conditions. The D2 event, characterised by a mylonitic foliation that is pervasive in the MZ, occurred at ca. 0.95–1.1 GPa and ca. 380–500 °C, i.e. under epidote-blueschist-facies conditions. The D2 PT conditions in the MZ rocks are similar to those predicted for the blocks that constitute the RCTU mélange, and they overlap with the exhumation paths of the EMC and LM units. Therefore, the RCTU, EMC and LM rocks became coupled together during the D2 event. This coupling occurred during the exhumation of the different tectono-metamorphic units belonging to both continental and oceanic lithosphere and under a relatively cold thermal regime, typical for an active oceanic subduction zone, pre-dating Alpine continental collision.

Source of Detritus in Subducted Turbidites, Tectonic Mélange, Port Macquarie Block, Southern New England Orogen, Australia—A Geochemical Perspective

A tectonic mélange containing blueschists and eclogites, Middle Ordovician mid-ocean ridge basalt, cherts, and clastic sediments occurs at Port Macquarie in the southern New England Orogen, Australia. The clastics are quartz-poor and are dominated by mafic volcanic and fragmented plagioclase clasts; felsic volcanic clasts are less common. They exhibit erosional bases, graded bedding, load structures, and lithologies ranging from laminated mudstones to pebbly sandstones. Based on these features, they are interpreted as turbidites. During subduction, these turbidites were deformed and metamorphosed under prehnite–pumpellyite and lower greenschist facies conditions. Geochemically, they have a calc-alkaline, intra-oceanic arc signature; show no recycling; and have been derived from a provenance dominated by mafic volcanic rocks of basaltic-andesite composition. Further, chemical index of alteration (44–69) and Index of Compositional Variability (0.8–2.4) data reveal they show little weathering and are immature. The lack of weathering of rocks in a location where tropical climatic conditions existed is attributed to extreme erosion associated with a dynamic setting resulting in rapid transportation of the sediments to the fore arc basin and subsequently to the trench. As a consequence, little time was available for weathering to take place. The detritus in the turbidites is thought to have been derived from Late Ordovician volcanics in the Macquarie Arc and fore arc basin sequences of the Murrawong Formation. The cherts with which they are associated record both a continental and oceanic arc geochemical signature.

The Sierra de Aguirre Formation, Uruguay: Post-collisional Ediacaran volcanism in the southernmost Dom Feliciano Belt

The Sierra de Aguirre Fm. in southern Uruguay constitutes one of several post-collisional basins of the Dom Feliciano Belt, preserving an important volcanic record associated with this protracted stage of the orogenic system. This study combines new stratigraphic, structural, geochronological and isotopic geochemical results, together with a reassessment of the available geochemical data, to present new insights in the evolution and sources of the basin, as well as a contextualization of it within the post-collisional development of the belt. The opening of the basin was related to a major discontinuity within the belt, with geometrical features suggesting an inverted half-graben structure. Stratigraphic and petrographic studies indicate that the Sierra de Aguirre Fm. preserves the original unconformity with its basement, and represent distal volcanic deposits. U–Pb SHRIMP-IIe zircon ages establish an interval of ca. 10 m.y. for the filling of the basin, between 581.7 ± 5.1 Ma and 571 ± 8 Ma. After the end of deposition, the basin underwent folding associated with the development of axial plane cleavage under lower greenschist facies conditions. This event is interpreted to represent regional transpression recorded also in nearby shear zones between 570 and 560 Ma, as constrained by new K–Ar ages in muscovite and white mica fine fractions. Geochemical and isotopic signature indicate dominant crustal sources for the volcanism, compatible with the basement of the eastern domain of the Dom Feliciano Belt, supporting a trend also observed in the coeval plutonic magmatism.