The lower limb exoskeletons are used to assist wearers in various scenarios such as medical and industrial settings. Complex modeling errors of the exoskeleton in different application scenarios pose challenges to the robustness and stability of its control algorithm. The Radial Basis Function (RBF) neural network is used widely to compensate for modeling errors. In order to solve the problem that the current RBF neural network controllers cannot guarantee the asymptotic stability, a neural network robust control algorithm based on computed torque method is proposed in this paper, focusing on trajectory tracking. It innovatively incorporates the robust adaptive term while introducing the RBF neural network term, improving the compensation ability for modeling errors. The stability of the algorithm is proved by Lyapunov method, and the effectiveness of the robust adaptive term is verified by the simulation. Experiments wearing the exoskeleton under different walking speeds and scenarios were carried out, and the results show that the absolute value of tracking errors of the hip and knee joints of the exoskeleton are consistently less than 1.5°and 2.5°, respectively. The proposed control algorithm effectively compensates for modeling errors and exhibits high robustness.