Compacted Clay Research Articles

Quality assessment method proposal for compacted bentonite clay buffer block using combined non-destructive tests

The compacted bentonite buffer block, as part of the engineered barrier system, plays a pivotal role in the long-term containment of high-level radioactive waste within deep geological repositories. Assessing the density and integrity of these blocks post-manufacturing is essential for ensuring in-situ performance. However, conventional core sampling and destructive investigation of weighty blocks present technical challenges incur high cost. This study introduces a novel approach to estimate the engineering properties of bentonite buffer blocks for using three non-destructive testing (NDT) methods. Specifically, we conducted laboratory investigations on identical compacted bentonite buffer blocks manufactured under varied initial water content and compression pressure conditions, employing ultrasonic pulse velocity, gamma-ray attenuation, electrical resistivity, thermal conductivity, and unconfined uniaxial compression tests. Statistical analyses were performed to discern correlations among properties and revealed several key insights: a strong negative correlation between water content and electrical resistivity, a strong positive correlation between the linear gamma-ray attenuation coefficient and dry density, and strong positive correlations among ultrasonic P-wave velocity, unconfined compressive strength, and thermal conductivity. This study proposes optimal regression models to estimate the major engineering properties of bentonite buffer blocks, offering valuable insights into the use of NDT techniques for post-manufacturing quality assessment of blocks before installation in disposal hole.

Heat mitigation in basal compacted clay liners in municipal solid waste landfills.

In municipal solid waste (MSW) landfills, biodegradation of the organic MSW fraction results in elevated waste and basal liner temperatures which have the potential to cause the clay component of the basal liner to experience severe moisture loss over time and eventually undergo desiccation cracking. Cracking of the basal liner's clay component would result in an uncontrolled release of contaminants into the surrounding environment and ultimately give rise to a variety of major environmental concerns. Accordingly, this study examined the variation of temperature-moisture profiles along the depth of a compacted clay liner (CCL) exposed to different constant elevated waste temperatures (CETs) in the absence and presence of two heat reduction techniques, respectively. Rockwool insulation layers with varying thicknesses and galvanized steel cooling pipes with varying flowrates were introduced separately as the two heat reduction techniques. Introduction of both techniques led to a significant attenuation of the temperature rise and desiccation experienced by the CCL in the face of different CETs. An increase in rockwool thickness increments led to a progressive reduction of CCL temperature, while an increase in flow rate under turbulent condition did not have a significant influence on the temperature and desiccation reduction of the CCL. Nevertheless, the present study certainly highlights the potential of the two proposed heat reduction techniques to minimize desiccation and consequently increase the service life of CCLs exposed to different elevated temperatures in MSW landfills.

A Novel Landfill Liner Material for Solidified Lake Sediment Based on Industrial By-Product and Construction Waste: Engineering Behavior and Cr(VI) Breakdown Characteristics

Engineering sludge, industrial waste, and construction waste are marked by high production volumes, substantial accumulation, and significant pollution. The resource utilization of these solid wastes is low, and the co-disposal of multiple solid wastes remains unfeasible. This study aimed to develop an effective impermeable liner material for landfills, utilizing industrial slag (e.g., granulated blast furnace slag, desulfurized gypsum, fly ash) and construction waste to consolidate lake sediment. To assess the engineering performance of the liner material based on solidified lake sediment presented in landfill leachate, macro-engineering characteristic parameters (unconfined compressive strength, hydraulic conductivity) were measured using unconfined compression and flexible wall penetration tests. Simultaneously, the mineral composition, functional groups, and microscopic morphology of the solidified lake sediment were analyzed using microscopic techniques (X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy + energy dispersive spectroscopy). The corrosion mechanism of landfill leachate on the solidified sediment liner material was investigated. Additionally, the breakdown behavior of heavy metal Cr(VI) within the solidified sediment liner barrier was investigated via soil column model experiments. The dispersion coefficient was computed based on the migration data of Cr(VI). Simultaneously, the detection of Cr(VI) concentration in pore water indicated that the solidified sediment liner could effectively impede the breakdown process of Cr(VI). The dispersion coefficient of Cr(VI) in solidified sediments is 5.5 × 10−6 cm2/s–9.5 × 10−6 cm2/s, which is comparable to the dispersion coefficient of heavy metal ions in compacted clay. The unconfined compressive strength and hydraulic conductivity of the solidified sediment ranged from 4.90 to 5.93 MPa and 9.41 × 10−8 to 4.13 × 10−7 cm/s, respectively. This study proposes a novel approach for the co-disposal and resource utilization of various solid wastes, potentially providing an alternative to clay liner materials for landfills.

3775-year-old wood burial supports "wood vaulting" as a durable carbon removal method.

Six-times more carbon dioxide (CO2) is removed each year by terrestrial photosynthesis than fossil fuel emissions. However, the carbon is mostly returned to the atmosphere by decomposition. We found a 3775-year-old ancient wood log buried 2 meters belowground that was preserved far beyond its expected lifetime. The wood had near-perfect preservation, with carbon loss less than 5% compared to a modern sample. The lack of decay is likely due to the low permeability of the compact clay soil at the burial site. Our observation suggests a hybrid nature-engineering approach for carbon removal by burying woody biomass in similar anoxic environments. We estimate a global sequestration potential of up to 10 gigatonnes CO2 per year with existing technology at a low cost of $30 to $100 per tonne after optimization.

Enhanced understanding on permanent deformation behaviour of subgrade compacted clay under long-term cyclic loading

The long-term performance of pavement structures is heavily reliant on the sustained load-carrying capacity of the subgrade soil. Under repetitive traffic loads, permanent deformation (PD) gradually accumulates in the subgrade due to plastic yielding and soil particle rearrangement, which can compromise the serviceability and durability of overlying pavement layers. This study aimed to enhance the understanding of compacted clay response under long-term cyclic loads through a systematic repeated load triaxial (RLT) testing approach. The proposed approach considered depth-dependent static and dynamic stresses exerted on compacted clay beneath pavement structures and traffic loads. A series of RLT tests were conducted to investigate the impact of key factors, including soil properties (moisture content and compaction degree), stress conditions (confining pressure and deviator stress), and load characteristics (load duration and rest period), on the PD behaviour of compacted clay subgrade. Stress-strain hysteresis loops and damping ratios were analyzed to enhance the fundamental understanding of subgrade PD evolution. The results showed that higher moisture content and lower compaction degree significantly increased PD, with the PD response transitioning from plastic shakedown to plastic creep. Greater deviator stress also exacerbated PD accumulation. Variations in loading duration and rest period influenced the PD behaviour, demonstrating the importance of accurately simulating the stress history experienced by subgrade soil elements under traffic loading. The findings provide valuable insights to optimize subgrade design and implement performance-based management of pavements.

Determining the Suction Capacity of Compacted Clays with Fuzzy-Set Theory

Water suction capacity is an important parameter affecting the swelling properties and volumetric change of soil. Determination of the water suction capacity is made by the experiments which are needed long time in laboratory. However, this has random errors due to the heterogeneous and anisotropic structure of soil sample together with the error caused by the operator made the experiment. Such an estimation problem, included the errors, may be easily solved with the fuzzy-set theory. In this study, the suction capacity of compacted clayey soils is predicted with the fuzzy-set theory. For this reason, the engineering properties of clayey soil (plasticity index, dry density, initial water content and suction capacity) are partitioned into fuzzy subsets, and fuzzy rules are formed. Later, a computer program in the Fortran language is written to estimate the suction capacity of compacted clayey soil from these properties. It is shown that there is a good similarity between the results of the tests and proposed fuzzy logic model.

Effects of Remolding Water Content and Compaction Degree on the Dynamic Behavior of Compacted Clay Soils

The stable and safe operation of highway/railway lines is largely dependent on the dynamic behavior of subgrade fillings. Clay soils are widely used in subgrade construction and are compacted at different remolding water contents and compaction degrees, depending on the field conditions. As a result, their dynamic behaviors may vary, which have not been fully investigated until now. To clarify this aspect, a series of cyclic triaxial tests were carried out in this study with three typical remolding water contents (w = 19%, 24%, and 29%), corresponding to the optimum water content as well as its dry and wet sides, and two compaction degrees (Dc = 0.8 and 0.9), which were selected according to the field-testing data. Scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) tests were also conducted on typical samples to investigate the corresponding soil fabric variations. The findings indicate the following: (a) The soil fabric at the optimum remolding water content and its dry side was characterized by a clay aggregate assembly with a bimodal pore size distribution. In contrast, the soil fabric on the wet side of the optimum water content consisted of dispersed clay particles with a unimodal pore size distribution. (b) As the compaction degree increased, to ensure the optimum water content and its dry side, large pores were compressed to make them smaller, while small pores remained unchanged. Comparatively, all the pores on the wet side were compressed to make them smaller. (c) For each compaction degree, as the remolding water content increased, a non-monotonic changing pattern was identified for both the permanent strain and resilient modulus; the permanent strain first decreased and then increased, while, for the resilient modulus, an initial increasing trend and then a decreasing trend were identified. In addition, a larger changing rate of the permanent strain (resilient modulus) was observed on the dry side, indicating a larger effect of the remolding water content. (d) For each remolding water content, as the compaction degree increased, the permanent strain exhibited a decreasing trend, but an increasing trend was identified for the resilient modulus. Moreover, the rate of change in the permanent strain (resilient modulus) on the dry side of the optimum water content was larger than that on the wet side. In contrast, the minimum rate of change was identified at the optimum water content. The obtained results allowed for the effects of the remolding water content and compaction degree on the dynamic behavior to be analyzed, and they helped guide the construction and maintenance of the subgrade.

Characterization of pore water microdynamics and microstructure of clays: The effect of pore fluid chemistry and temperature

It is crucial to figure out the microdynamics of pore water and the microstructure of clays under various thermal and chemical environments when characterizing the physical properties of clays. In this study water microdynamics in clay was investigated via the nuclear magnetic resonance (NMR) technique. The NMR measurements were performed on three clays saturated with distilled water and three salt solutions from 25 to 75°C. The saline and thermal effect on soil-water interaction, water microdynamics and microstructure of clays has been investigated through relaxation times by invoking the DDL theory and the ionic hydration mechanism. Number of jumps (τS/τm) for water molecule is 82 for soils A or C and 520 for soil B when saturated with distilled water, implying the larger surface molecular affinity of soil B. Salt solutions increase the values of τS/τm in the sequence of K+>Ca2+>Na+. Effective activation energy of pore waterΔE= 2.33 kcal/mol, 1.49 kcal/mol and 1.19 kcal/mol for soils A, B and C when saturated with distilled water are obtained. The effect of salt solution on ΔE depends on cation exchange capacity (CEC) and specific surface area (SSA), the larger the CEC and SSA, the smaller the saline effect. In addition, it is found that the pore size distribution of the compacted clay is bimodal, and inter-aggregate pores are greatly influenced by pore fluid chemistry, due to clay aggregation.

Coupled effects of temperature and suction on the anisotropic elastic shear moduli of unsaturated soil

Elastic shear moduli of soil at various temperatures and suctions are important for analysing the serviceability limit state of energy piles and many other structures. Up to now, however, the coupled effects of temperature and suction on elastic shear modulus and the stiffness anisotropy, have not been well understood. This experimental study investigated the anisotropic elastic shear modulus of a compacted lateritic clay. A temperature and suction-controlled triaxial apparatus equipped with bender element probes and local strain measurements was used. Soil suctions from 0 to 300 kPa, and a temperature range of 5–40 °C were applied. The results at saturated and unsaturated conditions consistently reveal that the shear modulus is smaller after heating at a given stress and suction. Several mechanisms may contribute to this thermal-induced reduction in shear modulus, such as the heating-induced reduction of interparticle force and air–water surface tension. Moreover, the reduction in shear modulus upon heating depends on the shear plane and the degree of anisotropy changes.

Structural, soil-water, and dynamic characteristics of clay with different moisture and temperature histories

Variations in the hydro-mechanical properties of pavement subgrade soils are complex under long-term, repeated, and interlaced moisture and temperature (M-T) effects, such as wetting-drying (WD) and freeze-thaw (FT) processes. This study compares the soil structure, soil-water characteristic curves, and accumulated plastic strain (ɛ p) of compacted Heilongjiang clay with three different M-T histories. Experimental results demonstrated that (i) after M-T actions, structural pores develop while textural pores shrink, leading to a reduction in the water retention capacity and an increase in the desaturation rate. Following the stabilization of the M-T effects, the soil structure and soil-water characteristics of specimens with different M-T histories become similar; (ii) at high moisture content (w), ɛ p is more sensitive to moisture changes (including w and suction, s). Following the FT cycles, ε p and ε pa (the difference between the ε p at 5000th and 3000th cyclic loading) become more sensitive to moisture changes; (iii) after M-T effects, the ε pa-w relationship is nonlinear while the ε pa-logs relationship is linear. Different M-T histories generated differences in only the ε p at the beginning of the FT processes while such differences disappear after M-T effects have stabilized. The experimental data presented in this paper could prove valuable in understanding the behaviors of pavement soils under complex environmental conditions.

Determination of the geophysical signature of soft-clay and hard lateritic soils and the implications on geotechnical works using electrical resistivity imaging

Understanding the geophysical signature of subsurface is quite essential in mapping site conditions for geotechnical engineering and simulating geophysical surveys, especially in coastal areas. This article presents a comparative geophysical study of topsoil (often refer as engineering layer) of soft clay deposit and hard lateritic soil to evaluate the implications on geotechnical work using electrical resistivity imaging (ERI). The results of the 2D ERI show that the hard lateritic soil produces three distinctive geological layers with the topsoil having high apparent electrical resistivity (AER) values varying between 300 Ωm–1000 Ωm and a thickness between 2.0 m – 10.0 m. The layer between the unsaturated and saturated regions has a moderate layer AER and thickness values ranging from 100 Ωm–300 Ωm and 2.5 m–9.5 m, respectively. In contrast, the saturated (weathered) layer has a low AER value (< 100Ω m), which represents the regional groundwater unit, located beneath the subsurface of a depth > 6.0 m. However, the soft clay soil shows no distinctive subsurface layers, as it is characterized by a nearly homogeneity subsurface of poor AER variability. The top-soft clay deposit has very AER values ranging from 11.0 Ωm–80 Ωm, which extends beyond 6.5 m. Higher and lower AER values noted within the overburdened topsoil of lateritic and clay extractions, respectively, were due to the accumulations of compacted clay and lateritic soil, which are very essential for geotechnical works. In addition, the geophysical signal was conspicuously attenuated in soft clay soil, which shows that soft clay soil is not a favourite target of geophysical investigation. However, the geophysical signals in hard lateritic generate a fine geo-electrical layer pattern. It was also noted that the existence of soft clay and lateritic soil decreases with depth. This kind of information is very essential in geotechnical works.

Simultaneous diffusion of Re(VII) and Se(IV) in compacted Tamusu clay by capillary method

Simultaneous diffusion of Re(VII) and Se(IV) in compacted Tamusu clay by capillary method

Analysis of natural organic matter chemistry in bentonite clay under compaction using different dry densities and duration

The Nuclear Waste Management Organization of Canada has adopted an adaptive phased management plan for the long-term storage of used nuclear fuel in a Deep Geological Repository (DGR). The DGR barrier system employs copper-coated used fuel containers (UFCs) surrounded by buffer material which is composed of highly compacted bentonite clay. The natural organic matter (NOM) composition of the compacted bentonite is of practical importance for the safety assessment as it regulates the biogeochemical processes at the interface between the UFCs and the buffer layer. However, insufficient investigations on NOM constituents limits the understanding of biogeochemical dynamics in bentonites compacted under different dry densities. This study analyzed the carbon content and NOM composition using targeted compound analysis and solid-state 13C nuclear magnetic resonance (NMR) spectroscopy with bentonites compacted at 1.1, 1.4 or 1.6 g/cm3 dry density for 1, 3, 6, 12 or 18 months. Organic carbon contents were similar across bentonites with different compaction densities at various durations as compared to the reference clay (powdered bentonite sample before compaction). The overall NOM composition measured by solid-state 13C NMR suggested a predominance of alkyl and aromatic carbon in bentonite samples. No marked variations were observed for the NOM components (i.e., alkyl, O-alkyl and aromatic carbon) between the compacted bentonites and the reference clay. Targeted compound analysis revealed that the extractable lipid concentrations in the compacted clays did not significantly vary from the reference bentonite with only some compounds exhibiting nano-gram level differences. Bentonites with relatively lower dry densities (1.1 and 1.4 g/cm3) demonstrated slightly higher extractable compound concentrations, but these differences were not statistically significant. In contrast, the compound concentrations of bentonites compacted to 1.6 g/cm3 were similar or slightly lower compared with the reference bentonite, likely associated with limited microbial growth under high dry compaction density. Taken together, these results suggested that NOM composition and quantity did not significantly alter in bentonites under various pressures nor with longer experimental durations. These findings highlight that compacted bentonite exhibited geochemical stability under the simulated repository environments, which provides critical insight for design and performance of engineered barrier system in a DGR concept.

Investigation on the size effect of compacted clay mode I fracture based on NDB specimens

The size effect is closely related to the cracking resistance of compacted clay, which is crucial in engineering applications, but little attention has been given to it in previous studies. This study investigated the size effect on mode I fracture behaviors of compacted clay using single-edge notched deep beam (NDB) specimens. Through the digital image correlation (DIC) method, the crack initiation mechanism of compacted clay was analyzed. The results showed that the specimen size and dimensionless crack length did not change the failure pattern, while peak load, peak displacement, and fracture energy gradually increased with the increase of specimen size. Based on the load–displacement curves and the horizontal strain evolution laws, the three horizontal strain stages at the crack tip crack initiation point were defined, i.e., the steady strain growth stage, the nonlinear strain growth stage, and the nonlinear strain intensification stage. Through the Bažant size effect model (SEM), the fracture process zone length Cf and mode I fracture toughness KIC of compacted clay without the size effect were inferred. The separated form of SEM was applied, and the contribution ratios of the strength criterion and linear elastic fracture mechanics were quantitatively analyzed. Combing the characteristics of the NDB specimens, a prediction model considering the support spacing, specimen structure parameters, and fracture toughness was established.

A study on porosity investigation of compacted bentonite in various densities by using micro-computed tomography images analysis

Abstract Compacting a material means applying pressure so that the material itself loses its internal pores. It improves the homogeneity of the material itself and increases its density. The pore structure of compacted clay is also an important factor that affects its mechanical properties, permeability and water absorption. In this study, MX-80 bentonite clay was first compacted into round cakes of different densities and then subjected to tomography image analysis technique using micro-computed tomography (micro-CT) at millimeter scale of accuracy for 1.0–2.0 g/cm3 compacted clay (thickness of 0.3 cm bentonite compacted clay). In this paper, we use the latest commercial specifically for scientific visualization, materials science, non-destructive testing, numerical simulation of chromatographic imaging and other functions of a powerful visualization of the image analyzing method.

Membrane behavior of clay under mixed solution conditions

Compacted clay is employed as the buffer material for landfills, and multiple ions are dissolved in the leachate restricted by the compacted clay layer. The membrane efficiency is an important indicator to assess the barrier properties of the compacted clay layer and is measured through membrane tests. However, most membrane tests are currently conducted with a single solute solution, which does not reflect the mixed solution characteristics of leachates. To assess the membrane efficiency of compacted clay under mixed solution conditions, 13 membrane tests were conducted on a bentonite-amended soil using KCl–NaCl mixed solutions, KCl–CaCl2 mixed solutions, and KCl–AlCl3 mixed solutions with different mixing ratios at a total concentration of 20 mM. Nuclear magnetic resonance (NMR) tests were conducted on the soil specimen after the membrane tests to investigate the micromechanism of the membrane behavior under mixed solution conditions. Results indicate that the membrane efficiency increased with the mixing ratio of Na+ but decreased with the mixing ratio of Ca2+ or Al3+. In the 13 membrane tests, the lowest membrane efficiency was achieved when the specimen was tested with pure AlCl3 solution. The relationship between the membrane efficiency and mixing ratio was also investigated at the microscopic scale. As the ion valence increases, the diffuse double layer thickness is smaller and the proportion of macropores is larger, as verified by NMR tests.

Compressibility and microstructure of compacted lateritic clay at different suction levels

Compressibility and microstructure of compacted lateritic clay at different suction levels

Diffusive transport of selenium oxyanions in compacted natural clays: role of selenium speciation and clay geochemistry

Diffusive transport of selenium oxyanions in compacted natural clays: role of selenium speciation and clay geochemistry

Macroscopic Mechanical Properties and Microstructure Characteristics of Solid Waste Base Capillary Retarded Field Covering Material

In the practical operation of traditional landfills, compaction clay often experiences cracking, while the HDPE geomembrane may tear and bulge, resulting in a compromised performance of the landfill covering system. To address this issue, a capillary retarding covering material for landfill sites is proposed by utilizing municipal sludge and construction waste particles as substrates and incorporating a small quantity of calcium bentonite. The mechanical characteristics of the covering material were investigated using a standard consolidation test and a triaxial compression test. A permeability test and a soil water characteristic curve (SWCC) test were conducted to examine the permeability and capillary retarding effect of the covering material. Microscopic tests including SEM scanning, laser particle size analysis, and T2 NMR analysis were performed to investigate the connection mode, particle size composition, and pore structure characteristics of the covered particles. Based on the aforementioned research, the following conclusions can be drawn: The cohesion of the covering material ranged from 50 to 150 kPa, while the internal friction angle ranged from 24.23° to 31°. The cohesion was directly proportional to the content of construction waste, whereas the internal friction angle was inversely proportional to calcium bentonite content. The permeability coefficient ranged from 5.04 × 10−6 cm/s to 7.34 × 10−5 cm/s, indicating a certain level of impermeability. Both the sludge and the calcium bentonite contents jointly influenced the final permeability coefficient in a negative correlation manner, with a notable hydraulic hysteresis phenomenon observed. A higher content of construction waste leads to a more pronounced supporting force exerted by the formed skeleton structures within a load pressure range between 0 and 1600 kPa. When considering a mass ratio of municipal sludge: construction waste: calcium bentonite as 30:60:7, respectively, only a decrease in the pore ratio by approximately 13.20% was observed. This study provides valuable data support for designing and applying capillary retarding cover barrier systems in landfills.

Microbial responses to elevated temperature: Evaluating bentonite mineralogy and copper canister corrosion within the long-term stability of deep geological repositories of nuclear waste

Deep Geological Repositories (DGRs) consist of radioactive waste contained in corrosion-resistant canisters, surrounded by compacted bentonite clay, and buried few hundred meters in a stable geological formation. The effects of bentonite microbial communities on the long-term stability of the repository should be assessed. This study explores the impact of harsh conditions (60 °C, highly-compacted bentonite, low water activity), and acetate:lactate:sulfate addition, on the evolution of microbial communities, and their effect on the bentonite mineralogy, and corrosion of copper material under anoxic conditions. No bentonite illitization was observed in the treatments, confirming its mineralogical stability as an effective barrier for future DGR. Anoxic incubation at 60 °C reduced the microbial diversity, with Pseudomonas as the dominant genus. Culture-dependent methods showed survival and viability at 60 °C of moderate-thermophilic aerobic bacterial isolates (e.g., Aeribacillus). Despite the low presence of sulfate-reducing bacteria in the bentonite blocks, we proved their survival at 30 °C but not at 60 °C. Copper disk's surface remained visually unaltered. However, in the acetate:lactate:sulfate-treated samples, sulfide/sulfate signals were detected, along with microbial-related compounds. These findings offer new insights into the impact of high temperatures (60 °C) on the biogeochemical processes at the compacted bentonite/Cu canister interface post-repository closure.