Oxide Composites Research Articles

Selection of internal standards for the determination of rare earth elements by atomic emission spectrometry with microwave plasma

The method of atomic emission spectrometry with excitation spectra in microwave plasma was used to determine the composition of lanthanum sulfide crystals and europium-doped gadolinium oxide, as well as elements in the melt (tin, boron, and lithium). Calibration curves for rare earth elements are nonlinear and do not provide the required accuracy of analysis. To reduce errors and linearize the calibration curves, the internal standard method was used. Molecular ions N2, N2+ and OH did not correct for changes in plasma conditions and inter-element effects. Internal standard elements were selected based on the proximity of the first ionization potential to the analytes, considering Ba, Al, Ga, and In. The use of these elements as internal standards allowed the linearization of calibration curves, achieving an analytical accuracy of 95−105%. The found total mass of the elements was 97−103% of the sample mass, with accuracy confirmed by the method of standard additions.

Microneedle Electrode Patch Modified with Graphene Oxide and Carbon Nanotubes for Continuous Uric Acid Monitoring and Diet Management in Hyperuricemia.

Hyperuricemia is a common disorder induced by purine metabolic abnormality, which will further cause chronic kidney disease, cardiovascular disease, and gout. Its main pathological characteristic is the high uric acid (UA) level in the blood, so that the detection of UA is highly important for hyperuricemia diagnosis and therapy. Herein, we report a biocompatible and minimally invasive microneedle electrode patch (MEP) for continuous UA monitoring and diet management in hyperuricemia. The composite of graphene oxide and carboxylated multiwalled carbon nanotubes was modified on the microneedle electrode surface to enhance its sensitivity, selectivity, and stability, thus realizing the continuous detection of UA in the interstitial fluid to accurately predict the UA level in the blood. This further allowed us to study the hypouricemic effect of anthocyanins on the hyperuricemia model mouse. It was found that anthocyanins extracted from blueberry can effectively inhibit the activity of xanthine oxidase to reduce the production of UA. The UA level of hyperuricemia model mice fed with anthocyanins is ∼1.7 fold lower than that of the control group. We believe that this MEP offers enormous promise for continuous UA monitoring and diet management in hyperuricemia.

Investigation of nanomaterial and hazardous emissions at coal-fired power stations in Mpumalanga, South Africa

Coal-fired power stations remain the main source of electricity generation in South Africa. The combustion of coal creates fly ash and slag, and increases emissions of particulate matter, which is composed of nano-sized materials. In this study, we investigated nanoparticle emissions from coal-fired power stations. Soil samples were collected at 500 m and 1 km radii from Matla and Kriel power stations. The soil samples were examined using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray fluorescence (XRF) spectrometry. SEM images confirmed polydisperse particles in the form of semi-spherical, semi-oval, irregular-shaped and amorphous particles in dust and soil samples. The particle size range was 4–150 nm. Carbon sheet–metal oxide composites of As, Zn, Cu, Cr, Ni and V were observed. We found that coal-fired power stations are a potential source of nano-pollution, pointing to elevated human and environmental exposure around such sites. Currently, there are no environmental limits for nanomaterials due to the lack of robust risk assessment; however, this study suggests that coal-fired power stations may be hotspots that could be used as priority cases to examine the environmental implications of nano-pollution.

Thermal effects of ternary Casson nanofluid flow over a stretching sheet: An investigation of Thomson and Troian velocity slip

The present research analyzes the properties of a Casson ternary nanofluid over a stretching sheet with Thomson and Troian slip conditions, taking into consideration the influences of electromagnetohydrodynamic (EMHD). The ternary nanofluid comprises three different nanoparticles, which include titanium dioxide (TiO2), copper (Cu), and silver (Ag), all being suspended in oil, which is the base fluid. They are involved because of their good thermal conductivity and chemical stability, and AgCuTiO2 /Oil nanofluid is a composite of copper, titanium oxide, and oil. Hence, carrying out the said procedure, the ternary nanofluid becomes AgCuTiO2/Oil. The sheet is, however, thought to be stretching vertically while the flow is determined by the effect of the gravity force through the free convention. Moreover, the phenomena of EMHD, porous medium, thermal slip, thermal radiation, Joule heating, and heat source/sink are included to make the energy equation more real-life. This leads to a set of partial differential equations (PDEs) based mathematical models transformed into ordinary differential equations (ODEs)-appropriate similarity transformation. The Runge–Kutta–Fehlberg (RKF-45) method solves the given ordinary differential system. According to the research’s findings, the temperature of the ternary Casson nanofluid rises when the suspension of silver, copper, and titanium dioxide nanoparticles increases, and the velocity of flow for merely silver and copper decreases when the density decreases. This causes the flow rate to be constricted through the velocity slip condition, at the same time as the nanofluid’s temperature increases.

Synthesis of biochar and its metal oxide composites and application on next sustainable electrodes for energy storage devices

Biochar materials have been applied in energy storage due to their unique properties, such as high storage of ions, high conductivity, chemical stability and ease of production. Combining it with the high specific capacitance could be a promising strategy to develop devices and improve the properties. Through a hydrothermal technique the biochar powders were synthesized from sugarcane biomass. An acid pretreatment was carried out before and after the graphitization process aiming to obtain carbon materials with high surface area and porosity. The morphological characterization reveals powders with pores of submicrometer diameter. For the pure biochar it was determined a superficial area of 477.66 m2.g−1 with a median pore size of 42.92 Å and a pore volume of 0.21 cm3.g−1. A carbon-based paste was then prepared to deposit on nickel foam and obtain the electrodes. In a 3-electrode system characterization, biochar has showed higher specific capacitance than the metal oxide composites due to higher surface area and higher medium pore diameter. It was calculated a resistance of 2.7 Ω, a capacitance of 446 mF.g−1, a power density of 46.2 W.kg−1 and an energy density of 1.8 W.h.kg−1. These results indicate the potential use of biochar-based electrodes with high electrical conductivity and improved surface area to obtain higher capacitance properties for development of advanced devices.

Electrochemical immunosensor for the predictive cancer biomarker SLFN11 using reduced graphene oxide/MIL-101(Cr)-NH2 composite

SLFN11 is a predictive cancer biomarker essential for identifying tumors that are sensitive to DNA-damaging agents, facilitating more personalized and effective treatment approaches. Detecting this biomarker can guide therapeutic decisions and improve outcomes for cancer patients. However, existing detection methods for SLFN11 are complex and require advanced techniques. In this study, we introduce the first immunosensor designed for on-site detection of SLFN11. An advanced electrochemical immunosensor platform utilizing a composite of graphene oxide (GO) and chromium-based metal organic framework (MIL-101 (Cr)-NH2) was developed. The integration of GO and MIL-101(Cr)-NH2 was characterized through FT-IR, XRD, SEM, and XPS, affirming the formation of the composite. The subsequent electrochemical reduction to rGO/MIL-101(Cr)-NH2 significantly improved the electrochemical performance and stability. A glutaraldehyde cross-linker was then utilized to attach the SLFN11-specific antibody to the amine groups of the MOF-modified electrodes. This led to the development of rapid, sensitive, portable, and cost-effective immunosensor for SLFN11 at concentrations as low as 8.9 pg/mL which holds promise for early cancer diagnosis. High specificity was achieved, with minimal cross-reactivity observed with other cancer biomarkers such as pepsinogen I, claudin 18.2 and Programmed cell death protein 1. Demonstrating practical applicability, the electrochemical immunosensor validated by commercial ELISA kit showed successful detection in serum samples with high recovery rates and reproducibility. This research highlights the potential of rGO/MOFs composites in electrochemical biosensors developments for early cancer diagnostics and personalized medicine.

An Evaluation of the Damping Characteristics of Some Silicon Rubber/Ferric Oxide Composites

ABSTRACTGenerally, polymeric materials with superior damping characteristics are in great demand for many advanced functional applications, such as in building, aerospace, electronics, and transport sectors. However, it still remains a challenge to improve the damping characteristics of such materials owing to the lack of adequate practical knowledge in this area. Here, we report on the successful fabrication of silicon rubber (SR)/ferric oxide (Fe3O4) composites with excellent damping characteristics. The results obtained from the study showed that the damping characteristics of the specimens increased with the loading of Fe3O4 within a range of −105°C to 200°C. Specifically, the damping factor (tanδ) is 0.45 at room temperature, and the effective working temperature, the temperatures that correspond to the tanδ > 0.3, ranged from −105°C to 165°C for the loading of Fe3O4 at 60 phr. The scanning electron microscopy results showed that the excellent damping characteristics of composites can be attributed to the good dispersion of Fe3O4 in the SR matrix. This work, therefore, opens up a pathway toward a relatively easy and up‐scalable means for fabricating polymer composites that have superior damping characteristics and ones with a wider applicability.

Biodegradation and mechanical performance of Silane-chitosan-graphene oxide composite coating on AZ31 magnesium alloys for biomedical applications.

Biodegradable magnesium alloy medical implants have attracted considerable interest thanks to their remarkable biocompatibility and mechanical properties. However, the rapid corrosion rate of magnesium alloys in physiological environments presents a major challenge to their practical application. Therefore, this study attempted to design a silane/chitosan /graphene oxide composite coating that reduces the corrosion and enhances the biodegradation of magnesium alloys used in temporary implants. The composite fabrication process adopted a cost-effective spin-coating technique providing a uniform coating of magnesium alloy substrates. Fourier transform infrared spectroscopy (ATR-FTIR), Raman spectroscopy, scanning electron microscopy (SEM) and energy dispersion spectroscopy (EDS) results showed a dense and compact silane/chitosan/graphene oxide (Silane/CS/GO) coating on the magnesium coated alloy surface. The mechanical properties of the fabricated silane/chitosan/graphene oxide composite were also investigated by microindentation and scratch tests. The hardness of the magnesium alloy increased from ~268 HV ±13.4 to ~644.13 HV ± 32.2 upon the application of the coating. Moreover, the results showed that the cohesive critical load (LC) of the ternary composite was greater than LC ~ 3.02 ± 0.15 N. In addition, compared to uncoated AZ31 alloys, the friction coefficient and wear volume of the ternary composite decreased from ~0.13 ± 0.02 to ~0.07 ± 0.004 and from ~18 to ~0.04 (106μm3), respectively. Finally, the corrosion of the composite coating was assessed in simulated body fluid (SBF) in vitro at 37 °C. Hydrogen evolution results revealed that graphene oxide seemed to delay the diffusion of corrosive ions into the Mg matrix, while Silane prevented the coupling of GO graphene oxide sheets to the metal surface. Consequently, silane / chitosan /graphene oxide composite coatings could be a very useful material for coating magnesium implant devices. It contributed to reduce the corrosion of the substrate and alleviate the cost and discomfort of implants.

Development of a reagent-free electrochemical disposable sensor strip for the quantification of sweat chloride

In this work, we developed a reagent-free disposable sweat chloride sensor using silver platinum reduced graphene oxide composite. The sensing mechanism involves the silver chloride formation from electro-oxidized silver in the presence of chloride ions. The combination of platinum with silver and reduced graphene oxide resulted in an approximately sixfold increase in sensitivity, significantly enhancing the sensor performance. The developed disposable strip exhibited an excellent sensitivity of 6.592 ± 0.007 and 17.420 ± 0.011 mA (log mM)−1 cm−2 for 5–40 mM and 40–200 mM chloride concentration ranges, respectively with a detection limit of 12 µM. The developed sensor exhibited exceptional selectivity against interfering molecules in sweat samples. The practical applicability of the developed sensor was evaluated in sweat samples, revealing an outstanding sensitivity of 0.901 ± 0.007 mA (log mM)−1 cm−2 for detecting sweat chloride ions. The estimated chloride concentrations are in good agreement with the clinically tested values with a relative error of less than 1.5%. The performance of the fabricated Ag-Pt/rGO/SPE sensor opens advanced point-of-care testing opportunities through non-invasive, and convenient analysis.

Investigating the environmental impacts of lithium-oxygen battery cathode production: A comprehensive assessment of the effects associated with oxygen cathode manufacturing

Lithium-oxygen batteries offer remarkably high energy density compared to current lithium-ion batteries. The key to their electrochemical performance lies in the processes occurring at the air cathode. However, the complexity of these reactions, coupled with the by-products generated during discharge, can make the reaction process slow or impede their efficiency. This study evaluates the environmental impact of high-efficiency lithium-oxygen batteries cathodes, including titanium oxide composites, graphene-based composites and activated carbon-based composites, through a life cycle assessment across 18 impact categories using a cradle-to-gate approach with a functional unit of 25 kWh. Results show that active material production was the largest contributor to environmental impact, particularly Global Warming Potential. Among the evaluated cathodes, reduced graphene oxide/α-mnaganese oxide/palladium (rGO/α-MnO2/Pd) demonstrated the highest environmental impact, with a global warming potential of 1130.71 kg carbon dioxide from active material production, due to its energy-intensive synthesis and the use of chemicals like sulfuric acid, sodium borohydride, hydrochloric acid, and hydrogen peroxide. Additionally, the rGO/α-MnO2/Pd cathode had the highest Human Toxicity Potential and Ozone Depletion Potential. Batteries with graphene-based cathodes achieved a specific capacity of 7500 mAh.g-1, underscoring their performance potential while highlighting the need for more sustainable cathode manufacturing methods. These findings emphasize the environmental considerations necessary for large-scale lithium-oxygen batteries implementation.

Effect of titanium oxide nano‐filler on mechanical and sliding wear properties of hairy cotton grass fibre reinforced epoxy composites

AbstractThis study explores the synergistic influence of hybridizing titanium oxide (TiO2) filler on the mechanical properties and sliding wear behavior of epoxy composites reinforced with hairy cotton grass (HCG) fibres. The experimental results reveals that the combination with 9 wt‐% HCG/4 wt‐% titanium oxide observed better mechanical results (tensile‐51.03 MPa, flexural‐28.66 MPa, and impact energy‐3.1 J) whereas higher hardness (40.77 HV) achieved at 9 wt‐% hairy cotton grass/6 wt‐% titanium oxide composites. There is deterioration in mechanical results at higher titanium oxide (6 wt‐%) loading due to uneven distribution and particle agglomeration in hairy cotton grass‐epoxy composites. The design of expert was generated by using control parameters, sliding velocity (1 m ⋅ s−1–4 m ⋅ s−1), TiO2 content (0 wt‐%–6 wt‐%), and normal load (15 N–30 N) respectively. The optimization of the sliding wear rate was analysed by the Taguchi approach followed by an analysis of variance used for evaluating the significant of control parameters. The results showed a combination with significance sliding velocity of 1 ms−1 (78.15 %)>titanium oxide content of 6 wt‐% (20.28 %) >normal load of 30 N (1.57 %) exhibited an optimum value of specific wear rate.

Effects of exopolysaccharides from Rhizobium tropici on transformation and aggregate sizes of iron oxides

Iron oxide transformations in soil significantly impact nutrient availability and plant health. This study investigated the interaction between exopolysaccharides (EPS), produced by Rhizobium tropici, and iron oxide (Fe3O4), focusing on their impact on the transformation, particle size, and zeta potential of iron oxides. The characterization of the EPS-iron oxide composites was carried out using X-ray Powder Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM)/Energy Dispersive X-ray Analysis (EDX). The EPS adsorption kinetics revealed chemisorption and diffusion as controlling processes for EPS adsorption on Fe3O4, while isotherm data with releasing proton indicated possible ion exchange and heterogeneous layered adsorption. Desorption studies suggested the high stability of EPS-iron complexes. Notably, EPS significantly increased the aggregate size of EPS-iron complexes at low EPS/iron oxide molar ratios but shrank the aggregate size at higher ratios (> EPS/iron oxide 2 × 10−4). Additionally, EPS complexation resulted in a shift in the zeta potential towards more negative surface functionality. Functional groups within EPS, specifically –COOH, –OH and –NH played a crucial role in the interaction of EPS with iron oxides. The study concluded that EPS coating prevented the transformation of Fe3O4 into other iron oxide forms like β-FeOOH, α-Fe2O3, and γ-Fe2O3, elucidating the significant role of EPS in soil mineral processes.

Oxidation of Ni(H2O)6@MoO3 to Ni2O3/MoO3 Composites by Aerial Annealing: Electrocatalytic Hydrogen Evolution.

Molybdenum trioxide (α-MoO3) is a promising and inexpensive alternative to platinum group metals (PGMs), for electrocatalytic hydrogen evolution reaction (HER). However, to make it a viable candidate for electrocatalytic systems, we must address the hurdles associated with its inferior electrical conductivity and lack of active sites. Unlike Mo-based compounds such as MoS2 and MoSe2, which possess catalytically active edges, α-MoO3 lacks inherent active sites for HER. Previous studies have employed various strategies to activate MoO3 for HER, yet its activation in near-neutral conditions remain largely unexplored. In this study, a previously known α-MoO3 intercalating {Ni(H2O)6}2+, [MoVI2O6(CH3COO){NiII(H2O)6}0.5]·H2O (Ni(H2O)6@MoO3) is prepared via a simple and scalable room-temperature aqueous synthesis. In the subsequent aerial thermal annealing process at 300, 400 and 500 °C, Ni(H2O)6@MoO3 acts as a self-sacrificial template, yielding mixed metal oxide composites of nickel and molybdenum (named as MoO3-300, MoO3-400 and MoO3-500). The HR-TEM and XPS analyses confirm the formation of the Ni2O3 phase alongside the orthorhombic α-MoO3. The annealing temperature plays a key role in the crystallinity, phase, morphology, and electrocatalytic performance of the resulting composites. The composite formed at 400 °C (MoO3-400) shows the best electrocatalytic performance among them.

Graphene oxide and hydroxyapatite-based composite extracted from fish scale: Synthesis, characterization and water treatment application

In this study the removal of hydrocarbon pollutants from refinery waste water has been described through a convenient adsorption technique using a novel composite of graphene oxide (GO) and n-hydroxyapatite (n-HAp). The main aim was to synthesized composite which are not only sustainable and biodegradable but also exhibit high adsorption capacity and selectivity for hydrocarbon pollutants. Both the HAp and GO were synthesized from fish scales in the laboratory. The synthesized material was then characterized by XRD, FTIR, SEM, and EDX. At 40 °C and 80 min of reaction time, the adsorbent utilized in a batch mode study attained a maximum 97 % organic pollutant adsorption rate. The adsorption activity was spontaneous, exothermic, useful, and it adhered to the pseudo-2nd order kinetic model. without noticeably losing its activity, the adsorbent retained a high level of efficiency over four consecutive cycles. Adsorption of hydrocarbon wastes using composite adsorbent was carried out under batch mode of adsorption experiments. We also studied the effect of dose, temperature, time and pH of the solution on adsorption. Ethanol was used to regenerate the adsorbent, and it was then dried at 70 °C for re-use. The SEM investigation showed that the morphology of huge caves is rough, layered, and wrinkled. The oxygen and phosphate containing groups were found via FT-IR analysis. Freundlich and Langmuir kinetic models were used to measure the adsorption behavior by applying them to the adsorption data. The results demonstrated a strong correlation between the Freundlich isotherm model and the real data. This study showed a highly effective and cost-efficient methodology for the removal of toxic hydrocarbon contaminants in refinery wastewater.

Iron-containing tailings catalyst modified by Mn for SCR of NO with NH3 at low temperature: Study of carrier treatment and calcination temperature

The development of cost-effective low temperature selective catalytic reduction (NH3-SCR) catalysts for nitrogen oxides is a major challenge. To this end, a low-cost rare earth tailings catalyst modified by Mn was successfully synthesized by the impregnation method using rare earth tailings as raw materials. The iron-containing tailings catalyst modified by Mn exhibited high NH3 SCR activity with high N2 selectivity at low temperature range (150–200 ℃). The H2SO4 modification resulted in the weakening of the Fe-O bonds on the catalyst, thereby producing the active component, iron sulfate salt. The coordination occupancy of Brønsted acid sites is increased, thereby facilitating electron transfer and redox cycling of SCR. Furthermore, by modulating the calcination temperature, the synergistic effect of Fe and Mn is augmented, resulting in the generation of a substantial number of Mn-Fe composite oxides, which is conducive to the enhancement of NH3 adsorption and activation on the catalyst. The formation of additional Brønsted acids was identified as a primary factor influencing the enhancement of N2 selectivity in the catalyst. The catalytic process followed both the E-R and L-H mechanisms on the catalyst. The Iron-containing tailings catalyst modified by Mn represents a cost-effective and resource-conserving alternative. The provision of high denitrification efficiency, coupled with the capacity to address the issue of low N2 selectivity, offers a sustainable and low-carbon solution for the industrial reduction of NOx.

Harnessing carbon-based adsorbents for poly- and perfluorinated substance removal: A comprehensive review

Poly- and perfluoroalkyl substances (PFAS) are synthetic, highly fluorinated chemicals commonly used in products like water-resistant materials, personal care items, non-stick cookware, and cleaning agents. Due to the strength of their CF bonds, PFAS are extremely persistent in the environment, creating significant challenges for pollution control. Traditional degradation methods often prove ineffective, making adsorption a promising alternative for PFAS removal from contaminated water. Carbon-based adsorbents, valued for their sustainability and efficiency, are particularly effective for this purpose. This review provides a detailed analysis on PFAS properties and their removal using various carbon-based adsorbents, including activated carbon, biochar, graphene oxide, carbon nanotubes, and magnetic composites. Adsorption capacities of these materials were seen vary significantly, from as low as 10.7 mg/g for Fe3O4-hybrid biochar, to as high as 713.85 mg/g for functionalized graphene-based adsorbent, highlighting the superior adsorption efficiency of modified graphene adsorbents compared to traditional biochar and activated carbons. Most of these adsorbents fit the Langmuir isotherm model and pseudo-second-order kinetic model with high coefficient of determination, indicating efficient monolayer adsorption and strong interaction with PFAS. The review also explores different adsorption mechanisms, the effects of process parameters on adsorption efficiency, strategies for adsorbent regeneration, and concludes with a bibliometric analysis that highlights key research gaps. These insights are intended to guide future advancements in the development of effective, scalable PFAS remediation technologies using carbon-based adsorbents.

Enhancement of Thermoelectric Properties of Zinc Oxide Composites via Doping with Active Metal Oxide

Enhancement of Thermoelectric Properties of Zinc Oxide Composites via Doping with Active Metal Oxide

Study on interfacial reaction behavior between CaO-Y2O3 ceramic and Ni-based superalloy melt during vacuum induction melting

The reaction mechanism at the interface between CaO-Y2O3 composite oxide refractories and superalloy melt during vacuum induction melting of Ni-based superalloys was investigated. Once the reaction occurred, the interfacial layer consisted of exterior CaS layer and interior CaYAlO4 layer. CaS was formed by the desulfurization reaction of CaO and S from alloy melt. While the CaYAlO4 was formed by the reaction of 12CaO·7Al2O3 or Al2O3 (CaO and Y2O3 were replaced by Al), CaO and Y2O3. The whole interfacial reaction was: CaO(s)+[S]Ni(l)+[Al]Ni(l)+Y2O3(s)=CaYAlO4(s)+ CaS(s)+[Y]Ni(l).

Synthesis, and structural characterization of FeMoO4/r-GO nanocomposite as an electrode material for energy storage application

Improving the energy density of electrochemical supercapacitors requires the urgent development of novel electroactive materials. Metal molybdate-based nanostructures are promising candidates as effective electrode materials for the next generation of energy storage solutions. In the present work, a FeMoO4/r-GO nanocomposite was synthesized via the hydrothermal method and used as anode material for supercapacitor application. The structural, and topographical properties were investigated by XRD, FE-SEM, and TEM analysis. Field Emission Scanning Electron Microscopy (FE-SEM) and Transmission electron microscope (TEM) images of FeMoO4/reduced graphene oxide (r-GO) composites show an irregular, rod-like structure coated with r-GO sheets. The FeMoO4/r-GO nanocomposite electrode material exhibited a remarkable specific capacitance of 240 F/g at the current density of 1 A/g, which is significantly higher than the 167 F/g capacitance of pure FeMoO4. The continued charge–discharge (GCD) (5,000) life cycle performance of FeMoO4/r-GO was the retention and coulombic efficiency of 90 % to 86 % after 10 A/g.

A high-performance flexible biopolymer-based Ce oxide composite electrolyte for lithium-ion battery dendrite reduction

We propose a novel solid-state composite polymer electrolyte (CPE) that includes Li7La2.5Ce0.5Zr2O12 (Ce-LLZO), chitosan (CS)/agar-agar (AA) polymer, polyethylene glycol (PEG) plasticizer, and LiClO4 salt. At 25 °C, the CPE3 formulation, consisting of 15 wt% Ce-LLZO, 60 wt% CS-AA, 15 wt% PEG, and 10 wt% LiClO4, demonstrated exceptional lithium (Li)-ion conductivity of 5.18 × 10-3 S cm−1 and an optimal transference number (TLi+) of 0.937. We assessed the electrochemical stability of CPE3 using linear sweep voltammetry, which revealed a maximum stability limit of 4.1 V (versus Li/Li+). In addition, the coin cell made with the Li||CPE3||NMC configuration had an amazing discharge capacity of 163 mAhg-1 and stayed stable for up to 100 cycles at 0.1 °C in room temperature. Conversely, when subjected to Li-plating/stripping cycles, the symmetric Li||CPE3||Li cell exhibited stability for 550 h and maintained a current density of 2.0 mA cm−2. Compared to Li-metal, the proposed material exhibited reduced overpotential while simultaneously enhancing electrochemical stability.