Decrease In Compressive Strength Research Articles

Composite Materials with Glass Fiber Waste and Blast Furnace Slag

Fiberglass is a waste generated in the construction materials industry, which is not dangerous for the environment, but long-term and very long-term storage is expensive. Finding a method of reuse as in creating a useful composite material led to the research work in this study. The impact of waste fiberglass and furnace slag on the characteristics of novel composite materials was examined in this study. The density and mechanical properties of the composite samples were examined to determine the impact of waste fiberglass (WFG) concentration in it. Washed river aggregates were replaced with WFG in various ratios in our laboratory tests. Concrete class C16/20 was utilized, having 0.35–0.7 w. % WFG and 2–10% slag. The obtained material was evaluated for density, workability, and compressive strength. The experiments were carried out in an accredited concrete station laboratory. The density of the resulting materials decreased as the WFG content was increased. The densities were higher than the witness sample, ranging from 2358 to 2405 kg/m3. The findings show that adding WFG and slag to concrete has a positive impact on its characteristics. With the addition of WFG, the mixture became more non-homogenous, but these characteristics can be optimized in future. Because of the differential in density between WFG and natural coarse aggregates, the fresh density of obtained composites dropped as the percentage of WFG increased; this could be an advantage, as the newly obtained material became lighter. The findings show that adding waste to concrete has a detrimental impact on its qualities. The introduction of blast furnace slag up to 5% does not modify the compressive strength, compared to the reference samples, but 10% slag causes a decrease in compressive strength of 4.2%. A proportion of 0.25% WFG causes a slight increase in mechanical strength; therefore, 0.25% WFG and 5% slag increased the compressive strength, the maximum value being obtained for a composite with 0.25% WFG, 5% slag, 5% sand and aggregates. Capitalization of WFG and slag resulted in significant economic and environmental benefits by reducing waste storage costs and production costs, and advantages resulted from the new material.

Performance Research of Cement Concrete Pavements with a Lower Carbon Footprint

The growing interest in the use of building materials with a reduced carbon footprint was the aim of this research assessing the impact of four different types of low-emission cements on the properties of cement concretes used for the construction of local roads. This research work attempted to verify the strength characteristics and assess the durability of such solutions, which used the commonly used CEM I 42.5 R pure clinker cement and three multi-component cements: CEM II/A-V 42.5 R, CEM III/A 42.5 N-LH/HSR/NA, and CEM V/A S-V 42.5 N-LH/HSR/NA. Cement was used in a constant amount of 360 kg/m3, sand of 0/2 mm, and granite aggregate fractions of 2/8 and 8/16 mm. This research was carried out in two areas: the first concerned strength tests and the second focused on the area of assessing the durability of concrete in terms of frost resistance F150, resistance to de-icing agents, water penetration under pressure, and an analysis of the air entrainment structure in concrete according to the PN EN 480-11 standard. Analyzing the obtained test results, it can be concluded that the highest compressive strength of more than 70 MPa was obtained for CEM III concrete, 68 MPa for CEM V concrete, and the lowest for CEM I cement after 90 days. After the durability tests, it was found that the smallest decrease in compressive strength after 150 freezing and thawing cycles was obtained for CEM III (−0.9%) and CEM V (−1.4%) concretes. The high durability of concrete is confirmed by water penetration tests under pressure, because for newly designed recipes using CEM II, CEM III, and CEM V, water penetration from 17 mm to 18 mm was achieved, which proves the very high tightness of the concrete. The assessment of the durability of low-emission cements was confirmed by tests of resistance to de-icing agents and the aeration structure performed under a microscope in accordance with the requirements of the PN-EN 480-11 standard. The obtained analysis results indicate the correct structure and minimal spacing of air bubbles in the concrete, which confirms and guarantees the durability of concrete intended for road construction. Concretes designed using CEM V cement are characterized by a carbon footprint reduction of 36%, and for the mixture based on CEM III, we even observed a decrease of 39% compared to traditional concrete. Concrete using CEM II, CEM III, and CEM V cements can be successfully used for the construction of local roads. Therefore, it is necessary to consider changing the requirements of the technical specifications recommended for roads in Poland.

C–S–H-PCE nanoparticles and anionic surfactants as nucleation agent in cement based materials: Focus on the antagonism

The small solid particles and surfactants inclusion have the potential to furnish abundant nucleation sites, yet the concurrent operation mechanisms in cement remain unclear. Thus, calcium-silicate-hydrate-polycarboxylate ether (C–S–H-PCE) nanoparticles and calcium stearate (CaSt2) all were introduced as composites nucleation agents in this work, and then the properties of fresh cement paste, hydration process and microstructure of hardened pastes were especially investigated. Experimental results demonstrated that C–S–H-PCE and CaSt2 enhanced cement hydration by utilizing their ability to provide nucleation sites, but they were less compatible. Therefore, the combination showed the antagonistic effects: a decrease in fluidity and compressive strength. The decrease in fluidity was mainly attributed to the lowered particle dispersion. The decrease in compressive strength was associated with a lower overall density and increased cumulative porosity of the C–S–H gels. This work establish the theoretical foundation for selecting components of green composite nucleation agents.

Effects of basalt fibre and rubber particles on the mechanical properties and impact resistance of concrete

The application of waste rubber particles and basalt fibre (BF) in concrete can not only improve the performance of the resulting concrete but also alleviate the environmental pressures related to waste tire disposal. In this study, the impacts of rubber particles and BF on the mechanical and impact performance of concrete are experimentally investigated. Additionally, the macroscopic test phenomenon is explained based on the appearance of the microstructure. The results show that for basalt fibre-reinforced concrete (BFC), when the BF content increases from 0 to 0.4 %, the cube compressive strength and elastic modulus decrease from 71.5 MPa to 62.5 MPa and 44.5 GPa to 41.0 GPa, respectively, while the bending strength increases from 5.9 MPa to 6.6 MPa and then decreases to 6.3 MPa. A BF content of 0.3 % is selected to prepare basalt fibre-reinforced rubber concrete (BFRC). As the rubber particle content of BFRC increases from 0 to 20 %, the cube compressive strength, elastic modulus and bending strength decrease from 64.3 MPa to 51.5 MPa, 41.9 GPa to 33.5 GPa and 6.6 MPa to 5.9 MPa, respectively. However, the reduction rate of the mechanical properties of BFRC is approximately half that of fibre-free rubber concrete at the same rubber content. The shapes of the stressstrain curves of the BFC and normal concrete (NC) are similar, whereas the descending stage of the stressstrain curve of the BFRC is obviously gentler, and the whole BFRC stressstrain curve is much fuller, reflecting typical ductile failure. Both the BF and rubber particles contribute to impact performance improvement, but the effect of the rubber particles is much greater than that of the BF. Compared with that of the NC, the incorporation of 0.3 % BF increases the initial crack impact energy (W1) and final crack impact energy (W2) by 71 % and 79 %, respectively, but when 20 % rubber particles are additionally added, the increase rates of W1 and W2 reach 668 % and 686 %, respectively. The impact life evolutions of BFC and BFRC can be described effectively by a two-parameter Weibull distribution function.

Exploring enhanced high-temperature resistance: Analyzing the combined impact of fibers and nanoparticles in mortars

This study aims to explore the potential synergistic effect of polypropylene (PP) fiber and different types of nanoparticles to improve the high-temperature resistance of cementitious materials. For that, mortar samples with different PP fiber percentages, 0.6 wt% and 1.2 wt%, were produced. Different percentages of both colloidal nano-silica (CNS), 0.3 %, 0.6 %, and 0.9 %, and nano calcium carbonate (NCC), 0.5 %, 1 %, and 2 %, were used in the study. To test the resistance to elevated temperatures, mortar samples were exposed to different peak temperatures of 300°C, 600°C, and 900°C for 2 h, using unexposed samples as reference. Flexural and compressive strength, water absorption, surface electrical resistivity, and thermogravimetric analysis (TGA) of the heated and unheated samples were conducted. Results showed that, at 300°C heating regime, all samples with 0.6 % PP fiber exhibited an increase in flexural and compressive strength compared to their corresponding reference samples. For instance, specimens containing 0.6 % PP fiber and 2 % NCC content exhibited a 19 % increase in flexural strength compared to the unheated sample, whereas samples with 0.6 % PP fiber and 0.5 % NCC increased 32 % their compressive strength. In contrast, at 600°C, there was a major decline in mechanical properties in all samples, with samples containing NCC exhibiting the lowest amount (average of 61 % reduction in flexural strength and 32 % decrease in compressive strength). In general, a higher dosage of nanoparticles and lower PP fiber content will be better to resist temperatures up to 600 °C.

The Influence of Recycled Coarse Aggregate Content on the Properties of High-Fly-Ash Self-Compacting Concrete

In Vietnam, solid waste from construction activities significantly impacts environmental pollution. Recycled concrete aggregate (RCA), derived from waste concrete, can serve as a coarse aggregate in concrete production. However, compared to natural aggregates, RCA exhibits distinct characteristics, including lower strength, higher water absorption, and an increased angular and rough surface. These properties may influence concrete’s workability, compressive strength, and durability. This research investigates the influence of RCA on the properties of High-Fly-Ash Self-Compacting Concrete (SCC). The study explores various replacement levels of natural coarse aggregate with RCA (0%, 50%, 75%, and 100%), alongside a 50% volume fraction of fly ash. Key concrete properties evaluated include workability, compressive strength, flexural strength, and chloride ion permeability. The findings reveal that using 100% RCA in combination with a high fly ash content (50%) produces SCC that meets workability requirements according to EFNARC standards. However, there are trade-offs: the compressive strength decreases by 4.61%, the flexural strength decreases by 3.1%, and chloride ion permeability increases by 57.57% compared to the control sample (using natural aggregates). Notably, the chloride ion permeability of SCC using 100% RCA falls into the category of low permeability. Doi: 10.28991/CEJ-SP2024-010-04 Full Text: PDF

Predicting the failure of rock using critical slowing down theory on acoustic emission characteristics

The joint surfaces and size affect the mechanical behavior and failure precursors of shale. Therefore, this paper studies the mechanical behavior, the response characteristics of acoustic emission (AE) and critical slowing down (CSD) characteristics of AE for shale with different joint surfaces and size. The results show that with an increase in the number of joint surfaces and the size of the sample, the crack initiation stress, uniaxial compressive strength (UCS), peak strain, and fractal dimension decrease. During the plastic stage, the occurrence of a sharp rise in AE ringing count, RA, a low-frequency, high-amplitude AE signal, and a rapid drop in AF can be characteristics of impending sample failure. Variance and autocorrelation coefficients can be used to characterize the CSD phenomenon. The optimal window length and lag step are determined to be 400 and 100, respectively. The CSD characteristics of the autocorrelation coefficient and the variance of multi-AE parameters are obtained. The variance-based early warning time provides short-term early warning, while the autocorrelation coefficient-based early warning time provides early warning. The research results can provide theoretical references for the mechanical design and failure prediction of underground rock engineering.

Experimental and Numerical Simulation Investigation of Cement Sheath Integrity during Multi-Stage Fracturing in Offshore Tight Oil Reservoir

The integrity of the cement sheath is susceptible to failure during multi-stage fracturing. In this study, the failure mechanisms of cement sheath integrity during multi-stage fracturing in the A offshore tight oil reservoir wells were investigated. The cement samples were subject to triaxial compression test (TCT), triaxial cyclic loading test (TCLT), and permeability test. A full-scale device was constructed for cement sheath integrity experiments. Additionally, a 3-D finite element model was developed to simulate the interface debonding and the subsequent growth of micro-annuli throughout multi-stage fracturing. The results revealed that TCLT induced cumulative plastic deformation in the cement samples, resulting in a 10.7% decrease in triaxial compressive strength, an 8.3% decrease in elastic modulus, and a 150% increase in permeability. Despite these significant variations, no serious damage was caused to the cement sheath matrix. It was observed that gas leakage occurred at the 8th, 10th, and 14th cycles under cyclic loading with upper limits of 70 MPa, 80 MPa, and 90 MPa, respectively. After 15 cycles, the experimentally measured widths of micro-annuli were 117 μm, 178 μm, and 212 μm, which were in good agreement with simulation results of 130 μm, 165 μm, and 205 μm, respectively. These findings elucidate the causes of cement sheath integrity failure, providing insights into the failure mechanisms of cement sheath integrity during multi-stage fracturing.

Mechanics and permeability properties of ecological concrete mixed with recycled engineering muck particles

The excavation of construction foundation pits, tunnels, channels, and other projects generates a significant volume of engineering muck, posing challenges in management. Prolonged accumulation of this muck can lead to environmental pollution. The effective recycling of this type of construction waste is crucial for the advancement of a circular economy, necessitating immediate attention to research and solutions. In this study, a novel method is introduced for the preparation of low-carbon and environmentally friendly ecological concrete. This method involves the utilization of recycled engineering muck particles to substitute a portion of the natural aggregate and enables the comprehensive recycling of engineering muck. Subsequently, the mechanical and permeability properties of ecological concrete under varying muck particle content and porosity conditions are analyzed through experiments, taking into account the impact of relative average pore diameter and pore tortuosity. A predictive model has been developed for the tortuosity of pore channels in ecological concrete, taking into account effective porosity and average pore diameter. The enhanced Kozney-Carman model is employed to describe the correlation between pore properties and hydraulic conductivity. The findings indicate that a composite curing agent is formed by combining ordinary Portland cement with a hydrophilic polyurethane solution. This composite curing agent demonstrates superior performance compared to pure cement in the solidification of engineering muck. As the replacement rate of unsintered recycled residue particles increases, the porosity of concrete may increase by up to 29.7 %. This results in enhanced permeability characteristics but a decrease in compressive strength. In contrast to lightweight aggregates manufactured through the sintering process, the carbon emissions of unsintered recycled residue particles are reduced by 57.7 %. This study provides suggestions for the repurposing of construction waste and contributes to the advancement of sustainable practices within the concrete production sector.

Effects of carbonation curing on chemical attack in cement paste incorporating liquid-crystal display glass powder as a partial binder replacement

This study investigates the chemical resistance of cement paste by incorporating liquid-crystal display (LCD) glass powder as a partial replacement for cement. The samples, cured under water and carbonation, were subjected to adverse chemical attacks over a period of up to 90 days, using MgSO4 and H2SO4 for the sulphate attack and acid attack, respectively. The results demonstrate a decrease in compressive strength by upto 14.63% and 32.32% for water- and carbonation-cured samples, respectively, and an increase in carbonation degree by upto 100% with the incorporation of glass powder at 28 days. Under sulphate attack, water curing and carbonation curing displayed strength increase of 21.24–36.13% and 7.56–8.06%, respectively, at 90 days. However, carbonation-cured samples experienced greater leaching of silica and calcium. The compressive strength decreased with acid attack duration, with glass powder incorporation mitigating strength loss in carbonation-cured samples. At 30 days, with an incorporation rate of 30% glass powder, the strength loss was reduced by 37.66% for the carbonation-cured samples. The enhanced resistance with incorporation of glass powder was also evident from mercury intrusion porosimetry results that indicated decreased intrusion levels. Visual inspection revealed a different consistency of white substance deposition, suggesting resistance mechanisms differed between curing methods.

Development and characterization of a composite material with geopolymer matrix obtained by incorporation of microparticles from plastic bottles

The composite material with a geopolymer matrix of 7 M molarity, obtained by incorporating microparticles from plastic bottles is developed and characterized in the present paper. To do this, we made cylindrical specimens whose the diameters are the half of their heights and stored them at a temperature of (31±2°C). The compression test using a hydraulic press is carried out, as well as the thermal characterization test using a device respecting the experimental method of the asymmetric hot plane, which was used to determine the thermal conductivity, the volumetric heat capacity, the effusivity and the diffusivity. Then optical characterization tests on hardened samples were carried out, namely chemical analyses of the composition of the kaolin, and particle size characterization of the raw microscopic imaging of the specimens. The results found showed that as the amount of polyethylene terephthalate increases, the compressive strength decreases by 33.65 % for 10%polyethylene terephthalate and 67.77 % for 20 % polyethylene terephthalate. According to the thermal conductivity, it improves with the percentage of polyethylene terephthalate added as: at 10% it is 1.19Wm−1K−1 and at 20%, one has 0.595Wm−1K−1; similarly for effusivity where we obtained 1376.05 JK−1m−2s−1/2 and 560.81 JK−1m−2s−1/2 for 0 and 20% respectively. According to these results, the use of polyethylene terephthalate aggregates as a partial substitute of aluminosilicate raw material for the development of a composite can be a good alternative for recycling plastic bottle waste. The composite obtained could be used for the manufacture of ceiling lights and brick facings, and therefore would significantly reduce the amount of waste plastic produced every day in environment.

Study on the evolution patterns of concrete lining’s physical and mechanical properties under sulfuric acid corrosion conditions

During operation, deep water storage and drainage tunnels may face sulfuric acid corrosion resulting from microbiologically induced chemical reactions. In this study, sulfuric acid corrosion experiments were performed on C60 concrete specimens with steel fiber volume ratios of 0% (plain) and 1% using a sulfuric acid solution with an initial pH of 1. For one-face corrosion, five faces of cubic concrete samples were coated with exposed resin, leaving only one face exposed to sulfuric acid. For all-face corrosion, all faces were exposed to sulfuric acid. Concrete corrosion under different loading conditions was compared by adding weights on top of the concrete. Rate of mass change variations and uniaxial compressive strength at various corrosion time points were monitored. The results indicated that after sulfuric acid corrosion, there was an increase in the mass but an overall decrease in the strength of the specimens. Compared with all-face corrosion, one-face corrosion led to a smaller increase in the mass of the concrete specimens and a more substantial decrease in strength, primarily because of the slower corrosion rate and reduced gypsum formation. Compared to plain concrete, steel fiber-reinforced concrete experienced a lower increase in the mass of the concrete specimens because the steel fibers obstructed sulfuric acid infiltration. However, there was significant corrosion of the steel fibers and surrounding concrete owing to accumulation of sulfuric acid around the former, resulting in a more substantial decrease in the uniaxial compressive strength of the steel fiber-reinforced concrete. With increasing load, the rate of change in the concrete mass initially decreased and then increased; this could be because increased loads densify the concrete, hindering sulfuric acid infiltration and promoting the development of microcracks within the concrete, thereby enhancing the effects of sulfuric acid corrosion.

A comprehensive study on bioactivity, mechanical and tribological behavior of copper-doped borosilicate glass derived from natural waste for dental applications

The present study investigates in-vitro biomineralization, mechanical, and tribological properties of bioactive borosilicate glass composed of 31B2O3–20SiO2-(24.5-x)Na2O-24.5CaO and xCuO (mol%). Glass was manufactured using conventional melt-quench technique, utilizing chemicals partially derived from bio-waste, with varying copper oxide (CuO) content (x = 0, 1, 3, and 5). In-vitro study was conducted by immersing the specimens in simulated body fluid for 21 days. The formation of apatite layer was confirmed using FTIR, XRD and FESEM-EDS. Vicker's micro hardness tester and a universal testing machine measured hardness and compressive strength, while a pin-on-disc tribometer assessed wear. MTT assay was performed for all the specimens using osteosarcoma MG63 cell line. The study revealed that substituting copper in place of sodium increased the ion dissolution and improved the formation of the apatite layer hence, enhanced the bioactivity, however, accompanied by a gradual decrease in hardness and compressive strength. BSG-0 exhibited the highest hardness (6.64 GPa) and compressive strength (86.81 MPa), while wear resistance weakened with higher CuO content, notably in BSG-5 with the highest specific wear rate (0.072 mm³/N-m) under a 5 N load. Although MTT assay showed non-toxicity for all specimens, except BSG-5, the compounds demonstrated cell tolerance and growth stimulation. In conclusion, the study suggests that CuO-doped borosilicate glasses exhibit superior bioactivity, making them potentially effective for bone filling, wound healing, and dental applications, despite a compromise in mechanical strength and wear resistance.

Effect of activator concentration on setting time, workability and compressive strength of sustainable concrete with alkali-activated slag binder

The global need to reduce carbon dioxide (CO2) emissions prompted studies on sustainable alternatives to conventional concrete made with ordinary Portland cement (OPC) binders. Alkali-activated ground granulated blast furnace slag (GGBS) is a promising sustainable to OPC in terms of the impact on the environment and reduction of CO2 emissions. Concretes and mortars made with alkali-activated binders demonstrate promising fresh and mechanical properties. This article presents the findings of an experimental study investigating the fresh and mechanical properties of mortar using alkali-activated GGBS binder. The activators used were sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) solution with 6 M, 8 M, 10 M, and 12 M molarities. The study assessed their initial setting time, workability, and 28-day compressive strength. The study evaluated the effect of partial replacement of GGBS with 5 % silica fume. The compressive strength was determined after 28 days of curing in three different environments: 1) ambient air temperature, 2) water submersion, and 3) water immersion for 7 days followed by 21 air curing in ambient temperature. The results showed an increase in compressive strength with higher NaOH concentration but a corresponding decrease in initial setting time and flowability. Depending on the curing method, efflorescence, and blue-green pigmentation were seen during the physical assessment of the samples. The highest 28-day compressive strength was 67.5 MPa when the NaOH activator molarity was 10 mol/L which represents an optimum concentration for strength development. Replacing 5 % of the GGBS binder with silica fume resulted in a decrease in the 28-day compressive strength and workability without affecting the initial setting time.

The effects of temperature and hygrothermal aging on the properties of CF/PA6 composite and its compression failure mechanisms

AbstractCarbon fiber reinforced polyamide composites have outstanding properties, but their applications are significantly affected by the service environment. This work evaluates the effects of temperature (25, 80, 140, and 200°C) and hygrothermal conditions on the mechanical properties of CF/PA6 composite containing delamination damage, and studies its damage behaviors and failure mechanisms. After hygrothermal aging, recrystallization of PA6 improves the heat resistance of CF/PA6 composites, but water absorption reduces the interfacial strength of composites, resulting in the decrease of modulus and compressive strength (24% and 42%, respectively). With the increase in temperature, the compressive strength of CF/PA6 composites gradually decreases (from 132 MPa at 25°C to 24 MPa at 200°C), and the failure mode transitions from fiber fractures, interlayer shear fractures, delamination to kinking. In addition, the compressive failure process of CF/PA6 composites is divided into three stages: buckling, delamination bulging and kinking failure.Highlights Hygrothermal aging reduces the fiber/resin interface performance. Fiber fracture, interlayer shear and delamination convert to kinking failure. The failure process is divided into buckling, delamination and kinking.

Size effect of compressive performance of concrete under elevated temperatures: Tests and meso-scale analysis

This study investigates the size effect of concrete under ambient and elevated temperatures through tests and numerical simulations. Compressive performance of prismatic and cylindrical concrete specimens with varying dimensions were tested at temperatures ranging from ambient temperature to 600°C. Meso-scale finite element analysis (FEA), assuming that the mechanical properties of matrix and interfacial transition zones (ITZ) followed Weibull distribution, was employed to simulate the tested specimens and to conduct parametric analysis on specimens with larger or smaller sizes and under temperatures up to 800°C. Both experimental and numerical results showed that the cracks on the specimen surface became finer and denser as an increase of specimen sizes under elevated temperatures. A noticeable decrease in concrete compressive strength with increasing specimen dimensions was observed below 600°C, but peak strain and elastic modulus did not exhibit significant size effect. Size effect on strength diminished at temperatures exceeding 800°C. Classic Size Effect Laws (SEL), such as Weibull's and Bažant's SEL, were applicable to characterize the size effect on strength of specimens within common lab test dimensions under elevated temperatures. Based on the results from experiments, FEA and Bažant's SEL, a stress-strain model under elevated temperatures considering size effect was proposed. The predicted results from this model showed good agreement with test results.

Impact of Electronic Waste Glass on the Properties of Cementitious Materials

The article analyses the impact of two different types of dispersive glass on cement hydration and compressive strength at 7 and 28 days. The study employed dispersive glass from various LCDs (TV sets, computer monitors, smart phones), characterised by a composition of approximately 8% SrO, and dispersive glass from washing machines, which consists mainly of SiO2, Na2O, and CaO. The chemical composition and particle-size distribution of different types of dispersive glass were analysed. The study compares the effect of electronic waste glass on cement hydration by evaluating the amount and rate of heat released during the process. In addition, the results of X-ray diffraction (XRD), thermogravimetric analysis (TG), and scanning electron microscopy (SEM) are provided. Different types of glass were determined to have a similar effect on the physical and mechanical properties as well as the mineral composition of cementitious samples: density and UPV decrease up to 6% and compressive strength decreases by about 30%, when 5–20% of cement was replaced by glass waste. However, more prominent differences were observed in the workability of the mixtures: the waste glass from home appliances increased the spread by up to 25%, while the waste glass from electronic devices decreased the spread compared to the reference sample by approximately 20%. The mixtures modified with the waste glass of electronic devices had a higher degree of early hydration (96%) due to the higher water absorption of the mixtures compared to the waste glass of home appliances (88%).

COMPRESSIVE STRENGTH, FLOWABILITY, AND ULTRASONIC PULSE VELOCITY TESTS OF PORTLAND CEMENT-FLY ASH-CALCINED CLAY MORTARS

The cement production process significantly affects the environment and contributes to air pollution. Consequently, there is a growing emphasis on employing alternative materials or minimizing cement usage as a solution to address environmental issues and reduce air pollution. In this investigation, an examination was conducted by substituting Portland cement with a weight of 50% with both fly ash and calcined clay. The findings revealed that replacing Portland cement with fly ash resulted in a decrease in compression strength. However, concurrently incorporating calcined clay increased compressive strength. Higher compressive strength compared to the 50% Fly ash mix was achieved by adding 20 wt.% Metakaolin and 20 wt.% Calcined clay Lopburi due to their finer particle size. As a result, the pozzolanic reaction is better than Lampang calcine clay (30FA20CClam). Additionally, ultrasonic pulse velocity testing indicated that higher values in the specimen correlated with increased compressive strength.

Gas CO2 foaming and intermixing in portland cement paste to sequester CO2

In this study, concentrated CO2 gas was used to create foamed cement paste, and concentrated CO2 gas was intermixed in fresh cement paste to produce regular cement paste materials that were not foamed. The potential of both methods to form CaCO3 from calcium ions that would form Ca(OH)2 was investigated. After curing the materials for different ages, the Ca(OH)2 and CaCO3 contents were measured using thermogravimetric analysis; the large void size distributions, dynamic modulus, and compressive strength were tested and compared against Control (no gas added), and N2 foamed and N2 intermixed specimens. A 10% increase in dynamic modulus and compressive strength was measured in CO2 foamed specimens compared to N2 foamed specimens. The increase in mechanical properties was the result of both a narrow void diameter distribution and CaCO3 formation in place of Ca(OH)2. The CO2 foamed cement generation method shows the potential to sequester 0.06 ton of CO2 for every ton of cement which is a CO2 emission reduction of 7.0% of the CO2 production associated with cement production. For the CO2 intermixing method, the void content, compressive strength, and dynamic modulus results were consistent between the Control and CO2 intermixed specimens while the N2 intermixed specimens showed a decrease in compressive strength and dynamic modulus. The CO2 intermixing method showed potential to sequester 0.04 ton of CO2 for every ton of cement or a 4.7% CO2 emission reduction of the total CO2 production associated with cement manufacturing. The reported CO2 emissions are not based on life cycle assessment and do not account for emissions associated with CO2 collection, transportation, and intermixing. The present paper does not investigate the mechanisms of hydration under CO2 intermixing.

Assessing the risk of ASR in LC3 binders based on low-grade calcined clay

The research investigates the impact of limestone calcined clay cement (LC3) on the mechanical properties and durability of cement-based materials in the context of alkali-silica reactions (ASR) for sustainable construction. Comparative experiments were conducted on binary and ternary blends of low-grade kaolinitic calcined clays and conventional supplementary cementitious materials (SCMs). Two distinct low-grade kaolinitic clays were calcined, and blends with Portland cement, ground-granulated blast-furnace slag (GGBFS), and silica fume (SF) were prepared for comparative analysis. Results reveal that replacing 30 wt% of Portland cement with these calcined clay blends substantially reduces expansion in mortar and concrete during accelerated and long-term tests, altering micropore structure. These blends demonstrate superior performance compared to other studied SCMs. Despite a slight decrease in compressive strength compared to the control mixture, there is a noteworthy improvement in permeability and resistance against expansion. Also, in the early stages of ASR, an improvement in concrete's mechanical properties and durability is observed, attributed to the ASR gel filling the pores.