Complex Organic Molecules Emission Research Articles

PRODIGE - envelope to disk with NOEMA III. The origin of complex organic molecule emission in SVS13A

Complex organic molecules (COMs) have been found toward low-mass protostars, but the origins of the COM emission are still unclear. It can be associated with, for example, hot corinos, outflows, and/or accretion shock and disk atmospheres. We aim to disentangle the origin of the COM emission toward the chemically rich protobinary system SVS13A using six O-bearing COMs. We conducted NOrthern Extended Millimeter Array (NOEMA) observations toward SVS13A as part of the PROtostars DIsks: Global Evolution (PRODIGE) program. Our previous DCN observations reveal a possible infalling streamer, which may affect the chemistry of the central protobinary by inducing accretion outbursts and/or shocked gas. We further analyzed six O-bearing COMs: CH3OH aGg'- (CH2OH)2 C2H5OH CH2(OH)CHO CH3CHO and CH3OCHO . Although the COM emission is not spatially resolved, we constrained the source sizes to $ arcsec (90$-$120 au) by conducting uv-domain Gaussian fitting. Interestingly, the high-spectral-resolution data reveal complex line profiles with multiple peaks; although the line emission is likely dominated by the secondary, VLA4A, at LSR =7.36$ km s$^ $, the numbers of peaks (sim $2-5$), the velocities, and the linewidths of these six O-bearing COMs are different. The local thermodynamic equilibrium (LTE) fitting unveils differences in excitation temperatures and emitting areas among these COMs. We further conducted multiple-velocity-component LTE fitting to decompose the line emission into different kinematic components. As a result, the emission of these COMs is decomposed into up to six velocity components from the LTE modeling. The physical conditions (temperature, column density, and source size) of these components from each COM are obtained, and Markov chain Monte Carlo sampling was performed to test the fitting results. We find a variety in excitation temperatures ($100-500$ K) and source sizes (D$ au) from these kinematic components from different COMs. The emission of each COM can trace several components, and different COMs most likely trace different regions. Given this complex structure, we suggest that the central region is inhomogeneous and unlikely to be heated by only protostellar radiation. We conclude that accretion shocks induced by the large-scale infalling streamer likely exist and contribute to the complexity of the COM emission. This underlines the importance of high-spectral-resolution data when analyzing COM emission in protostars and deriving relative COM abundances.

Complex organic molecules uncover deeply embedded precursors of hot cores. An APEX unbiased spectral survey of infrared quiet massive clumps

During the process of star formation, the dense gas undergoes significant chemical evolution leading to the emergence of a rich variety of molecules associated with hot cores and hot corinos. However, the physical conditions and the chemical processes involved in this evolution are poorly constrained. In particular, the early phases, corresponding to a stage prior to the emergence of any strong ionising emission from the protostar, are still poorly studied. In this work, we provide a full inventory of the emission from complex organic molecules (COMs) to investigate the physical structure and chemical composition of six high-mass protostellar envelopes. We aim to investigate the conditions for the emergence of COMs in hot cores. We performed an unbiased spectral survey towards six infrared-quiet massive clumps between 159 GHz and 374 GHz with the APEX 12\,m telescope, covering the entire atmospheric windows at 2\,mm, 1.2\,mm, and 0.8\,mm. To identify the spectral lines, we used rotational diagrams and radiative transfer modelling assuming local thermodynamic equilibrium. We detect up to 11 COMs plus three isotopologues, of which at least five COMs (CH$_3$OH, CH$_3$CN, CH$_3$OCHO, CH$_3$OCH$_3$, and CH$_3$CHO) are detected towards all sources. Towards all the objects, most of the COM emission is found to be cold, with respect to the typical temperatures at which COMs are found, with a temperature of 30\,K and extended with a size of sim 0.3\,pc. Although the bulk of the gas for our sample of young massive clumps has a cold temperature, we also detect emission from COMs originating from the immediate vicinity of the protostar. This warm component of the envelope is best traced by methanol and methyl cyanide, in particular methyl cyanide traces a compact (sim 1$''$) and the hottest ($T component of the envelope. Only three out of the six sources exhibit a robustly detected hot gas component (T$>$100\,K) traced by several COMs. We find a gradual emergence of the warm component in terms of size and temperature, together with an increasing molecular complexity, allowing us to establish an evolutionary sequence for our sample based on COMs. While they can already be well characterised by an emerging molecular richness, gas temperatures of COMs in the hot gas and molecular abundances suggest that COMs may become abundant in the gas phase at temperatures below the thermal desorption temperature. Our findings confirm that the sources of our sample of infrared-quiet massive clumps are in an early evolutionary stage during which the bulk of the gas is cold. The presence of COMs is found to be characteristic of these early evolutionary stages accompanying high-mass star and cluster formation. While the extent of the compact heated regions resembles that of hot cores, the molecular abundances, except for complex cyanides, resemble those of hot corinos and are lower than the peak COM abundances of hot cores. We suggest that the emergence of hot cores is preceded by a phase in which mostly O-bearing COMs appear first with similar abundances to hot corinos albeit with larger source sizes.

Chemistry of Complex Organic Molecules in the V883 Ori Disk Revealed by ALMA Band 3 Observations

Complex organic molecules (COMs) in protoplanetary disks are key to understanding the origin of volatiles in comets in our solar system, yet the chemistry of COMs in protoplanetary disks remains poorly understood. Here, we present Atacama Large Millimeter/submillimeter Array Band 3 observations of the disk around the young outbursting star V883 Ori, where the COMs sublimate from ices and are thus observable thanks to the warm condition of the disk. We have robustly identified ten oxygen-bearing COMs including 13C isotopologues in the disk-integrated spectra. The radial distributions of the COM emission, revealed by the detailed analyses of the line profiles, show the inner emission cavity, similar to the previous observations in Band 6 and Band 7. We found that the COMs abundance ratios with respect to methanol are significantly higher than those in the warm protostellar envelopes of IRAS 16293-2422 and similar to the ratios in the solar system comet 67P/Churyumov-Gerasimenko, suggesting the efficient (re)formation of COMs in protoplanetary disks. We also constrained the 12C/13C and D/H ratios of COMs in protoplanetary disks for the first time. The 12C/13C ratios of acetaldehyde, methyl formate, and dimethyl ether are consistently lower (∼20–30) than the canonical ratio in the interstellar medium (∼69), indicating the efficient 13C-fractionation of CO. The D/H ratios of methyl formate are slightly lower than the values in IRAS 16293-2422, possibly pointing to the destruction and reformation of COMs in disks. We also discuss the implications for nitrogen and sulfur chemistry in protoplanetary disks.

The Principal Component Analysis Filtering Method for an Unbiased Spectral Survey of Complex Organic Molecules

A variety of interstellar complex organic molecules (COMs) have been detected in various physical conditions. However, in the protostellar and protoplanetary environments, their complex kinematics make line profiles blend together and the line strength of weak lines weaker. In this paper, we utilize the principal component analysis technique to develop a filtering method that can extract COM spectra from the main kinematic component associated with COM emission and increase the signal-to-noise ratio (S/N) of spectra. This filtering method corrects non-Gaussian line profiles caused by the kinematics. For this development, we adopt the ALMA BAND 6 spectral survey data of V883 Ori, an eruptive young star with a Keplerian disk. A filter was, first, created using 34 strong and well-isolated COM lines and then applied to the entire spectral range of the data set. The first principal component (PC1) describes the most common emission structure of the selected lines, which is confined within the water sublimation radius (∼0.″3) in the Keplerian disk of V883 Ori. Using this PC1 filter, we extracted high-S/N kinematics-corrected spectra of V883 Ori over the entire spectral coverage of ∼50 GHz. The PC1-filtering method reduces the noise by a factor of ∼2 compared to the average spectra over the COM emission region. One important advantage of this PC1-filtering method over the previously developed matched-filtering method is the ability to preserve the original integrated intensities of COM lines.

ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP): The Warm-envelope Origin of Hot Corinos

Hot corinos are of great interest due to their richness in interstellar complex organic molecules (COMs) and the consequent potential prebiotic connection to solar-like planetary systems. Recent surveys have reported an increasing number of detected hot corinos in Class 0/I protostars; however, the relationships between their physical properties and the hot-corino signatures remain elusive. In this study, our objective is to establish a general picture of the detectability of hot corinos by identifying the origins of the hot-corino signatures in the sample of young stellar objects (YSOs) obtained from the Atacama Large Millimeter/submillimeter Array Survey of Orion Planck Galactic Cold Clumps project. We apply spectral energy distribution modeling to our sample and identify the physical parameters of the modeled YSOs directly, linking the detection of hot-corino signatures to the envelope properties of the YSOs. Imaging simulations of the methanol emission further support this scenario. We therefore posit that the observed COM emission originates from the warm inner envelopes of the sample YSOs, based on both the warm region size and the envelope density profile. The former is governed by the source luminosity and is additionally affected by the disk and cavity properties, while the latter is related to the evolutionary stages. This scenario provides a framework for detecting hot-corino signatures toward luminous Class 0 YSOs, with fewer detections being observed toward similarly luminous Class I sources.

Resolving desorption of complex organic molecules in a hot core

Context. The presence of many interstellar complex organic molecules (COMs) in the gas phase in the vicinity of protostars has long been associated with their formation on icy dust grain surfaces before the onset of protostellar activity, and their subsequent thermal co-desorption with water, the main constituent of the grains’ ice mantles, as the protostar heats its environment to ~100 K. Aims. Using the high angular resolution provided by the Atacama Large Millimetre/submillimetre Array (ALMA), we want to resolve the COM emission in the hot molecular core Sagittarius B2 (N1) and thereby shed light on the desorption process of COMs in hot cores. Methods. We used data taken as part of the 3 mm spectral line survey Re-exploring Molecular Complexity with ALMA (ReMoCA) to investigate the morphology of COM emission in Sagittarius B2 (N1). We also used ALMA continuum data at 1 mm taken from the literature. Spectra of ten COMs (including one isotopologue) were modelled under the assumption of local thermodynamic equilibrium (LTE) and population diagrams were derived for these COMs for positions at various distances to the south and west from the continuum peak. Based on this analysis, we produced resolved COM rotation temperature and column density profiles. H2 column density profiles were derived from dust continuum emission and C18O 1–0 emission and used to derive COM abundance profiles as a function of distance and temperature. These profiles are compared to astrochemical models. Results. Based on the morphology, a rough separation into O- and N-bearing COMs can be done. The temperature profiles span a range of 80–300 K with power-law indices from −0.4 to −0.8, which is in agreement with expectations of protostellar heating of an envelope with optically thick dust. Column density and abundance profiles reflect a similar trend as seen in the morphology. While abundances of N-bearing COMs peak only at the highest temperatures, those of most O-bearing COMs peak at lower temperatures and remain constant or decrease towards higher temperatures. Many abundance profiles show a steep increase at ~100 K. To a great extent, the observed results agree with results of astrochemical models that, besides the co-desorption with water, predict that O-bearing COMs are mainly formed on dust-grain surfaces at low temperatures, while at least some N-bearing COMs and CH3CHO are substantially formed in the gas phase at higher temperatures. Conclusions. Our observational results, in comparison with model predictions, suggest that COMs that are exclusively or, to a great extent, formed on dust grains desorb thermally at ~100 K from the grain surface, likely alongside water. A dependence on the COM binding energy is not evident from our observations. Non-zero abundance values below ~100 K suggest that another desorption process of COMs is at work at these low temperatures: either non-thermal desorption or partial thermal desorption related to the lower binding energies experienced by COMs in the outer, water-poor ice layers. In either case, this is the first time that the transition between two regimes of COM desorption has been resolved in a hot core.

Importance of source structure on complex organics emission

Context. Complex organic molecules (COMs) are often observed toward embedded Class 0 and I protostars. However, not all Class 0 and I protostars exhibit COM emission. Aims. The aim is to study variations in methanol (CH3OH) emission and use this as an observational tracer of hot cores to test if the absence of CH3OH emission can be linked to source properties. Methods. A sample of 148 low-mass and high-mass protostars is investigated using new and archival observations with the Atacama Large Millimeter/submillimeter Array (ALMA) that contain lines of CH3OH and its isotopologues. Data for an additional 36 sources are added from the literature, giving a total of 184 different sources. The warm (T ≳ 100 K) gaseous CH3OH mass, MCH3OH, is determined for each source using primarily optically thin isotopologues and is compared to a simple toy model of a spherically symmetric infalling envelope that is passively heated by the central protostar. Results. A scatter of more than four orders of magnitude is found for MCH3OH among the low-mass protostars, with values ranging between 10−7 M⊙ and ≲10−11 M⊙. On average, Class I protostellar systems seem to have less warm MCH3OH(≲10−10 M⊙) than younger Class 0 sources (~10−7 M⊙). High-mass sources in our sample show more warm MCH3OH, up to ~10−7−10−3 M⊙. To take into account the effect of the source’s overall mass on MCH3OH, a normalized CH3OH mass is defined as MCH3OH/Mdust,0, where Mdust,0 is the cold plus warm dust mass in the disk and inner envelope within a fixed radius measured from the ALMA dust continuum. A correlation between MCH3OH/Mdust,0 and Lbol is found. Excluding upper limits, a simple power-law fit to the normalized warm CH3OH masses results in MCH3OH/Mdust,0 ∝ Lbol0.70±0.05 over an Lbol range of 10−1−106 L⊙. This is in good agreement with the toy model, which predicts that the normalized MCH3OH increases with Lbol0.70 due to the snow line moving outward. Sources for which the size of the disk is equivalent to or smaller than the estimated 100 K radius fall within the 3σ range of the best-fit power-law model, whereas sources with significantly larger disks show normalized warm CH3OH masses that are up to two orders of magnitude lower. Conclusions. The agreement between sources that are rich in CH3OH with the toy model of a spherically symmetric infalling envelope implies that the thermal structure of the envelopes in these sources is likely not strongly affected by a disk. However, based on the disagreement between the toy model and sources that show less warm CH3OH mass, we suggest that source structure such as a disk can result in colder gas and thus fewer COMs in the gas phase. Additionally, optically thick dust can hide the emission of COMs. Advanced modeling is necessary to quantify the effects of a disk and/or continuum optical depth on the presence of gaseous COMs in young protostellar systems.

Protostellar Interferometric Line Survey of the Cygnus X region (PILS-Cygnus)

Context. Complex organic molecules (COMs) are commonly detected in and near star-forming regions. However, the dominant process in the release of these COMs from the icy grains – where they predominately form – to the gas phase is still an open question. Aims. We investigate the origin of COM emission in a high-mass protostellar source, CygX-N30 MM1, through high-angular-resolution interferometric observations over a continuous broad frequency range. Methods. We used 32 GHz Submillimeter Array observations with continuous frequency coverage from 329 to 361 GHz at an angular resolution of ~1″ to do a line survey and obtain a chemical inventory of the source. The line emission in the frequency range was used to determine column densities and excitation temperatures for the COMs. We also mapped out the intensity distribution of the different species. Results. We identified approximately 400 lines that can be attributed to 29 different molecular species and their isotopologues. We find that the molecular peak emission is along a linear gradient, and coincides with the axis of red- and blueshifted H2CO and CS emission. Chemical differentiation is detected along this gradient, with the O-bearing molecular species peaking towards one component of the system and the N- and S-bearing species peaking towards the other. The chemical gradient is offset from but parallel to the axis through the two continuum sources. The inferred column densities and excitation temperatures are compared to other sources where COMs are abundant. Only one deuterated molecule is detected, HDO, while an upper limit for CH2DOH is derived, leading to a D/H ratio of <0.1%. Conclusions. We conclude that the origin of the observed COM emission is probably a combination of the young stellar sources along with accretion of infalling material onto a disc-like structure surrounding a young protostar and located close to one of the continuum sources. This disc and protostar are associated with the O-bearing molecular species, while the S- and N-bearing species on the other hand are associated with the other continuum core, which is probably a protostar that is slightly more evolved than the other component of the system. The low D/H ratio likely reflects a pre-stellar phase where the COMs formed on the ices at warm temperatures (~30 K), where the deuterium fractionation would have been inefficient. The observations and results presented here demonstrate the importance of good frequency coverage and high angular resolution when disentangling the origin of COM emission.

Complex organic molecules in low-mass protostars on Solar System scales

Context. Complex organic molecules (COMs) are thought to form on icy dust grains in the earliest phase of star formation. The evolution of these COMs from the youngest Class 0/I protostellar phases toward the more evolved Class II phase is still not fully understood. Since planet formation seems to start early, and mature disks are too cold for characteristic COM emission lines, studying the inventory of COMs on Solar- System scales in the Class 0/I stage is relevant. Aims. Our aim is to determine the abundance ratios of oxygen-bearing COMs in Class 0 protostellar systems on scales of ~100 AU radius. We aim to compare these abundances with one another, and to the abundances of other low-mass protostars such as IRAS 16293-2422B and HH 212. Additionally, using both cold and hot COM lines, the gas-phase abundances can be tracked from a cold to a hot component, and ultimately be compared with those in ices to be measured with the James Webb Space Telescope (JWST). The abundance of deuterated methanol allows us to probe the ambient temperature during the formation of this species. Methods. ALMA Band 3 (3 mm) and Band 6 (1 mm) observations are obtained for seven Class 0 protostars in the Perseus and Serpens star-forming regions. By modeling the inner protostellar region using local thermodynamic equilibrium models, the excitation temperature and column densities are determined for several O-bearing COMs including methanol (CH3OH), acetaldehyde (CH3CHO), methyl formate (CH3OCHO), and dimethyl ether (CH3OCH3). Abundance ratios are taken with respect to CH3OH. Results. Three out of the seven of the observed sources, B1-c, B1-bS (both Perseus), and Serpens S68N (Serpens), show COM emission. No clear correlation seems to exist between the occurrence of COMs and source luminosity. The abundances of several COMs such as CH3OCHO, CH3OCH3, acetone (CH3COCH3), and ethylene glycol ((CH2OH)2) are remarkably similar for the three COM-rich sources; this similarity also extends to IRAS 16293-2422B and HH 212, even though collectively these sources originate from four different star-forming regions (i.e., Perseus, Serpens, Ophiuchus, and Orion). For other COMs like CH3CHO, ethanol (CH3CH2OH), and glycolaldehyde (CH2OHCHO), the abundances differ by up to an order of magnitude, indicating that local source conditions become important. B1-c hosts a cold (Tex ≈ 60 K), more extended component of COM emission with a column density of typically a few percent of the warm/hot (Tex ~ 200 K) central component. A D/H ratio of 1–3% is derived for B1-c, S68N, and B1-bS based on the CH2DOH/CH3OH ratio (taking into account statistical weighting) suggesting a temperature of ~15 K during the formation of methanol. This ratio is consistent with other low-mass protostars, but is lower than for high-mass star-forming regions. Conclusions. The abundance ratios of most O-bearing COMs are roughly fixed between different star-forming regions, and are presumably set at an earlier cold prestellar phase. For several COMs, local source properties become important. Future mid-infrared facilities such as JWST/MIRI will be essential for the direct observation of COM ices. Combining this with a larger sample of COM-rich sources with ALMA will allow ice and gas-phase abundances to be directly linked in order to constrain the routes that produce and maintain chemical complexity during the star formation process.

Questioning the spatial origin of complex organic molecules in young protostars with the CALYPSO survey

Context. Complex organic molecules (COMs) have been detected in a few Class 0 protostars but their origin is not well understood. While the usual picture of a hot corino explains their presence as resulting from the heating of the inner envelope by the nascent protostar, shocks in the outflow, disk wind, the presence of a flared disk, or the interaction region between envelope and disk at the centrifugal barrier have also been claimed to enhance the abundance of COMs. Aims. Going beyond studies of individual objects, we want to investigate the origin of COMs in young protostars on a statistical basis. Methods. We use the CALYPSO survey performed with the Plateau de Bure Interferometer of the Institut de Radioastronomie Millimétrique to search for COMs at high angular resolution in a sample of 26 solar-type protostars, including 22 Class 0 and four Class I objects. We derive the column densities of the detected molecules under the local thermodynamic equilibrium approximation and search for correlations between their abundances and with various source properties. Results. Methanol is detected in 12 sources and tentatively in one source, which represents half of the sample. Eight sources (30%) have detections of at least three COMs. We find a strong chemical differentiation in multiple systems with five systems having one component with at least three COMs detected but the other component devoid of COM emission. All sources with a luminosity higher than 4 L⊙ have at least one detected COM whereas no COM emission is detected in sources with internal luminosity lower than 2 L⊙, likely because of a lack of sensitivity. Internal luminosity is found to be the source parameter impacting the COM chemical composition of the sources the most, while there is no obvious correlation between the detection of COM emission and that of a disk-like structure. A canonical hot-corino origin may explain the COM emission in four sources, an accretion-shock origin in two or possibly three sources, and an outflow origin in three sources. The CALYPSO sources with COM detections can be classified into three groups on the basis of the abundances of oxygen-bearing molecules, cyanides, and CHO-bearing molecules. These chemical groups correlate neither with the COM origin scenarios, nor with the evolutionary status of the sources if we take the ratio of envelope mass to internal luminosity as an evolutionary tracer. We find strong correlations between molecules that are a priori not related chemically (for instance methanol and methyl cyanide), implying that the existence of a correlation does not imply a chemical link. Conclusions. The CALYPSO survey has revealed a chemical differentiation in multiple systems that is markedly different from the case of the prototypical binary IRAS 16293-2422. This raises the question of whether all low-mass protostars go through a phase showing COM emission. A larger sample of young protostars and a more accurate determination of their internal luminosity will be necessary to make further progress. Searching for correlations between the COM emission and the jet/outflow properties of the sources may also be promising.

First hot corino detected around an isolated intermediate-mass protostar: Cep E-mm

Context. Intermediate-mass (IM) protostars provide a bridge between the low- and high-mass protostars. Despite their relevance, little is known about their chemical diversity. Aims. We want to investigate the molecular richness towards the envelope of I-M protostars and to compare their properties with those of low- and high-mass sources. Methods. We have selected the isolated IM Class 0 protostar Cep E-mm to carry out an unbiased molecular survey with the IRAM 30 m telescope between 72 and 350 GHz with an angular resolution lying in the range 7–34″. Our goal is to obtain a census of the chemical content of the protostellar envelope. These data were complemented with NOEMA observations of the spectral bands 85.9–89.6 GHz and 216.8–220.4 GHz at angular resolutions of 2.3″ and 1.4″, respectively. Results. The 30 m spectra show bright emission of O- and N-bearing complex organic molecules (COMs): CH3OH and its rare isotopologues CH2DOH and 13CH3OH, CH3CHO, CH3OCH3, CH3COCH3, HCOOH, HCOOCH3, H2CCO, NH2CHO, CH3CN, C2H3CN, C2H5CN, HNCO and H2CO. We identify up to three components in the spectral signature of COMs: an extremely broad line (eBL) component associated with the outflowing gas (FWHM > 7kms−1), a narrow line (NL) component (FWHM < 3kms−1) associated with the cold envelope, and a broad line (BL) component (FWHM ≃ 5.5kms−1) which traces the signature of a hot corino. The eBL and NL components are detected only in molecular transitions of low excitation and dominate the emission of CH3OH. The BL component is detected in highly excited gas (Eup > 100 K). The NOEMA observations reveal Cep E-mm as a binary protostellar system, whose components, Cep E-A and Cep E-B, are separated by ≈1.7″. Cep E-A dominates the core continuum emission and powers the long-studied, well-known, high-velocity jet associated with HH377. The lower flux source Cep E-B powers another high-velocity molecular jet, reaching velocities of ≈80 km s−1, which propagates in a direction close to perpendicular with respect to the Cep E-A jet. Our interferometric maps show that the emission of COMs arises from a region of ≈0.7″ size around Cep E-A, and corresponds to the BL component detected with the IRAM 30 m telescope. On the contrary, no COM emission is detected towards Cep E-B. We have determined the rotational temperature (Trot) and the molecular gas column densities from a simple population diagram analysis or assuming a given excitation temperature. Rotational temperatures of COMs emission were found to lie in the range 20−40 K with column densities ranging from a few times 1015 cm−2 for O-bearing species, down to a few times 1014 cm−2 for N-bearing species. Molecular abundances are similar to those measured towards other low- and intermediate-mass protostars. Ketene (H2CCO) appears as an exception, as it is found significantly more abundant towards Cep E-A. High-mass hot cores are significantly less abundant in methanol and N-bearing species are more abundant by two to three orders of magnitude. Conclusions. Cep E-mm reveals itself as a binary protostellar system with a strong chemical differentiation between both cores. Only the brightest component of the binary is associated with a hot corino. Its properties are similar to those of low-mass hot corinos.

First results from the CALYPSO IRAM-PdBI survey

We investigate the origin of complex organic molecules (COMs) in the gas phase around the low-mass Class~0 protostar NGC1333-IRAS2A, to determine if the COM emission lines trace an embedded disk, shocks from the protostellar jet, or the warm inner parts of the protostellar envelope. In the framework of the CALYPSO (Continuum And Lines in Young ProtoStellar Objects) IRAM Plateau de Bure survey, we obtained large bandwidth spectra at sub-arcsecond resolution towards NGC 1333-IRAS2A. We identify the emission lines towards the central protostar and perform Gaussian fits to constrain the size of the emitting region for each of these lines, tracing various physical conditions and scales. The emission of numerous COMs such as methanol, ethylene glycol, and methyl formate is spatially resolved by our observations. This allows us to measure, for the first time, the size of the COM emission inside the protostellar envelope, finding that it originates from a region of radius 40-100 AU, centered on the NGC 1333-IRAS2A protostellar object. Our analysis shows no preferential elongation of the COM emission along the jet axis, and therefore does not support the hypothesis that COM emission arises from shocked envelope material at the base of the jet. Down to similar sizes, the dust continuum emission is well reproduced with a single envelope model, and therefore does not favor the hypothesis that COM emission arises from the thermal sublimation of grains embedded in a circumstellar disk. Finally, the typical scale $\sim$60 AU observed for COM emission is consistent with the size of the inner envelope where $T_{\rm{dust}} > 100$ K is expected. Our data therefore strongly suggest that the COM emission traces the hot corino in IRAS2A, i.e., the warm inner envelope material where the icy mantles of dust grains evaporate because they are passively heated by the central protostellar object.