Combustion Of Powders Research Articles

Development aspects of cable cutter cartridge for helicopter application

This research work emphasizes on the development aspects of a cartridge cable cutter for helicopter application. This cartridge is used to rescue hoist system during emergency for helicopter application under adverse conditions. It is an electrically initiated cartridge in which two electrical squibs are used with specified current and voltage. As the cartridge is initiated, the squib gets incandescent and initiates an explosive train. A cartridge cable cutter is a propellant actuated device (PAD) that generates hot combustion gases having high temperature and pressure on burning of gun powder and propellant inside the cartridge case. The cable cutter cartridge under study is filled with energetic materials (EM) such as propellants and gun powder. It releases the energy very quickly which acts on the projectile i.e. the cutter in actual system. A projectile velocity measurement was carried out using Doppler RADAR (radio detection and ranging). To assess the projectile velocity is the unique design feature in armament field. It is responsible for the measurement of the projectile velocity at the muzzle end of velocity test rig (VTR). The minimum and maximum projectile velocities were experimentally measured in between 70 ms−1 and 150 ms−1. The projectile velocity measurement is an evaluation methodology as performance parameter of this cartridge. The cartridge under study has been developed meeting structural, functional and mechanical requirements. The cartridge has undergone various exhaustive qualification tests during development phase. The cartridge was thus designed, qualified and validated through rigorous development trials. The main objective of this article is to address development aspects of the cartridge cable cutter for helicopter application. In conclusion, after successful design, development and qualification trials, the cartridge was found to meet all the functional and operational requirements considering the end use.

The synergy of polyvinylidene fluoride and CuO to enhance the combustion of boron powder

The synergy of polyvinylidene fluoride and CuO to enhance the combustion of boron powder

Towards an efficient metal energy carrier for zero–emission heating and power: Iron powder combustion

In this study, the metal cyclonic combustor (MC2) was utilized to investigate the formation of nanoparticles (nPMs) and NOx during the combustion of iron powder under varying input conditions of equivalence ratio and oxygen concentration. Findings unveiled a consistent trend: both nanoparticle and NOx formations exhibit a similar response to changes in input conditions. Specifically, as the input equivalence ratio was increased or the oxygen concentration decreased, a simultaneous reduction in the formation of these pollutants was observed. This suggests a common influence of these factors on both nanoparticle and NOx formation. Additionally, the research highlighted a critical parameter in maintaining a self-sustainable stationary flame: ensuring that the iron particles remained relatively close together, with a maximum particle-to-particle distance of approximately 0.5 mm or a minimum total iron particle surface area of at least 0.02 mm2 per mm3 volume burner for oxidizer oxygen concentrations ranging from 13.5 % to 21 %. These findings provide valuable insights for optimizing the utilization of iron powder as a suitable option for burning in combustion processes and in the iron energy carrier cycle, enabling good energy conversion while minimizing environmental impacts. Novelty and Significance StatementThis study includes the first-ever measurements of nanoparticles and NOx formation during iron powder combustion at different input equivalence ratios and oxygen concentrations using a practical lab-scale burner. The concept can be adapted for commercial and industrial uses in heating and power. Furthermore, the findings of this study can be used to determine the optimum conditions for low emissions with a self-sustainable stationary flame during iron powder combustion, providing valuable insights into the combustion characteristics of iron powder and offering practical guidance for optimizing its combustion processes in the iron energy carrier cycle.

A preliminary study of combustion flame by digital image processing and residue for fireworks flash powder

Fireworks play a vital role in festive celebrations and entertainment. These fireworks industries are administered by the Petroleum and Explosives Safety Organisation (PESO), Nagpur, Government of India. Even though PESO prescribed the standard composition for various fireworks products, concerns persist regarding the potential deviation from these standards, particularly in the pursuit of increased noise levels to attract consumers. This change in the burning and reactive properties of chemicals could potentially lead to accidents and environmental pollution. The current work investigated the combustion characteristics of two unknown market flash powder samples and a PESO standard sample. The samples were openly ignited in a controlled atmosphere, and video recordings of the resulting chemical flames were analyzed to determine fire area, flame intensity, and motion magnitude. The residues were also collected for EDAX and SEM analysis. Fire pixels from video frames are segmented to create a comprehensive database detailing flame area and motion magnitude under different circumstances. From the flame area profile, motion magnitude and SEM/EDAX analysis, it is found that PESO standard sample combustion is better than the unknown flash powder combustion.

In situ preparation of aluminum-copper pentafluorobenzoate energy microspheres: Enhancing aluminum combustion properties in composite propellants

Aluminum powder is the main metal fuel in composite propellants, and upgrading the proportion of aluminum powder loaded in solid propellants is currently one of the most effective means of increasing propellant energy. Nonetheless, the substantial disparity in boiling points between the core aluminum particles and the alumina layer enveloping their surfaces often results in reduced reactivity, inadequate combustion, and combustion agglomeration during the combustion process of the aluminum powder. Herein, copper pentafluorobenzoate (CuPF) interfacial layer was established on the surface of aluminum powder through the self-assembly coordination reaction between pentafluorobenzoic acid and copper ions, and Al-CuPF energy microspheres were successfully prepared. A comprehensive examination was carried out to scrutinize the surface morphology, elemental composition, and distribution of the Al-CuPF energy microspheres. Furthermore, meticulous studies were conducted on the ignition and combustion properties of these Al-CuPF energy microspheres under various atmospheric conditions. It was found that the Al-CuPF interfacial layer within the Al-CuPF energy microspheres plays a pivotal role in enhancing ignition initiation and acting as a catalyst to facilitate the more efficient combustion of aluminum powder. Moreover, the combustion behavior of Al-CuPF energy microspheres when integrated into composite propellants has been exhaustively researched. Notably, composite propellants incorporating Al-CuPF energy microspheres exhibit heightened burning temperatures and an increased burning rate. Additionally, the combustion and agglomeration dynamics of Al-CuPF energy microspheres on the propellant burning surface were meticulously documented using a high-speed camera. The findings revealed that Al-CuPF energy microspheres spend a significantly shorter duration on the propellant burning surface and notably mitigate the occurrence of aluminum agglomeration issues thereon. This research contributes fresh insights into the application of innovative aluminum-based fuels within the realm of composite propellants.

Improved ignition and combustion performance of Al-Zn-Mg ternary alloys by incorporating Mg into Al-Zn alloys

Al-Zn alloys exhibited lower reaction temperature and micro-explosion phenomenon when compared to Al which benefited from the low melting point and boiling point of Zn. To further improve the energetic performance of Al-Zn alloys, Mg with low reaction temperature was originally incorporated into Al-Zn alloys via centrifugal atomization. The addition of Mg results in the production of Mg32(Al,Zn)49 with the low melting point and stepwise oxidation, which can effectively improve the reactivity and combustion. The results show that the prepared Al-Zn-Mg alloys display uniform particle size distribution, regular morphology, and excellent sphericity, which are composed of α-Al and Mg32(Al,Zn)49 compounds. The initiation oxidation temperature of AlZn10Mg5 and AlZn10Mg10 alloy powders is lower than that of AlZn10 alloy powders, and the oxidation efficiency is higher than that of AlZn10 alloys, which may be attributed to the oxidation of Mg32(Al,Zn)49. Adding Mg to the AlZn10 alloy significantly increases the peak pressure and pressurization rate during combustion. In the meanwhile, Al-Zn-Mg alloys burn faster, more intensely, and more completely when compared to AlZn10 alloys. The combustion of the spherical AlZn10Mg10 alloy powders is the most intense visually. It can be ascribed that during the combustion, a large amount of melt and gas breaks through the oxide layer, increasing the contact intimacy between oxygen and the alloy, which can significantly shorten the combustion time. In summary, the spherical AlZn10Mg5 and AlZn10Mg10 alloy powders prepared in this study show promising applications in fuels with high reactivity and better combustion performance.

The Heat Flux Method for hybrid iron–methane–air flames

Recently, a cyclic energy storage concept was proposed involving the use of metal powder as CO2-free energy carrier, known as the metal fuel cycle. In this cycle, the burning of iron powder is considered as the discharge agent of the energy carrier. However, for this cycle to be an efficient one, a better understanding of the laminar burning velocity of iron powder is required. This study presents a newly developed burner based on the Heat Flux Method (HFM), which can measure the burning velocities of flat hybrid iron–methane–air flames. Since laminar iron flames are difficult to stabilize and have – even for micron-sized particles – burning velocities in close proximity to their terminal velocity, methane is used as a stabilizing agent. In this paper, the design of the new burner system is presented with results for burning velocities of iron–methane–air flames. The results show a steady decrease in burning velocity when iron is added to a stoichiometric methane–air flame down to 16 cm/s. It is hypothesized that in the case of relatively low iron concentrations, the iron acts as a heat sink within these flames, consequently reducing the flame temperature and laminar burning velocity. For these low concentrations, methane is the governing fuel. At concentrations above 250 g/m3, the reduction of the burning velocity comes to a halt, and the iron becomes the governing fuel in the flame. A comprehensive error analysis reveals that the primary sources of uncertainty stem from fluctuations in the iron content and parabolic fitting of the thermocouple measurements in the HFM.Novelty and Significance statementThe novelty of this study is a newly developed burner based on the well-known Heat Flux Method (HFM). In accordance with the HFM, a new burner was designed to facilitate stable flat adiabatic hybrid iron–methane–air flames for the first time and measure its key parameter, the adiabatic burning velocity. Further, a metered iron powder dispersion system was developed for accurate iron mass flow measurements. The results show a steady decrease in burning velocity when iron is added to a stoichiometric methane–air flame in relatively low concentrations and show a very weak dependence of the burning velocity on the iron content at iron concentrations above 250 g/m3. These findings enable the validation of 1D simulations for iron-laden flames. A detailed assessment of the measurement uncertainties reveals that the largest source of uncertainty can be derived back to the stability of iron mass flow, leading to small flame propagation fluctuations on relatively short intervals.

Iron as Recyclable Metal Fuel: Unraveling Oxidation Behavior and Cyclization Effects Through Thermogravimetric Analysis, Wide-Angle X-ray Scattering and Mössbauer Spectroscopy.

The carbon-free chemical storage and release of renewable energy is an important task to drastically reduce CO2 emissions. The high specific energy density of iron and its recyclability makes it a promising storage material. Energy release by oxidation with air can be realized by the combustion of micron-sized iron powders in retro-fitted coal fired power plants and in fixed-bed reactors under milder conditions. An experimental parameter study of iron powder oxidation with air was conducted based on thermogravimetric analysis in combination with wide-angle X-ray scattering and Mössbauer spectroscopy. In agreement with literature the oxidation was found to consist of a very fast initial oxidation of the outer particle layer followed by much slower oxidation due to diffusion of iron ions through the Fe2O3/Fe3O4 layer being the rate-limiting step. Scanning electron microscopy analysis of the iron particle before and after oxidation reveal a strong particle morphology transformation. This impact on the reaction was studied by cyclization experiments. Up to 10 oxidation-reduction cycles show that both, oxidation and reduction rates, increase strongly with cycling due to increased porosity.

Decoupling pyrolysis and combustion of organic powders to determine the laminar flame speed

AbstractDetermining the laminar flame speed of dusts is far from straightforward. A strong dependency on the experimental setup and the data treatment's high complexity makes it a true challenge. This work compares three complementary experimental setups to measure the laminar flame speed of organic dust (here, cellulose): a modified Hartmann tube, a 20 L sphere, and a micro‐fluidized bed (MFB) burner. The first two consider the flame propagation phenomenon in its globality, which means that numerous steps are involved simultaneously (particle heating, pyrolysis, oxidation, radiative transfer, flame stretching), while the third one decouples pyrolysis and combustion, to focus mainly on the oxidation rate. An MFB was conceived to generate pyrolysis products and burn them in a laminar flame. Unstretched flame velocities determined with the first two setups were consistent and equal to 22.0 and 26.6 cm ∙ s−1, respectively. Using Silvestrini's equation, values ranging between 14.0 and 33.4 cm ∙ s−1 were obtained according to the dust concentration. With the MFB burner, the flame speed was much higher (135–155 cm ∙ s−1), due to the higher temperature of the fresh mixture and the fact that only the oxidation of the pyrolysis gases is considered. A numerical simulation (Chemkin) confirmed these results since the range 135 to 231 cm ∙ s−1 was obtained for equivalence ratios of 0.6 and 1.2, respectively. The discrepancy between the laminar flame speed determined in the sphere or in the tube and that obtained in the MFB highlights the significant influence of particle heating and pyrolysis during a dust explosion.

Iron powder particles as a clean and sustainable carrier: Investigating their impact on thermal output

The utilization of iron powder as a sustainable energy carrier, conducive to a carbon-free future, has garnered substantial attention due to its commendable attributes such as high energy density, widespread availability, and absence of emissions. To harness its potential optimally, a comprehensive understanding of the combustion behavior of iron powder and the development of corresponding combustion technologies are imperative. This study endeavors to investigate the influence of iron powder particle size, as well as the flow rate of air and iron powder, on the temperature at the exit of the ignition chamber. Experimental trials were conducted utilizing a metal cyclonic combustor (MC2) equipped with a system for feeding iron powder. The findings reveal that an increase in the diameter of iron particles corresponds to an elongation of the path from the ignition chamber to the outlet. Consequently, this elongation induces prolonged ignition delay time and burning duration. Notably, larger particles exhibit enhanced combustion efficiency in comparison to their smaller counterparts. The outcomes demonstrate that particles approximately 50 µm in size achieve an efficiency of 94%, as opposed to 72% for particles below 20 µm. Temperature measurements and spectrometric analysis expose a discernible relationship between particle size and temperature during combustion, elucidating that larger particles yield higher temperatures. Comprehending the intricate correlation between particle size and combustion behavior is crucial for optimizing combustion systems when utilizing iron powder as an energy carrier. By controlling particle size and combustion conditions, the efficiency and efficacy of iron powder combustion processes can be enhanced, thereby contributing to cleaner and more sustainable energy solutions. The implications of this study extend to the enhancement of burner system design and functionality, along with an overall improvement in combustion efficiency. These findings hold significance within the realm of combustion science, presenting opportunities for the development of more sustainable and environmentally friendly energy solutions. Implementing the insights derived from this research empowers researchers to harness the potential of iron powder as an energy carrier, thereby advancing progress toward a greener future through environmentally conscious combustion processes.

IMPACTS of SUPERSONIC and SUBSONIC AMMUNITION on GUNSHOT RESIDUE DISTRIBUTION

In incidents where firearms are involved, the determination of the firing distance is one of the basic steps of the analysis aimed at determining the origin of the incident with Forensic Shot Analysis studies. Shot residues consist of partially burned and unburnt powder grains, gunpowder gas, capsule residues and inorganic and organic residues. As a result of determining the presence and density of shot residues on the target, the distance from which the shot was fired can be determined. The pattern and density of shot residues exhibit a direct correlation with the specifications of firearms and ammunition. The intended use and traits of the weapon affect the properties of the ammunition. An instance of specialised ammunition is subsonic cartridges which have lower powder burn rates and amounts compared to supersonic cartridges. To ensure accurate gunshot residue analysis, gunshot residue density and pattern from reference test-fires are necessary. The key factors affecting the GSR analysis are the type of weapon and ammunition used during test-fires, which should closely match those used in the incident. Any variation in these variables can reduce the precision of the residue analysis. In the study, an independent T-test was applied to determine whether there is a significant difference between the gunshot residue density on the target during test firing of 9×19mm diameter and type Supersonic and Subsonic cartridges with semi-automatic pistols at distances of 0cm, 15cm, 30cm, 60cm and 100cm. It was determined that a significant difference existed between supersonic and subsonic cartridges in the density and patterns of gunshot residue on the target resulting from shots fired at the mentioned distances.

Experimental investigation on synergistic slow oxidation and rapid combustion of micron-sized iron and aluminum powders for energy storage application

The investigation into the individual application of iron and aluminum as carbon-free fuel sources has been extensively explored and holds significant promise. However, there remains a gap in understanding synergistic effects achievable through the blending of these two fuels, as well as a need for comparative analyses between the slow oxidation and rapid combustion processes of these fuels to complement each other. This research proposes blending micron aluminum and iron powders to analyze their slow oxidation and rapid combustion features under diverse atmospheric conditions and heating rates, using thermogravimetric methods, kinetic calculations, and in-flow experiments. The research blending micron iron and aluminum powders to analyze their slow oxidation and rapid combustion features under diverse atmospheric conditions and heating rates, using thermogravimetric methods, kinetic calculations, and in-flow experiments. The findings reveal that the combination of aluminum and iron powders promotes oxidation, resulting in increased weight gain and heat flux rate compared to individual metals. Moreover, the triggering temperature rises from 545 to 652 °C with an increase in aluminum powder content. As heating rates increase, characteristic parameters T1, T2, and Hpeak2, rise for both fuels. However, aluminum powder tends to decrease Ti, while iron powder slightly increases it due to differences in oxide layers. The slow oxidation of aluminum and iron powders conforms to different models, yielding distinct oxidation patterns. The apparent activation energy of aluminum decreases from 258.4 to 238.7 kJ·mol−1 with rising heating rates, while that of iron exhibits a lower increase and remains lower than aluminum providing insights into combustion initiation conditions. Combustion initiation is contingent upon the concentration of metal powder and oxygen, with both aluminum and iron powders combustion being enhanced and subsequently attenuated with increasing excess air ratio. However, due to differing reactivity and surface passivation layers, the excess air ratio required for aluminum powder combustion (1.2–2.4) exceeds that of iron powder (1.3–1.7). The research elucidates the mechanisms underlying the slow oxidation of iron and aluminum fuels, delineates suitable combustion conditions, and furnishes new empirical and theoretical underpinnings for the oxidation characteristics of mixed iron-aluminum fuels, thereby advancing metal-fueled energy storage technologies.

An experimental study on gas-solid two-phase rotating detonation ramjet engine based on aluminum powder fuel

In order to explore the feasibility of solid powder detonation technology, the ground direct connection test of aluminum powder/hydrogen/air fuel detonation engine was carried out in this paper. The experimental results show that hydrogen is needed to achieve detonation combustion of aluminum powder with a diameter of 1 μm. A series of tests were carried out in the range of equivalence ratio of 0.8-1.2. With the increase of equivalence ratio, the mean value of steady pressure, average peak pressure, and average wave velocity of rotating detonation combustion increased first and then decreased gradually, and reached the maximum at the equivalence ratio of 0.9. The maximum propagation frequency of the detonation wave is 2653 Hz, and the average wave velocity is 1667 m/s.

Combustion performance of aluminum modified boron nanoparticles coated with silane coupling agent

Boron (B) powder, with its high mass and volumetric heat values, makes it highly promising in the field of energetic materials. However, the oxide layer on the B surface is the most significant barrier to realizing its full potential as a fuel. How to eliminate or disrupt the oxide layer is currently an urgent problem that needs to be addressed. This study proposes an approach to enhance the combustion of nano-B powder by coating aluminum (Al) onto its surface using a silane coupling agent. The combustion characteristics of Al-modified B powder with different Al contents were investigated through experimental and molecular dynamic simulation methods, and the bidirectional diffusion mechanism on the interfacial layer of modified B particles was revealed. A small amount of Al powder can largely lower the initial oxidation temperature of B powder, increase the maximum flame temperature, and enhance the heat release. However, an excessive amount of Al powder leads to a deterioration in the combustion of B powder but can alter the combustion behavior and suppress the aggregation of B powder during the combustion. Additionally, combination reaction and redox reaction occurring during the combustion of B@Al samples not only reduce the burning time of B powder but also accelerate the flame expansion speed and improve the combustion efficiency. These results lay the foundation for the application of B@Al in the field of energetic materials.

Experimental Investigation on Oxy-Hydrogen Gas Flame Injecting Coal Powder Gasification and Combustion

Hydrogen energy is an important carrier for energy terminals to achieve green and low-carbon transformation. Hydrogen, as a carbon-free fuel, has great research and development value in the field of thermal power generation. This article proposes a solution for the stable combustion of coal powder using Oxy-hydrogen Gas ignition technology. An Oxy-hydrogen Gas flame injection coal powder combustion testing device was constructed to experimentally study the temperature distribution in the combustion chamber under Oxy-hydrogen Gas ignition technology, with primary air coal powder concentrations of 0.27, 0.32, and 0.36 (kg coal powder/kg air), as well as the concentration changes of volatile CO emissions during the ignition of coal powder using both Oxy-hydrogen Gas and CH4 flames. The sensitivity of the NO generation during coal gasification combustion under the Oxy-hydrogen Gas ignition was simulated and analyzed. The results show that at a coal powder concentration of 0.32 (kg coal/kg air) and an Oxy-hydrogen Gas flow rate of 2.1 L/min, the combustion effect of coal powder is the best, and the highest combustion chamber temperature can reach 1156 K; when the concentration of coal powder varies within a range from 0.32 to 0.27, the combustion chamber temperature can be maintained at around 850K, achieving stable combustion conditions for coal powder. The only product generated by the Oxy-hydrogen Gas combustion is high-temperature water vapor, which helps the rapid gasification of coal powder and releases a large amount of volatile CO, which is beneficial for the ignition and stable combustion of coal powder.

A parameter determination method of powder burn model based on Levenberg-Marquardt optimization

ABSTRACT The powder burn model is a mathematical model used to characterize the combustion behavior of energetic materials. In this paper, a parameter determination method for the powder burn model is proposed based on the Levenberg-Marquardt (L-M) optimization algorithm, establishing connections between internal ballistics parameters and powder burn model parameters. Taking a 4/1 single-base propellant as an example, the detailed fitting process is presented, and error analysis is conducted. The fittings of the gas state equation and reaction rate equation of powder burn model converge at the 15th and 22nd iterations, respectively. Both fittings displayed a high level of accuracy, with an R-squared value of 0.999. The comparison with the results of the closed bomb experiments demonstrates excellent agreement between pressure-time curves calculated by the powder burn model and the internal ballistics model, confirming their suitability for describing the combustion behavior of propellants. This method provides a foundation for numerically simulating the internal ballistics combustion behavior of energetic materials.

“The Smoking Gun” Evidence in the Tragic Death of Vincent Van Gogh

It has been widely accepted in the past that Vincent Van Gogh died of a self-inflicted gunshot wound in a field outside of Auvers-sur-Oise, France. However, much of the new evidence points to another theory: Van Gogh didn’t kill himself but was murdered. The updated forensic research into this cold case is significant for the art community and art historians interested in the truth. Interviews, letters, and records were compiled and reviewed in detail, including evidence regarding the potential weapon and possible persons of interest. Van Gogh’s wound was described as pea sized, surrounded by discoloration with no exit wound or powder burn. The records of these details have been reviewed by a forensic pathologist, who concluded the unlikelihood of self-infliction. No potentially related gun, bullet, or other weapon were found immediately following his death. However, 60 years later a rusted and significantly damaged non-functioning Lefaucheux pinfire revolver was found in a wheat field, coincidentally and somewhat suspiciously, as the movie, LUST FOR LIFE, was being filmed on site. Whether this weapon, recently auctioned for approximately $183,000 USD, was related to his death is debated. Further investigation by a qualified gunsmith or forensic firearms examiner needs to be undertaken to determine if this gun was actually functional when it was “dropped” in the field or placed there to create additional buzz for BIG budget Hollywood production. Vincent van Gogh was allegedly shot in the abdomen on July 27, 1890, allegedly as critically there is no definitive evidence to support a gunshot wound. There is no smoking gun in evidence, no bullet, no suicide note, no exit wound, no black powder, no autopsy, no known crime scene, no witnesses, and no solid evidence of any kind to support a gun shot. All that is known for certain is that he sustained a penetrating wound to his abdomen. All one has to go on to make any kind of forensic analysis, or even confirm the possibility of a gunshot wound, is a description of the wound 26 years later.

Physico-chemical analysis and characterization of the flammability of metallic powders

When fine particles known as flammable powders are suspended in the air under specific circumstances, they have the potential to explode. There could be many serious fatalities, injuries, and structural damage as a result of a dust explosion. By being aware of the flammability parameters and the physico-chemical analysis for flammable powders and taking additional protective measures as a result of the occurrence of these kinds of catastrophic mixes, the risk of such incidents can be decreased. The goal of this study was to determine the flammability characteristics of two combustible powders, magnesium and aluminum powder. These characteristics included the lowest ignition temperature of the dust cloud and dust layer as well as certain physicochemical studies of the composition.

Research on Pollutant Emission Characteristics of Typical Biomass-fired Boilers

The combustion of biomass fuel boilers not only produces inorganic pollutants such as carbon oxides, nitrogen oxides, sulfur compounds, but also organic pollutants such as VOCs and PAHs, which directly affect the global biogeochemical cycle and atmospheric changes. Compared with foreign countries, there is relatively less research and related standards on the emission of organic pollutants from biomass fuel boilers in China. Therefore, it is necessary to study the emission characteristics of organic pollutants from biomass boilers, which can provide reference for the establishment of organic pollutant emission standards for biomass fuel boilers in China.The emission characteristics of volatile organic compounds(VOCs) and polycyclic aromatic hydrocarbons(PAHs) organic pollutants in the flue gas of three typical biomass-fired boilers in Chongqing were studied, and the emission concentrations of particulate matter, sulfur dioxides(SO2), and nitrogen oxides(NOX) were measured.The results show that the sulfur dioxide emissions from the three types of biomass-fired boilersrs are lower than the local standards in Chongqing, while nitrogen oxides and particulate matter have a phenomenon of exceeding the emission limits of the local standards in Chongqing. The main components of VOCs emitted from biomass powder and biomass particle combustion are OVOCs and aromatic hydrocarbons, while the main components of VOCs emitted from wood biomass combustion are alkynes. The gas-solid distribution pattern of PAHs during the combustion of three types of biomass is basically consistent. Low ring PAHs are mainly enriched in the gas phase, while medium and high ring PAHs are mainly enriched in particulate matter.

Experimental investigation on the self-ignition behavior of dangerous dust accumulations

A process known as spontaneous combustion is brought on by the gradual oxidation of flammable organic particles and takes place when air passes over a mass of dust. Combustible powders react with air oxygen in a process known as oxidation, which produces carbon dioxide, carbon oxide, water, and other gases whose contents depend on the temperature at which the oxidation occurs. Combustible dusts can self-ignite depending on their chemical makeup, the characteristics of their constituent components, the particle size and mass geometry, and last but not least, the ambient temperature. Self-ignition is a complicated process that occurs in three subsequent or concurrent stages of development, namely self-heating, humidity evaporation, and self-ignition. Self-ignition is a complicated process that occurs in three separate or concurrent stages of development, namely self-heating, humidity evaporation and self-ignition, all of which interact with one another. Even at normal temperatures, the molecules on the surface of combustible dust particles are prone to exothermic interactions with oxygen in the air conveyed in the free volume between particles, which is the cause of self-heating (or possibly self-ignition). The temperature of the reactive-air dust system will then rise as a result of any heat emitted, hastening the reactivity of other dust molecules with oxygen. By using drying tests at constant temperatures, this work aims to demonstrate the self-ignition behavior of flammable dusts by volume.