Ice-core Concentrations Research Articles

Estimation of gas record alteration in very low-accumulation ice cores

Abstract. We measured the methane mixing ratios of enclosed air in five ice core sections drilled on the East Antarctic Plateau. Our work aims to study two effects that alter the recorded gas concentrations in ice cores: layered gas trapping artifacts and firn smoothing. Layered gas trapping artifacts are due to the heterogeneous nature of polar firn, where some strata might close early and trap abnormally old gases that appear as spurious values during measurements. The smoothing is due to the combined effects of diffusive mixing in the firn and the progressive closure of bubbles at the bottom of the firn. Consequently, the gases trapped in a given ice layer span a distribution of ages. This means that the gas concentration in an ice layer is the average value over a certain period of time, which removes the fast variability from the record. Here, we focus on the study of East Antarctic Plateau ice cores, as these low-accumulation ice cores are particularly affected by both layering and smoothing. We use high-resolution methane data to test a simple trapping model reproducing the layered gas trapping artifacts for different accumulation conditions typical of the East Antarctic Plateau. We also use the high-resolution methane measurements to estimate the gas age distributions of the enclosed air in the five newly measured ice core sections. It appears that for accumulations below 2 cm ice equivalent yr−1 the gas records experience nearly the same degree of smoothing. We therefore propose to use a single gas age distribution to represent the firn smoothing observed in the glacial ice cores of the East Antarctic Plateau. Finally, we used the layered gas trapping model and the estimation of glacial firn smoothing to quantify their potential impacts on a hypothetical 1.5-million-year-old ice core from the East Antarctic Plateau. Our results indicate that layering artifacts are no longer individually resolved in the case of very thinned ice near the bedrock. They nonetheless contribute to slight biases of the measured signal (less than 10 ppbv and 0.5 ppmv in the case of methane using our currently established continuous CH4 analysis and carbon dioxide, respectively). However, these biases are small compared to the dampening experienced by the record due to firn smoothing.

Stratospheric eruptions from tropical and extra-tropical volcanoes constrained using high-resolution sulfur isotopes in ice cores

The record of volcanic forcing of climate over the past 2500 years is based primarily on sulfate concentrations in ice cores. Of particular interest are large volcanic eruptions with plumes that reached high altitudes in the stratosphere, as these afford sulfate aerosols the longest residence time in the atmosphere, and thus have the greatest impact on radiative forcing. Sulfur isotopes measured in ice cores can be used to identify these large eruptions because stratospheric sulfur is exposed to UV radiation, which imparts a time-evolving mass independent fractionation (MIF) that is preserved in the ice. However, sample size requirements of traditional measurement techniques mean that the MIF signal may be obscured, leading to an inconclusive result. Here we present a new method of measuring sulfur isotopes in ice cores by multi-collector inductively coupled plasma mass spectrometry, which reduces sample size requirements by three orders of magnitude. Our method allows us to measure samples containing as little as 10 nmol of sulfur, with a precision of 0.11‰ for δ34S and 0.10‰ for Δ33S, enabling a high-temporal resolution over ice core sulfate peaks. We tested this method on known tropical (Tambora 1815 and Samalas 1257) and extra-tropical (Katmai/Novarupta 1912) stratospheric eruptions from the Tunu2013 ice core in Greenland and the B40 ice core from Antarctica. These high-resolution sulfur isotope records suggest a distinct difference between the signatures of tropical versus extra-tropical eruptions. Furthermore, isotope mass balance on sulfate from extra-tropical eruptions provides a means to estimate the fraction of sulfate deposited that was derived from the stratosphere. This technique applied to unidentified eruptions in ice cores may thus improve the record of explosive volcanism and its forcing of climate.

Method for Correcting Continuous Ice-Core Elemental Measurements for Under-Recovery.

Measurement of elemental concentrations in ice cores are critical for determining atmospheric aerosol variations. For such measurements, acidified ice-core meltwater typically is analyzed continuously (<5 min after acidification) or discretely (∼3 months after acidification). The reduced acidification time during continuous analysis may result in a measured elemental concentration that is lower than the concentration of discrete analysis if particulates are not fully dissolved. To evaluate this, sections of three ice cores from Greenland and Antarctica were measured both continuously (4.5 min after acidification) and discretely (repeatedly from 1 to 151 days after continuous measurements), with discrete samples collected from the meltwater sample stream prior to continuous measurement. We show that elements such as Na, Sr, and S dissolved readily and therefore were fully recovered during continuous measurements. Average recovery for other elements was between 70 to 100% for Cd, Gd, Mg, Mn, U, and Yb, 50 to 90% for Ca, Ce, Sm, and V, and less than 50% for Al, Fe, and La. Given the advantages of continuous measurements, we conclude that the preferred method for ice-core measurements is continuous analysis with simultaneous discrete sample collection, followed by adjustment of the continuous measurements based on discrete sample analysis at least 3 months after acidification.

Annual layer counting using pollen grains of the Grigoriev ice core from the Tien Shan Mountains, central Asia

ABSTRACTPollen grains are commonly found in ice cores, particularly those from mountain glaciers at low to middle latitudes. Because the release of pollen from flowers has a seasonality and varies among the plant species, pollen concentrations in ice cores are useful for distinguishing annual or seasonal layers and inferring past vegetation near glaciers. We analyzed major pollen grains in an 87-m-deep ice core drilled at the top of the Grigoriev Ice Cap (4563 m.a.s.l.) in the Tien Shan Mountains, Kyrgyz Republic. Microscopy showed that mainly five pollen taxa were contained in the ice core. Their abundance fluctuated with the depth of the core, indicating their seasonal deposition on the ice cap, while the seasonality of the stable isotopes was not particularly clear because of melting and refreezing signatures. Based on the pollen profiles, annual layers were determined back in time to 1780 AD at a depth of 63.6 m; at greater depth, they could not be distinguished due to ice layer thinning in the glacier. The pollen assemblages have gradually changed during the last 220 years and were particularly distinctive in the deeper part, suggesting the drastic change of vegetation in this region during the Holocene.

Concomitant variability in high-latitude aerosols, water isotopes and the hydrologic cycle

The interpretation of ice-core records rests on understanding the processes affecting trace constituents of the atmosphere that are preserved in ice. Stable-isotope ratios of ice are widely used as a palaeothermometer, an interpretation backed by well-established theory. In contrast, the interpretation of aerosols such as mineral dust and sea salts has remained a topic of debate. Here, we demonstrate that both the fractionation of water isotopes and the scavenging of aerosols are fundamentally driven by the same process, the condensation of water from the atmosphere. Water isotope ratios and aerosol concentrations in ice cores are remarkably coherent on all timescales longer than a few centuries. This shared low-frequency variability is dominated by the essential physics of the hydrologic cycle, which also accounts for the difference in variability between marine- and terrestrial-sourced aerosols in ice cores, as well as the global spatial pattern of aerosol changes recorded in both marine sediments and ice. These results have implications for past changes in radiative forcing and other fundamental aspects of climate, such as polar amplification, which are imprinted on the relationships between these proxy records. On timescales of centuries and longer, aerosol concentrations in Antarctic ice are controlled by changes in the nature of mid- and high-latitude precipitation, according to analyses of palaeoclimate data.

Dependence of ice-core relative trace-element concentration on acidification

AbstractTo assess the role of methodological differences on measured trace-element concentrations in ice cores, we developed an experiment to test the effects of acidification strength and time on dust dissolution using snow samples collected in West Antarctica and Alaska. We leached Antarctic samples for 3 months at room temperature using nitric acid at concentrations of 0.1, 1.0 and 10.0% (v/v). At selected intervals (20 min, 24 hours, 5 days, 14 days, 28 days, 56 days, 91 days) we analyzed 23 trace elements using inductively coupled plasma mass spectrometry. Concentrations of lithogenic elements scaled with acid strength and increased by 100–1380% in 3 months. Incongruent elemental dissolution caused significant variability in calculated crustal enrichment factors through time (factor of 1.3 (Pb) to 8.0 (Cs)). Using snow samples collected in Alaska and acidified at 1% (v/v) for 383 days, we found that the increase in lithogenic element concentration with time depends strongly on initial concentration, and varies by element (e.g. Fe linear regression slope = 1.66; r = 0.98). Our results demonstrate that relative trace-element concentrations measured in ice cores depend on the acidification method used.

Production rate and climate influences on the variability of 10Be deposition simulated by ECHAM5‐HAM: Globally, in Greenland, and in Antarctica

Ice core concentrations of 10Be are used as a proxy for solar activity, but they might be affected by atmospheric transport and deposition and their changes. During the Holocene, the influence is likely to be small, but during glacials it has to be accounted for. First, the climate influence has to be understood during the present climate. This study uses an ECHAM5‐HAM 30‐year climatological simulation of 10Be to investigate the production and climate‐related influences on 10Be deposition with focus on Greenland and Antarctica. We examine the climate modes driving snow accumulation and hence potentially 10Be deposition over a climatologically relevant period. The North Atlantic Oscillation (NAO) is found to be the main driver of changes in precipitation and 10Be deposition in Greenland, in agreement with previous studies. In Antarctica, the picture is more complex as precipitation and 10Be deposition are only weakly correlated with the Southern Annular Mode (SAM), El Niño‐Southern Oscillation (ENSO), or Zonal Wave 3 pattern (ZW3). The results suggest that on seasonal scale, 10Be deposition is linked with both precipitation rate and tropopause height, mainly due to the similar seasonal cycle. However, the correlation with tropopause height persists on the annual time scale. All in all, 10Be variability in Antarctica is an interplay of several processes whose contribution varies in time and space. When interpreting 10Be ice core records for solar activity, the time scale is essentially important. On seasonal scale, the 10Be signal is dominated by weather influences, but on multiannual scales, the production rate is the main driver. On multidecadal scale, large long‐term trends in climatic factors have the potential to distort the signal again as is seen in 10Be records during glacials. This study shows how climate modes connect to 10Be variability and how this connection could be used to correct for the climate impact. The established connections during present climatic conditions can be used as a basis to investigate these connections during glacial climate in a glacial model simulation.

Little Ice Age climate and oceanic conditions of the Ross Sea, Antarctica from a coastal ice core record

Abstract. Increasing paleoclimatic evidence suggests that the Little Ice Age (LIA) was a global climate change event. Understanding the forcings and associated climate system feedbacks of the LIA is made difficult by the scarcity of Southern Hemisphere paleoclimate records. We use a new glaciochemical record of a coastal ice core from Mt. Erebus Saddle, Antarctica, to reconstruct atmospheric and oceanic conditions in the Ross Sea sector of Antarctica over the past five centuries. The LIA is identified in stable isotope (δD) and lithophile element records, which respectively demonstrate that the region experienced 1.6 ± 1.4 °C cooler average temperatures prior to 1850 AD than during the last 150 yr and strong (&gt;57 m s−1) prevailing katabatic winds between 1500 and 1800 AD. Al and Ti concentration increases of an order of magnitude (&gt;120 ppb Al) are linked to enhanced aeolian transport of complex silicate minerals and represent the strongest katabatic wind events of the LIA. These events are associated with three 12–30 yr intervals of cooler temperatures at ca. 1690 AD, 1770 AD and 1840 AD. Furthermore, ice core concentrations of the biogenic sulphur species MS− suggest that biological productivity in the Ross Sea polynya was ~80% higher prior to 1875 AD than at any subsequent time. We propose that cooler Antarctic temperatures promoted stronger katabatic winds across the Ross Ice Shelf, resulting in an enlarged Ross Sea polynya during the LIA.

A new approach to the long-term reconstruction of the solar irradiance leads to large historical solar forcing

The variable Sun is the most likely candidate for natural forcing of past climate change on time scales of 50 to 1000 years. Evidence for this understanding is that the terrestrial climate correlates positively with solar activity. During the past 10,000 years, the Sun has experienced substantial variations in activity and there have been numerous attempts to reconstruct solar irradiance. While there is general agreement on how solar forcing varied during the last several hundred years --- all reconstructions are proportional to the solar activity --- there is scientific controversy on the magnitude of solar forcing. We present a reconstruction of the Total and Spectral Solar Irradiance covering 130 nm--10 $\mu$m from 1610 to the present with annual resolution and for the Holocene with 22-year resolution. We assume that the minimum state of the quiet Sun in time corresponds to the observed quietest area on the present Sun. Then we use available long-term proxies of the solar activity, which are $^{10}$Be isotope concentrations in ice cores and 22-year smoothed neutron monitor data, to interpolate between the present quiet Sun and the minimum state of the quiet Sun. This determines the long-term trend in the solar variability which is then superposed with the 11-year activity cycle calculated from the sunspot number. The time-dependent solar spectral irradiance from about 7000 BC to the present is then derived using a state-of-the-art radiation code. We derive a total and spectral solar irradiance that was substantially lower during the Maunder minimum than observed today. The difference is remarkably larger than other estimations published in the recent literature. The magnitude of the solar UV variability, which indirectly affects climate is also found to exceed previous estimates. We discuss in details the assumptions which leaded us to this conclusion.

Constituent elements of insoluble and non-volatile particles during the Last Glacial Maximum exhibited in the Dome Fuji (Antarctica) ice core

AbstractIn order to find environmental signals based on the dust and calcium-ion concentrations in ice cores, we determine the constituent elements of residue particles obtained after melting ice samples. We have designed a sublimating system that operates at −45°C, below the eutectic temperatures of major salts. This system permits us to obtain a great many non-volatile particles. After studying the non-volatile particles, we immersed them in water to remove soluble particles and compounds. We thereby analyzed a total of 1272 residue particles (from the melted sample), 2418 non-volatile particles (after sublimation) and 1463 insoluble particles taken from five sections of Last Glacial Maximum ice from the Dome Fuji (Antarctica) ice core. Their constituent elements were determined by scanning electron microscopy/energy-dispersive X-ray spectrometry (SEM-EDS) and compared to the dust, calcium-ion and sodium-ion concentrations measured by ion chromatography. Our results indicate that &gt;99.9% of the insoluble particles contain silicon but no sulfur, nitrogen or chlorine. A significant number of the non-volatile particles, however, contain sulfur and chlorine. We conclude that insoluble dust consists mostly of silicate, that almost all calcium ions originate from calcium sulfate and that almost all sodium ions originate from sodium sulfate and sodium chloride.

Ecological responses of Antarctic krill to environmental variability: can we predict the future?

AbstractAntarctic krill are a key species in the Southern Ocean ecosystem, and their life cycle appears to be correlated with, and by implication dependent upon, seasonal sea ice dynamics. Moving from correlations with environmental parameters to an understanding of the mechanisms that lead to these correlations may allow predictions of the consequences of climate change on the distribution of favourable habitat for Antarctic krill. During winter cruises in 2001 and 2002 in the region west of the Antarctic Peninsula, one of the most rapidly warming regions on the planet, ice camps were established for periods of 3–9 days. Timing of sea ice advance, chlorophyll a concentrations in ice cores, and growth rates and pigment content of larval krill all differed significantly between winters. Growth rates and pigment content of larval krill from the same ice floe were correlated, suggesting that growth rates in winter are a function of the biomass of the sea ice microbial community. Apossible mechanism underlying the correlation between recruitment success and timing of ice advance is proposed. In conjunction with other postulated habitat requirements, this proposed mechanism allows for speculation about future changes in the geographic location of favourable habitat for Antarctic krill.

Sea‐salt aerosol distribution during the Last Glacial Maximum and its implications for mineral dust

Sea‐salt aerosols and mineral dust in ice cores are complementary in their use as indicators of past climate because of their differing dependence on the various factors affecting their deposition rates, such as winds, precipitation, and soil properties. Here sea‐salt aerosol distributions for the Last Glacial Maximum (LGM) and for the modern climate are simulated using an online passive aerosol model in the Canadian Centre for Climate Modelling and Analysis second‐generation general circulation model. Comparison of simulated deposition rates of sea salt from the open ocean with polar ice core concentrations indicates that a 75‐fold enhancement, beyond that indicated by the model, is necessary for consistency with the Greenland ice core observations and an approximate tenfold additional enhancement is necessary for Antarctica. However, considering sea ice as a possible sea‐salt aerosol source allows greater simulated LGM deposition in Greenland, though there is a great deal of uncertainty in the possible magnitude of this. Using very simple models for which 1–2% of the total modern sea‐salt aerosol comes from ice‐covered areas, the ice core data can be accommodated by a sevenfold to tenfold overall additional LGM source enhancement. The fact that these additional enhancement factors are similar to the enhancement factor previously determined for mineral dust using the same general circulation model suggests that some combination of increased LGM surface winds and transport or deposition to ice core locations is necessary for agreement with the ice core data.

Are changes in atmospheric cleansing responsible for observed variations of impurity concentrations in ice cores?

A simple model tests the effect on ice-core impurity concentrations of climate-induced changes in the physical conditions of the atmosphere influencing transport and deposition processes, while keeping source areas and production rates constant. The model results show that the increased glacial concentrations observed for most impurities can be explained entirely by changes in transport and deposition. No increase in source emission is necessary, however possible, to explain the ten-fold increase in impurity concentrations during the Last Glacial Maximum. This shows that the effect of dynamic changes in the atmosphere can be large and has to be taken into account before translating deposition records into emission records. The total impurity content in the global atmosphere during the glacial period was higher if dynamic changes in the atmosphere rather than source-emission changes were responsible for the variations observed in polar areas. This implies that a climate-forcing mechanism is to be found in the dynamics of the atmosphere, since the radiative properties of the atmosphere depend on the total content of impurities in the atmosphere. The effect on the climate can probably be compared with, although opposite in sign to, the present-day anthropogenic greenhouse forcing.

Are changes in atmospheric cleansing responsible for observed variations of impurity concentrations in ice cores?

A simple model tests the effect on ice-core impurity concentrations of climate-induced changes in the physical conditions of the atmosphere influencing transport and deposition processes, while keeping source areas and production rates constant. The model results show that the increased glacial concentrations observed for most impurities can be explained entirely by changes in transport and deposition. No increase in source emission is necessary, however possible, to explain the ten-fold increase in impurity concentrations during the Last Glacial Maximum. This shows that the effect of dynamic changes in the atmosphere can be large and has to be taken into account before translating deposition records into emission records. The total impurity content in the global atmosphere during the glacial period was higher if dynamic changes in the atmosphere rather than source-emission changes were responsible for the variations observed in polar areas. This implies that a climate-forcing mechanism is to be found in the dynamics of the atmosphere, since the radiative properties of the atmosphere depend on the total content of impurities in the atmosphere. The effect on the climate can probably be compared with, although opposite in sign to, the present-day anthropogenic greenhouse forcing.

An ice-core record of atmospheric response to anthropogenic sulphate and nitrate

RECORDS of sulphate and nitrate concentrations in ice cores show that these concentrations have increased recently because of the long-range transport of pollution from middle latitudes1–5. But these records have been neither complete enough nor long enough to allow an assessment of their sensitivity to variations in the emissions of sulphate and nitrate precursors. We have now analysed sections from an ice core in South Greenland which have allowed us to extend its sulphate and nitrate record back from 1869 to 1767. This longer record has enabled us to determine the pre-industrial natural interannual variability of non-sea-salt sulphate and nitrate. We find that the background concentration in the remote atmosphere over South Greenland is sensitive to changes in the anthropogenic emissions of sulphate and nitrate, and responds to these variations on a timescale of the order of decades.

The past 5000 years history of solar modulation of cosmic radiation from 10 Be and 14 C studies

10 Be is produced in a similar way as 14 C by the interaction of cosmic radiation with the nuclei in the atmosphere. Assuming that the 10 Be and 14 C variation are proportional and considering the different behaviour in the Earth system, the 10 Be concentrations in ice cores can be compared with the 14 C variations in tree rings. A high correlation is found for the short-term variations ( 14 C-Suess-wiggles). They reflect with a high probability production rate variations. More problematic is the interpretation of the long-term trends of 14 C and 10 Be. Several explanations are discussed. The reconstructed CO 2 concentrations in ice cores indicate a rather constant value (280 ± 10 p.p.m. by volume) during the past few millenia. Measurements on the ice core from Byrd Station, Antarctica, during the period 9000 to 6000 years BP indicate a decrease that might be explained by the extraction of CO 2 from the atmosphere-ocean system to build the terrestrial biomass pool during the climatic optimum.

10Be in polar Ice: Data reflect changes in cosmic ray flux or polar meteorology

We have theoretically estimated the expected changes in the global cosmic ray production of 10Be in the atmosphere with changes in solar activity, and the consequent variations in its fallout in the polar regions. The global 10Be production rate is found to be about 20% higher during periods of very low solar activity, compared to the average solar modulation level observed during the past 3 solar cycles. The stratospheric 10Be fallout pattern has been derived using the fallout data for 90Sr as an analog. This fallout shows an amplitude attenuation by a factor of about three at 70°; the higher the latitude, the higher the attenuation. The results have been compared with the long time series available for 10Be in polar ice in Greenland and in Antarctica, 70°‐78° latitude. It is concluded that the observed variations in 10Be concentrations in ice cores are primarily due to climatic changes, for both short and long period variations. Thus 10Be data can be used as a proxy for climate induced meteorological changes in the polar region.

Sodium, magnesium, potassium and calcium concentrations in ice cores from the Law Dome, Antarctica

The concentrations of Na, Mg, K and Ca have been determined in three ice cores drilled along a flow line on the Law Dome, Antarctica. Average cationic concentrations in the upper sections of the cores show a marked decrease in concentration with increasing distance from the coast. A depth profile of the core drilled 5 km from the coast near Cape Folger indicates that the ice below 260 m was precipitated in a colder climate regime, probably towards the end of the Wisconsin stage. The depth profile of the core located at the summit of the dome, 110 km from the coast, shows an unexpected steady increase in the concentration of cations with depth. This may indicate an increase in precipitation, or a gradual change in wind patterns on the dome over recent centuries.