Condensation Behavior Research Articles

Dynamics of droplet adsorption by liquid film on a grooved surface

Abstract Understanding the dynamics of droplet adsorption by liquid film on a grooved surface is of great significance for the possible manipulation of dropwise condensation on the grooved surface. In this study, an improved phase-field lattice Boltzmann model is proposed to describe the process of droplet adsorption from the ridge to the liquid film within the channel. The results indicate that the leading edge of the droplet undergoes two accelerations during the adsorption process, obeying the power law of l/R = t^2.2 and l/R = t^0.9, respectively. The adsorption process between droplets with different sizes and the liquid film exhibits self-similarity characteristics including the same first peak velocity, the similar droplet displacement-time curve and the equal dimensionless spreading length of l/R=5.5. Decreasing the contact angle of the droplet from θe = 120° to θe = 60° accelerates the displacement of the leading edge and extends the spreading length. These findings may help reveal the mechanics of droplet adsorption by the liquid film on the grooved surface and thus manipulate the condensation behavior for the heat transfer enhancement.

3D Numerical Investigation of Bubble Upflow Condensation Behaviors During Subcooled Flow Boiling in Mini-Channel with VOSET

In the subcooled flow boiling process, bubble condensation is an inevitable basic phenomenon. This paper studies the condensation phenomenon of the single, double vertical/horizontal saturated bubbles rising in a three-dimensional mini-rectangular channel based on the interface capture method VOSET (coupled volume-of-fluid and level set method) and the phase transition model. Bubble condensation behaviors are investigated at different initial diameters, inlet velocity distributions, subcooling temperatures, bubble gaps, and arrangement for the two-bubble condensing system especially. The effects of these parametric on bubble motion trajectory, shape evolution, volume variation, and condensation rate are presented. The numerical results indicated that the initial bubble size and liquid subcooling play an important role in influencing the shape and volume variation of condensing bubble behaviors significantly, while the inlet velocity distribution only affects bubble motion trajectory. Furthermore, the interaction and coalescence between the bubbles will affect the bubble behaviors and the condensation rate. Finally, the condensation heat transfer coefficients at the bubble surfaces for different cases simulated in this paper are presented, seemingly first in the literature.

On the non-linearity of rheological film condensation

Condensation of non-Newtonian fluids is a less explored research field but has tremendous potential in the industry. We propose a mathematical theory to model the behaviour of non-Newtonian film condensation on vertical surfaces. The simple theory can contribute to understanding the operation of many engineering appliances using motor oils, polymeric liquids, and fuels. The well-known power-law model approximates the viscosity of condensate. We vary the power-law index (n) within 0.8≤n≤1.2 to encompass the behaviour of shear-thinning, Newtonian and shear-thickening films, while the flow consistency index (μ0) remains constant throughout the study. Since the film flow is gravity-driven, stream-wise advection is expected to dominate over cross-stream advection. We, however, establish the subtle role of cross-stream advection within the thin condensate film. We have identified a thinner film, a lower condensate drainage rate and a greater average heat transfer coefficient (hm) as an influence of the cross-stream advection. An exclusion of cross-stream advection transforms temperature distribution across the film from non-linear to linear. The linear temperature distribution is unrealistic for Ja≥0.5. We illustrate approximately 5% error incurred for neglecting cross-stream advection in estimating hm at Ja=0.81 and n=0.8. The error increases with a further decrease in n values or an increase in the Ja. The exclusion of cross-stream advection affects the film-thickness and average heat transfer disproportionately in shear-thinning and shear-thickening regimes. Finally, we propose mathematical expressions to estimate heat transfer coefficient and Nusselt number, which would be helpful for field engineers.

Effects of the Characterization Methods of Heptane Plus Components (C7+) on the Phase Behavior of Volatile Fluids

For reservoir fluids with strong volatile tendencies, such as gas condensate and volatile oil, the determination of the characteristic parameters of the equation of state has a great influence on the fluid phase behavior and subsequent reservoir engineering, production engineering, and surface facilities design calculations. However, the process of characterizing reservoir fluid lacks a unified and standardized procedure, and the methods are largely empirical and rather complicated. In this paper, three main stages are defined for the characterization of the equation of state parameters for these volatile reservoir fluids, including (1) determining the C7+ distribution, (2) calculating the equation of state parameters for the C7+ single-carbon component, and (3) lump components. The typical calculation methods in each step and their effects on the fluid phase behavior calculations are quantitatively analyzed and compared. Finally, the workflow and the suitable characterization methods for gas condensate and volatile oil phase behavior calculations are selected. The results show that C7+ distribution and C7+ single carbon component properties have a greater influence on the phase behavior prediction of condensate gas and volatile oil, while the lumping of C7+ single carbon component has relatively little influence.

The Effect of Dipeptide Repeat Proteins on FUS/TDP43-RNA Condensation in C9orf72 ALS/FTD.

Condensation of RNA binding proteins (RBPs) with RNA is essential for cellular function. The most common familial cause of the diseases ALS and FTD is C9orf72 repeat expansion disorders that produce dipeptide repeat proteins (DPRs). We explore the hypothesis that DPRs disrupt the native condensation behavior of RBPs and RNA through molecular interactions resulting in toxicity. FUS and TDP43 are two RBPs known to be affected in ALS/FTD. We use our previously developed 1-bead-per-amino acid and a newly developed 3-bead-per-nucleotide molecular dynamics model to explore ternary phase diagrams of FUS/TDP43-RNA-DPR systems. We show that the most toxic arginine containing DPRs (R-DPRs) can disrupt the RBP condensates through cation-π interactions and can strongly sequester RNA through electrostatic interactions. The native droplet morphologies are already modified at small additions of R-DPRs leading to non-native FUS/TDP43-encapsulated condensates with a marbled RNA/DPR core.

Water vapor condensation behavior on different wetting surfaces via molecular dynamics simulation

Understanding water vapor condensation behavior at molecular level provides critical insights and useful guidance towards applications such as atmospheric water harvesting. In this work, condensation behavior of water vapor with a range of concentrations is investigated by molecular dynamics simulation on surfaces with different wetting states, viz. hydrophilic, hydrophobic, superhydrophilic, and superhydrophobic under five levels of water vapor content. The effect of water vapor content on condensation morphology, condensation beginning time, number of water molecules condensed over time, and accumulation rate are quantitatively examined. The results demonstrate that water condensation mass increases linearly with time on hydrophilic and superhydrophilic surfaces, while displaying a two-stage behavior on hydrophobic and superhydrophobic surfaces. The increase at the first stage is slower than the second stage. Higher water vapor content enables earlier nucleation and shortens the duration of the slow increase stage for hydrophobic and superhydrophobic surfaces. Quantitatively, water condensation mass increases linearly with the relative humidity of the vapor, and the coefficient with relative humidity on the hydrophilic, hydrophobic, superhydrophilic and superhydrophobic surfaces is 25.74 × 10–19, 8.31 × 10–19, 27.63 × 10–19, and 1.34 × 10–19, respectively. Our results show that increasing water vapor content has more significant impact on hydrophilic and superhydrophilic surfaces than hydrophobic and superhydrophobic surfaces. In addition, increasing water vapor content has minor effect on condensation rate in the slow increase stage on hydrophobic and superhydrophobic surfaces, but significantly increase the condensation rate on the rapid increase stage.

Non-specific yet selective interactions contribute to small molecule condensate partitioning behavior.

Biomolecular condensates are essential in various cellular processes, and their mis-regulation has been demonstrated to be underly disease. Small molecules that modulate condensate stability and material properties offer promising therapeutic approaches, but mechanistic insights into their interactions with condensates remain largely lacking. We employ a multiscale approach to enable long-time, equilibrated all-atom simulations of various condensate-ligand systems. Systematic characterization of the ligand binding poses reveals that condensates can form diverse and heterogeneous chemical environments with one or multiple chains to bind small molecules. Unlike traditional protein-ligand interactions, these chemical environments are dominated by non-specific hydrophobic interactions. Nevertheless, the chemical environments feature unique amino acid compositions and physicochemical properties that favor certain small molecules over others, resulting in varied ligand partitioning coefficients within condensates. Notably, different condensates share similar sets of chemical environments but at different populations. This population shift drives ligand selectivity towards specific condensates. Our approach can enhance the interpretation of experimental screening data and may assist in the rational design of small molecules targeting specific condensates.

Supersonic separation benefiting the decarbonization of natural gas and flue gas

Supersonic separation utilizes the cryogenics created by gas expansion to purify the mixture. This method is a novel carbon capture scheme. In this work, the models of N2-CO2 (flue gas) and CH4-CO2 (natural gas) are established to calculate the condensation flow. The condensation behavior of CO2 in natural gas and flue gas is clarified respectively, and the difference between the two is compared for the first time. Under the same conditions, CO2 in flue gas reaches the limit non-equilibrium state first, forming non-equilibrium condensation with limit nucleation rate of 7.78 × 1020 m−3s−1 and maximum droplet growth rate of 8.19 × 10−3 m s−1. However, the maximum droplet growth rate in natural gas is only 2.22 × 10−3 m s−1, which implies that the interphase mass transfer rate in flue gas is larger during the CO2 condensation. In addition, the condensation behavior of CO2 in natural gas is more sensitive to the changes of inlet parameters. This work provides an invaluable contribution to the development of supersonic carbon capture.

Study of the effects of external imaginary electric field and chiral chemical potential on quark matter

The behavior of quark matter with both external electric field and chiral chemical potential is theoretically and experimentally interesting to consider. In this paper, the case of simultaneous presence of imaginary electric field and chiral chemical potential is investigated using the lattice QCD approach with Nf=1+1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$N_f=1+1$$\\end{document} dynamical staggered fermions. We find that overall both the imaginary electric field and the chiral chemical potential can exacerbate chiral symmetry breaking, which is consistent with theoretical predictions. However we also find a non-monotonic behavior of chiral condensation at specific electric field strengths and chiral chemical potentials. The behavior of Polyakov loop in the complex plane is not significantly affected by chiral chemical potential in the region of the parameters considered.

Investigating condensation from humid air under mixed convection regime

A wide range of industrial applications rely heavily on heat transfer during vapor condensation from a mixture of water vapor and noncondensable gases (NCG). For a vertically-mounted condenser plate, the vapor-diffusion boundary-layer thickness is influenced by the interplay of the thermogravitational and forced flow fields, eliciting classical mixed convection scenario. This thickness in turn dictates the condensation heat and mass transfer rates. While condensation in presence of NCG under free and forced convection scenarios are well-characterized in the literature, its counterpart in the mixed convection regime is relatively uncharted. Herein, condensation from an upward stream of humid air over a vertically mounted mild steel condenser surface is characterized under different flow velocities. The free-stream flow is thus directed opposite to the thermogravitational flow induced next to the plate. We observe that with increasing the magnitude of the upward flow velocity of the free stream, the condensation heat transfer coefficient (CHTC) initially decreases until it reaches a minimum at 0.4 m/s, beyond which the CHTC rises again with the flow velocity. Using the Nusselt analogy for mixed convection for the relevant flow regimes we substantiate our experimental findings and extend the observation for predicting condensation behavior under different experimental ambient conditions.

Refinement of Kelvin equation for condensation of water in CSH slits based on molecular simulation

The adsorption and condensation of water molecules in the pores of cementitious materials play a crucial role in the mechanical performance and durability of concrete. The Kelvin equation is generally employed to describe the water condensation in porous materials. However, it requires modification for condensation behavior in nano and micro scales of pores. In the present work, various widths of slit models for several cementitious minerals were established. The adsorption isotherms in slit pores were calculated using the hybrid of Grand Canonical Monte Carlo and Molecular Dynamics simulations, obtaining the relationship between the critical pressures for condensation and pore sizes. Then, a modified Kelvin equation was proposed, with discussion on a new reasonable method for determining the real thickness of adsorbed water film. The results demonstrate that condensation will occur in the slits within the critical width range, which promotes the surface adsorption to achieve complete adsorption. Therefore, the location of the interface between the adsorbed water film and condensed water bulk is fixed in the same mineral during condensation. The modified Kelvin equation shows higher accuracy than traditional Kelvin equations at the nano and micro scale. This work promotes a deeper understanding of the interaction mechanism of water with cementitious minerals and inspires more fundamental realization in the design of concrete durability.

Preferential water vapor condensation on a corrugated surface: A molecular dynamics study

In this study, we investigate the nucleation and subsequent growth of water clusters on corrugated surfaces using molecular dynamics simulations, with a specific focus on scenarios where the nanostructure sizes are comparable to the critical nucleus size. The primary objective is to reveal the coupled effects of different surface morphologies, i.e., plane, convex, and concave, on water vapor condensation. Regardless of the nanostructures, the condensation process can be divided into two stages, the nucleation stage and the growth stage. It is shown that in the nucleation stage, the concave areas are more conducive to nucleation compared to plane areas, aligning with classical nucleation theory. The total number of condensed molecules is generally proportion to the nucleation ability, while the average size of condensation clusters is affected by the surface nanostructures, with the combination of concave and plane surfaces exhibiting the strongest capability for both water vapor nucleation and cluster growth. Compared to the plane regions, the convex regions not only inhibit nucleation but also block collision and coalescence between clusters. Additionally, increasing the characteristic width of concave and convex structures leads to condensation behaviors approaching those on the plane surface. This indicates that the regulation of the condensation process is feasible by nanostructures within prescribed structural size limits.

Enhancing carbon capture: Exploring droplet wetting and gas condensation of carbon dioxide on nanostructured surfaces

The investigation of carbon dioxide (CO2) condensation on heat exchange surfaces is essential to the advancement of carbon capture, utilization, and storage (CCUS) technology. Molecular dynamics simulations are employed to explore the wetting and condensation behavior of CO2 on nanostructured surfaces. The results indicate that the contact angle of CO2 droplets on nanostructured surfaces is greater than that on smooth surfaces. Increasing the pillar height (h) or solid fraction (f) induces the transition of CO2 droplets from the Wenzel to Cassie state, resulting in an increased contact angle. Nanostructured surfaces significantly enhance the nucleation rate, with molecules initially nucleating at the bottom of the pillars. A higher h or f accelerates the nucleation rate during the condensation. Droplets in the Wenzel state exhibit higher heat transfer efficiency than those in the Cassie state. Additionally, the formation of Cassie-state CO2 droplets undergoes a dewetting transition, altering the heat conduction mode. The dewetting behavior of CO2 droplets favors their detachment from the surface, potentially reducing the initial heat resistance. Therefore, appropriately increasing h and f can promote nucleation and droplet growth, enhancing dewetting transition and mass transfer performance. These simulation results hold great importance for inspiring the design of future CO2-phobic surfaces and guiding CO2 condensation production.

Controlled condensation by liquid contact-induced adaptations of molecular conformations in self-assembled monolayers

Surface condensation control strategies are crucial but commonly require relatively tedious, time-consuming, and expensive techniques for surface-chemical and topographical engineering. Here we report a strategy to alter surface condensation behavior without resorting to any molecule-type or topographical transmutations. After ultrafast contact of liquids with and removal from surfaces, the condensation rate and density of water droplets on the surfaces decrease, the extent of which is positively correlated with the polarity of the liquid and the duration of contact. The liquid contact-induced condensation rate/density decrease (LCICD) can be attributed to the decrease of nucleation site density resulted from the liquid contact-induced adaption of surface molecular conformation. Based on this, we find that LCICD is applicable to various surfaces, on condition that there are flexible segments capable of shielding at least part of nucleation sites through changing the conformation under liquid contact induction. Leveraging the LCICD effect, we achieve erasable information storage on diverse substrates. Furthermore, our strategy holds promise for controlling condensation of other substances since LCICD is not specific to the water condensation process.

A novel numerical approach for assessing the gas-liquid flow characteristics in pipelines utilizing a two-fluid model

The accumulation of liquid condensate in the wet gas pipelines gives negative effects on the piping efficiency and flow managements. Accurate prediction of the condensate behavior is of crucial importance in the pipeline engineering. In this study, the one-dimensional two-fluid model with the stratified modeling in its source term is used to describe the gas-liquid kinetic motion along the pipe and the flow fields obtained from the newly proposed numerical approach are utilized to analyze the flow characteristics. Firstly, four cases with varying inlet liquid fractions, outlet pressures, and different meshes are utilized to investigate the gas-liquid steady-state variations along the pipe. The numerical results indicate that the outlet pressure influences the working pressure of the inlet gas-liquid, subsequently altering the equilibrium state and momentum exchange direction near the inlet, resulting in different condensate distributions in the pipeline. In the transient analysis with initial empty pipe, the inlet gas-liquid mainly impacts the pressure wave propagations in pressure spread stage, the gas kinetic motion in gas filling stage and the motion of the dividing interface between different regions in liquid filling stage, which is validated by the proposed numerical approach through comparison with the simulation tool OLGA designed by Schlumberger. Furthermore, when the liquid condensates appear in the initial state, the transition zones have two physical forms between different flow regions, which include the sudden dividing interface due to the high liquid amount carried by the inlet gas and the transition region resulted from the liquid accumulations.

The noise of the charge density waves in quasi-1D NbSe3 nanowires — contributions of electrons and quantum condensate

Low-frequency electronic noise in charge-density-wave van der Waals materials has been an important characteristic, providing information about the material quality, phase transitions, and collective current transport. However, the noise sources and mechanisms have not been completely understood, particularly for the materials with a non-fully gapped Fermi surface where the electrical current includes components from individual electrons and the sliding charge-density wave. We investigated noise in nanowires of quasi-one-dimensional NbSe3, focusing on a temperature range near the Pearls transition TP1 ∼ 145 K. The data analysis allowed us to separate the noise produced by the individual conduction electrons and the quantum condensate of the charge density waves before and after the onset of sliding. The noise as a function of temperature and electric bias reveals several intriguing peaks. We explained the observed features by the depinning threshold field, the creep and sliding of the charge density waves, and the possible existence of the hidden phases. It was found that the charge density wave condensate is particularly noisy at the moment of depinning. The noise of the collective current reduces with the increasing bias voltage in contrast to the noise of the individual electrons. Our results shed light on the behavior of the charge density wave quantum condensate and demonstrate the potential of noise spectroscopy for investigating the properties of low-dimensional quantum materials.

Water content in CO2–CH4 mixtures: New saturation setup and measurements using a quartz-crystal microbalance.

This study presents experimental data on water content in CO2, methane, and their mixtures. A new saturation process was developed using a PVT cell connected to a variable-volume cylinder filled with deionized water. Dry gas with a known composition was injected into the cylinder, and the temperature and pressure conditions were adjusted accordingly. The water content of the saturated gas was then analyzed using a quartz-crystal microbalance (QCM). Various mixtures with different CO2 and methane mole ratios were investigated at different pressures for a given temperature. The PC-SAFT and CPA equations of state were applied to correlate the moisture data. The association scheme employed included 2B, 3B, and 4C types, considering the cross-association between water and CO2. The results for pure methane showed that the water content increased as the pressure decreased across all pressure ranges. However, for pure CO2 above 70 bar, the water content increased due to the condensation behavior of CO2. The same trend was observed for mixtures, where the water content increased with increasing pressure for CO2 mole fractions above 0.74. For all the systems studied, the PC-SAFT and CPA equations of state successfully correlated the water content data using a single constant binary interaction parameter and considering the cross-association between water and CO2.

An Overview of Enhancing the Efficiency of Vapor Compression Cooling Systems by the Implementation of Evaporative Condensers

This paper explores the significance of energy conservation in the context of rising energy consumption and its impact on economic growth. With a focus on cooling systems, particularly evaporative condenser technology, the study aims to investigate its fundamentals, operating principles, and theoretical aspects. The paper delves into the various types of condensers used in cooling systems, emphasizing the role of evaporative condensers in enhancing heat transfer efficiency. The operating principles of evaporative condensers are detailed, considering factors such as air and water flow rates, wet bulb temperatures, and heat transfer coefficients. Theoretical models and mathematical approaches for evaluating evaporative condenser performance are also reviewed. The research includes an extensive review of existing literature on evaporative condenser technology, covering refrigeration models, HVAC systems, and various experimental studies. Theoretical models are discussed, highlighting the challenges in accurately modeling evaporative condenser behavior. The paper also presents achievements and advancements in research, including experiments that demonstrate the positive impact of evaporative cooling on air-cooled condenser systems. Various case studies and experimental validations showcase the potential energy savings and improved performance achieved through the incorporation of evaporative condensers in cooling systems. By switching from an air-cooled to an evaporatively-cooled condenser, one can reduce electricity consumption by 58%, according to research. This alternate condenser type improves performance by 113.4% at from 3 to 3000 kW of cooling power.

Understanding the impact of isoelectric amino acids on biomolecular condensate behavior

Understanding the impact of isoelectric amino acids on biomolecular condensate behavior

Phase Behaviors of Gas Condensate at Pore Scale: Direct Visualization via Microfluidics and In-Situ CT Scanning

Summary Gas condensate is stored in multiscale pores, fractures, and vugs within geological formations. Confinement within these structures significantly influences the phase behavior of gas condensate, rendering it challenging to characterize through conventional bulk pressure/volume/temperature (PVT) measurements. In this study, we used microfluidics and in-situ computed tomography (CT) scanning to directly measure the upper dewpoint of gas condensate and the gas/oil ratio in porous media during depressurization. We used two microfluidic chips with different pore sizes to investigate the confinement effects on gas condensate phase behavior at various scales, including pores as small as 50 nm. Our results revealed a significant increase in the upper dewpoint within the pores compared to bulk PVT measurements, with a more pronounced deviation at smaller pore sizes. Additionally, the proportion of condensate oil in porous media exceeded that observed in bulk PVT measurements at the same pressure. To validate our microfluidic findings, we conducted in-situ CT scanning experiments using a porous media model created by packing quartz particles. CT scans revealed pores ranging from a few micrometers to over 100 micrometers. Consistently, we observed an increase in the upper dewpoint and liquid ratio within these pores. Our study provides crucial experimental evidence indicating that the phase behavior of gas condensate in porous media deviates from bulk PVT measurements. The observed increase in the upper dewpoint, even within micrometer-sized pores, has important implications for phase equilibrium calculations.