Abstract Viscoelastic data from dynamic measurements show that modifying resins produce complex changes in the properties of styrenic block copolymers. These property changes are generally consistent with compatibility concepts. Resins which are compatible with the midblock of these polymers, Resins AL-1, Al-2, and RE, will increase the tan δ peak temperature and reduce plateau modulus, as is observed with other elastomers. They will also reduce the temperature of entry into the terminal zone. This is believed to result from a reduction in the concentration of the endblock phase as well as dilution of the entanglement network at elevated temperatures. A resin which is incompatible with the midblock, Resin AR, has no effect on the tan δ peak temperature but does cause an increase in the plateau modulus of S-B-S and S-EB-S, as seen with typical high molecular weight rubbers. However, in the S-I-S polymers, Resin AR appears to be at least partially compatible at the low volume fractions examined. It does not increase the plateau modulus, but appears to reduce it slightly. The aromatic resin, Resin AR, has no effect on the G′, G″ crossover temperature of S-EB-S or S-I-S(20) at the concentration examined. However, it increases the temperature of the high diblock S-I-S(40) and lowers the temperature of S-B-S, suggesting at least partial compatibility at elevated temperatures. G′(tan δmin ) data are useful for estimating the compatibility of resins with styrenic block copolymers. Minimum and maximum values, calculated from rubber elasticity theory and filler effects, can serve as reference points for compatibility.
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