Characterization Of Composites Research Articles

Mechanical characterization and performance evaluation of twisted Jute-Kevlar hybrid composites with varied fiber orientations

Abstract Composite materials play a vital role in developing new materials in engineering and technology. Composites show how the properties of the matrix and reinforcement work together to create more robust, more rigid materials than would be possible from the individual components working alone. They consist of two or more component materials combined with notably dissimilar physical or chemical characteristics. Two categories of composite coupons have been developed in this research work: the first category (C1) is made up of jute twisted-Kevlar twisted jute fiber (0/90 degree), and the second category (C2) is made up of jute twisted-Kevlar twisted jute fiber (0/45 degree). The nano-silica is reinforced with the matrix with a weight percentage of 0%,5%,10% and 15%. The necessary interfacial adhesion and bonding between fiber layers have been accomplished using a 10:1 mixture of epoxy resin (LY556) and hardener (HY951). According to ASTM guidelines, the tensile, flexural, impact, double shear, wear, and hardness tests were carried out. This study uses two natural and synthetic fibers—twisted Jute and Kevlar fibers—as reinforcement. The Jute fibers have a high strength since they are high in cellulose. Efforts have been made to create a composite material with completely different twisted fiber orientations and to assess the mechanical properties of the composites. This involved various mechanical tests, analysis of wear surfaces, as well as DMA, DSC, FEA testing, and ultimately, the machining of the composites studied. The machining parameters used in waterjet machining have been carefully analyzed.

Influence of castor oil‐derived bio‐resin on mechanical and visco‐elastic properties of dynamic covalent imine bond based epoxy and its composite

AbstractThe widespread use of thermoset composites has raised significant environmental and economic concerns due to their non‐recyclable nature. This study addresses these issues by developing vitrimers and their composites featuring dynamic imine bonds synthesized from vanillin, 3,3′‐dimethyl‐4,4′‐diaminodicyclohexylmethane, and epoxy. To enhance toughness and bio‐content in the vitrimer and its composites, a green reactive monomer, epoxy methyl ricinoleate (EMR), was synthesized via the transesterification of epoxidized castor oil (ECO) and incorporated as the reactive diluent. The effect of EMR on bio‐resin mechanical, thermo‐mechanical, and relaxation times (τ) of the vitrimer was examined. The inclusion of EMR reduced the relaxation time, indicating improved dynamic bond exchange efficiency. EMR incorporation decreased the relaxation time, suggesting enhanced efficiency in the interchange of dynamic bonds. In addition, the incorporation of 20% EMR increased the impact strength of the epoxy vitrimer by 37.8%. The study also details the manufacturing and characterization of greener composites made with these vitrimers and flax fabric, which were evaluated for various mechanical and thermo‐mechanical properties. Morphological analysis using a scanning electron microscope revealed good interfacial adhesion between the fiber and matrix. Furthermore, the flax fiber vitrimer‐based composite demonstrated effective chemical recyclability. The results indicate that these composites possess mechanical and thermal‐mechanical properties well‐suited for lightweight engineering applications.Highlights Recyclable vitrimers were developed from vanillin and epoxy. Toughness and bio‐content were enhanced by adding EMR. Relaxation time was reduced by EMR, improving bond exchange efficiency. Epoxy vitrimer impact strength was increased by 37.8% with 20% EMR. Green composites with vitrimers and flax fabric were manufactured.

Mechanical characterization of Al2219-SiC metal matrix composites

The present work conducted an experimental examination to assess the tensile behaviour and microstructural characteristics of Al2219 metal alloy reinforced with 4 and 8 wt. % of SiC composites. The investigation employed the liquid metallurgical method to fabricate composites of the Al2219 alloy including SiC particles at weight percentages of 4 and 8. This work employed supplementary methods, including scanning electron microscopy (SEM), to determine the microstructural characteristics. An investigation of the mechanical characteristics of Al2219 alloy with SiC reinforced composites is conducted in accordance with ASTM Standards. Furthermore, the incorporation of silicon carbide particles into aluminium 2219 demonstrates remarkable characteristics in the field of composite materials, therefore augmenting its potential for a broad spectrum of uses. Enhancements in hardness and tensile strengths of the composites were achieved by combining different materials. The fractured surfaces of the Al2219-SiC composites displayed both brittle and ductile fracture characteristics, as indicated by their tensile test results.

Post-processing and characterization of AA2024 RAM2 and RAM10 metal matrix composites realized through 3D printing

Post-processing and characterization of AA2024 RAM2 and RAM10 metal matrix composites realized through 3D printing

Characterization of SLA-printed ceramic composites for dental restorations

Characterization of SLA-printed ceramic composites for dental restorations

Development and Characterisation of Myristic Acid-Paraffin Wax, Silica Fume and Zinc Oxide Cementitious Composites for Thermal Control in Buildings

This study focuses on the development of a cement-based phase change material (CBPCM) to improve thermal performance in construction applications. The CBPCM was synthesised by blending 90 wt% of myristic acid with 10 wt% of paraffin wax, absorbed into 10 wt% of silica fume to prevent leakage. Additionally, 5 wt% of zinc oxide was added to improve thermal conductivity. A leakage test conducted with 10 wt% of SF exhibited no signs of leakage during thermal cycling. Scanning electron microscopy (SEM) established the uniform dispersion of the nano-enhanced phase change material (NEPCM) within the cement. Fourier transform infrared spectroscopy (FTIR) analysis revealed no chemical structure changes after 100 thermal cycles. Thermogravimetric analysis (TGA) confirmed thermal stability in the temperature range of 74.8 to 236.64 °C with a mass loss of 6.3 wt%. The material demonstrated minimal variation in phase change temperatures and latent heats after 100 cycles. The latent heat of the CBPCM was 1.09 J/g during melting and 1.887 J/g during solidification. Incorporating NEPCM into the cement increased the thermal conductivity of the cement matrix to 0.559 W/m K. These findings underline the potential of the CBPCM for energy-efficient construction, offering enhanced thermal storage, stability, and conductivity.

Investigation on Erosion Resistance in Polyester–Jute Composites with Red Mud Particulate: Impact of Fibre Treatment and Particulate Addition

This research investigates the manufacturing and characterisation of polyester-based composites reinforced with jute fibres and red mud particulates. The motivation stems from the need for sustainable, high-performance materials for applications in industries, like aerospace and automotive, where resistance to erosion is critical. Jute, a renewable fibre, combined with red mud, an industrial byproduct, offers an eco-friendly alternative to conventional composites. The composites were fabricated using compression moulding with varying red mud contents (10, 20, and 30 wt.%) and a fixed 40 wt.% of jute fibre. Fibre treatments included sodium hydroxide (NaOH) and silane treatments to improve bonding and performance. Erosion tests were performed using an air-jet erosion tester, examining the effects of the red mud content, fibre treatment, and impact angles. Scanning Electron Microscope (SEM) analysis provided insights into the erosion mechanisms. A distinctive reduction in erosion rates at higher impact angles (30°–60°) was observed, attributed to the semi-ductile nature of the composites. The addition of red mud enhanced erosion resistance, although an excess of 30 wt.% reduced resistance due to poor surface bonding. Silane-treated composites showed the lowest erosion rates. This study provides new insights into the interplay among material composition, fibre treatment, and erosion dynamics, contributing to the development of optimised, eco-friendly composite materials.

Upcycling EPS waste and mineral wool to produce new lightweight gypsum composites with improved thermal performance

Energy efficiency and waste management are crucial for sustainability of construction sector. In this research, a new gypsum composite material is presented in which traditional raw materials have been partially replaced by thermal insulation waste from facades energy retrofitting projects, using an innovative process to recover this waste. Consequently, a novel lightweight gypsum composite has been developed with a replacement of up to 14.7% by weight of the original material with EPS waste, adding mineral wool as reinforcement fibres (0.375%wt.). Thus, thermal behaviour analysis of these new composites has been conducted, both material itself and of its performance as part of a real construction system, including finite element analysis of the construction system. In addition, the physicochemical, physical and mechanical characterisation of the new composites has been carried out. Results show that the developed new material has a density 20.3% lower than the traditional gypsum composite, resulting in a 30.4% reduction in thermal conductivity. Furthermore, the use of these new lightened gypsum composites as finishing boards in lightweight steel frame (LSF) wall systems reduces the overall thermal resistance of the wall by up to 10.6% with just 25mm thickness. On the other hand, the mechanical resistance of this new material exceeds the reference values established by current standards, ranging between 4.18-1.87MPa for flexural strength and between 7.87-4.27MPa for compressive stresses. Additionally, the developed composites have shown a reduction in both total and capillary water absorption compared to traditional gypsum by 19.6% and 40.0% respectively, enhancing the material’s durability and its excellent thermal properties throughout its lifespan.

Dynamic fracture characterization of glass fiber composites reinforced with through-thickness nylon fibers

ABSTRACT A detailed experimental study is performed to investigate the mode-I dynamic fracture initiation toughness of through-thickness Nylon fibers reinforced glass/epoxy composites using a wet electrostatic flocking method. Composites of a double cantilever beam specimen configuration of two different deniers 1.5D and 3D of 0.75 mm long Nylon fibers with two different fiber densities 150 and 300 fiber/mm2 and composites without Nylon fibers (control) are fabricated. The dynamic fracture initiation toughness is investigated by using a modified split Hopkinson pressure bar setup with a novel fixture in conjunction with a high-speed video camera. In addition, rate sensitivity on dynamic fracture initiation toughness is also investigated for control and composites of 1.5D with fiber density of 300 fibers/mm2 as a function of three different rates of dynamic fracture toughness ( G ˙ = 1500, 2010, and 2,150 kJ/m2/s). Results show that for the composite of 3D–0.75 mm Nylon fiber, G IC values reach 0.78 kJ/m2 (110% increase) and 1.3 kJ/m2 (250% increase) at flock densities of 150 and 300 fibers/mm2 compared to the control sample with the lowest G IC value at 0.37 kJ/m2. The same pattern is observed for a 1.5D–0.75 mm configuration at the flock fiber density of 150 fiber/mm2 where G IC value demonstrates a 75% increase compared to control conditions. The dynamic fracture initiation toughness of flocked composites demonstrates significant rate sensitivity.

Development of sustainable flame-retardant bio-based hydrogel composites from hemp/wool nonwovens with chitosan-banana sap hydrogel

Flame retardant (FR) finishing is crucial for developing protective textiles, traditionally relying on halogen, phosphorus, and phosphorus-nitrogen chemistries, which have limitations like toxicity and fabric stiffening. Innovative approaches such as nanotechnology, plasma treatments, and natural resource-based finishes are being explored to achieve sustainable FR textiles. This study presents the development and comprehensive characterization of hydrogel composites made from nonwoven fabrics composed of various hemp/wool blends (70/30, 80/20, and 90/10). The nonwoven fabrics were treated with a chitosan hydrogel incorporating banana sap to enhance their properties. Scanning electron microscope (SEM) examined the surface morphology and structural integrity of the composites, while Fourier transform infrared spectroscopy (FTIR) identified chemical interactions and functional groups. Differential scanning calorimeter (DSC) revealed thermal properties, water absorbency tests demonstrated hydrophilicity, mechanical testing assessed tensile strength, and vertical flammability tests evaluated fire resistance. SEM and FTIR revealed a successful coating of chitosan hydrogel with banana sap inclusions onto the hemp/wool nonwoven fabric, forming a composite structure. DSC analysis suggests higher chitosan content and hemp fiber ratio (like 70/30) lead to increased thermal stability of hydrogel composites. Higher chitosan concentrations in the hydrogel significantly improve the flame-retardant properties of hemp/wool nonwoven fabrics by reducing char length and enhancing protective char layer formation, with banana sap further promoting charring. These results indicate that the developed composite can be effectively used in flame-retardant textiles.

Fabrication and characterization of HfCZrCTiC composites: role of carbonaceous and metallic additives

Fabrication and characterization of HfCZrCTiC composites: role of carbonaceous and metallic additives

Time-dependent variations in desorbed gas composition: methodological analysis of asphaltite vein investigation results

In this study, a phenomenon that can have significant technical and economic impacts in the mining and unconventional gas production of hydrocarbon resources is discussed, change of gas composition during desorption period. The change is analyzed, related findings are obtained and engineering tools are forged. In this scope, a member of the Southeastern Turkey asphaltite’s gas content and composition character was examined. 12+1 samples were collected at equal intervals from an inclined drillhole that cut through the asphaltite vein. The United States Bureau of Mines (USBM) direct method was employed to determine the gas content. Gas composition analysis was performed on gas samples, which were collected four times throughout the desorption period. Residual gas composition is determined as well. During desorption period, methane and hydrogen ratios exhibited decreasing trends, while others have increasing trends. In evaluating of the collected data, the desorption order between gas compounds are revealed. Logarithmic trend functions are generated to estimate the concentrations of gas compounds at specific time points. With these functions and gas content measurement data, weighted average concentrations for gas compounds are determined. These concentration functions and the weighted average results are used to create engineering tools showing unit energy content of desorbed gas through desorption period both instantaneous and cumulative. Similarly, change in lower explosive limit and auto-ignition temperature during desoption period is shown. The weighted average gas concentrations obtained are used to interpret geological insights as they are the actual gas composition of the samples. In the study, gas content characteristic properties of Üçkardeşler asphaltite vein is comprehensively presented. Accordingly, the mean gas content, excluding one sample with a value of 2.78 m3/t at a location near a fault intersection, was found to be 1.66 m3/t. The average volumetric concentrations of methane, ethane, propane, and acetylene in the desorbed gas were determined as 61.6%, 24.5%, 10.7%, and 2.3%, respectively. The remaining part primarily consisted of heavier hydrocarbons, with low amounts of carbon dioxide and hydrogen.

Chemometrics and analytical blank on the at-line monitoring of Zika-VLP production using near-infrared spectroscopy

The Zika disease caused by the Zika virus was declared a Public Health Emergency by the World Health Union (WHO), with microcephaly as the most critical consequence. Aiming to reduce the spread of the virus, biopharmaceutical organizations invest in vaccine research and production, based on multiple platforms. A crescent vaccine production approach is based on virus-like particles (VLP), for not having genetic material in its composition, hypoallergenic and non-mutant character. For bioprocess, it is essential to have means of real-time monitoring, which can be assessed using process analysis techniques such as Near-infrared (NIR) spectroscopy, that can be combined with chemometric methods, like Partial-Least Squares (PLS) and Artificial Neural Networks (ANN) for prediction of biochemical variables. This work proposes a biochemical Zika VLP upstream production at-line monitoring model using NIR spectroscopy comparing sampling conditions (with or without cells), analytical blank (air, ultrapure water), and spectra pre-processing approaches. Seven experiments in a benchtop bioreactor using recombinant baculovirus/Sf9 insect cell platform in serum-free medium were performed to obtain biochemical and spectral data for chemometrics modeling (PLS and ANN), composed by a random data split (80 % calibration, 20 % validation) for cross-validation of the PLS models and 70 % training, 15 % testing, 15 % validation for ANN. The best models generated in the present work presented an average absolute error of 1.59 × 105 cell/mL for density of viable cells, 2.37 % for cell viability, 0.25 g/L for glucose, 0.007 g/L for lactate, 0.138 g/L for glutamine, 0.18 g/L for glutamate, 0,003 g/L for ammonium, and 0.014 g/L for potassium.

Robust quantitative X-ray phase diagnostic for carbon composite characterisation in the context of lightning induced risk

Getting complementary physical information from a single image acquisition is particularly valuable for materials analysis. Grating based X-ray Phase Contrast Imaging (XPCI) methods allow decoupling attenuation, phase and scattering information. However, the phase and scattering extraction processes can easily suffer from artefacts, which is detrimental to implement this imaging technique in societal applications. In this paper, we demonstrate that grating based XPCI can provide a robust phase measurement in complex materials such as damaged composites. The technique allows the phase to be analysed using a self-assessment method that first identifies the artefacts from the imaging setup, and then can be used as an indicator to interpret the signal from a material. We focus on carbon fibre reinforced polymers which we subjected to laboratory-controlled lightning strikes. We evidence that the combined information from phase and attenuation allow identifying the type of defect induced by the lightning current. The phase information is converted into relative mass density variation within the sample and depicts areas with a loss in density up to 40%. We ensure that these results are valid by comparing them with an X-ray attenuation contrast tomographic reconstruction.

Highly efficient recovery of lithium from spent ternary NCM cathode materials via a selective chlorination method

The recovery of lithium from spent lithium-ion batteries (LIBs) is an important approach to solve the global shortage of lithium resource. Considering the difference in stability of various metal element chlorides in Ni-Co-Mn ternary (NCM) cathode materials, lithium element was selectively and high-efficiently extracted from spent ternary NCM cathode material by ammonium chloride roasting in oxygen atmosphere followed by water leaching. The effects of roasting temperature, roasting time, and NH4Cl dosage on lithium leaching efficiency and selectivity were systematically investigated. In addition, the conversion mechanism during chloride roasting was discussed in detail in conjunction with thermodynamic analysis as well as structural and compositional characterizations. After roasting with NH4Cl in oxygen atmosphere at 600°C, the spent NCM cathode material was thoroughly decomposed and converted into mixture of LiCl, NiO, and MnCo2O4. Due to the high aqueous solubility of LiCl, more than 95 % of the lithium in the mixture was leached in ∼30 minutes at room temperature, and Li2CO3 with a purity of 99.40 % can be obtained in the subsequent recovery process. This simple and efficient method can be generally useful for the recovery of a wide range of spent cathode materials and provide inspiration for the lithium recovery process of spent LIBs.

Inverse gas chromatographic characterization of halloysite-carbon composites as adsorbents for skin disinfectants from water solutions

Inverse gas chromatographic characterization of halloysite-carbon composites as adsorbents for skin disinfectants from water solutions

Microwave-Assisted Fabrication and Characterization of Carbon Fiber-Sodium Bismuth Titanate Composites

Lead-based piezoelectric materials cause many environmental problems, regardless of their exceptional performance. To overcome this issue, a lead-free piezoelectric composite material was developed by incorporating different percentages of carbon fiber (CF) into the ceramic matrix of Bismuth Sodium Titanate (BNT) by employing the microwave sintering technique. The aim of this study was also to evaluate the impact of microwave sintering on the microstructure and the electrical behavior of the carbon-fiber-reinforced Bi0.5Na0.5TiO3 composite (BNT-CF). A uniform distribution of the CF and increased densification of the BNT-CF was achieved, leading to improved piezoelectric properties. X-ray diffraction (XRD) showed the formation of a phase-pure crystalline perovskite structure consisting of CF and BNT. A Field Emission Scanning electron microscope (FESEM) revealed that utilizing microwave sintering at lower temperatures and shorter dwell times results in a superior densification of the BNT-CF. Raman Spectroscopy confirmed the perovskite structure of the BNT-CF and the presence of a Morphotropic Phase Boundary (MPB). An analysis of nanohardness indicated that the hardness of the BNT-CF increases with the increasing amount of CF. It is also revealed that the electrical conductivity of the BNT-CF at a low frequency is significantly influenced by the amount of CF and the temperature. Moreover, an increase in the carbon fiber concentration resulted in a decrease in dielectric properties. Finally, a lead-free piezoelectric BNT-CF showing dense and uniform microstructure was developed by the microwave sintering process. The promising properties of the BNT-CF make it attractive for many industrial applications.

Failure analysis and structural optimization of unequal-parameter metal bellows in resistance to bending and torsional composite deformation

In practical engineering applications, metal bellows are subjected to complex environmental conditions, and they usually deform under the combined effects of tension, bending and torsion. In this paper, the bending and torsion composite deformation of unequal parameter metal bellows arranged alternately by large wave and wavelet is studied. Firstly, the finite element model of metal bellows is constructed, and the finite element simulation analysis of its mechanical properties is carried out. Taking the simulation results as samples, the multi-objective structural optimization of unequal parameter metal bellows under the condition of bending and torsion composite deformation is carried out. Combined with the bending-torsion composite deformation test and fracture microscopic characterization, the bending-torsion composite deformation characteristics and fracture failure mechanism of equal-parameter metal bellows (EPMB) and unequal-parameter metal bellows (Un-EPMB) were compared and analyzed. The results show that under the same deformation conditions, compared with the EPMB, the elastic limit bending line displacement and elastic limit torsion angle displacement of Un-EPMB are increased by 52.94 %, and the bending and torsional stiffness are greatly improved, moreover, the alternating waveform arrangement led to relatively gradual stress transfer through the Un-EPMB during the bending-torsion composite deformation process, thereby reducing stress concentration. Thus, the Un-EPMB exhibited more favorable mechanical properties. Unlike in the EPMB, which underwent fracture along the grain boundary, the cracks in the Un-EPMB appeared in the middle layer and propagated to both sides in a wavelike pattern. The dimples were distributed in the middle layer of the fracture, which indicates ductile behavior.

Characterization of wood plastic composites made with recycled waste tire rubber

Abstract Green materials are currently demanded for construction as well as other products since the 26th UN Climate Change Conference of the Parties (COP26) in 2021. Using renewable and sustainable resources to innovate new materials such as composites is encouraged. This study aimed to investigate the physical and mechanical characteristics of wood plastic composites (WPCs) when adding waste tire rubber as filler for 10% or 20% by weight. The results showed that the density of the WPC samples (50 wt% wood − 50 wt% high density polyethylene) increased with the addition of the waste tire rubber (WTR) while the dimensional stability of samples was reduced. The mechanical properties of the WPC samples were determined, including flexural strength, flexural modulus, elongation at break, tensile strength, tensile modulus, and impact strength. The WTR as filler in the WPC tended to decrease the tensile strength and flexural strength whereas it improved the impact strength of materials. The results indicated that the WTR as recycled material in WPC affected the physical and mechanical properties of the WPCs. Although the use of the WTR in the production of the WPC adversely affects the mechanical properties, the use of 10 wt% WTR was acceptable. The results of the study showed that the addition of the WTR to the WPC production process can be useful for its recycling and for reducing the cost of the WPC.

Damage characterisation of GFRP composites based on clustering acoustic emission events utilizing single-failure-cause tests as reference

A new method to identify causes of fracture in composites based on acoustic emission (AE) and clusterization of AE data based on reference datasets is presented within the manuscript. Acoustic Emission (AE) is a widely used non-destructive method for fracture analysis, but data due to their multidimensionality are not easy to analyze especially if the acoustic events appear simultaneously and have similar parameters even if they are an effect of different failure mechanisms. In this research, we utilize an unsupervised learning algorithm besides the simplest K-means, through fuzzy c-means to Gaussian Mixture Model (GMM) and spectral clustering to investigate the dataset obtained from the three-point bending test manufactured by us composite. The analysis is preceded by data curation, feature determination (Laplacian score) and the best number of cluster investigations (DB index, Caliński-Harabasz score, and Silhouette method) To enable interpretation of the clustering we run an additional three groups of tests covering fibre breakage (two methods), resin fracture (in tension and in compression) and delamination (DCB test) creating reference datasets. These datasets were statistically analyzed and kernel density estimators were generated for each AE feature as well as amplitude-frequency characteristics. Clusters obtained for the main dataset were then assigned to particular causes of failure by comparing them with the reference dataset. It was found that clusters generated using spectral clustering were the most realistic ones, as it was possible to assign the cause of failure to them.