This paper reports experimental and numerical studies on the cross-sectional compression resistance and behaviour of a novel L-shaped concrete-filled steel tube system. The novel composite system is proposed to eliminate concave corners and enhance the confinement of the outer steel tube to the concrete infill. A testing programme was firstly conducted, including nine tensile steel coupon tests, six compressive concrete cube tests and ten stub column tests. Upon testing, all the ten L-shaped concrete-filled steel tube stub column specimens were found to fail by local buckling. Finite-element models were then developed in the finite-element analysis software ABAQUS and validated against test results. The validated models were then employed to perform parametric studies to obtain an additional set of 48 numerical data. Test and numerical results were used to perform a design analysis, in which the suitability of the design rules in the European code EN 1994–1-1, the American specification ANSI/AISC 360 and the Chinese code GB 50936 for the developed L-shaped concrete-filled steel tube stub column system was assessed. The analysis results reveal that both EN 1994–1-1 and GB 50936 yield unsafe compression resistance predictions for the studied L-shaped concrete-filled steel tube stub columns, owing to the improper consideration of the contributions of the outer steel tube and the concrete infill to the overall capacity, while ANSI/AISC 360 offers safe design with high accuracy. The research findings are expected to contribute to the safe and wide use of the proposed novel L-shaped concrete-filled steel tube system in structural engineering and also to the further development of the current international design standards.