Condensation Behavior Research Articles

Phase Behavior and Compression Factors of Ultradeep Condensate and Dry Gas Reservoir under High Temperature and Pressure: Experiment and Calculation

Phase Behavior and Compression Factors of Ultradeep Condensate and Dry Gas Reservoir under High Temperature and Pressure: Experiment and Calculation

Modeling condensation of Methane-Water vapor mixtures in the Hedbäck Nozzle: A comparative study of 2D and 3D geometries

This study investigated the condensation behavior of a binary mixture of methane (CH4) and water vapor (H2O) within the Hedbäck nozzle, employing both 2D and 3D modeling approaches. The 2D model was initially developed to analyze the effects of inlet parameters and mixture’s condensation characteristics. However, the inherent limitations of the 2D model in capturing the full complexity of the flow dynamics prompted a transition to a 3D modeling approach. The research explored two distinct 3D geometries: one created by extruding the 2D section and another by rotating the 2D cross-section around its axis. The latter, which more accurately represented real-world nozzle conditions, revealed differences in flow patterns, condensation behavior, and entropy generation, emphasizing the crucial role of 3D effects in the condensation process. The sensitivity of the numerical simulation results to various nucleation theories and droplet growth models was acknowledged, and the most appropriate theory and model were meticulously selected. This approach minimized discrepancies between numerical modeling outcomes and experimental data, enhancing the accuracy and reliability of the findings. The 2D results indicate a 40.5% increase in the inlet partial pressure with a constant temperature and mass fraction, resulting in a 56% rise in maximum liquid mass fraction. Similarly, a 3.6% decrease in inlet temperature under constant pressure and mass fraction increases the average radius of outlet droplets by more than 13%. In addition, entropy generation analysis revealed that less than 1% of entropy generation is attributed to mean flow, whereas 99% is linked to turbulent fluctuations. Moreover, the 3D models demonstrated markedly different entropy generation rates compared to the 2D model, highlighting the importance of 3D approach for a comprehensive understanding of thermodynamic irreversibility within the system.

An experimental comparative study on condensing supersonic steam jets in water tank: Square, rectangular, and circular cross-sectional shapes

The direct contact condensation phenomenon has gained significant attraction among researchers due to positive aspects such as low driving potential and rapid heat transfer rates in its industrial uses. The present study explores the effect of the cross-sectional shape of converging-diverging on steam-submerged jet condensation behavior. The influence of three cross-sections (circular, square, and rectangular) on steam jet shapes, jet length, average heat transfer coefficient, and maximum expansion ratio were studied. The dimensionless steam jet length for circular, square, and rectangular nozzles has been found in the range of 2.2–7.7, 2.43–8.41, and 2.22–8.35, respectively. The maximum expansion ratio for circular, square, rectangular major axis plane, and rectangular minor axis plane has been found in the range of 1–1.71, 1.14–2.15, 1.22–2.82, and 1.06–1.45. Results show that the maximum expansion ratio and dimensionless jet length rise with steam pressure and water temperature rise. Dimensionless jet length decreases in the order of nozzle with cross-section: square > rectangular > circular. Correlation for dimensional jet length of both circular and non-circular nozzles is presented using the analytical and curve fitting methods. The maximum expansion ratio decreases in order: major axis plane > square > circular > minor axis plane. The average heat transfer coefficient (MW/m2 oC) for circular, square, and rectangular nozzles has been found in the range of 1.16–4.88, 0.89–3.14, and 1.01–3.49. Results show that the average heat transfer coefficient falls with the rise in steam pressure and water temperature. The average heat transfer coefficient decreases in order: circular > rectangular > square. Condensation regime maps are proposed for circular, square, and rectangular nozzles, including diagonal plane effects in square and rectangular nozzle.

LncRNAs maintain the functional phase state of nucleolar prion-like protein to facilitate rRNA processing.

Liquid-to-solid phase transition of proteins with prion-like domains (PLDs) has been associated with neurodegenerative diseases and aging. High protein concentration is one important aspect triggering the transition; however, several prion-like proteins, including fibrillarin (FBL), an important phase-separated protein in the nucleolus for pre-rRNA processing, show relatively high expression levels in certain cells, especially cancer cells, without obvious phase transitions and growth arrest. How cells maintain prion-like protein proteostasis is still unknown. Here, we attempt to answer the question, with FBL as an example. We find that lncRNA DNAJC3-AS1 can buffer the behavior of FBL condensation and maintain the state and function of fibrillar component/dense fibrillar component (FC/DFC) units in human cell lines through two mechanisms, not only facilitating FBL condensation but also inhibiting excessive aggregation by binding multiple PLDs and partially blocking their interactions. We propose that lncRNAs could supply buffered systems to sustain functional phase states of prion-like proteins.

Antimony Vaporization and Condensation in Simulated Flash Smelting Off-Gas Train Conditions

AbstractAntimony is one of the most deleterious impurity elements in copper smelting and has a strong tendency to vaporize in the smelting furnace resulting in an enrichment of antimony in smelter flue dusts. The vaporization and condensation behavior of antimony species was studied in dust-free conditions simulating the off-gas train of a Flash Smelting Furnace at temperatures below 1273 K (1000 °C). The influences of the oxygen partial pressure and the condensate formation temperature on the characteristics of the precipitated antimony species were determined. It was found that practically all the vaporized antimony species precipitated between 853 K and 546 K (580 °C and 273 °C) and that a higher oxygen partial pressure favored precipitation at higher temperatures. The formation of antimony sulfate, which thermodynamically is the most stable antimony species in the studied conditions at temperatures below approximately 723 K (450 °C), was found to be kinetically constrained and the vaporized antimony species precipitated as oxides or sulfides depending on the oxygen partial pressure and the precipitate formation temperature.

Dynamics of droplet adsorption by liquid film on a grooved surface

Understanding the dynamics of droplet adsorption by liquid film on a grooved surface is of great significance for the possible manipulation of dropwise condensation on the grooved surface. In this study, an improved phase-field lattice Boltzmann model is proposed to describe the process of droplet adsorption from the ridge to the liquid film within the channel. The results indicate that the leading edge of the droplet undergoes two accelerations during the adsorption process, obeying the power law of and , respectively. The adsorption process between droplets with different sizes and the liquid film exhibits self-similarity characteristics including the same first peak velocity, the similar droplet displacement-time curve and the equal dimensionless spreading length of . Decreasing the contact angle of the droplet from to accelerates the displacement of the leading edge and extends the spreading length. These findings may help reveal the mechanics of droplet adsorption by the liquid film on the grooved surface and thus manipulate the condensation behavior for the heat transfer enhancement.

3D numerical investigation of bubble upflow condensation behaviors during subcooled flow boiling in mini-channel with VOSET

In the subcooled flow boiling process, bubble condensation is an inevitable basic phenomenon. This paper studies the condensation phenomenon of the single, double vertical/horizontal saturated bubbles rising in a three-dimensional mini-rectangular channel based on the interface capture method VOSET (coupled volume-of-fluid and level set method) and the phase transition model. Bubble condensation behaviors are investigated at different initial diameters, inlet velocity distributions, subcooling temperatures, bubble gaps, and arrangement for the two-bubble condensing system especially. The effects of these parametric on bubble motion trajectory, shape evolution, volume variation, and condensation rate are presented. The numerical results indicated that the initial bubble size and liquid subcooling play an important role in influencing the shape and volume variation of condensing bubble behaviors significantly, while the inlet velocity distribution only affects bubble motion trajectory. Furthermore, the interaction and coalescence between the bubbles will affect the bubble behaviors and the condensation rate. Finally, the condensation heat transfer coefficients at the bubble surfaces for different cases simulated in this paper are presented, seemingly first in the literature.

On the non-linearity of rheological film condensation

Condensation of non-Newtonian fluids is a less explored research field but has tremendous potential in the industry. We propose a mathematical theory to model the behaviour of non-Newtonian film condensation on vertical surfaces. The simple theory can contribute to understanding the operation of many engineering appliances using motor oils, polymeric liquids, and fuels. The well-known power-law model approximates the viscosity of condensate. We vary the power-law index (n) within 0.8≤n≤1.2 to encompass the behaviour of shear-thinning, Newtonian and shear-thickening films, while the flow consistency index (μ0) remains constant throughout the study. Since the film flow is gravity-driven, stream-wise advection is expected to dominate over cross-stream advection. We, however, establish the subtle role of cross-stream advection within the thin condensate film. We have identified a thinner film, a lower condensate drainage rate and a greater average heat transfer coefficient (hm) as an influence of the cross-stream advection. An exclusion of cross-stream advection transforms temperature distribution across the film from non-linear to linear. The linear temperature distribution is unrealistic for Ja≥0.5. We illustrate approximately 5% error incurred for neglecting cross-stream advection in estimating hm at Ja=0.81 and n=0.8. The error increases with a further decrease in n values or an increase in the Ja. The exclusion of cross-stream advection affects the film-thickness and average heat transfer disproportionately in shear-thinning and shear-thickening regimes. Finally, we propose mathematical expressions to estimate heat transfer coefficient and Nusselt number, which would be helpful for field engineers.

Effects of the Characterization Methods of Heptane Plus Components (C7+) on the Phase Behavior of Volatile Fluids

For reservoir fluids with strong volatile tendencies, such as gas condensate and volatile oil, the determination of the characteristic parameters of the equation of state has a great influence on the fluid phase behavior and subsequent reservoir engineering, production engineering, and surface facilities design calculations. However, the process of characterizing reservoir fluid lacks a unified and standardized procedure, and the methods are largely empirical and rather complicated. In this paper, three main stages are defined for the characterization of the equation of state parameters for these volatile reservoir fluids, including (1) determining the C7+ distribution, (2) calculating the equation of state parameters for the C7+ single-carbon component, and (3) lump components. The typical calculation methods in each step and their effects on the fluid phase behavior calculations are quantitatively analyzed and compared. Finally, the workflow and the suitable characterization methods for gas condensate and volatile oil phase behavior calculations are selected. The results show that C7+ distribution and C7+ single carbon component properties have a greater influence on the phase behavior prediction of condensate gas and volatile oil, while the lumping of C7+ single carbon component has relatively little influence.

The Effect of Dipeptide Repeat Proteins on FUS/TDP43-RNA Condensation in C9orf72 ALS/FTD.

Condensation of RNA binding proteins (RBPs) with RNA is essential for cellular function. The most common familial cause of the diseases ALS and FTD is C9orf72 repeat expansion disorders that produce dipeptide repeat proteins (DPRs). We explore the hypothesis that DPRs disrupt the native condensation behavior of RBPs and RNA through molecular interactions resulting in toxicity. FUS and TDP43 are two RBPs known to be affected in ALS/FTD. We use our previously developed 1-bead-per-amino acid and a newly developed 3-bead-per-nucleotide molecular dynamics model to explore ternary phase diagrams of FUS/TDP43-RNA-DPR systems. We show that the most toxic arginine containing DPRs (R-DPRs) can disrupt the RBP condensates through cation-π interactions and can strongly sequester RNA through electrostatic interactions. The native droplet morphologies are already modified at small additions of R-DPRs leading to non-native FUS/TDP43-encapsulated condensates with a marbled RNA/DPR core.

Water vapor condensation behavior on different wetting surfaces via molecular dynamics simulation

Understanding water vapor condensation behavior at molecular level provides critical insights and useful guidance towards applications such as atmospheric water harvesting. In this work, condensation behavior of water vapor with a range of concentrations is investigated by molecular dynamics simulation on surfaces with different wetting states, viz. hydrophilic, hydrophobic, superhydrophilic, and superhydrophobic under five levels of water vapor content. The effect of water vapor content on condensation morphology, condensation beginning time, number of water molecules condensed over time, and accumulation rate are quantitatively examined. The results demonstrate that water condensation mass increases linearly with time on hydrophilic and superhydrophilic surfaces, while displaying a two-stage behavior on hydrophobic and superhydrophobic surfaces. The increase at the first stage is slower than the second stage. Higher water vapor content enables earlier nucleation and shortens the duration of the slow increase stage for hydrophobic and superhydrophobic surfaces. Quantitatively, water condensation mass increases linearly with the relative humidity of the vapor, and the coefficient with relative humidity on the hydrophilic, hydrophobic, superhydrophilic and superhydrophobic surfaces is 25.74 × 10–19, 8.31 × 10–19, 27.63 × 10–19, and 1.34 × 10–19, respectively. Our results show that increasing water vapor content has more significant impact on hydrophilic and superhydrophilic surfaces than hydrophobic and superhydrophobic surfaces. In addition, increasing water vapor content has minor effect on condensation rate in the slow increase stage on hydrophobic and superhydrophobic surfaces, but significantly increase the condensation rate on the rapid increase stage.

Non-specific yet selective interactions contribute to small molecule condensate partitioning behavior.

Biomolecular condensates are essential in various cellular processes, and their mis-regulation has been demonstrated to be underly disease. Small molecules that modulate condensate stability and material properties offer promising therapeutic approaches, but mechanistic insights into their interactions with condensates remain largely lacking. We employ a multiscale approach to enable long-time, equilibrated all-atom simulations of various condensate-ligand systems. Systematic characterization of the ligand binding poses reveals that condensates can form diverse and heterogeneous chemical environments with one or multiple chains to bind small molecules. Unlike traditional protein-ligand interactions, these chemical environments are dominated by non-specific hydrophobic interactions. Nevertheless, the chemical environments feature unique amino acid compositions and physicochemical properties that favor certain small molecules over others, resulting in varied ligand partitioning coefficients within condensates. Notably, different condensates share similar sets of chemical environments but at different populations. This population shift drives ligand selectivity towards specific condensates. Our approach can enhance the interpretation of experimental screening data and may assist in the rational design of small molecules targeting specific condensates.

Supersonic separation benefiting the decarbonization of natural gas and flue gas

Supersonic separation utilizes the cryogenics created by gas expansion to purify the mixture. This method is a novel carbon capture scheme. In this work, the models of N2-CO2 (flue gas) and CH4-CO2 (natural gas) are established to calculate the condensation flow. The condensation behavior of CO2 in natural gas and flue gas is clarified respectively, and the difference between the two is compared for the first time. Under the same conditions, CO2 in flue gas reaches the limit non-equilibrium state first, forming non-equilibrium condensation with limit nucleation rate of 7.78 × 1020 m−3s−1 and maximum droplet growth rate of 8.19 × 10−3 m s−1. However, the maximum droplet growth rate in natural gas is only 2.22 × 10−3 m s−1, which implies that the interphase mass transfer rate in flue gas is larger during the CO2 condensation. In addition, the condensation behavior of CO2 in natural gas is more sensitive to the changes of inlet parameters. This work provides an invaluable contribution to the development of supersonic carbon capture.

Study of the effects of external imaginary electric field and chiral chemical potential on quark matter

The behavior of quark matter with both external electric field and chiral chemical potential is theoretically and experimentally interesting to consider. In this paper, the case of simultaneous presence of imaginary electric field and chiral chemical potential is investigated using the lattice QCD approach with Nf=1+1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$N_f=1+1$$\\end{document} dynamical staggered fermions. We find that overall both the imaginary electric field and the chiral chemical potential can exacerbate chiral symmetry breaking, which is consistent with theoretical predictions. However we also find a non-monotonic behavior of chiral condensation at specific electric field strengths and chiral chemical potentials. The behavior of Polyakov loop in the complex plane is not significantly affected by chiral chemical potential in the region of the parameters considered.

Investigating condensation from humid air under mixed convection regime

A wide range of industrial applications rely heavily on heat transfer during vapor condensation from a mixture of water vapor and noncondensable gases (NCG). For a vertically-mounted condenser plate, the vapor-diffusion boundary-layer thickness is influenced by the interplay of the thermogravitational and forced flow fields, eliciting classical mixed convection scenario. This thickness in turn dictates the condensation heat and mass transfer rates. While condensation in presence of NCG under free and forced convection scenarios are well-characterized in the literature, its counterpart in the mixed convection regime is relatively uncharted. Herein, condensation from an upward stream of humid air over a vertically mounted mild steel condenser surface is characterized under different flow velocities. The free-stream flow is thus directed opposite to the thermogravitational flow induced next to the plate. We observe that with increasing the magnitude of the upward flow velocity of the free stream, the condensation heat transfer coefficient (CHTC) initially decreases until it reaches a minimum at 0.4 m/s, beyond which the CHTC rises again with the flow velocity. Using the Nusselt analogy for mixed convection for the relevant flow regimes we substantiate our experimental findings and extend the observation for predicting condensation behavior under different experimental ambient conditions.

Refinement of Kelvin equation for condensation of water in CSH slits based on molecular simulation

The adsorption and condensation of water molecules in the pores of cementitious materials play a crucial role in the mechanical performance and durability of concrete. The Kelvin equation is generally employed to describe the water condensation in porous materials. However, it requires modification for condensation behavior in nano and micro scales of pores. In the present work, various widths of slit models for several cementitious minerals were established. The adsorption isotherms in slit pores were calculated using the hybrid of Grand Canonical Monte Carlo and Molecular Dynamics simulations, obtaining the relationship between the critical pressures for condensation and pore sizes. Then, a modified Kelvin equation was proposed, with discussion on a new reasonable method for determining the real thickness of adsorbed water film. The results demonstrate that condensation will occur in the slits within the critical width range, which promotes the surface adsorption to achieve complete adsorption. Therefore, the location of the interface between the adsorbed water film and condensed water bulk is fixed in the same mineral during condensation. The modified Kelvin equation shows higher accuracy than traditional Kelvin equations at the nano and micro scale. This work promotes a deeper understanding of the interaction mechanism of water with cementitious minerals and inspires more fundamental realization in the design of concrete durability.

Preferential water vapor condensation on a corrugated surface: A molecular dynamics study

In this study, we investigate the nucleation and subsequent growth of water clusters on corrugated surfaces using molecular dynamics simulations, with a specific focus on scenarios where the nanostructure sizes are comparable to the critical nucleus size. The primary objective is to reveal the coupled effects of different surface morphologies, i.e., plane, convex, and concave, on water vapor condensation. Regardless of the nanostructures, the condensation process can be divided into two stages, the nucleation stage and the growth stage. It is shown that in the nucleation stage, the concave areas are more conducive to nucleation compared to plane areas, aligning with classical nucleation theory. The total number of condensed molecules is generally proportion to the nucleation ability, while the average size of condensation clusters is affected by the surface nanostructures, with the combination of concave and plane surfaces exhibiting the strongest capability for both water vapor nucleation and cluster growth. Compared to the plane regions, the convex regions not only inhibit nucleation but also block collision and coalescence between clusters. Additionally, increasing the characteristic width of concave and convex structures leads to condensation behaviors approaching those on the plane surface. This indicates that the regulation of the condensation process is feasible by nanostructures within prescribed structural size limits.

Enhancing carbon capture: Exploring droplet wetting and gas condensation of carbon dioxide on nanostructured surfaces

The investigation of carbon dioxide (CO2) condensation on heat exchange surfaces is essential to the advancement of carbon capture, utilization, and storage (CCUS) technology. Molecular dynamics simulations are employed to explore the wetting and condensation behavior of CO2 on nanostructured surfaces. The results indicate that the contact angle of CO2 droplets on nanostructured surfaces is greater than that on smooth surfaces. Increasing the pillar height (h) or solid fraction (f) induces the transition of CO2 droplets from the Wenzel to Cassie state, resulting in an increased contact angle. Nanostructured surfaces significantly enhance the nucleation rate, with molecules initially nucleating at the bottom of the pillars. A higher h or f accelerates the nucleation rate during the condensation. Droplets in the Wenzel state exhibit higher heat transfer efficiency than those in the Cassie state. Additionally, the formation of Cassie-state CO2 droplets undergoes a dewetting transition, altering the heat conduction mode. The dewetting behavior of CO2 droplets favors their detachment from the surface, potentially reducing the initial heat resistance. Therefore, appropriately increasing h and f can promote nucleation and droplet growth, enhancing dewetting transition and mass transfer performance. These simulation results hold great importance for inspiring the design of future CO2-phobic surfaces and guiding CO2 condensation production.

Controlled condensation by liquid contact-induced adaptations of molecular conformations in self-assembled monolayers

Surface condensation control strategies are crucial but commonly require relatively tedious, time-consuming, and expensive techniques for surface-chemical and topographical engineering. Here we report a strategy to alter surface condensation behavior without resorting to any molecule-type or topographical transmutations. After ultrafast contact of liquids with and removal from surfaces, the condensation rate and density of water droplets on the surfaces decrease, the extent of which is positively correlated with the polarity of the liquid and the duration of contact. The liquid contact-induced condensation rate/density decrease (LCICD) can be attributed to the decrease of nucleation site density resulted from the liquid contact-induced adaption of surface molecular conformation. Based on this, we find that LCICD is applicable to various surfaces, on condition that there are flexible segments capable of shielding at least part of nucleation sites through changing the conformation under liquid contact induction. Leveraging the LCICD effect, we achieve erasable information storage on diverse substrates. Furthermore, our strategy holds promise for controlling condensation of other substances since LCICD is not specific to the water condensation process.

A novel numerical approach for assessing the gas-liquid flow characteristics in pipelines utilizing a two-fluid model

The accumulation of liquid condensate in the wet gas pipelines gives negative effects on the piping efficiency and flow managements. Accurate prediction of the condensate behavior is of crucial importance in the pipeline engineering. In this study, the one-dimensional two-fluid model with the stratified modeling in its source term is used to describe the gas-liquid kinetic motion along the pipe and the flow fields obtained from the newly proposed numerical approach are utilized to analyze the flow characteristics. Firstly, four cases with varying inlet liquid fractions, outlet pressures, and different meshes are utilized to investigate the gas-liquid steady-state variations along the pipe. The numerical results indicate that the outlet pressure influences the working pressure of the inlet gas-liquid, subsequently altering the equilibrium state and momentum exchange direction near the inlet, resulting in different condensate distributions in the pipeline. In the transient analysis with initial empty pipe, the inlet gas-liquid mainly impacts the pressure wave propagations in pressure spread stage, the gas kinetic motion in gas filling stage and the motion of the dividing interface between different regions in liquid filling stage, which is validated by the proposed numerical approach through comparison with the simulation tool OLGA designed by Schlumberger. Furthermore, when the liquid condensates appear in the initial state, the transition zones have two physical forms between different flow regions, which include the sudden dividing interface due to the high liquid amount carried by the inlet gas and the transition region resulted from the liquid accumulations.