The complementary relationship (CR) of evaporation is one of widely-used approaches in estimating terrestrial evapration (E). However, the determination of the parameter values in CR-based models remains a difficult task. This is especially true for the new power-function complementary relationship (PCR) model developed recently, in which the key parameter that accounts for the effect of moisture advection over the drying land, b, must be well calibrated with consideration of an approporiate physical basis. Here, by proposing a new isenthalpic index that can be used for determining b directly without resorting to any a priori information of global E, this study found that the resulting b values (median = 1.64, standard deviation = 0.73) are generally smaller and display a narrower range than those reported recently by Kim et al. (2024). When applied with monthly input variables of 124 FLUXNET stations, the gridded b values improve upon E estimates that employ either i) a standard value of b (=2), or; ii) a calibrated value (same for all stations). The global distribution of the gridded b values –in contrast to those obtained by Kim et al. (2024) –aligns with its physical interpretation: low values (1 < b < 2) where the effect of moisture advection is weak (i.e., permanently/periodically wet, humid regions or regions far away from any significant external moisture source) and high ones (b > 2) when strong (i.e., warm arid/semi arid regions near a sea or high mountains of abundant moisture). The gridded b values improve the calibration-free PCR that employs a constant b (=2) and a Priestley-Taylor coefficient linked to the wet-environment air temperature.