Coal Combustion Research Articles

Strategic control of combustion-induced ammonia emissions: A key initiative for substantial PM2.5 reduction in Tianjin, North China Plain

Information on the temporal and spatial variations in the sources of ammonium salts (NH4+), a crucial alkaline component in PM2.5, is limited. Here, we simultaneously collected PM2.5 and gaseous ammonia (NH3) samples in both summer and winter from two sites in Tianjin: an urban site (Tianjin University, TJU) and a suburban site (Binhai New-region, BH). NH3 concentrations, the contents of major water-soluble inorganic ions in PM2.5, and the compositions of ammonium‑nitrogen isotopes (δ15N-NH4+) were measured. As a result, (NH4)2SO4 and NH4NO3 were the predominant forms of NH4+ in PM2.5 during summer and winter, respectively. However, the NH4NO3 concentrations were notably greater at TJU (6.2 ± 7.3 μg m−3) than at BH (3.8 ± 4.7 μg m−3) in summer, with no regional differences observed in winter. Both sites displayed almost half the contribution of c-NH3 (combustion-related NH3) to NH4+, differing from the finding of previous isotope-based studies. This discrepancy could be attributed to the combined effects of NHx isotope fractionation and seasonal δ15N value variations in NH3 sources. The contribution fractions of v-NH3 (volatile NH3) and c-NH3 exhibited similar patterns at both sites seasonally, probably caused by coal combustion for heating in winter and temperature fluctuations. However, the contribution fraction of c-NH3 was lower at BH than at TJU in summer but greater in winter than at TJU. In summer, NH4NO3 was unstable and limited its delivery to TJU from BH, and the high contribution of c-NH3 to NH4+ at TJU could be attributed to local vehicle emissions. In winter, the stable particulate NH4NO3 that formed from the c-NH3 in the upwind area could be transported to the downwind area, increasing the NH4+ concentration at BH. Our study provides valuable insights for devising emission mitigation strategies to alleviate the increasing burden of NH3 in the local atmosphere.

Comprehensive review on fly ash: Turning waste into a valuable resource for sustainable development

Fly ash, a byproduct of coal combustion in the power plants has long been viewed as a waste material with potential environmental hazards. However, in recent years, there has been a paradigm shift in the perception of fly ash, as it is increasingly recognized as a valuable resource with numerous applications in field of construction, agriculture, and environmental remediation. This Paper explores the various facets of fly ash and the diverse ways in which it is being harnessed for sustainable development for the society.

Influence of composite chloride salt retardant on the characteristics of coal spontaneous combustion and comprehensive evaluation methodology

ABSTRACT In this study, we aimed to improve the efficacy and longevity of single inhibitors. NaCl, CaCl2, MgCl2, and layered double hydroxides (LDHs) were selected as the inhibitory components for experimental study. The impact of the composite inhibitors on the spontaneous combustion characteristics of the coal was studied through temperature programmed experiment, thermal analysis experiments, thermogravimetric mass spectrometry and entropy weight method, and the optimal inhibitor was determined. The findings indicate that the apparent activation energy (E a ) of the coal sample, with the addition of inhibitors during the oxidation stage, was improved. E a of MgCl2 +1.0 LDHs + Coal was the highest (127.28 kJ/mol), i.e. 35.99 kJ/mol higher than that of the original coal. The inclusion of the inhibitor increased the characteristic ignition temperatures of the coal samples compared with the original coal. The highest ignition temperature was observed for MgCl2 +0.5 LDHs + Coal, reaching (323.98°C), i.e. 11.42°C higher than that of the original coal. The addition of inhibitors significantly inhibited the production of CO. Among the three chloride salts, MgCl2 exhibited the strongest inhibitory effect on CO production. According to the entropy weight method, MgCl2 +0.5 LDHs showed the best inhibitory effect. The results show that the composite halogen inhibitor can effectively inhibit the spontaneous combustion of coal.

Exploring the Tar Component Characteristics of Coalfield Fire Residual Coal Under Different Constant Temperature Oxidation

ABSTRACT Due to incomplete combustion of coal, a large amount of tar will be produced in coal fire area, which will cause serious pollution to the environment. In this paper, we dissolve the tar components in the residual coal by solvent extraction technique, analyze the organic components in the residual coal tar at different temperatures by GC-MS, study the characteristics of the residual coal tar components at different temperatures, and analyze the influence of the residual coal tar on the combustion and rekindling characteristics of the fire zone of the coalfield. The results show that: the components of coal combustion residual tar are mainly alkane organics which are easy to be oxidized and volatilized, and the content is more than 55%. At 300°C, the color of residual tar extract is light yellow or yellowish brown, and becomes colorless with the increase of temperature. At 300–500°C, the lower the temperature in the fire zone, the more residual tar in the coal, and the greater the risk of reignition in the extinguishing fire zone. The types of organic compounds in the tar residue from combustion have obvious characteristics at different temperature stages. Organic species have obvious characteristics at different temperature stages. By identifying the temperature stage of the coalfield fire area development, the organic structure characteristics and change trend of the residual coal tar can be deduced, and mastering the organic structure characteristics of the residual tar in the coalfield fire area can also reflect the temperature stage of coal fire area to a certain extent.

Influence of fly-ash filler and moisture content on vibrational and acoustic properties of basalt fibre reinforced composites

ABSTRACT Fly ash, a by-product of coal combustion consisting of particulates and flue gases expelled from coal-fired furnaces, has found application as a substitute for organic fillers in the composites industry. In this study, the focus lies on assessing the vibrational and acoustic performance of composites composed of epoxy-based basalt combined with fly ash. Experimental investigations were carried out on specimens containing different weight percentages of fly ash (0%, 10%, 15% and 20% of the epoxy weight) to evaluate free vibration and acoustic impedance. Additionally, the impact of moisture on the vibrational and acoustic properties of Basalt/Fly ash-Epoxy composites was examined by subjecting the specimens to 3 months of ageing in distiled water. The results revealed that increasing the filler content up to 15% led to an increase in natural frequencies (8.5 Hz) and stiffness (3.8 N/mm) of the material, although the damping ratio (0.219) has decreased. Notably, as the specimens aged, the damping ratio is improved by 9%, while the natural frequency and stiffness decline by 9.67% and 12.5%, respectively. The material density emerged as a critical factor influencing the sound absorption capability of the specimens. The inclusion of fly ash in the epoxy matrix has enhanced the acoustic properties of the tested specimens.

Long-Term and Seasonal Changes in Emission Sources of Atmospheric Particulate-Bound Pyrene and 1-Nitropyrene in Four Selected Cities in the Western Pacific

Abstract: Estimating the source contribution to polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in the atmosphere is necessary for developing effective disease control and pollution control measures. The NPAH-PAH combination method (NP method) was used to elucidate the contributions of vehicles and coal/biomass combustion to seasonal and long-term urban atmospheric particulate matter (PM)-bound Pyr and 1-NP concentrations in Kanazawa, Kitakyushu, Shenyang and Shanghai in the Western Pacific region from 1997 to 2021. Among the four cities, Kanazawa demonstrated the lowest Pyr concentration. The contribution of vehicles to Pyr before and after 2010 was 35% and 5%, respectively. The 1-NP concentration was reduced by a factor of more than 1/10. These changes can be attributed to the emission control from vehicles. Kitakyushu revealed the second-lowest Pyr and the lowest 1-NP concentrations. Coal combustion was found to be the main contributor to Pyr, while its contribution to 1-NP increased from 9% to 19%. The large contribution of coal combustion is attributed to iron manufacturers. Shenyang demonstrated the highest atmospheric Pyr concentration with its largest seasonal change. Vehicles are the largest contributors to 1-NP. However, coal combustion, including winter coal heating, contributed 97% or more to Pyr and more than 14% to 1-NP. Shanghai revealed the second-highest Pyr and 1-NP concentrations, but the former was substantially lower than that in Shenyang. Coal combustion was the major contributor, but the contribution of vehicles to Pyr was larger before 2010, which was similar to Kanazawa.

Hydraulic conductivity of bentonite-polymer geosynthetic clay liners to aggressive solid waste leachates

Hydraulic conductivity of conventional mock sodium bentonite (Na–B) and bentonite-polymer (B–P) geosynthetic clay liners (GCLs) were evaluated with three synthetic leachates that are chemically representative of aggressive leachates from coal combustion product (CCR) (I = 3179 mM), mining waste (MW) (I = 2127 mM, pH = 2.0), and municipal solid waste incineration ash landfill (MSWI) (I = 2590 mM). The mock B–P GCLs were created by dry mixing bentonite with branched, linear, or crosslinked polymer. The polymer loading of mock B–P GCLs ranged from 3 to 15%. Comparative tests were also conducted with Na–B GCLs. The mock Na–B GCLs cannot maintain low hydraulic conductivity to aggressive CCR, MW, and MSWI leachates. Mock B–P GCLs with 10% branched polymer had low hydraulic conductivity (< 1.0 × 10−10 m/s) to synthetic MW and MSWI leachates at 20 kPa effective confining stress, whereas the hydraulic conductivity of mock B–P GCLs with 10% linear or crosslinked polymer ranged from 1.5 × 10−9 to 1.4 × 10−7 m/s. As the effective stress increased, the B–P GCLs branched polymer showed a faster decreasing trend than that of Na–B and B–P GCLs with linear or crosslinked polymer.

Measurement report: Optical characterization, seasonality, and sources of brown carbon in fine aerosols from Tianjin, North China: year-round observations

Abstract. To investigate the optical characteristics and sources of brown carbon (BrC) in North China, where the atmospheric aerosol loadings are high and have severe impacts on Earth's climate system, we collected fine aerosols (PM2.5) at an urban site in Tianjin over a 1-year period. We measured the ultraviolet (UV) light absorption and excitation emission matrix (EEM) fluorescence of the water-soluble BrC (WSBrC) and the water-insoluble but methanol-soluble BrC (WI-MSBrC) in the PM2.5 using a three-dimensional fluorescence spectrometer. The average light absorption efficiency of both WSBrC (Abs365, WSBrC) and WI-MSBrC (Abs365, WI-MSBrC) at 365 nm was found to be highest in winter (10.4 ± 6.76 and 10.0 ± 5.13 Mm−1, respectively) and distinct from season to season. The averages of the fluorescence index (FI) and the biological index (BIX) of WSBrC were lower in summer than in the other seasons and opposite to that of the humification index (HIX), which implied that the secondary formation and further chemical processing of aerosols were more intensive during the summer period than in the other seasons. However, in winter, the higher HIX together with the higher FI and BIX of WI-MSBrC suggested that the BrC loading was mainly influenced by primary emissions from biomass burning and coal combustion. Based on the EEM, the types of fluorophores in WSBrC were divided into humic-like substances (HULIS), including low-oxygenated and high-oxygenated species and protein-like compounds (PLOM), though mostly PLOM in the WI-MSBrC. The direct radiation absorption by both WSBrC and WI-MSBrC in the range of 300–400 nm accounted for ∼ 40 % of that (SFEAbs, 4.97 ± 2.71 and 7.58 ± 5.75 W g−1, respectively) in the range 300–700 nm.

Ash Properties and Environmental Impact of Coal and Its Blend with Patent Fuel for Climate Sustainability

Fossil fuels are still widely used today, and exploring more sustainable ways of using coal is crucial. One promising approach is to develop a patented fuel with reduced harmful gas emissions during combustion. This study aims to investigate the properties of the ash produced by burning steam coal mixed with various ratios of patent fuel. The combustion process was carried out using a standard solid fuel boiler with a power output of 70 kW. The ash samples were analyzed using various analytical methods, and ash leaching tests were conducted. The study found that adding patent fuel to coal affects combustion and ash composition. Determining the thermal stability of ash samples showed that adding patent fuel to coal results in decomposition starting earlier and in stronger combustion. The ash produced by patent fuel–coal mixtures contains lower concentrations of Ba, Cr, Ga, Li, Mn, V, and Zn than pure coal combustion. Leaching tests showed that coal ash leachates had higher concentrations of environmental pollutants, such as As, Cd, Co, Mn, Mo, Sb, and U, than patent fuel leachates. Adding patent fuel to coal affects combustion, ash properties, emissions, and disposal. Understanding these implications can help to develop sustainable coal usage and reduce environmental impact.

Study on detonation characteristics of pulverized coal and evolution law of detonation residue

This study explores the detonation characteristics and compositional changes of pulverized coal, focusing on its use in Rotary Detonation Wave (RDW) technologies. While pulverized coal has shown high fuel efficiency in RDW settings, transitioning from theory to practical detonation engineering presents substantial scientific and technical hurdles. A key issue is the reprocessing of detonation byproducts for in-situ coal mine gob filling, a topic that has received little attention. Utilizing advanced methods like X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR), this paper investigates the micro-morphology, composition, and aromatic structures of gas–solid products pre and post-detonation at the Tashan Coal Mine's 2305 working face. Results indicate that coal dust from the underground mining face has enhanced detonation characteristics, with the addition of coal powder fuel extending the gas detonation limits. This benefits economic aspects by reducing reliance on gas fuel and lowering detonation fuel costs. The highest recorded detonation wave velocity was 2450 m/s, 14.8% greater than that of coal dust from external sources, suggesting more effective energy release and pressure gain. Furthermore, the study links detonation combustion intensity to coal's aromatic properties, noting a post-detonation aromaticity index (I) of 0.4941. This indicates an improvement in the aromatic structure under high-temperature conditions, vital for coal's reactivity and energy efficiency in RDW applications. This research not only deepens the understanding of coal dust combustion mechanisms but also advances clean coal utilization and deep coal fluidization mining, addressing significant RDW technological challenges.

Uncovering sources, distribution, and seasonal patterns of trace element deposition: the elemental puzzle of the western Himalayas.

The transport and deposition of atmospheric pollutants in the Himalayas have a adverse impact on the climate, cryosphere, ecosystem, and monsoon patterns. Unfortunately, there is a insufficiency of data on trace element concentrations and behaviors in the high-altitude Himalayan region, leading to limited research in this area. This study presents a comprehensive and detailed comprehension of trace element deposition, its spatial distribution, seasonal variations, and anthropogenic signals in the high-altitude Kashmir region of the Western Himalayas. Our investigation involved the analysis of 10 trace elements (Al, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb) in glacier ice, snow pits, surface snow, and rainwater collected at various sites including Kolahoi, Thajwas, Pahalgam (Greater Himalayan ranges), and Kongdori and Shopian (Pir Panjal Ranges) during 2021.The study reveals distinct ranges of concentrations for the trace elements at different sampling sites. Our analysis of trace element concentration depth profiles in snow pits reveals seasonal fluctuations during the deposition year. The highest concentrations were found in the autumn(below 20cm) and summer (top layer), compared to the winter concentration (10-20cm). The high enrichment factors (EFs) suggest the severity of human-induced trace metal deposition in the western Himalayan region, relative to surrounding regions. Surprisingly, the concentrations and EFs of trace elements showed seasonal contradictions, with lower concentration values and higher EFs during the non-monsoon season and vice versa. A source apportionment analysis using the positive matrix factorization (PMF) technique identified five sources of trace element deposition in the region, including crustal sources (32.33%), coal combustion (15.62%), biomass burning (17.63%), traffic emission (18.8%), and industrial sources (15.6%). Additionally, the study incorporated backward trajectories coupled with δ18O using the NOAA HYSPLIT model to estimate moisture sources in the region, which suggests atmospheric pollutants predominately deposited from the large-scale atmospheric circulation from westerlies (75%) during non-monsoon season. These findings underscore the urgent need for enhanced monitoring and research efforts in the future.

Experimental and mesoscopic simulation study of size effect on splitting tensile performance of spontaneous combustion coal gangue concrete

The spontaneous-combustion coal gangue concrete (SCGAC) demonstrates different mechanical behavior compared to ordinary concrete owing to its distinct porous structure and the presence of fibrous materials in its coarse aggregates. Presently, research on the macroscopic mechanical properties of SCGAC is reasonably comprehensive; however, it falls short of fully understanding its size effect. This study examines the splitting tensile strength of cubic SCGAC specimens with three strength grades, i.e., C30, C35, and C40, and three sizes, i.e., 100 mm, 150 mm, and 200 mm; proposes a mesoscopic modeling approach based on the computer vision; analyzes the intrinsic mechanisms of splitting failure and the size effect of different strength grades on the SCGAC by utilizing mesoscopic simulation methods. Subsequently, an analysis of the size effect on the splitting tensile strength of SCGAC is conducted based on classical size effect laws. The results reveal the following: The method proposed in this study for mesoscopic modeling is recognized for its low cost, high efficiency, and accurate simulations, fulfilling the required standards for mesoscopic mechanical analysis. SCGAC, as a heterogeneous material, demonstrates significant size effect phenomena that become more pronounced with enhancements in strength grades. The Carpinter fractal size effect law is ideally suited to characterize the size effect patterns in SCGAC. This paper enhances the comprehension of the size effect of SCGAC through a combination of macroscopic experiments and mesoscopic simulations, thereby facilitating its engineering applications.

Numerical modeling of hydrodynamics of spouted bed in solid fuel boiler

The issues of numerical modeling of hydrodynamics of a spouted fuel bed in the furnace of a solid-fuel boiler are considered. At present, solid-fuel boilers are widely used in the power industry of the Russian Federation, with the share of coal-fired generation to remain significant in the projected terms. Therefore, the study of the efficiency of thermal and hydrodynamic processes that ensure the implementation of clean coal technologies is a relevant task both today and in the long term. The article presents the following main stages of numerical modelling of the hydrodynamics of the spouted bed: problem formulation with selection of boundary and initial conditions, methods of solving the Navier-Stokes and continuity equations for the air flow, Newton's equations and diffusion equations for particles. The k-omega turbulence model was used in the calculations that is described by means of two partial differential equations for the variables k (kinetic energy of turbulence) and omega (specific dissipation rate). A comparative analysis of environmental advantages and disadvantages of existing methods of combustion of low-grade coal in schemes with in-cycle gasification (ICG) is carried out. Advantages and difficulties of switching to structures with CFB in the spouted bed mode are shown. Numerical modeling of the cold spouted bed created by means of particle injection is performed, a set of initial settings and boundary conditions is presented, the adequacy of the obtained results is verified by hydrodynamic characteristics of the isothermal process. The obtained results allow us to proceed to the next stages with non-isothermal models, with heat exchange and combustion reactions in the spouted bed of coal taken into account. The following refinement of the physical model will allow to achieve more accurate and reliable results and to ensure their correct scaling.

Evaluation of the applicability of carbon-based materials for arsenic removal from flue gases

Arsenic is an highly toxic element which may be released into the atmosphere during the combustion of solid fuels. This paper verifies the possibility of using char from tires CT and lignite dust LD as materials for the adsorption of gaseous forms of As. The source of the gaseous forms of arsenic was coal combustion under laboratory conditions. Adsorption tests included both different sorbent bed temperatures (120–180°C) and various flue gas compositions (resulting from the combustion of bituminous and lignite coals). It was shown that sorption temperature did not affect the arsenic removal efficiency for both analysed sorbents. The average As removal efficiency for tire char and lignite dust was 88 and 92%, respectively. The composition of the burned coal, and thus the composition of the flue gas, significantly influences the efficiency of Asgas adsorption. While for LD the level of As removal was still high (more the 90%), the sorption of Asgas by tire char from the flue gas when lignite was burned was less effective (the efficiency was below 80%). It was additionally indicated via a leachability test that "used" CT could be safely disposed of while LD would require appropriate management. Based on the comparison of the performance of CT and LD with commercial AC activated carbon and the differences in their market price, it can be concluded that the studied alternative sorbents are competitive with AC.

Study on the Explosion Characteristics of CH4 with the Addition of Coal Spontaneous Combustion Gases

Study on the Explosion Characteristics of CH₄ with the Addition of Coal Spontaneous Combustion Gases

Assessment of the surface water quality and primary health risk in urban wastewater and its receiving river Kathajodi, Cuttack of eastern India.

Kathajodi, the principal southern distributary of the Mahanadi River, is the vital source of irrigation and domestic water use for densely populated Cuttack city which receives anthropogenic wastes abundantly. This study assesses the contamination level and primary health status of urban wastewater, and its receiving river Kathajodi based on the physicochemical quality indices employing inductively coupled plasma mass spectroscopy and aligning with guidelines from the United States Environmental Protection Agency (USEPA) and WHO. The high WQI, HPI, and HEI in the catchment area (KJ2, KJ3, and KJ4) indicate poor water quality due to the influx of domestic waste through the primary drainage system and effluents of healthcare units. A high BOD (4.33-19.66mg L-1) in the catchment indicates high organic matter, animal waste, bacteriological contamination, and low DO, resulting in deterioration of water quality. CR values beyond limits (1.00E - 06 to 1.00E - 04) in three locations of catchment due to higher Cd, Pb, and As indicate significant carcinogenic risk, while high Mn, Cu, and Al content is responsible for several non-carcinogenic ailments and arsenic-induced physiological disorders. The elevated heavy metals Cd, Cu, Fe, Mn, Ni, and Zn, in Kathajodi, could be due to heavy coal combustion, vehicle exhaust, and industrial waste. On the other hand, Cu, Fe, K, and Al could be from agricultural practices, weathered rocks, and crustal materials. Positive significant (p ≤ 0.05) Pearson correlations between physicochemical parameters indicate their common anthropogenic origin and similar chemical characteristics. A strong correlation of PCA between elements and physiological parameters indicates their role in water quality deterioration. Assessing the surface water quality and heavy metal contents from this study will offer critical data to policymakers for monitoring and managing public health concerns.

Phytoremediation of radium contaminated soils: recent advances and prospects

Abstract Radioactive radium (Ra) mainly comes from the mining and milling of uranium and other metal or non-metal mines, phosphate production and fertilizer use, production of oil and gas, coal combustion, wastewater treatment, and various wastes from the above activities, which is ubiquitous in the environment. Phytoremediation is a green and cheap remediation technology for metal/radionuclide-contaminated sites. Radium is often of particular interest and there are many literatures on parameters of Ra concentration in plants and transfer factors from soil to plant from a radiological impact assessment point of view. However, review articles on phytoremediation of Ra-polluted soil are relatively few. This review focused on radium-polluted soil phytoremediation, involving two main strategies of phytoextraction and phytostabilization, which covered the potential (hyper)accumulators for Ra, characteristics of Ra uptake from soil by plants, influencing factors, and phytostabilization application. In future research works, more attention should be paid to the deep insights and mechanism researches of Ra uptake/immobilization by plants. This review will deepen the understanding of the relationship of radium-soil-plants, and to enhance the potential application of phytoremediation as an alternative treatment technology for remediation of Ra-polluted soil site.

Characteristics of Carbon Monoxide and Ethylene Generation in Mine’s Closed Fire Zone and Their Influence on Methane Explosion Limits

Methane explosions often occur during the closure process of mine fire zones, during which the concentration of combustible gases such as monoxide and ethylene produced by coal combustion dynamically changes, which changes the risk of methane explosion. Therefore, studying the gas concentration distribution and methane explosion limits during the process of mine closure is of great significance for disaster prevention and control. In this paper, a three-dimensional physical model of gob was built, and the distribution of monoxide and ethylene in the process of fire zone closure was investigated. Further, the explosion limits of methane enriched with CO and C2H4 in the closed fire zone of gob were analyzed. The results indicate that CO and C2H4 would form a small-scale accumulation phenomenon near the fire zone after the closure of the fire zone, and when the fire zone is closed for more than 15 min, the mixed combustible gases in the environment lose their explosiveness.

PM2.5 exposure contributes to anxiety and depression-like behaviors via phenyl-containing compounds interfering with dopamine receptor

As a global problem, fine particulate matter (PM2.5) really needs local fixes. Considering the increasing epidemiological relevance to anxiety and depression but inconsistent toxicological results, the most important question is to clarify whether and how PM2.5 causally contributes to these mental disorders and which components are the most dangerous for crucial mitigation in a particular place. In the present study, we chronically subjected male mice to a real-world PM2.5 exposure system throughout the winter heating period in a coal combustion area and revealed that PM2.5 caused anxiety and depression-like behaviors in adults such as restricted activity, diminished exploratory interest, enhanced repetitive stereotypy, and elevated acquired immobility, through behavioral tests including open field, elevated plus maze, marble-burying, and forced swimming tests. Importantly, we found that dopamine signaling was perturbed using mRNA transcriptional profile and bioinformatics analysis, with Drd1 as a potential target. Subsequently, we developed the Drd1 expression-directed multifraction isolating and nontarget identifying framework and identified a total of 209 compounds in PM2.5 organic extracts capable of reducing Drd1 expression. Furthermore, by applying hierarchical characteristic fragment analysis and molecular docking and dynamics simulation, we clarified that phenyl-containing compounds competitively bound to DRD1 and interfered with dopamine signaling, thereby contributing to mental disorders. Taken together, this work provides experimental evidence for researchers and clinicians to identify hazardous factors in PM2.5 and prevent adverse health outcomes and for local governments and municipalities to control source emissions for diminishing specific disease burdens.

Dynamic prediction of high-temperature points in longwall gobs under a multi-field coupling framework

Spontaneous coal combustion (SCC) in longwall gobs is a serious disaster and requires prediction tools to accurately and reliably predict the temperature in gobs, but currently, there has been a lack of simple and efficient predictors. To address this issue, the temperature distributions in a longwall gob under different mining state parameters were simulated using a multi-fields coupled model. The temperature distribution and the mining state parameters were extracted to serve as input variables for prediction. Two machine learning models, integrating parameter optimization and ensemble learning strategies, respectively, were proposed to establish the functional relationships between the dynamic change boundary temperature and the maximum temperature in the gob. The results show that these two models have good prediction accuracy on the high-temperature points in longwall gobs, indicating that the ensemble learning has improved prediction accuracy. There is a positive correlation between the number of measuring points and the prediction accuracy, and three measurement points at the key locations can deliver reliable predictive performance.