Composite Structures Research Articles

Community composition of the entomopathogenic fungal genus Metarhizium in soils of tropical and temperate conventional and organic strawberry fields

Studies on community composition and population structure of entomopathogenic fungi are imperative to link ecosystem functions to conservation biological control. We studied the diversity and abundance of Metarhizium spp. from soil of conventionally and organically farmed strawberry crops and from the adjacent field margins in two different climatic zones: Brazil (tropical) and Denmark (temperate), using the same isolating methods. In Brazilian strawberry soil, Metarhizium robertsii (n = 129 isolates) was the most abundant species, followed by M. humberi (n = 16); M. anisopliae (n = 6); one new taxonomically unassigned lineage Metarhizium sp. indet. 5 (n = 4); M. pingshaense (n = 1) and M. brunneum (n = 1). In Denmark, species composition was very different, with M. brunneum (n = 33) being isolated most commonly, followed by M. flavoviride (n = 6) and M. pemphigi (n = 5), described for the first time in Denmark. In total, 17 haplotypes were determined based on MzFG543igs sequences, four representing Danish isolates and 13 representing Brazilian isolates. No overall difference between the two climatic regimes was detected regarding the abundance of Metarhizium spp. in the soil in strawberry fields and the field margins. However, we found a higher Shannon's diversity index in organically managed soils, confirming a more diverse Metarhizium community than in soils of conventionally managed agroecosystems in both countries. These findings contribute to the knowledge of the indigenous diversity of Metarhizium in agricultural field margins with the potential to contribute to pest regulation in strawberry cropping systems.

Exploiting Co-C interface and graphitic carbon belts for enhanced structural stability of a porous layered Co-C catalyst for CO2 hydrogenation

Addressing the urgent need for efficient CO2 reduction, a novel Co@C catalyst was synthesized through the pyrolysis of a unique layered metal–organic framework (MOF), featuring tunable thickness, pore sizes. The CO2 hydrogenation performance demonstrates an enhancement by an optimized structure that significantly improves stability, maintaining a 25% CO2 conversion rate over an extended 80-hour period. The catalyst's composite structure exhibits a dual-confinement effect, where the Co-C interface and graphitic carbon belt stabilize Co nanoparticles, preventing sintering during reaction cycles. This study delves into the structural modifications necessary for catalytic optimization in CO2 hydrogenation, offering valuable insights for designing efficient catalysts for CO2 reduction and advancing sustainable energy solutions.

Stability of Thin-Walled Composite Structures with Closed Sections Under Compression

Stability of Thin-Walled Composite Structures with Closed Sections Under Compression

Layer effects on MXenes electrode and it applied to silicon composite structures

Despite the very high capacity of Si (4200mAh g−1), the widespread application of Si anodes has been hampered by drastic volume changes (up to 300 %) during cycling, leading to electrical contact losses and thus a sharp drop in capacity as the cycle life is shortened. Here we present a class of layered MXene/Si electrodes, which consist of nano-Si embedded in the interlayers of MXene to form a coupling effect, which can inhibit the huge volume change of Si during cycling. Therefore, layered MXene/Si has a highly reversible capacity, much improved cycling performance and excellent mechanical properties. First-principles calculations reveal the excellent electronic conductivity and good diffusion ability of layered MXene/Si, confirming the rapid storage of Li ions. This study provides useful information for the development and production of anode materials with high energy density and good mechanical properties.

Comparative Analysis of Framed-Tube & Braced-Tube System in Tall Buildings Using ETABS

Abstract: Since the rigid frame became popular in the first half of the 20th century, tall buildings with structural systems have evolved. The development of underlying frameworks for tall structures lays on reasonable realism, economy of material utilization, effortlessness and polish, and worry for constructability. We are now able to build buildings that are ever higher thanks to cutting-edge building materials, sophisticated computational software, and sturdy structural systems. The rationale behind the creation of structural systems for tall buildings is to achieve architectural expression, ensure safety and serviceability, and make rational and effective use of materials. The use of composite structures, which combine the advantages of various materials, has been the trend in structural systems for tall buildings. In both static and dynamic conditions, these high-rise structures ought to be able to withstand a variety of lateral loads, such as wind load and earthquake load. This study examines the responses of the Framed Tube, Braced Tube, structural systems to various parameters such as Story displacement, Story drift, Story shear, and time period. The analysis focuses on 60-story structures situated in Seismic Zone III with medium soil conditions. The static analysis of the structures is conducted using the linear static method, which involves wind load calculations using the force coefficient method. On the other hand, the dynamic analysis is performed using the response spectrum method, with wind load calculations carried out using the gust factor calculation method.

RCS-reduced patch antenna with wide frequency tuning range based on absorbing metasurface

A frequency-tunable patch antenna with reduced radar cross section (RCS) based on absorbing metamaterial is proposed. By controlling the external voltage of the varactor diodes, the working frequency of the patch can be adjusted. Through an investigation of the composite structure of the patch and absorbing metamaterial, RCS reduction is achieved over the entire wide tunable frequency range of the antenna. Measured results illustrate that the proposed patch antenna can dynamically operate in the range from 2.28 to 3.6 GHz with a gain variation of 7.1–8.7 dBi. Meanwhile, the RCS can be reduced by at least 7 dB and up to 20 dB in a fractional bandwidth of 44.9% of the antenna under a normal incidence. In comparison to conventional RCS-reduced antennas, the proposed one features a broader frequency tuning range and has potential value in wideband radar systems under complex electromagnetic interference environments.

Utilizing in-nozzle impregnation for enhancing the strength of recycled PET-derived 3D printed continuous banana fiber reinforced bio-composites

Purpose This study aims to evaluate the potential of using the in-nozzle impregnation approach to reuse recycled PET (RPET) to develop continuous banana fiber (CBF) reinforced bio-composites. The mechanical properties and fracture morphology behavior are evaluated to establish the relationships between layer spacing–microstructural characteristics–mechanical properties of CBF/RPET composite. Design/methodology/approach This study uses RPET filament developed from post-consumer PET bottles and CBF extracted from agricultural waste banana sap. RPET serves as the matrix material, while CBF acts as the reinforcement. The test specimens were fabricated using a customized fused deposition modeling 3D printer. In this process, customized 3D printer heads were used, which have a unique capability to extrude and deposit print fibers consisting of a CBF core coated with an RPET matrix. The tensile and flexural samples were 3D printed at varying layer spacing. Findings The Young’s modulus (E), yield strength (sy) and ultimate tensile strength of the CBF/RPET sample fabricated with 0.7 mm layer spacing are 1.9 times, 1.25 times and 1.8 times greater than neat RPET, respectively. Similarly, the flexural test results showed that the flexural strength of the CBF/RPET sample fabricated at 0.6 mm layer spacing was 47.52 ± 2.00 MPa, which was far greater than the flexural strength of the neat RPET sample (25.12 ± 1.94 MPa). Social implications This study holds significant social implications highlighting the growing environmental sustainability and plastic waste recycling concerns. The use of recycled PET material to develop 3D-printed sustainable structures may reduce resource consumption and encourages responsible production practices. Originality/value The key innovation lies in the concept of in-nozzle impregnation approach, where RPET is reinforced with CBF to develop a sustainable composite structure. CBF reinforcement has made RPET a superior, sustainable, environmentally friendly material that can reduce the reliance on virgin plastic material for 3D printing.

Multifunctional Applications Enabled by Fluorination of Hexagonal Boron Nitride.

2D materials exhibit exceptional properties as compared to their macroscopic counterparts, with promising applications in nearly every area of science and technology. To unlock further functionality, the chemical functionalization of 2D structures is a powerful technique that enables tunability and new properties within these materials. Here, the successful effort to chemically functionalize hexagonal boron nitride (hBN), a chemically inert 2D ceramic with weak interlayer forces, using a gas-phase fluorination process is exploited. The fluorine functionalization guides interlayer expansion and increased polar surface charges on the hBN sheets resulting in a number of vastly improved applications. Specifically, the F-hBN exhibits enhanced dispersibility and thermal conductivity at higher temperatures by more than 75% offering exceptional performance as a thermofluid additive. Dispersion of low volumes of F-hBN in lubricating oils also offers marked improvements in lubrication and wear resistance for steel tribological contacts decreasing friction by 31% and wear by 71%. Additionally, incorporating numerous negatively charged fluorine atoms on hBN induces a permanent dipole moment, demonstrating its applicability in microelectronic device applications. The findings suggest that anchoring chemical functionalities to hBN moieties improves a variety of properties for h-BN, making it suitable for numerous other applications such as fillers or reinforcement agents and developing high-performance composite structures.

Elasto-Plastic Constitutive Behaviour Prediction and Uncertainty Quantification of Damaged Composite Structure under High-Strain Rate Loading

Abstract The current research assesses the consequences of various damages (crack and delamination) and high-strain loading conditions on the fibre-reinforced composite structure's elasto-plastic stress-strain (EPSS) characteristics. The constitutive responses are obtained numerically (finite element discretization) using higher-order polynomials (to count the deformation) with the help of the MATLAB platform. The EPSS responses are evaluated via the modified Ludwik equation and Cowper Symonds model under high strain rate loadings. The model accuracy has been tested through the comparison between the present numerical and the published experimental data available in open domain. Furthermore, various numerical examples present the effect of damages (debond and/or crack), forces and stress-strain characteristics for a wide range of strain rates (ranging from 0.001 s−1 to 50 s−1). The stochastic constitutive model is obtained to show the modelling importance and the corresponding analysis parameters including the uncertainty quantification. Finally, a detailed understanding of the damages and geometries on the polymeric composite structure are enumerated via the delve model for the futuristic design.

α-Fe2O3 nanorods on CoFe-LDH@MX via interfacial interactions for Congo red removal: Experimental and mechanistic studies

Developing a 3D material to support α-Fe2O3 nanorods to improve their adsorption performance for Congo Red (CR) is a major challenge. Herein, a novel 3D composite adsorbent was designed, where 2D material Ti3C2 MX and CoFe-LDH stacked on top of each other as the support material of α-Fe2O3 nanorods (α-Fe2O3@LDH@MX). The specific surface area of the α-Fe2O3@LDH@MX was increased by 2 times (101.28 m2/g) than original CoFe-LDH@MX, thus more favorable for capturing CR (698.25 mg/g). The results of kinetic studies demonstrate that the effective 3D composite structure enables unhindered movement of CR within the α-Fe2O3@LDH@MX. The Langmuir model can accurately describe the adsorption process of CR on the α-Fe2O3@LDH@MX, which means that the process belongs to monomolecular layer chemisorption. Molecular dynamics simulations revealed that the α-Fe2O3 interface primarily interacts with oxygen within the -SO3 group, achieving an adsorption energy up to Einteraction= −20,375.89 kcal/mol. The results of XPS analysis further revealed that interaction between Fe and O achieved the removal of CR. In this paper, the enhancement of α-Fe2O3 adsorption performance has been successfully achieved through innovative structural design. This significantly advances its potential applications and offers new insights for future material design.

Extraction of Pithecellobium clypearia Benth polysaccharides by dual-frequency ultrasound-assisted extraction: Structural characterization, antioxidant, hypoglycemic and anti-hyperlipidemic activities

In this research, the extraction process of polysaccharides from Pithecellobium clypearia Benth (PCBPs) was optimized using dual-frequency ultrasound-assisted extraction (DUAE). The biological activities of PCBPs were investigated by in vitro antioxidant, hypoglycemic, and anti-hyperlipidemic assay. High-performance anion-exchange chromatography, high-performance gel permeation chromatography, SEM, UV–Vis spectroscopy, and FT-IR spectra were used to analyze the monosaccharide composition, molecular weight, microscopic morphology, and characteristic structure of PCBPs. The results showed that the maximum extraction rate of PCBPs was 9.90 ± 0.16% when the ultrasonic time was 8 min, the liquid-to-material ratio was 32 mL/g, and the ultrasonic power was 510 W. The PCBPs also possessed excellent in vitro antioxidant, hypoglycemic, and anti-hyperlipidemic activities. In addition, the average molecular weight of PCBPs was 15.07 kDa. PCBPs consisted of rhamnose, arabinose, galactose, glucose, xylose, mannose, and glucuronic acid, with the molar ratios of 11.07%, 18.54%, 48.17%, 10.44%, 4.62%, 4.96%, and 2.20%, respectively. Moreover, the results of SEM showed that PCBPs mainly showed a fine spherical mesh structure. The above studies provided a valuable theoretical basis for the subsequent in-depth study of PCBPs.

Numerical simulation of concrete strength based on microstructure and mineral composition analysis using micro-CT and XRD technology

The investigation of mechanical properties in porous materials, such as concrete, has been a significant area of interest in the fields of civil engineering and architecture. Traditional macroscopic mechanical testing methods are limited due to destructive experimental conditions, time-consuming procedures, and the inability to characterize internal structures. To overcome these limitations, researchers have utilized microscopic factors with micro-CT and simulation models. Different simulation methods demand mechanical parameters to effectively model the constituent materials; however, there exists variability in the amount and standard values of these input parameters, which leads to a decrease in the reliability of the obtained results. In order to tackle this issue, a novel approach is proposed, which integrates mineral component analysis using X-ray diffraction (XRD) and establishes coefficients to minimize the number of necessary input parameters. Simulation results demonstrate excellent agreement with experimental measurements, accurately reproducing the stages of elastic deformation, failure, and fracture in the stress-strain curve of concrete. Our findings reveal that changes in the concrete skeletal structure, microstructure, and mineral composition significantly influence compressive strength. Coarse aggregates and high-mechanical-performance minerals, in particular, have a substantial impact. Additionally, the mechanical properties show a significant linear relationship with the strength reduction coefficient of aggregates and concrete cores. In conclusion, the proposed method, combining CT scanning and XRD with FDEM, proves to be a reliable and practical approach for accurately assessing the mechanical properties of concrete. This methodology simplifies the intricate processes associated with the time-intensive parameter calibration, leading to a more efficient parameter allocation procedure. As a result, this method enhances concrete design, promotes a better understanding of parameter impacts, and enables accurate prediction of concrete behavior across diverse scenarios.

Revealing the Nature of Binary-Phase on Structural Stability of Sodium Layered Oxide Cathodes.

The emergence of layered sodium transition metal oxides featuring a multiphase structure presents a promising approach for cathode materials in sodium-ion batteries (SIBs), showcasing notably improved energy storage capacity. However, the advancement of cathodes with multiphase structures faces obstacles due to the limited understanding of the integrated structural effects. Herein, we comprehend the integrated structural effects by an in-depth structure-chemistry analysis in the developed layered cathode system NaxCu0.1Co0.1Ni0.25Mn0.4Ti0.15O2 with purposely designed P2/O3 phase integration. Our results affirmed that integrated phase ratio plays a pivotal role in electrochemical/structural stability, particularly at high voltage and with the incorporation of anionic redox. In contrast to previous reports advocating solely for the enhanced electrochemical performance in biphasic structures, we demonstrated an inappropriate composite structure is more destructive than a single-phase design. The in situ X-ray diffraction (XRD) results, coupled with density functional theory (DFT) computations further confirm the biphasic structure with P2:O3 = 4:6 shows suppressed irreversible phase transition at high desodiated states and thus exhibits optimized electrochemical performance. These fundamental discoveries provide clues to the design of high-performance layered oxide cathodes for next-generation SIBs. This article is protected by copyright. All rights reserved.

Dynamic analysis of the three-phase magnetic-electric-elastic (MEE) structures with the finite element method enriched by proper enrichment functions

Abstract In this work, a carefully designed enriched finite element method (EFEM) is presented to improve the solution accuracy of the conventional FEM in analyzing the dynamic behaviors of the magnetic-electric-elastic (MEE) composite structures which are frequently used in designing various smart and intelligent devices. In formulating the proper EFEM with ideal numerical performance, different enrichment functions are considered and the corresponding solution quality of different versions of the EFEM are compared and examined in great detail. When the Lagrange polynomial basis functions together with the harmonic trigonometric functions are used as the enrichment functions, the obtained EFEM shows extremely powerful and ideal numerical performance, which are obviously better than the other versions of EFEM and the conventional FEM, in studying the free vibration and harmonic frequency responses of the MEE structures. The nearly exact numerical solutions for three-phase physical fields of MEE structures can be generated by the proposed EFEM even if very coarse mesh patterns are used. Intensive numerical studies are conducted to confirm and verify the excellent properties of the proposed EFEM in performing dynamic analysis of the MEE structures.

Synergistic Enhancement Effect of Ag/rGO as SERS Platform for Capture and Trace Detection of Fenvalerate Molecules

Surface-enhanced Raman scattering (SERS) provides an alternative rapid detection method for pesticide residues in food, but fenvalerate possesses poor affinity to the novel metal substrate, thus restricting its analysis. To break this bottleneck, a SERS-active platform with an Ag/rGO composite structure was engineered using a facile method for fenvalerate detection. Ag nanoparticles with a 60 nm diameter can grow evenly on the top and bottom of rGO layers under intense ultrasonic oscillation, and rGO in hybrid material acts as an ideal hotspot holder between the gaps of Ag nanoparticles, not only allowing the interaction area to be enhanced both electromagnetically and chemically but also enabling the capture and enrichment of fenvalerate pesticide molecules into the “hotspot” area to improve detection sensitivity. Ag/rGO composite substrate possesses superior SERS performance with an ultralow detectable concentration of 4-aminothiophenol (10−10 M) and good reproducibility, endowing the material with a better enhancement effect than pure Ag nanoparticles. When used as the SERS substrate for fenvalerate detection, Ag/rGO composite material showed excellent performance in both experiments and theoretical calculation, with the limit of detection (LOD) of fenvalerate being as low as 1.69 × 10−5 mg/kg and a detection model with an R2 of 99.2%, demonstrating its exciting potential as a SERS substrate for pesticides detection.

Electrochemical detection of antimalarial drug (Amodiaquine) using Dy-MOF@MWCNT composites to prevent erythrocytic stages of plasmodium species in human bodies

Herein, we report on fabrication of dysprosium-based metal–organic framework (Dy-MOF)@multiwalled carbon nanotubes (MWCNT) composites modified with glassy carbon electrode (Dy-MOF@MWCNT/GC) as a working electrode for Antimalarial drug detection. Dy-MOF@MWCNT composites was prepared by sonochemical process along with ultrasonication. The composite structure, phase purity, morphology and composition of the composites were confirmed by X-ray diffraction, Scanning electron microscope, and X-ray photoelectron spectroscopy. Further, Dy@MWCNT composites were deposited on a glassy carbon electrode by drop casting method, and used as an electrode material to efficiently detect Amodiaquine (ADD) by electrochemical techniques such as CV and DPV. The as-prepared Dy@MWCNT composite material showed the oxidation peak current of ADD to be ∼ 60 % higher than other unmodified GC electrodes and showed a low charge transfer resistance (R ct) of 24 Ω. The Dy@MWCNT provided a broad linear range of 0.4 to 20 µM with a limit of detection of 0.377 μM and sensitivity of 1.817 μA.μM−1 for the detection of ADD. According to the pH study, the amount of electrons and protons involved in the electrochemical processes of ADD was calculated and a plausible mechanism for ADD electro-oxidation was proposed. Thus, the prepared sensor exhibited practical usefulness by determining the ADD drug in human urine samples. Hence, the results shows that the Dy@MWCNT- modified sensor has good electrocatalytic activity for the redox of ADD.

Mathematical Modelling for Failure Analysis of Composite Drive Shaft Using Modal Flexibility and Curvature Method

Early damage identification in composite structures has attracted a lot of attention in post-failure examinations in recent years. In the research, torsional fatigue test of composite drive shafts has been done and numerical methodologies have been employed for the validation for premature failure using modal flexibility and modal curvature methods. Initially, the eigenvalue and eigenvectors of healthy and fractured drive shafts are evaluated using a numerical model and verified by fatigue experimental approach. Flexibility variance and the absolute curvature difference between the drive shafts that are fractured and those that are healthy are evaluated after mass normalization. Variations in absolute modal curvatures and variations in local flexibilities that are utilized to identify the existence, location, and severity of a drive shaft fracture. The position and severity of the fracture are predicted more precisely by the modal curvature approach than by the modal flexibility approach.

Sound absorber based on a sonic black hole and multi-layer micro-perforated panels

In order to achieve low-frequency and broadband sound absorption simultaneously, we propose a structure that combines a sonic black hole with multilayer micro-perforated panels. Firstly, we present finite element models for composite structures based on sonic black holes and micro-perforated panels and describe the sound absorption mechanism of the composite structure by comparing the sound absorption phenomena of micro-perforated panels with sonic black holes and micro-perforated panels with ordinary circular tubes. Secondly, the effects of the end coordinates of the sonic black hole, the number of panels and the parameters of the micro-perforated panels are discussed. Thirdly, the theoretical model of the proposed structure is developed using the transfer matrix method. Finally, the sound absorption test of the proposed structure is carried out using impedance tubes. The test results show that the sound absorption coefficient of the sample with a geometric length of 203 mm reaches 0.8 at 223 Hz and stabilizes above 0.9 at 398–1600 Hz. The sound absorber based on a sonic black hole and multi-layer micro-perforated panels has excellent sound absorption performance and has great research potential and application value.

Development of Anisogrid Lattice Composite Structures for Fighter Wing Applications

This paper presents research on the use of anisogrid lattice structures in fighter wing applications. While the anisogrid lattice structure has been widely used in spacecraft structures, its implementation in main aircraft structures is still limited. The study is aimed at investigating the feasibility of utilizing an anisogrid lattice structure in fighter wing design. The analysis and optimization focus on determining the optimal weight of the composite wing structure, considering static, buckling, and flutter failure constraints. Various lift distributions, including triangular, Schrenk, and constant, are applied to evaluate the structure’s response to static failure caused by aerodynamic loads. The anisogrid structure design incorporates inclined lattice elements between ribs and spars, with spar arrangement in the wing box featuring an anisogrid configuration. The anisogrid lattice structure is expected to produce higher bending and torsional stiffness compared to conventional orthogonal structures, producing better flutter and buckling characteristics. The optimized wing structure successfully meets static, buckling, and flutter load requirements at speeds below 500 m/s. The study showcases triangular, Schrenk, and constant load distributions resulting in half-wing masses of 504, 571, and 707 kg, respectively. The results show that flutter and buckling loads are no longer the critical loads in wing structural design but static load.

Combinatorial investigation on corrosion resistance of Ir-Ni-Ta alloys

Metallic glasses are often considered to exhibit remarkable corrosion resistance. However, the respective roles of chemical composition and amorphous structure remain unclear. In this work, we take Ir-Ni-Ta alloy system as a model system and utilize combinatorial fabrication and high-throughput characterizations to reveal the correlations between alloy composition and corrosion current density and corrosion potential. The results indicate strong correlations of corrosion current density with metal-metal bond strength and metal-oxygen bond strength, suggesting that the corrosion of the Ir-Ni-Ta metallic glasses is primarily controlled by chemical composition. However, an amorphous structure can facilitate the formation of denser passive film, and thus superimpose a positive influence on alloys that inherently exhibit corrosion resistance. Our findings would help the designing metallic glasses of superior corrosion resistance.