When coal with a strong bursting liability is disturbed by a load, catastrophic instability disasters and rockbursts can easily occur. Loaded coal with a strong bursting liability undergoes complex damage evolution and failure behavior due to the intricate interplay among loads, gangue, fractures, and the coal matrix. Intuitively quantifying and characterizing the complex discontinuous structural features, deformation fields, and energy fields within coal is the foundation for the scientific analysis and prevention of disaster mechanisms caused by rockbursts. Therefore, studying the distribution and evolutionary processes of deformation fields and energy fields caused by the evolution of discontinuous structures within coal is highly important for the prevention and control of coal mine rockburst disasters and the protection of coal mine safety during mining operations. In this study, a series of X-ray computed tomography (X-CT) tests were conducted on coal specimens with varying gangue contents under uniaxial compressive loading. The X-CT images clearly illustrated the internal damage evolution of coal with a strong bursting liability, revealing fracture propagation, shear bands, and localized failure under varying loading conditions. Image segmentation was employed to quantitatively analyze the development of damage in coal with a strong bursting liability, revealing the influence patterns of gangue content on the prepeak deformation localization and strength of coal. Additionally, using digital volume correlation, the 3D volumetric displacement and strain of loaded impact-prone coal were determined based on the changes in natural speckle images. The nonuniform distribution of strain was mainly caused by the nonuniform distribution of gangue and pore fractures at the microscopic scale, which explains the localized deformation in coal materials. Importantly, this study provides new full-field strain tensor data and a novel method for measuring the elastic deformation energy of the 3D deformation and cracking processes of loaded coal.