Gasoline Components Research Articles

Bifunctional Catalytic Performance of Zn/ZSM-5 in the Aromatization of LPG and the Conversion of Pyrolytic Gases from Recycled Polypropylene

Zn-modified ZSM-5 zeolites with different zinc contents were successfully prepared by the impregnation method and compared with unmodified ZSM-5. Their potential for LPG (liquefied petroleum gas) aromatization and the conversion of pyrolysis gases obtained from recycled polypropylene was subsequently evaluated. In this process, various characterization tests were performed on the prepared catalysts, including SEM-EDS (scanning electron microscopy with energy-dispersive spectroscopy), TPD-NH₃ (temperature-programmed desorption of ammonia), and FTIR (Fourier-transform infrared spectroscopy). Under optimized conditions, the best results were obtained with 2% Zn/ZSM-5, which generated a higher production of BTX (benzene, toluene, and xylene) isomers, which are major components of gasoline. Likewise, in catalytic pyrolysis of recycled polypropylene, this catalyst generated a higher production of aromatic compounds. Therefore, this catalyst showed excellent performance in generating valuable hydrocarbons of great industrial interest, particularly aromatics.

Investigation of pyrolysis productions (pyrolysis oil, pyrolysis gas and carbon nanotubes) distribution in co-pyrolysis of torrefied oiltea camellia shells and polypropylene

The co-pyrolysis of torrefied oiltea camellia shells (OCS) and reused polypropylene (PP) was investigated for pyrolysis oil, pyrolysis gas and carbon nanotubes (CNTs) distribution characters in a two-stage pyrolysis system. Compared with raw OCS/PP, the quality of pyrolysis oil from torrefied OCS and PP was upgraded while yield decreased gradually. In particular, torrefaction pretreatment was beneficial to the formation of aromatic hydrocarbons and the higher selectivity of phenols in pyrolysis oil. And serious N2 torrefaction (260 N) and slight CO2 torrefaction (200C) is more conducive to the synthesis of C6–C11 (gasoline component). In addition, torrefaction could contribute to lower volatiles, which resulted in a lower yield of CNTs. For comparison, higher graphitized CNTs was prepared from the co-pyrolysis of torrefied OCS and PP. Appropriate torrefaction temperature and atmosphere have a potential for high value conversion of pyrolysis oil, pyrolysis gas and CNTs from co-pyrolysis of biomass and plastics.

A New Approach to Determining the Blending Octane Number of Gaseous Components of Motor Gasolines

A New Approach to Determining the Blending Octane Number of Gaseous Components of Motor Gasolines

Efficiency of oxygenates on increase of octane number of reforming gasoline

At present, gasoline occupies one of the leading places among primary energy sources. The need of mankind in it, in its high quality, is greater than in any other fraction of hydrocarbons. Therefore, very high requirements are made to the operational properties of automobile gasoline, and the problem of improving the quality of gasoline is one of the urgent problems of the chemical industry. Modern vehicles require fuel with a high-octane number with properties preventing detonation and having octane numbers of 92, 95 and 98 for engines. High anti-detonation performance can be achieved through complex gasoline processing using catalytic cracking, isomerization and alkylation methods or by adding special high-octane additives to fuel. The world's leading trend in improving the environmental and performance characteristics of motor gasoline is the use of multifunctional additives, in particular oxygenates – compounds containing oxygen (such as alcohols, ketones, esters and others). The use of oxygen-containing components (oxygenates) is one of the promising ways to produce high-octane gasoline. Currently, in industrialized countries, oxygenates are actively used as a preferred substitute for organometallic anti-detonation additives and components of high-octane gasoline. In the presented work the properties of a new oxygenate - dimethyl ethynylcarbinol (DMEC), as an additive that increases the octane number of gasoline, are investigated. The study of the effect of oxygenates as methyl tert-butyl ether (MTBE) and DMEK on increasing the octane number of reforming gasoline showed that the increase in the octane number of gasoline when adding DMEK and binary additive is higher than when adding MTBE. According to the results of research, tertiary acetylene alcohol - DMEK can be offered as an oxygen-containing additive for automobile gasoline. The use of DMEK allows to expand the resources of high-octane components, reduce the toxicity of gasoline and exhaust gases, increase the production of high-quality commercial gasoline for automotive engines.

SECONDARY POLYMERS AS A PROSPECTIVE RAW MATERIAL FOR THE PRODUCTION OF HIGH-OCTANE AUTOMOBILE GASOLINE

The article analyzes the possibility of expanding the raw material base of the production process of commercial high-octane automobile gasoline of the A-92 and A-95 brands due to the involvement of secondary polymer raw materials. The types of raw materials that will make it possible to obtain basic fractions or components of commercial gasolines that will be used in the production of commercial automobile gasolines that, according to their chemical composi- tion and properties, will meet the requirements of environmental safety standards adopted in Ukraine and the countries of the European Union have been determined. It was established that the main raw material capable of replacing oil and gas condensate is secondary polyolefin raw material, represented by polyethylene (HDPE and LDPE) and polypropylene (PP), and the main process of its processing is thermal or thermocatalytic pyrolysis. Priority is given to raw materials that are directly generated in production in the form of waste and raw materials that come from sorting points. At the same time, secondary polymer raw materials, regardless of their source of origin, must undergo a stage of preliminary preparation, which includes sorting, crushing, washing and drying of raw materials. Practical studies have shown that this process is implemented on reactor-type installations at temperatures of 320–450 °C and pressures of 0.1–3.5 MPa and allows obtaining a significant yield (35–70 %) of the liquid product of pyrolysis – a gasoline fraction with a boiling point of 30–200 °C. Along with liquid products, more than 15 % of gases (ethylene, propylene and butylene) are formed, which should be processed into polymer gasoline (base fraction) and high-octane components – alkylates. As a result of the research, a scheme for the production of commercial high-octane automobile gasoline from secondary polymer raw materials (HDPE, LDPE and PP) is proposed, which is based on the rational use of production resources and production by-products.

CONVERSİON OF n-HEXANE OVER CATALYSTS BASED ON SULFATED ZIRCONIUM DIOXIDE

The isomerization process is becoming increasingly important in the modern petroleum refining context due to the limitations on the content of benzene, aromatic compounds, and olefins in gasoline. Isomerization is an effective and profitable process for octane enhancement of gasoline unlike other octane increasing processes. Due to the low sulfur and benzene content, the isomerate can be used as an ideal blending gasoline component. Therefore, the isomerization process has a great importance in petroleum refineries to increase the fuel octane number. This article aimed to study the conversion process of normal hexane over palladium and platinum containing catalysts on the base of sulfated zirconium dioxide. It has been determined that due to their high-performance characteristics, catalytic systems based on sulfated zirconium dioxide can be considered the most promising for isomerization of normal alkanes. Moreover, comparison of palladium-containing catalysts based on sulfated zirconium dioxide with platinum-containing catalysts based on sulfated zirconium dioxide showed that palladium sulfated zirconia catalysts have high catalytic performance in the isomerization of normal hexane. Keywords: alkanes, catalyst, platinum, palladium, isomerization, temperature, sulfated zirconium dioxide. .

About the sonoluminescent spectral portrait of gasoline water pollution

Single-bubble sonoluminescence spectra of the following samples were recorded in the modes of standing and moving bubble in liquid near the center of its levitation under the action of ultrasound: water contaminated with additives of commercial gasoline (1.5 – 38 mg·L−1), water with additives of individual gasoline components (hexane, benzene, toluene, p-xylene, naphthalene, anthracene, and p-terphenyl), and solutions of these gasoline components in hexane. Characteristic bands λmax of gasoline component emitters are recorded in the sonoluminescence spectra of a moving bubble for water samples contaminated with additives of commercial gasoline: 290 (p-xylene), 340 (p-terphenyl), 381, 399, 424, 449 (anthracene), and 438, 474, 516, 564 nm (C2, a hydrocarbon decomposition product during sonolysis).These bands are as a spectral portrait of gasoline contamination of water: they make it possible to identify gasoline in water in the above mentioned range of its content and to find a quantitative content of individual gasoline components.

Novel variants conceptional technology to produce eco-friendly sustainable high octane-gasoline biofuel based on renewable gasoline component

The creation of green engine fuels from renewable and sustainable gasoline additives is essential as a consequence of ecological concerns and the energy problem. Bio-alcohols are currently a promising sustainable fuel substitute for gasoline in automotive transportation. In this perspective, the ongoing investigation intends to evaluate the influence of sustainable and renewable petrol additives, like isopropanol, which has outstanding anti-detonation properties and great chemical and physical characteristics on reformable naphtha (HSRN) and light naphtha (LSRN), which possess low chemical and physical characteristics, and low octane rating. Additionally, the second goal is to create biofuel with an eco-octane number of high by blending other gasoline components than those previously indicated. Several gasoline fuels and experimental setups compliant with European standard norms were used to carry out the current work. The results reported that gasoline RON92, RON95, and RON98 were produced based on isopropanol as a renewable and sustainable resource. Moreover, the quantity and quality of light naphtha were maximized. Likewise, the laboratory findings reported that the antiknocking efficiency could be ranked sequentially as isopropanol > reformate > isomerate > fluidized catalytic cracked gasoline (FCC) > PRF-70 > LSRN > HSRN by octane rating. Furthermore, the Reid vapor pressure (RVP) for petrol RON92 was bigger than gasoline RON95 and RON98, unlike the density at 15 °C for gasoline RON 98 was bigger than gasoline RON92 and RON95. Finally, major problems like energy, water scarcity, and the environment affect people all around the world. Two of the earlier environmental and energy-related problems will be resolved by using these sustainable and renewable additions.

Automation of the Formation of a Mathematical Formulation of Kinetics for Multistage Chemical Reactions and Numerical Solution to a Direct Problem

Introduction. The basis for research, analysis and mathematical optimization of any chemical process is an adequate mathematical model that takes into account the kinetics of the object. Kinetic analysis is a challenge in chemical technology, since it allows for optimizing synthesis processes and predicting their efficiency. Numerous chemical processes involve several stage reactions. For successful design and optimization, a mathematical model that describes each stage is needed. Creating such a model manually can be time-consuming and costly, since it requires processing a large amount of information. The modern level of automation makes it possible to accelerate the obtaining of a mathematical formulation of the kinetics of multistage reactions. In this case, working with data is greatly simplified, and the probability of making mistakes is reduced. The resulting mathematical model can be applied for further analysis and optimization of the process. The paper considers the industrial reaction of catalytic reforming of gasoline, which occupies an important place in the modern scheme of oil refining, since it is a source of high-octane components of commercial gasolines and individual aromatic hydrocarbons. This process is characterized by the participation of a large number (up to 300) of various hydrocarbons, a change in the number of moles, and non-isothermality in it. Mathematical modeling of such processes involves detailing the stages to the required level. The detailing of up to 173 stages is considered. In this setting, automation of the formation of a mathematical formulation of kinetics for catalytic reforming of gasoline has not been carried out before. Therefore, the presented work aimed at implementing effective numerical methods and algorithms for automating the building of a mathematical model taking into account kinetics, thermodynamics, and changes in the number of moles.Materials and Methods. The mathematical formulation of the kinetics of multistage reactions was developed on the basis of the mass action law. The kinetic parameters values were taken from literary sources. The direct kinetics problem was solved using algorithms: the Gear method, the Runge-Kutta method of the 4th order, and the scipy.odeint() method of the Python language. The automation concept was implemented using the IDEF0 methodology. The software was written in the Python programming language.Results. A new software was created to automate the process of forming a mathematical model, taking into account the kinetics, thermodynamics, and the volume of the reaction mixture. The program results were presented by the example of catalytic reforming of gasoline. The model implemented the possibility of taking into account the intermediate heating of the mixture in the reactor cascade. Numerical values of temperature changes corresponding to industrial data were obtained.Discussion and Conclusion. The results obtained through modeling chemical transformations in the cascade of gasoline catalytic reforming reactors confirmed the exothermic nature of the reaction. The developed software product provides displaying changes in the concentrations of reactants, as well as temperature variations in the reactor, and it can be used in scientific research organizations for the analysis of multistage catalytic processes. The results of the reaction kinetics modeling will be used in the subsequent optimization of the process conditions in production.

Experimental and simulation study on evaporation characteristics of E85 impinging spray under DISI cold-start condition

The direct injection of ethanol-gasoline blended fuel into the engine cylinder near the top dead center (TDC) is evitable to suffer from the wall impingement due to more injection mass required to maintain the same air/fuel ratio with traditional fossil fuels. In this study, the evaporation characteristics of E85 cold-start impinging spray were investigated by experiments and numerical simulation. A constant volume vessel was used to produce the direct-injection spark-ignition (DISI) engine-like conditions. The ultraviolet (UV) – visible (Vis) dual-wavelength laser absorption scattering (LAS) technique was employed to quantitatively measure the individual components evaporation in E85, with the emphasis on the effects of impinging distance, wall temperature and injection pressure on the mixture formation. The results show that although the larger impinging distance rarely influences the evaporation before impingement, it facilitates the E85 evaporation process after impingement due to the better atomization by low boiling point (LBP) components (e.g. ethanol). The effects of cold-start wall temperature on the E85 impinging spray are greatly dependent on the impinging distance. Under the small impinging distance, the ethanol and low boiling point (LBP) components of gasoline evaporate faster after impingement at higher wall temperature, but such effect becomes absent under long impinging distance. Therefore, the smaller impinging distance shows a higher sensitivity to wall temperature. Lower wall temperature leads to a high wall heat transfer, thus potentially extend the evaporation time at the near wall region along the spray axis. At either impingement timing or initial impingement, the LBP component with high latent heat evaporates fast, leading to a decrease of surrounding gas temperature. Increasing injection pressure helps to greatly improve the evaporation of the high boiling point (HBP) component in gasoline under cold-start impingement. The evaporation ratio of E85 increases up to about 18% ∼ 30% than that of E100 at the initial impinging period under cold-start condition.

An Overview of the Global Market, Fleet, and Components in the Field of Aviation Gasoline

Aviation gasoline is a fuel for spark-ignition piston internal combustion engines, which are usually used in light aircraft (small aviation and general aviation). This technique is widely used for regional and interregional transportation, for the initial training and retraining of aviation staff, for private use, for agricultural purposes, for the development of aviation sports and tourism, and for combat and rescue operations. This article gives some estimates of the production and consumption of aviation gasoline in the EU, North and South America, Asia–Pacific, Africa, and CIS countries. Export possibilities and the reliance on import within different regions are analyzed. Economic indicators for aviation gasoline are calculated by assessing the share of its production in the GDP and per capita consumption. In the context of the transition to unleaded aviation gasoline, the structure of the piston aviation fleet and its readiness for the transition are considered. The paper also analyzes the following existing components of unleaded aviation gasoline: technical capabilities and promising components.

Study on the adsorption of volatile gasoline components via HKUST‐1: Isobutylene as a model compound

AbstractAdsorption of volatile gasoline components at oil terminal by using metal organic frameworks (MOFs) is a prospective technology in reducing environment pollution and increasing oil resource recovery. In this study, a typical MOF of HKUST‐1 was facile prepared by solvothermal method and tested in the adsorption of volatile gasoline components. Isobutylene was selected as a model compound. The effects of preparation parameters Cu2+/H3BTC molar ratios, Cu2+ precursors, and solvent compositions on the structure of HKUST‐1 and its subsequent adsorption performance were systematically studied. The synthesized samples were characterized by XRD, SEM, and N2 physisorption. It was found that the HKUST‐1 prepared by using DMF as the unique solvent obtained the highest specific surface area (1076.7 m2/g) and the largest pore volume (0.90 cm3/g). Furthermore, the maximum isobutylene adsorption capacity of 31.9 mg/g was found on the HKUST‐1 which prepared under the conditions of Cu2+/H3BTC = 2, Cu (CH3COO)2 as the Cu2+ precursor, and a solvent composition of DMF:EtOH:H2O = 0:4:3.

A new approach to determining the blending octane number of gaseous components of motor gasolines

The octane number for gaseous components (GC) is currently determined using the calculation method proceeding from the hydrocarbon composition. The method provides determination of the research octane number (RON) only. A discrepancy between the actual and predicted values of the octane number thus determined leads to an overestimated introduction of these components into the fuel which results in the reduced fuel performance and economic indicators of the production. In this regard, the development of a new approach to the determination of the blending octane number of low-boiling components is extremely important for designing optimal formulations of motor fuels. A method for determining the blending octane numbers (both RON and MON) of motor gasoline gaseous components has been improved due to preliminary sample preparation by bubbling which provided taking into account the proportion of involving fractions of C4 hydrocarbon and pentane-amylene along with the chemical nature of the base fuel components. It is shown that the value of the blending octane number for gaseous components depends on the hydrocarbon composition of the base component. Application of the developed method to determining the blending octane number of gaseous components of motor fuels allowed us to obtain optimal formulations of gasoline with the involvement of low-boiling by-products and increased the accuracy of forecasting the composition of fuels thus improving the economic performance of the production.

An investigation into the process intensification of gasoline etherification by coupling with membrane separation

The etherification of gasoline is an efficient approach to diminish the olefin content as well as improve the stability and octane number of the fuel. Nevertheless, the olefin conversion rate during the gasoline etherification process is restricted by thermodynamic equilibrium. In this study, a novel method of coupling membrane separation technology with etherification process of gasoline is utilized to overcome this equilibrium limitation by separating the reactants and products of the etherification reaction. Specifically, a polydimethylsiloxane (PDMS) tubular membrane is employed to treat actual etherified gasoline with pressure-driven and cross-flow mode. The inherent hydrophobicity of PDMS membrane results in a preference of reactant active olefins with stronger hydrophobicity in the etherified gasoline for permeating the membrane. In contrast, the PDMS membrane preferentially retains product ether compounds in the etherified gasoline due to their lower hydrophobicity and higher molecular weights. This indicates that the primary separation mechanism for the components in etherified gasoline is their affinity differences to the PDMS membrane. In addition, transmembrane pressure and cross-flow rate are demonstrated both have the greatly effect on the PDMS membrane performance. Compared with the gasoline etherification reaction process in a fix-bed reactor, the introduction of membrane separation technology increases the C5 active olefin conversion rate in gasoline by 11.8%. This study presents a robust approach to enhance the gasoline etherification process by selectively separating reactants and products. This method holds significant implications for the advancement of the gasoline etherification technology.

From electronic structure to model application of key reactions for gasoline/alcohol combustion: Hydrogen-atom abstractions by CH3Ȯ radical

H-atom abstraction by methoxy radical (CH3Ȯ) plays an important role in capturing the kinetics of reactions between gasoline components and alcohols. This study focuses on determining the reaction rates and thermodynamic properties of methoxy radical reactions with five gasoline fuel components: n-heptane, iso-octane, 1-hexene, cyclopentane and toluene. Electronic structure calculations were performed for all the stationary points with M06-2X/6−311++g(d,p) method. G3 composite method with atomization method is used for determining ΔfH0 of all the closed shell and radical species, using which the necessary thermodynamic data of all the species was determined. Coupled cluster theory QCISD(T)/cc-pVXZ (where X = D and T) and Møller–Plesset perturbation theory MP2/cc-pVXZ (where X = D, T and Q) were used to calculate single point energies. Subsequently, rate constants for all hydrogen atom abstraction channels have been performed using conventional transition state theory with unsymmetric tunneling corrections. A systematic comparison of rates for abstraction from different sites within the same species and same site from different species is done in order to get insights into this reaction class. The computed thermodynamic properties and rate constants were incorporated in to a recent gasoline mechanism to investigate the impact of the calculations performed in this work. A shift in predicted NTC (negative temperature coefficient) behavior and significant reduction in model reactivity is observed upon incorporating the rates calculated herein.

A novelty detection diagnostic methodology for merit function calculations for various individual gasoline components

Gasoline merit function is proposed to assist in ranking gasoline components additives in a methodical technique when various gasoline-type fuel characteristics are changing contemporaneously. The current research seeks to suggest a new parameter of a fuel merit function to rank several individual gasoline blendstocks, involving oxygenates, paraffinic, isoparaffinic, olefinic, naphthenic, and aromatic gasoline components. This is a novelty detection diagnostic methodology for merit functions calculations for various individual gasoline components. The obtained results reported that the order of gasoline antiknocking could be increased in the series of oxygenated compounds > aromatics > naphthenes > olefins > branched paraffins > normal paraffins. Furthermore, the acquired results stated that the merit function score for methanol was higher than ethanol, isopropanol, isobutanol, ETBE, MTBE, TAME, and 2-methylfurane for oxygenated compounds. Moreover, the calculated results noted that the merit function score for prenol was higher than isobutene, alfa-isoamylene, diisobutylene, and dimate for olefinic gasoline components. Besides, the obtained results observed that the merit function score for isohexane was greater than isobutane, isopentane, and isoheptane for isoparaffinic gasoline components. Likewise, the results noted that the merit function score for toluene was higher than cumene, o-xylene, m-xylene, p-xylene, and ethylbenzene for aromatic gasoline components. The ranking of gasoline components using merit function has been investigated in order to enhance the technological comprehension of the dynamic relevance between engine performance and gasoline-type fuel properties, involving octane rating. Finally, the promising gasoline blendstocks will contribute to producing innovative gasoline-type fuel recipes as octane boosters.

Removal of a complex VOC mixture by potted plants-effects on soil microorganisms.

Microorganisms in the soil of potted plants are important for removal of volatile organic compounds (VOCs) from indoor air, but little is known about the subject. The aim of this study was therefore to obtain a better understanding of the effect of VOCs on the microbial community in potted plants. Hedera helix was exposed to gasoline vapors under dynamic chamber conditions for 21days and three main parameters were investigated. These were (1) removal of the target compounds heptane, 3-methylhexane, benzene, toluene, ethylbenzene, m,p-xylene, and naphthalene from the gasoline mixture; (2) toluene mineralization; and (3) bacterial abundance and bacterial community structure. H. helix was able to reduce the concentration of the target compounds in the continuously emitted gasoline by 25-32%, except for naphthalene, which was too low in concentration. The soil microcosm of gasoline exposed plants had for an initial 66h increased toluene mineralization rate compared to the soil microcosm in the soil of plants exposed to clean air. Bacterial abundance was decreased in response to gasoline exposure while bacterial community structure was changed. The change in bacterial community structure was, however, different between the two experiments indicating that several taxonomic units can degrade gasoline components. Especially the genera Rhodanobacter and Pseudonorcardia significantly increased in abundance in response to gasoline vapors. Bauldia, Devosia, and Bradyrhizobium, on the other hand, decreased.

Metal‐Organic Frameworks for C6 Alkane Separation

AbstractThe separation of alkane isomers is an important yet challenging process in the petrochemical industry. Being a crucial step to produce premium gasoline components as well as optimum ethylene feed, the current industrial separation by distillation is extremely energy intensive. Adsorptive separation based on zeolite is limited by insufficient adsorption capacity. Metal‐organic frameworks (MOFs) hold enormous promise as alternative adsorbents due to their diverse structural tunability and exceptional porosity. Precise control of their pore geometry/dimensions has led to superior performance. In this minireview, we highlight the recent progresses in developing MOFs for the separation of C6 alkane isomers. Representative MOFs are reviewed based on their separation mechanisms. Emphasis is put on the material design rationale for achieving optimal separation capability. Finally, we briefly discuss the existing challenges, possible solutions, and future directions of this important field.

Metal-Organic Frameworks for C6 Alkane Separation.

The separation of alkane isomers is an important yet challenging process in the petrochemical industry. Being a crucial step to produce premium gasoline components as well as optimum ethylene feed, the current industrial separation by distillation is extremely energy intensive. Adsorptive separation based on zeolite is limited by insufficient adsorption capacity. Metal-organic frameworks (MOFs) hold enormous promise as alternative adsorbents due to their diverse structural tunability and exceptional porosity. Precise control of their pore geometry/dimensions has led to superior performance. In this minireview, we highlight the recent progresses in developing MOFs for the separation of C6 alkane isomers. Representative MOFs are reviewed based on their separation mechanisms. Emphasis is put on the material design rationale for achieving optimal separation capability. Finally, we briefly discuss the existing challenges, possible solutions, and future directions of this important field.

Analysis of compositions and fuel specifications of the aqueous emulsion fuels of gasoline (RON 90)-ethanol-water in stable emulsions at low temperatures

Many countries worldwide encounter the greatest difficulties in improving people's life quality since fossil fuel reserves are decreasing, causing fuel prices to rise drastically. This problem has made many countries, including Indonesia, struggle to import them from producers in the Middle East. Adding a small part of ethanol to gasoline is one of the solutions that has been investigated and developed. The previous works relating to blended fuels, gasoline and ethanol, generally employed absolute alcohol, which was expensive. A small surfactant was added to the mixture to stabilize the emulsion, and the blending was conducted in normal conditions (room temperature). If the composition of gasoline and aqueous ethanol is not precise, the components can be separated at a specific temperature. The present study is aimed to report the analysis of compositions and fuel specifications of aqueous emulsions of gasoline (RON 90)-ethanol-water in a single phase without using a synthetic surfactant in the temperature range of 0–25 °C. The procedures were as follows: fermentation, ethanol distillation and purification, cooling, blending, and characterization of fuel specifications. Components of gasoline (RON 90)-ethanol-water formed a stable emulsion in the composition range of 28.00‒99.79 %, 0.20‒67.97 %, and 0.01‒3.58 %. The observation found that continually increasing the amount of aqueous ethanol and temperature after one phase was attained would not lead to the separation of components. Therefore, gasoline and aqueous ethanol can form a single phase functioning as a surfactant binding water and fossil fuel. The decrease in temperature after the emulsion is stabilized can separate the components whereby it is caused by the faster density change of aqueous ethanol than gasoline