Commercial Diode Research Articles

Nickel–Cobalt Layered Double Hydroxide Nanosheet-Decorated 3D Interconnected Porous Ni/SiC Skeleton for Supercapacitor

In this study, a three-dimensional (3D) interconnected porous Ni/SiC skeleton (3D Ni/SiC) was synthesized by binder-free hydrogen bubble template-assisted electrodeposition in an electrolyte containing Ni2+ ions and SiC nanopowders. This 3D Ni/SiC skeleton served as a substrate for directly synthesizing nickel–cobalt layered double hydroxide (LDH) nanosheets via electrodeposition, allowing the formation of a nickel–cobalt LDH nanosheet-decorated 3D Ni/SiC skeleton (NiCo@3D Ni/SiC). The multiscale hierarchical structure of NiCo@3D Ni/SiC was attributed to the synergistic interaction between the pseudocapacitor (3D Ni skeleton and Ni–Co LDH) and electrochemical double-layer capacitor (SiC nanopowders). It provided a large specific surface area to expose numerous active Ni and Co sites for Faradaic redox reactions, resulting in an enhanced pseudocapacitance. The as-fabricated NiCo@3D Ni/SiC structure demonstrated excellent rate capability with a high areal capacitance of 1565 mF cm−2 at a current density of 1 mA cm−2. Additionally, symmetrical supercapacitor devices based on this structure successfully powered commercial light-emitting diodes, indicating the potential of as-fabricated NiCo@3D Ni/SiC in practical energy storage applications.

Flexible Triboelectric Nanogenerators Based on Cadmium Metal-Organic Framework/Eethyl Cellulose Composites as Energy Harvesters for Selective Photoinduced Bromination Reaction.

The fabrication of self-driven systems with flexibility and tunable output for organic photoinduction is highly desirable but challenging. In this study, a 3D cadmium metal-organic framework (Cd-MOF) is synthesized and used as a filler for ethyl cellulose (EC) to create mechanically durable and flexible Cd-MOF@EC composite films. Due to its well-established platform with periodically precise structure nature, the outputs of Cd-MOF-based TENG are much higher than those of ligand-based TENGs. Furthermore, composite films with different doping ratios of Cd-MOF are employed to assemble Cd-MOF@EC-based triboelectric nanogenerators (TENGs). The results reveal that a doping ratio of 10 wt.% Cd-MOF in Cd-MOF@EC provides the highest TENG output. Subsequently, a flexible 10 wt.% Cd-MOF@EC-based TENG (FCEC-TENG), working in the contact-separation model, is constructed to harvest mechanical energy from the human body, demonstrating excellent output performance and stability. The energy harvested from FCEC-TENG can directly illuminate 14 commercial white light-emitting diodes (LEDs), providing visible light for the photoinduction of the bromination reaction, and generating bromide with good yield and tolerance. This study presents an effective method for constructing flexible MOF-based TENG for self-powered photoinduced organic transformation systems.

Highly stretchable carbon-based triboelectric nanogenerator textiles woven using coaxial fibres via direct ink writing

In recent years, triboelectric nanogenerators have seen great progress in the Internet of Things, wearable electronics, virtual reality and artificial intelligence technologies. However, current triboelectric nanogenerator devices generally face challenges of complex preparation processes and structures, hindering their application in large-area wearable textiles. In this study, we develop highly stretchable triboelectric fibres using direct ink writing as building blocks for further woven textiles. This consists of a conductive core and insulating sheath, namely composites of multi-wall carbon nanotube and fluorinated ethylene propylene particles, both doped in silicone rubber. The fibre enjoys outstanding electrical performance, as well as excellent mechanical stretchability. Particularly, a single-centimetre-long fibre, upon slight patting, can surprisingly produce an open-circuit voltage of 8 V, a short-circuit current of 110 nA and 2.5 nC short-circuit transferred charges, or equivalent lighting of four to five commercial light-emitting diodes alone, greatly outperforming current wearable devices. These fibres also can endure an extraordinary strain of up to ∼874 %. The fibres are then woven into wearable gloves and socks using traditional weaving techniques, which can realise motion pattern identification and recognition with classification accuracy as high as ∼96 % using convolutional neural networks. This creates application prospects in wearable electronics, providing a scalable and affordable method for weaving daily wearable textiles and favouring large-area, wearable, self-powered sensors and artificial intelligence technologies.

Revealing multiphase coexistence of R-O-T phases in BaTiO3-CaTiO3-BaSnO3 electroceramics for energy harvesting and storage response with piezo actuation

The (Ba1-xCax)(SnyTi1-y)O3 piezoelectric ceramics (where x=0.016, y=0.024; x=0.032, y=0.048; x=0.048, y=0.072; x=0.064, y=0.096; x=0.08, y=0.12) were designed by conventional solid state reaction method. The crystal structure for the composition of x=0.064 and y=0.096 (abbreviated as BCST-4) possesses the coexistence of non-centrosymmetric rhombohedral-orthorhombic-tetragonal (R-O-T) tri-lattice symmetries at room temperature, as demonstrated by the structural Rietveld refinement, Raman analysis, and temperature dependence of dielectric study. Because of the R-O-T multiphase coexistence, BCST-4 possesses a superior electromechanical and piezoelectric property viz. kp ∼ 0.45, strain ∼ 0.100 %, d33* ∼ 649 pm/V, and an improved d33 ∼ 452 pC/N, which is comparable to commercially available soft PZT ceramics (d33 ⁓ 370 pC/N). For BCST-4 ceramics, an exceptional electrostriction coefficient Q33 ∼ 0.0434 m4/C2 value was attained. The intrinsic piezo-actuation DC strain was observed to be 130 microstrain (με) and 188 με with ε33 and ε31 modes respectively. The BCST-4 ceramic exhibits a maximum output power of 1.03 mW, a power density of 13.5 µW/mm3, a maximum output current of 88 µA, and an open circuit voltage Vpp of 28 V which successfully glowed ‘SPPU’ panel having 40 red commercial light-emitting diodes (LEDs). The energy storage study reveals that BCST-4 ceramics exhibit a maximum energy storage density (Wrec) of 165.87 mJ/cm3 with efficiency (ƞ) 68.00 %. Therefore, the improvement in electrostriction coefficient, piezoelectric charge coefficient, and energy storage response indicates that BCST-4 ceramic has the potential for actuator, energy harvesting, and energy storage applications.

A DLTS analysis of alpha particle irradiated commercial 4H-SiC Schottky barrier diodes

4H-SiC Schottky barrier diodes (SBDs) were exposed to 5.4 MeV alpha particles with fluences of 2.55× 1011 cm−2, 5.11 × 1011 cm−2 and 7.67 × 1011 cm−2, respectively. Transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) was used to determine the structure and cross-sectional elemental composition of the device, while current–voltage and capacitance–voltage profiling were used to determine the primary electrical device-characteristics before and after irradiation. EDS revealed the presence of a <1 μm Ti layer, covered by 5 μm Al layer, in intimate contact with the SiC. Deep level transient spectroscopy (DLTS), performed in the temperature range 15–310 K, revealed one dominant peak around 50 K (Ec - 0.07 eV) in the unirradiated samples. This peak showed asymmetry suggesting that it may consist of more than one defect. Notably, Z1/2, the carbon vacancy-related (Vc) defect commonly observed in as-grown n-type 4H-SiC, was not detected in the unirradiated reference sample. After irradiation, a broad peak emerged around 280 K (at 80 Hz), most likely Z1/2, having a shoulder around 180 K, was detected. Increasing the fluence resulted in a corresponding decrease in the concentration of the electron trap observed around 50 K (Ec - 0.07 eV), while the concentration increases for the defect detected around 280 K. Notably, the concentration of Z1/2 was found to be strongly fluence dependent and linked to what we believe is a related to a silicon vacancy transition, labelled S1/2 in literature. Laplace DLTS confirmed that the peak observed around 50 K is composed of multiple defects.

Responses of mustard greens (Brassica juncea L.) to additional lighting duration of LED under greenhouse conditions in the tropical zone

ABSTRACT Light-emitting diodes have been beneficial for plant growth, especially for microgreens in countries with low radiation, greenhouses, and chambers. However, information about how plants respond to additional light-emitting diode lighting after 12 hours of sunlight exposure in tropical areas is limited. This study examines the effects of long-duration light-emitting diodes on mustard greens in Kien Giang province, Vietnam (105°14’33.21” E; 9°91’41.13” N). The trials were conducted in the greenhouse for two growing seasons with a completely randomized design, including 0, 2, 4, and 6 hours of assembled light-emitting diodes lighting and 4 hours of commercial light-emitting diodes lighting after 6 pm, with three replications. Results showed that weather factors in season 2 favorably influenced mustard’s growth. At 4 hours of lighting, commercial light-emitting diodes showed a higher chlorophyll index, flowering time, flowering rate, leaf number, and absolute growth rate of leaf number but less leaf and fresh shoot weight than assembled light-emitting diodes. Four hours of assembled light-emitting diodes positively affected most mustard growth, while 6 hours of assembled light-emitting diodes were superior for flowering aspects. Adding 4 hours of light-emitting diodes could increase leafy yield and shorten the harvesting time of mustard greens grown in greenhouses under tropical conditions.

High-Detectivity All-Polymer Photodiode Empowers Smart Vitality Surveillance and Computational Imaging Rivaling Silicon Diodes.

Near-infrared (NIR) organic photodetectors (OPDs), particularly all-polymer-based ones, hold substantial commercial promise in the healthcare and imaging sectors. However, the process of optimizing their active layer composition to achieve highly competitive figures of merit lacks a clear direction and methodology. In this work, celebrity polymer acceptor PY-IT into a more NIR absorbing host system PBDB-T:PZF-V, to significantly enhance the photodetection competence, is introduced. The refined all-polymer ternary broadband photodetector demonstrates superior performance metrics, including experimentally measured noise current as low as 6 fA Hz-1/2, specific detectivity reaching 8×1012 Jones, linear dynamic range (LDR) of 145 dB, and swift response speed surpassing 200 kHz, striking a fair balance between sensitivity and response speed. Comprehensive morphological and photophysical characterizations elucidate the mechanisms behind the observed performance enhancements in this study, which include reduced trap density, enhanced charge transport, diminished charge recombination, and balanced electron/hole mobilities. Moreover, the practical deployment potential of the proof-of-concept device in self-powered mode is demonstrated through their application in a machine learning-based cuffless blood pressure (BP) estimation system and in high-resolution computational imaging across complex environments, where they are found to quantitatively rival commercial silicon diodes.

A triboelectric nanogenerator based on a spiral rotating shaft for efficient marine energy harvesting of the hydrostatic pressure differential

Equipment used in underwater sensing and exploration typically relies on cables or batteries for energy supply, resulting in a limited and inconvenient energy supply and marine environmental pollution that hinder the sustainable development of distributed ocean sensing networks. Here, we design a deep-sea differential-pressure triboelectric nanogenerator (DP-TENG) based on a spiral shaft drive using modified polymer materials to harness the hydrostatic pressure gradient energy at varying ocean depths to power underwater equipment. The spiral shaft structure converts a single compression into multiple rotations of the TENG rotor, achieving efficient conversion of differential pressure energy. The multi-pair electrode design enables the DP-TENG to generate a peak current of 61.7 μA, the instantaneous current density can reach 0.69 μA cm−2, and the output performance can be improved by optimizing the spiral angle of the shaft. The DP-TENG can charge a 33 μF capacitor to 17.5 V within five working cycles. It can also power a digital calculator and light up 116 commercial power light-emitting diodes, demonstrating excellent output capability. With its simple structure, low production cost, and small form factor, the DP-TENG can be seamlessly integrated with underwater vehicles. The results hold broad prospects for underwater blue energy harvesting and are expected to contribute to the development of self-powered equipment toward emerging “smart ocean” and blue economy applications.

Experimental and Monte Carlo based dosimetric investigation of a novel 3mm radiosurgery 3MV beam using the microSilicon detector.

The ZAP-X system is a novel gyroscopic radiosurgical system based on a 3MV linear accelerator and collimator cones with a diameter between 4 and 25mm. Advances in imaging modalities to detect small and early-stage pathologies allow for an early and less invasive treatment, where a smaller collimator matching the anatomical target could provide better sparing of surrounding healthy tissue. A novel 3mm collimator cone for the ZAP-X was developed. This study aims to investigate the usability of a commercial diode detector (microSilicon) for the dosimetric characterization of this small collimator cone; and to investigate the underlying small field perturbation effects. Profile measurements in five depths as well as PDD and output ratio measurements were performed with a microSilicon detector and radiochromic EBT3 films. In addition, comprehensive Monte Carlo simulations were performed to validate the measurement observations and to quantify the perturbation effects of the microSilicon detector in these extremely small field conditions. It is shown that the microSilicon detector enables an accurate dosimetric characterization of the 3mm beam. The profile parameters, such as the FWHM and 20%-80% penumbra width, agree within 0.1 to 0.2mm between film and detector measurements. The output ratios agree within the measurement uncertainty between microSilicon detector and films, whereas the comparisons of the PDD results show good agreement with the Monte Carlo simulations. The analysis of the perturbation factors of the microSilicon detector reveals a small field correction factor of approximately 3% for the 3mm circular beam and a correction factor smaller than 1.5% for field diameters above 3mm. It could be shown that the microSilicon detector is well-suitable for the characterization of the new 3mm circular beam of the ZAP-X system.

Crystal growth and spectroscopic performances of Dy3+:YPO4 and Dy3+/Tb3+:YPO4 crystal as potential yellow laser gain mediums

Exploring new Dy3+-doped laser gain medium is still a challenge for constructing efficient yellow solid-state laser at current stage. In this paper, high quality Dy3+:YPO4 and Dy3+/Tb3+:YPO4 crystals were grown by the high temperature solution method. The crystal structure, chemical composition, phonon energy, polarized absorption and emission spectra, fluorescence lifetime were investigated. The obtained large FWHMs (6 nm) and absorption cross-sections (3.87×10−21 cm2) of Dy3+:YPO4 and Dy3+/Tb3+:YPO4 crystals at 454 nm indicate that they can be efficiently pumped by the commercial blue laser diodes. J-O intensity (Ω2, Ω4, Ω6), fluorescence branching rate and radiative lifetime of Dy3+ ions were calculated by J-O theory. Benefiting from the appropriate phonon energy, the emission cross-section of Dy3+: YPO4 crystal at 575 nm can reach 5.04×10−21 cm2. Moreover, after co-doping Tb3+ as deactivating ion, the emission cross-section of Dy3+/Tb3+: YPO4 crystal at 575 nm was promoted to 5.98×10−21 cm2 by a resonance energy transfer process between the Dy3+-6H13/2 and Tb3+-7F4. Therefore, both Dy3+:YPO4 and Dy3+/Tb3+:YPO4 crystals are potential candidates for yellow laser gain mediums.

In-situ growth of 3D amorphous Ni-Co-Mn phosphate on 2D Ti3C2Tx nanocomposite for commercial-level hybrid energy storage application

To overcome the limited electronic conductivity and capacity of single and binary transition metal phosphates (TMPs), highly electrochemical active materials and rational structural design of ternary TMPs composite are urgently required. In this study, we successfully synthesized an amorphous 3D Ni-Co-Mn phosphate@2D Ti3C2Tx (MXene) nanocomposite (NCMP series) through the electrodeposition method. The amorphous Ni-Co-Mn phosphate effectively restricts the self-accumulation of MXene nanosheets, resulting in the development of a porous nanostructure. This structure exposes more active sites, expands the ion transport path, and enhances the conductivity of the Ni-Co-Mn phosphate@Ti3C2Tx material. Owing to the synergistic effect offered by Ni-Co-Mn phosphate and MXene nanocomposite, the anchored Ni-Co-Mn phosphate@Ti3C2Tx (NCMP-5) electrode delivers an elevated capacity of 342 mAh/g (1230 C/g) at 5.0 A/g, surpassing the pristine Ni-Co-Mn phosphate (NCMP-4, 260 mAh/g) and MXene (33.3 mAh/g). Moreover, a hybrid solid-state supercapacitor (HSSC) device is assembled with NCMP-5 as a cathode and reduced graphene oxide (rGO) as an anode within a polymer gel (PVA-KOH) electrolyte. Notably, the fabricated HSSC device displays a supreme specific capacity of 27.5 mAh/g (99 C/g) and a high (volumetric) energy density of 22 Wh/kg (3.6 Wh/cm3) at a power density of 0.80 kW/kg (0.13 kW/cm3) for 1.0 A/g. Moreover, the HSSC device retains 95.4 % of its initial capacity even after 10,000 cycles. Importantly, the operational potential window of two serially connected HSSC devices approaches +3.2 V, enabling different colored commercial light-emitting diodes (LEDs) to be efficiently illuminated. Eventually, the remarkable supercapacitive characteristics of the 3D@2D amorphous Ni-Co-Mn phosphate@MXene nanocomposite make it an attractive choice for advanced electroactive materials in upcoming hybrid energy storage technologies.

Characterization of a commercial PIN diode for radiotherapy photon beam dosimetry

The dosimetric characterization of a commercial diode (BPW-34) was performed using a True Beam accelerator (Varian), with flattening filter (FF) photon beams of 6 and 15 MV and flattening filter free (FFF) of 6 MVFFF. The main performance characteristics, namely dose response, energy and dose rate dependence, field output factor, and percentage depth dose profile (PDD), were compared with those available in the literature and, whenever possible, benchmarked against the Varian Eclipse treatment planning system (TPS) predictions. Regardless of the energy, the results showed that the dose response curves are linear (R2 = 1) with nonlinearity parameters less than 0.1% and 0.3% of repeatability. Furthermore, the average dose rate effect (0.7%) is almost negligible within the range of 20–600 MU/min (6 MV, 15 MV) and 400–1400 MU/min (6 MVFFF). Despite these good results, the charge sensitivity measurements evidenced that the diode response depends slightly on the energy, being within 5% for 6 MV–15 MV. It is important to underline that all these results adhere to the standard radiotherapy dosimetry protocols. Moreover, the general output field factor measurements and the percentage depth dose profiles, which are in excellent agreement with the Eclipse TPS calculations, also demonstrated that the diode BPW-34 is a low-budget alternative radiotherapy photon beam dosimeter.

Deformable micro-supercapacitor fabricated via laser ablation patterning of Graphene/liquid metal

Deformable and miniaturized energy storage devices are essential for powering soft electronics. Herein, we fabricate deformable micro supercapacitors (MSCs) based on eutectic gallium-indium liquid metal (EGaIn) current collectors with integrated graphene. The well-define interdigitated electrode patterning with controlled gap is successfully realized by using the laser ablation because of a strong laser absorption of graphene and EGaIn. By judicious control of gap size between neighboring interdigitated electrodes and mass loading of graphene, we achieve a high areal capacitance (1336 µF cm−2) with reliable rate performance. In addition, owing to the intrinsic liquid characteristics of EGaIn current collector, the areal capacitance of fabricated MSC retains 90% of original value even after repetitive folding and 20% stretching up to 1000 cycles. Finally, we successfully integrate deformable MSC with a commercial light-emitting diode to demonstrate the feasibility of MSC as a deformable power source. The fabricated MSCs operate stably under various mechanical deformations, including stretching, folding, twisting, and wrinkling.

Improving the performance of triboelectric nanogenerators using flexible polyurethane nanocomposites foam filled with montmorillonite

Flexible polyurethane (FPU) foam is flexible and adaptable, making it a promising candidate for utilization as a triboelectric layer in triboelectric nanogenerator (TENG) devices. Nevertheless, the mechanical properties and output voltages of FPU foam are limited, prompting the need to explore modifications that can enhance its performance. In this study, FPU foam was modified through the incorporation of natural montmorillonite (Na-MMT) nanoclay at different weight ratios (0.1, 0.3, 0.5, and 0.7 wt%), resulting in the development of FPU/Na-MMT nanocomposites. The exfoliation of Na-MMT within the FPU matrix was established using XRD and TEM techniques. Morphology analysis by SEM confirmed that adding Na-MMT reduced the cavity and pore diameters of the FPU foam. The compressive strength of the FPU/Na-MMT0.3 composite showed the highest increase of 27.75% when compared to the pristine FPU foam. Moreover, adding Na-MMT to FPU showed an improvement in the output voltage of the TENG for all nanocomposites, with the FPU/Na-MMT0.3 exhibiting the highest improvement of + 62.37% at a force of 4.8 N and a frequency of 5 Hz, compared to pristine FPU. The fabricated TENG device achieved a maximum power density of 0.0328 mW/cm2 at a load resistance of 20 MΩ with a contact area of 9×5 cm2. This device could power three commercial white light-emitting diodes (LEDs) connected in series. Additionally, the fabricated TENG device was employed to charge a 10 µF capacitor, reaching an energy storage of 1185.8 µJ. This demonstrates the device’s effectiveness in energy harvesting. Consequently, the prepared flexible FPU/Na-MMT nanocomposite foams are a promising material to use in TENG devices to power flexible electronic devices.

A Triboelectric Nanogenerator Based on Bamboo Leaf for Biomechanical Energy Harvesting and Self-Powered Touch Sensing

Recently, natural material-based triboelectric nanogenerators (TENGs) have increasingly attracted attention in academic circles. In this work, we have developed an innovative triboelectric nanogenerator (BL-TENG) utilizing bamboo leaves to capture biomechanical energy. Bamboo leaf, as a natural plant material, possesses a diverse array of applications due to its remarkable durability, which surpasses that of many other types of trees. Furthermore, bamboo leaf has the advantages of low cost, widely distributed, non-toxic and environmentally protected. The output power of the BL-TENG (size: 5 cm × 5 cm) is able to generate approximately 409.6 µW and the internal resistance of the BL-TENG is 40 MΩ. Furthermore, the BL-TENG can realize an open-circuit voltage (Voc) of 191 V and a short-circuit current (Isc) of 5 µA, respectively. The biomechanical energy harvesting effect of the BL-TENG device means that it can drive 18 commercial light-emitting diodes (LEDs) through the full-wave bridge rectifier. Furthermore, the BL-TENG can also serve as a self-powered touch sensor to reflect hand touch states. This study proposed a novel plant-based TENG device that can enhance the development of green TENG devices and self-powered sensing systems.

Enhancing the Output of Liquid-Solid Triboelectric Nanogenerators through Surface Roughness Optimization.

The advent of liquid-solid triboelectric nanogenerators (LS-TENGs) has ushered in a new era for harnessing and using energy derived from water. To date, extensive research has been conducted to enhance the output of LS-TENGs, thereby improving water utilization efficiency and facilitating their practical application. However, in contrast to intricate chemical treatment methods and specialized structures, a straightforward operational process and cost-effective materials are more conducive to the widespread adoption of LS-TENGs in practical applications. This work presents a novel method to enhance the output of LS-TENGs by increasing the liquid-solid contact area. The approach involves creating roughness on the solid surface through sandpaper grinding, which is simple in design and easy to operate and significantly reduces the cost of the experiment. The theory is applied to the solid triboelectric layer commonly used in the LS-TENG, demonstrating its universality and wide applicability to improve the output of the LS-TENG. The practical performance of the device is demonstrated by charging the capacitor and external load and driving the hygrometer and commercial 5 W LED light bulb, which can directly light up 300 commercial light-emitting diodes (LEDs) driven by a drop of water. This work provides a new method for the optimization of LS-TENGs and contributes to the wide application of LS-TENGs. This is a significant step forward in the field of energy harvesting and utilization.

Observation of piezoelectricity in a lead-free Cs2AgBiBr6 perovskite: a new entrant in the energy harvesting arena.

Halide perovskite materials have recently been recognised as powerful ferroelectric and piezoelectric materials with applications in the energy harvesting arena, but their experimental proof is very limited. We achieved strong intrinsic piezoelectricity in the lead-free inorganic double perovskite Cs2AgBiBr6 at room temperature and utilized it for mechanical energy harvesting, with a piezoelectric co-efficient (d33) of 12.7 pC N-1. Hysteresis loop and structural analyses offered further validation for the substantial ferroelectric features of the as-synthesised double perovskite. Density functional theory (DFT) calculations revealed the presence of anharmonic phonon soft modes in tetragonal Cs2AgBiBr6 due to dynamic instability, which resulted in piezoelectricity. Under an optimal pressure of ≈25 kPa, a Cs2AgBiBr6 thin film-based piezoelectric nanogenerator device delivered instantaneous output values of ≈45 V and ≈200 nA. The strain-sensitive responses of the device were also exemplified to identify specific body motions from the detected instantaneous output values. The energy obtained from the device is shown to be effective for capacitor charging and commercial light-emitting diode (LED) lighting. Our study provides significant insights into the dielectric behaviour of materials as well as piezo- and ferroelectric behaviours, which are crucial for the development of modern electronic and energy harvesting devices.

Low thermal quenching of metal halide-based metal-organic framework phosphor for light-emitting diodes.

Phosphor-converted white light-emitting diodes (PC-WLEDs) have attracted considerable attention in solid-state lighting and display. However, urgent issues of thermal quenching and high cost remain formidable challenges. Herein, a novel metal-organic framework (MOF) phosphor [CdCl2(AD)] was facilely prepared using a mixture of CdCl2 and acridine (AD) under solvothermal conditions. It shows intensive green emission with a long lifetime of 31.88 ns and quantum yield of 65% while maintaining 95% and 84% of its initial emission intensity after remaining immersed in water for 60 days and being heated to 150 °C, respectively. The low thermal quenching of this MOF material is comparable to or can even exceed that of commercial inorganic phosphors. The combination of experiments and theoretical calculations reveals that the alternating arrangement of delocalized AD π-conjugated systems and CdCl2 inorganic chains through strong coordination bonds and π⋯π stacking interactions imparts the MOF phosphor with high thermal stability and optoelectronic performance. The successful fabrication of green and white LED devices by coating [CdCl2(AD)] and/or N630 red phosphor on a 365/460 nm commercial diode chip suggests a promising and potential alternative to commercial phosphors.

Improved Energy Harvesting Ability of Single-Layer Binary Fiber Nanocomposite Membrane for Multifunctional Wearable Hybrid Piezoelectric and Triboelectric Nanogenerator and Self-Powered Sensors.

While wearable self-powered electronic devices have shown promising improvements, substantial challenges persist in enhancing their electrical output and structural performance. In this work, a working mechanism involving simultaneous piezoelectric and triboelectric conversion within a monolayer-structured membrane is proposed. Single-layer binary fiber nanocomposite membranes (SBFNMs) (PVDF/CNTX@PAN/CNTX, DPCPCX) with two distinct interpenetrating nanocomposite fibers were created through co-electrospinning, incorporating multiwalled carbon nanotubes (CNTs) into polyvinylidene fluoride (PVDF) and polyacrylonitrile (PAN), respectively. The resulting membrane demonstrated an exceptional synergistic effect of piezoelectricity and triboelectricity along with a high machine-to-electric conversion capability. The addition of CNTs increased the PVDF β-phase and the PAN planar zigzag conformation. As a result, the DPCPC0.5-SBFNMs-based piezoelectric nanogenerator exhibited excellent electrical output (187 V, 8.0 μA, and 1.52 W m-2), maintaining an exceptionally high level of output voltage compared with other piezoelectric nanogenerators. It successfully illuminated 50 commercial light-emitting diodes simultaneously. The output voltage of DPCPC0.5-SBFNMs was 5.1 and 4.6 times higher than that of PAN or PVDF single-fiber membranes, respectively. Furthermore, the peak voltage of DPCPC0.5-SBFNMs exceeded that of co-electrospinning PVDF/CNT1.0@PAN (DPCP1.0) and PVDF@PAN/CNT1.0 (DPPC1.0) by 20 and 10 V, respectively. The piezoelectric sensor made of DPCPC0.5-SBFNMs accurately sensed human movement, ranging from tiny to large, and demonstrated utility as an alarm in medical treatment, fire fighting, and monitoring. Endogenous triboelectricity is proposed in SBFNM piezoelectric materials, enhancing electromechanical conversion and electrical output capacity, thereby promising a wide application potential in self-powered wearable electronic devices.

A pitched roof-like hybrid piezo/triboelectric nanogenerator with reliable supply capability for building a self-powered industrial monitoring system

As a result of increasingly stringent power supply requirements and diverse application scenarios, the development of hybrid nanogenerators that can combine multiple power generation modes has gradually become a hot research topic. In this work, the PR-HNG, a piezo/triboelectric hybrid nanogenerator based on a pitched roof structure, is proposed and is used efficiently to perform discrete mechanical energy harvesting. Using the flexible connection of its separated roof-like trigger mechanism, the PR-HNG operates through inertia under vibration conditions and achieves a satisfactory working state with very low mechanical loss. At 10 Hz, the instantaneous open-circuit voltage VOC and short-circuit current ISC of the PR-HNG can reach 800 V and 9.6 mA (1.60 A/m2), respectively, and no obvious attenuation occurs during high-intensity and long-term operation. After connection to a load via a rectifier bridge, the PR-HNG has a maximum power output of 575 μW/cm2 and can charge a 2 mF capacitor up to more than 2.5 V in only 30 s; these two performance parameters are better than the reported values for other similar types of HNG. In practical applications, this PR-HNG can easily drive more than 1440 commercial light-emitting diodes and can drive small electronic devices in real time. Therefore, the PR-HNG has been demonstrated to provide a credible and promising solution for fabrication of self-powered monitoring systems for use in industrial environments.