Soil Columns Research Articles

A comparison of ground motions predicted through one-dimensional site response analyses and three-dimensional wave propagation simulations at regional scales

One-dimensional (1D) site response analysis (SRA), which considers vertically propagating seismic waves from the bedrock to the surface, has been a common technique among geotechnical engineers to examine site-specific ground shaking. However, observations from past earthquakes and analytical studies indicate that idealizations ingrained in 1D SRA may be too severe to capture the ground truth, such as the omissions of spatial variability of soil properties, surface topography, and basin and directivity effects. Physics-based three-dimensional ground motion simulations (GMSs) can incorporate these factors and yield more reliable predictions. In this study, we utilize ground motions from 57 physics-based broadband (from 0 to 8–12 Hz) GMS for a region of Istanbul. A total of 2912 sites with experimentally measured soil profiles that are distributed over the 30 km-by-12.5 km area are also modeled as soil columns and analyzed through 1D SRA. The ground responses from 1D SRA and three-dimensional (3D) GMS are then compared for all 57 earthquake scenarios. These systematic comparisons are then used for examining model features that are correlated with variations in the ratios of various ground motion intensity measures (IMs) and for developing regression-based formulas that can be used for determining simple factors for the considered region to correctly scale (up or down) the site-specific ground motion intensities obtained from 1D SRA, including peak ground acceleration (PGA), peak ground velocity (PGV), and spectral acceleration ( Sa) values.

Analysis of Factors Affecting Vacuum Formation and Drainage in the Siphon-Vacuum Drainage Method for Marine Reclamation

Traditional drainage methods for marine reclamation typically consume large amounts of energy and have a negative environmental impact. The siphon-vacuum drainage method (SVD) automatically forms a vacuum and drains using less energy. It has significant potential for research and application. In this study, a theoretical model is used to calculate the vacuum formation process and drainage rate. Qualitative analysis and global sensitivity analysis were conducted to investigate the effect of various factors in the SVD on vacuum formation and drainage. The qualitative analysis suggests that modifying the length and diameter of the siphon pipe and the thickness of the sealing soil column to increase the siphon rate can improve the vacuum degree and drainage efficiency. Sobol global sensitivity analysis reveals that the sealing soil column thickness is the main factor affecting the vacuum, with a first-order sensitivity index accounting for up to 79.48%. The impact of cylinder diameter and the local resistance coefficient (0.43%) can be almost neglected. A fitting equation for estimating the maximum achievable vacuum is provided. Calculations show that the vacuum formed by the SVD can reach over 80 kPa. This work can help optimize SVD design and advance environmentally friendly marine reclamation projects.

Interaction of Biochar Addition and Nitrogen Fertilizers on Wheat Production and Nutrient Status in Soil Profiles.

To investigate the responses of crop production and soil profile nutrient status to biochar (BC) application, we conducted a soil column experiment considering two BC addition rates (0.5 and 1.5 wt% of the weight of 0-20 cm topsoil) combined with two nitrogen (N) input levels (low N: 144 kg ha-1, LN; high N: 240 kg ha-1, HN). The results showed that BC application increased the soil pH. The soil pH of the 0-10 cm profile under LN and the 20-40 cm profile under HN were both significantly increased by 0.1-0.2 units after BC addition. Under LN, BC addition significantly increased NH4+-N (17.8-46.9%), total N (15.4-38.4%), and soil organic carbon (19.9-24.0%) in the 0-10 cm profile, but decreased NH4+-N in the 20-30 cm soil profile and NO3--N in the 10-30 cm profile by 13.8-28.5% and 13.0-34.9%, respectively. BC had an increasing effect on the available phosphorus, the contents of which in the 10-20 and 30-40 cm soil profiles under LN and 20-30 cm profile under HN were significantly elevated by 14.1%, 24.0%, and 23.27%, respectively. However, BC exerted no effect on the available potassium in the soil profile. BC had a strong improving effect (15.3%) on the wheat yield, especially the N144 + BC0.5% treatment, which could be compared to the HN treatment, but there was no yield-increasing effect when high N fertilizer was supplied. In summary, BC improved the fertility of agriculture soil (0-20 cm) with wheat. In particular, low N inputs together with an appropriate rate of BC (0.5 wt%) could not only achieve the low inputs but also the high outputs in wheat production. In future study, we will compare the effects of multiple doses of N and BC on soil fertility and crop production.

Transport of nZVI/copper synthesized by green tea extract in Cr(IV)-contaminated soil: modeling study and reduced toxicity.

In this study, nano-zero-valent iron/copper was synthesized by green tea extracts (GT-nZVI/Cu) and produced a stable suspension than nano-zero-valent iron synthesized by green tea extracts (GT-nZVI) injected into Cr(VI)-containing soil column. The equilibrium 1D-CDE model was successfully used to fit the penetration curves of Fe(tot), Fe(aq), and Fe(0) in order to determine the relevant parameters. The hydrodynamic dispersion coefficient of chromium-contaminated soil was 0.401 cm2·h-1, and the pore flow rate was 0.144cm·h-1. The stable C/C0 of Fe(tot), Fe(aq), and Fe(0) in the effluent were retarded to 0.39, 0.79, and 0.11, respectively, compared to a ratio of 1 for the concentration of the tracer Cl- in the effluent to the concentration in the influent. Additionally, the 1D-CDE model describes the migration behavior of Cr(VI) with a high R2 (> 0.97). The obtained blocking coefficients declined gradually with increasing concentration of GT-nZVI/Cu suspension and decreasing concentration of Cr(VI). The content of reduced chromium in the soil decreased from 2.986 to 1.121 after remediation, while the content of more stable oxidizable chromium and residual chromium increased from 2.975 and 20.021 to 16.471 and 27.612. The phytotoxicity test showed that mung bean seeds still had a germination rate of 90% (control of 100%), root length of 29.63mm (control of 35.25mm), and stem length of 17.9cm (control of 18.96cm) after remediation with GT-nZVI/Cu. These indicated that GT-nZVI/Cu was effective in immobilizing Cr(VI) in the soil column and reduced the ecological threat. This study provides an analytical basis and theoretical model for the migration of chromium-contaminated soil in practical application.

Using 7Be and 137Cs for Assessing the Land Stability of Alexandria Region, Egypt

This paper presents an assessment of land stability using fallout environmental radioisotopes 7Be and 137Cs. The measurement of both isotopes was carried out in samples of soil collected from twenty-five sites covering the studied region. At each site, the samples were taken from five consecutive vertical depth levels to show the vertical displacement or compactness of the soil column. The collected samples were carefully transferred for radioactivity measurement at Alexandria University’s Institute of Graduate Studies and Research. A high-resolution gamma-ray spectrometer utilizing high-purity germanium was employed for the measurements. Surface distribution of the radionuclides levels was used to show the studied lands’ stability over the short- and long-term based on the used radionuclides’ nuclear half-life. For short-term (months) stability, 7Be (half-life: 35.5 days) levels showed that about 73% of the area is very low in stability, while the areas that recorded low, moderate, and high stability are at 18%, 4%, and 5%, respectively. For long-term (years) stability, 137Cs (half-life: 30 years) levels showed that about 80% of the areas are very low in stability, while the remaining areas, predicted as 12.8%, 5.6%, and 1.6%, are low, moderate, and high stability, respectively. It is clear that the eastern side of Alexandria is suffering from soil erosion and subsidence; on the other hand, the western side is more stable. Consequently, due to the origin of the soil, the nature of soil geological formations, and the environmental prevailing conditions, Alexandria is found to be more vulnerable to the consequences of sea-level rise and climate change. Therefore, adequate strategic management, including mitigation measures and adaptation, should be planned and implemented.

Flooding by sea and brackish waters enhances mobility of Cd, Zn and Pb from airborne dusts in coastal soils

Sea level rise and extreme weather conditions caused by climatic changes enhance the frequency and length of submersion events in coastal soils, causing deposited airborne dusts to get in contact with marine salts.The behaviour of Cd, Zn and Pb from pedogenetic minerals and from dusts from mining and smelting activities, added to two soils under different agricultural management (arable and grassland) was examined after soil flooding for 1, 7 and 30 days with waters of increasing salinities (0, 4.37, 8.75, 17.25 and 34.5 g L−1). A rain water event following 1 d flooding released an extra amount of metals. Concentration of potentially toxic elements (PTE), pH, dissolved inorganic and organic C were measured in solutions collected by gravity from soil columns. Speciation distribution of leached metals and oversaturation parameters were calculated by Visual Minteq 3.0 and showed that complexation by chloride ions for Cd and fulvic acids for Pb were the drivers of solubilisation, while Zn interacted with both.Results showed that marine salts enhance up to 300 times leaching of Cd, and several times that of Zn and Pb from contaminated soils and that airborne toxic elements are much more mobilized than pedogenic ones. Smelter exhaust metals, particularly Pb, were made more mobile than those in mine tailings (up to 55 against 0.7 ng μg-1 Pb). Soil management strongly also influence mobilization by saline water: much lower amounts were leached from the grassland soil. Soil organic matter quality (DOC and humification) affects the extent of mobilization. The length of the flooding period did not result in coherent time trend patterns for the three metals, probably because of the multiple changes in solution parameters, but leached metals were always highly linearly correlated negatively with pH and positively with DOC.

Unveiling the dynamic of nitrogen through migration and transformation patterns in the groundwater level fluctuation zone of a different hyporheic zone sediment

This study investigates the impact of water levels and soil texture on the migration and transformation of nitrate (NO3−-N) and ammonium (NH4+-N) within a soil column. The concentrations of NO3−-N gradually decreased from an initial concentration of 34.19 ± 0.86 mg/L to 14.33 ± 0.77 mg/L on day 70, exhibiting fluctuations and migration influenced by water levels and soil texture. Higher water levels were associated with decreased NO3−-N concentrations, while lower water levels resulted in increased concentrations. The retention and absorption capacity for NO3−-N were highest in fine sand soil, followed by medium sand and coarse sand, highlighting the significance of soil texture in nitrate movement and retention. The analysis of variance (ANOVA) confirmed statistically significant variations in pH, dissolve oxygen and oxidation–reduction potential across the soil columns (p < 0.05). Fluctuating water levels influenced the migration and transformation of NO3−-N, with distinct patterns observed in different soil textures. Water level fluctuations also impacted the migration and transformation of NH4+-N, with higher water levels associated with increased concentrations and lower water levels resulting in decreased concentrations. Among the soil types considered, medium sand exhibited the highest absorption capacity for NH4+-N. These findings underscore the significant roles of water levels, soil texture, and soil type in the migration, transformation, and absorption of nitrogen compounds within soil columns. The results contribute to a better understanding of nitrogen dynamics under varying water levels and environmental conditions, providing valuable insights into the patterns of nitrogen migration and transformation in small-scale soil column experiments.

Soil environment, carbon and nitrogen cycle functional genes in response to freeze-thaw cycles and biochar

Freeze-thaw cycles (FTCs) are a common phenomenon in seasonal frozen soil areas, which can significantly affect the changes in the soil environment and functional genes of microorganisms. To explore the effect of biochar application on soil carbon and nitrogen cycling under FTCs, an indoor soil column simulation test was used in this study. The experimental setup included different application rates of biochar (0%, 1%, 2%), with the carbon and nitrogen cycle functional genes serving as indicator genes. Real-time fluorescence quantitative PCR technology was employed for analysis. Based on the correlation heat map and redundancy analysis (RDA), the response mechanism of soil environment changes and carbon and nitrogen cycle functional genes before and after FTCs was analyzed. The results revealed that the application of biochar significantly increased soil's water-holding capacity held available nutrients in soil, and increased the ability of environmental change. Due to the influence of soil moisture and aeration, biochar reduced the variation of soil carbon sequestration gene cbbL, cbbM, and nitrogen fixation gene nifH abundance after FTCs. The application of 2 % biochar significantly increased the abundance of the nitrification gene amoA and denitrification gene nirK and enhanced the respiration of soil microorganisms. Soil moisture (SM) is the main environmental factor that determines the abundance changes of the soil carbon sequestration genes cbbL and cbbM. Soil organic matter (SOM), pH, nitrate nitrogen (NO3−-N), and ammonium nitrogen (NH4+-N) were the main environmental factors determining the abundance of soil nitrogen fixation gene nifH, nitrification gene amoA, and denitrification gene nirK. This study can provide new insights into the internal mechanism of the soil carbon and nitrogen cycle in seasonal frozen soil areas, and provide some reference for the rational application of biochar and the efficient utilization of water and soil resources in seasonal frozen soil areas in the future.

The geochemical evolution of basalt Enhanced Rock Weathering systems quantified from a natural analogue

Substantial quantities of fine-grained basaltic dust have fallen on South Iceland soils over at least the past 3300 years, making this region an ideal natural analogue to define the long-term consequences of current Enhanced Rock Weathering efforts. A relatively pristine South Iceland Gleyic/Histic Andosol, 3 m in height, receiving approximately 1250 mm of rainfall annually was selected for this study. This soil receives an estimated 500–800 g m−2y−1 of basaltic dust. The soil waters in this system were regularly sampled as a function of depth from May to November 2018. The fluid pH, alkalinity and the concentrations of most major elements increased with depth as the fluids became more reduced. In contrast, whereas numerous toxic trace metals are initially released to the fluid by the dissolution of the basalt near the surface they are scavenged at depth likely due to their uptake by secondary minerals. Equilibrium reaction path modelling suggests that 1) the added airborne basaltic dust dissolves throughout the soil column and 2) in total 0.26 cm3 of basalt dust dissolves per kg water in this soil–water system. Mass balance calculations indicate that the annual mass of basalt dissolved is less than 60 % of that added to the system, such that the mass of basaltic material in the soil column likely increases continuously over time. Basalt dissolution is maintained throughout the soil by the precipitation of Al-Si-minerals such as allophane, and organic anion ligands released from organic decay. These processes limit aqueous Al3+ activity and keep the soil waters undersaturated with respect to primary basaltic minerals and glass. The soil water pH is ∼6 and has a higher alkalinity than that of both Icelandic surface waters and the ocean. In contrast, if no basalt was present, the pH of the soil solutions would be 4.4, with zero alkalinity, illustrating the role of added basalt in drawing CO2 out of the atmosphere.

Impact of fully rotating steel casing bored pile on adjacent tunnels

Abstract Based on the theoretical model of a soil plug column, the stress analysis of the soil plug column during the spinning process of steel casing is carried out, and the critical depth of the soil column is determined using the stress and torsional shear ratio of the soil column. The effect of factors such as casing wall thickness, surface load, and steel casing spinning speed on the critical depth of soil columns has been explored, and more reasonable construction process parameters have been obtained quantitatively. Combined with the construction of small net distance test piles at a distance of 2.5 m from the tunnel, the impact of the construction process on the existing shield tunnel has been explored. The results indicate that during the construction process, when the wall thickness of the steel casing does not exceed 0.012 m, the surface load does not exceed 15 kPa, the spinning speed of the steel casing is maintained at 5/4/2/4 m/h or 5/3/2/3 m/h (corresponding to soil depths of 2.5/9.5/6/14 m), and the soil height of the soil column is controlled within 11 m, it is not easy to generate soil plug inside the steel casing, and the soil column has strong torsional shear resistance. According to the measured data of adjacent tunnels, it has been found that the construction method of fully rotating steel casing bored pile can effectively reduce the impact on adjacent shield tunnels, and has a good microdisturbance effect, which can control tunnel deformation not exceeding 1 mm and maintain within the warning value range.

Characterization of soil pores in strip-tilled and conventionally-tilled soil using X-ray computed tomography

Changes in soil pore size distribution and connectivity can affect contaminant transport. Climate, soil type, and agricultural management practices can influence these characteristics. Conservation tillage practices, such as strip tillage, have been promoted as agricultural management practices that can help reduce soil erosion and nutrient loss in runoff. However, limited information exists in the literature on the effect of strip tillage on soil pore characteristics. Thus, the objective of this research study was to assess the effects of different tillage practices i.e., conventional tillage (CT) vs. strip tillage (ST), on soil pore properties and quantify change in soil pore characteristics as a function of season. Undisturbed cylindrical soil columns (150 mm diameter and 640 mm length) were collected from a field in Alabama, USA planted with cotton (Gossypium hirsutum L.) under ST and CT treatments during two seasons i.e., fall 2021 and spring 2022. Soil cores were collected from CT and ST portions of the field, in the fall, following cotton harvest and before planting a cover crop (season 1), and in the spring, after the cover crop had matured (season 2). X-ray computed tomography was used to scan the soil cores and quantify soil pore characteristics. Results show that the ST treatment had significantly (p < 0.05) greater macroporosity values, network density, macropore length density, and interconnectivity compared to the CT in season 1. This was attributed to ST being a minimally disturbed treatment: thereby, it has a better chance of preserving cracks and biological activity as compared to CT, which is more prone to destruction of large macropores. The pore properties also showed a drastic decrease in values during season 2, especially for the top 200 mm of the soil profile in response to rainfall induced soil reconsolidation in both the tillage systems. Overall, this study showed that pore morphology can be affected by tillage and seasonal aspects associated with them.

Fate of dimethylsilanediol (DMSD) in outdoor bare surface soil and its relation to soil water loss

Dimethylsilanediol (DMSD) is a primary degradation product of silicone materials in the environment. Due to its low air/water partition coefficient and low soil/water distribution coefficient, this compound is not expected to undergo sorption and volatilization in wet soil. In an accompanying paper, we confirm that under controlled indoor conditions in test tubes, there is little to no volatilization of DMSD from soil and soil constituents if soil is wet. However, a significant amount of DMSD was volatilized when the soil substrates became air dried. Given the importance of water on the partition and fate of DMSD, we now report a continuation of this study focusing on the relation between DMSD removal and water loss in re-constituted soil columns under outdoor conditions. Consistent with predictions based on its partition properties and reconciling this evidence with previously reported field and laboratory studies, DMSD distribution was found to be largely dependent on water partitioning. The results suggested that DMSD moved upward in soil profile as soil water was evaporated from topmost layers with little DMSD retention by the soil matrix. As soil dried, a fraction of DMSD was sorbed by the soil matrix in the topmost layer, while most of the spiked radio-labeled DMSD was removed from soil through volatilization.

A stress-controlled soil column test equipment for investigating water seepage-consolidation characteristics of the compacted soil

For deep-filled building site, it is not acceptable to neglect water seepage and land settlement caused by the coupling effect of wetting and loading. However, previous soil column tests employed in investigating the water seepage always failed to consider the vertical stress. In this article, a stress-controlled soil column test was conducted to investigate the effect of vertical stress on water seepage and deformation of the compacted soil. The soil column was equipped with a vertical loading device and a water-recharge device to control the boundary conditions and water sensors, tensiometers, dial indicators and a data collector to monitor the displacement and water movement. The soil column test was utilised to perform seepage tests on compacted loess with vertical stresses of 0 and 400 kPa. The time-history data of wetting front depth, volumetric water content (VWC), suction and vertical displacement have been monitored directly. The VWC and suction profiles, soil–water characteristic curves and hydraulic conductivity curves were then obtained with the monitored data. The test results demonstrated that the vertical stress affected the water seepage and consolidation of the compacted soil, but this effect gradually decreased as the depth of the soil column increased. Moreover, the reliability of the proposed test method was verified by the comparison of some available test results. The findings of this study contribute to a better understanding of water seepage and consolidation characteristics of the compacted soil subjected to vertical stress.

Fate of dimethylsilanediol (DMSD) in soil-plant systems

Dimethylsilanediol (DMSD) is the degradation product of methylsiloxane polymers and oligomers such as volatile cyclic methylsiloxanes (cVMS). To better understand the environmental fate of this key degradation product, we conducted a three-part study on the movement of DMSD in soil. The objective of this third and final study was to determine the fate of DMSD in soil-plant systems under constant irrigation. Soil columns were constructed using two soils with the upper 20 cm layers spiked with 14C-labeled DMSD. Corn seedlings were transplanted into the soil columns and placed in a field plot underneath a transparent cover that prevented rainwater from reaching the soil columns while allowing soil water to be volatilized freely. The soil-plant columns were regularly irrigated with known amounts of DMSD-free plant growth solution to sustain the plant growth. At pre-determined time intervals (15–67 days), the plant and soil columns were sectioned and the distribution of 14Corganosilicon species in the soil profile and plant parts was determined using a combination of Liquid Scintillation Counting and High-Performance Liquid Chromatography-Flow Scintillation Analysis, while soil water loss was determined gravimetrically. It was found that the majority (>92 %) of DMSD initially spiked into the soil was removed from the soil-plant systems. Although DMSD was transported from the soil to the plant, it was subsequently volatilized from the plant via transpiration, with only a small fraction (∼5%) remaining at the conclusion of the experiments. In addition, little non-extractable DMSD was found in the top layer of soil in the soil-plant systems, suggesting that the air-drying of soil is a necessary pre-condition for the formation of such non-extractable silanol residue on topsoil.

Influence of Zeolite Application on Soil Infiltrated with Sewage Effluent

A laboratory-based soil column study was undertaken to assess the influence of zeolite application on soil treated with sewage effluent. Seven treatments, varying in zeolite proportions (T1=0.25%, T2=0.50%, T3=0.75%, T4=1.00%, T5=1.25%, T6=1.50%, and T7=control without zeolite), were replicated three times for the experiment. Analysis of leachate and residual soil after the experiment included parameters such as pH, electrical conductivity (EC), organic carbon (OC), available nitrogen, phosphorus, and potassium. Results indicated a significant increase in soil pH, EC, organic carbon, available nitrogen, phosphorus, and potassium with zeolite application. Leachate from the control column exhibited the highest values for pH (7.74), EC (190.33 µScm-1), BOD (34.33 mg L-1), COD (72.67 mg L-1), nitrate-N (40.23 mg L-1), phosphorus (5.96 mg L-1), and potassium (12.31 mg L-1), differing significantly from leachate collected from treatment columns.

Contamination Characteristics and Ecological Risk of Antibiotics in Contaminated Sites of Typical Pharmaceutical Factories in China

To understand the contamination characteristics and ecological risk of antibiotics in contaminated fields of pharmaceutical plants， samples of the surface soil， soil column， wastewater treatment process water， ground water， and residue dregs were collected from two typical antibiotic pharmaceutical plants in South and North China. A total of 87 commonly used antibiotics were quantified using ultrasound extraction-solid phase extraction and ultra-high performance liquid chromatography-mass spectrometry. The results showed that a total of 31 antibiotics of five classes were detected in all types of samples， and the maximum concentrations at each sampling point in the surface soil， soil column， residue dregs， wastewater treatment process water， and groundwater were 420 ng·g-1， 595 ng·g-1， 139 ng·g-1， 1 151 ng·L-1， and 6.65 ng·L-1， respectively. Most of the antibiotics were found in the surface soil， showing a decreasing trend with the depth of the soil column. The ecological risk assessment indicated that sulfamethazine， sulfaquinoxaline， tetracycline， chlorotetracycline， and D-sorbitol were at higher risk. Improving the efficiency of antibiotic removal from pharmaceutical wastewater and preventing production shop leaks are effective measures of controlling antibiotic contamination into and around fields in pharmaceutical plants.

Protecting groundwater in intensive agricultural areas through irrigation with treated wastewater: focus on nitrate, salt, and Escherichia coli

A set of 4 soil column duplicates was irrigated with treated wastewater to study the possible leaching of nitrate, salt, and Escherichia coli to groundwater. The reclaimed water was a municipal secondary effluent, stored for 5 days to attenuate microbial contamination. It had nitrate concentration of 36.1±4.9 mgN/L, electrical conductivity of 1.6±0.1 mS/cm, and E. coli content between 36 and 918 MPN/100 mL (median value of 194 MPN/100 mL). Soil column tests were carried out over a period of 80 days, considering both the cultivation of a typical Mediterranean crop (pepper) and the edge case of non-cultivated soil. Nitrate and salt were up-taken by crops for around 90% and 50%, respectively, while they leached through non-cultivated soil according to linear relationships, with nitrate moving faster than salts. Due to its natural decay, E. coli never reached 66 cm depth. Crop irrigation with reclaimed water can be managed so as not to cause significant leaching of E. coli and nitrate, even though it may result in a small leaching of salt. Replacing groundwater with reclaimed water as an irrigation source should be considered as a possible action to protect aquifers, and especially those suffering from saline contamination, from the effects of overexploitation and overfertilization practices.

Proportional impact prediction model of coating material on nitrate leaching of slow-release Urea Super Granules (USG) using machine learning and RSM technique

An accurate assessment of nitrate leaching is important for efficient fertiliser utilisation and groundwater pollution reduction. However, past studies could not efficiently model nitrate leaching due to utilisation of conventional algorithms. To address the issue, the current research employed advanced machine learning algorithms, viz., Support Vector Machine, Artificial Neural Network, Random Forest, M5 Tree (M5P), Reduced Error Pruning Tree (REPTree) and Response Surface Methodology (RSM) to predict and optimize nitrate leaching. In this study, Urea Super Granules (USG) with three different coatings were used for the experiment in the soil columns, containing 1 kg soil with fertiliser placed in between. Statistical parameters, namely correlation coefficient, Mean Absolute Error, Willmott index, Root Mean Square Error and Nash–Sutcliffe efficiency were used to evaluate the performance of the ML techniques. In addition, a comparison was made in the test set among the machine learning models in which, RSM outperformed the rest of the models irrespective of coating type. Neem oil/ Acacia oil(ml): clay/sulfer (g): age (days) for minimum nitrate leaching was found to be 2.61: 1.67: 2.4 for coating of USG with bentonite clay and neem oil without heating, 2.18: 2: 1 for bentonite clay and neem oil with heating and 1.69: 1.64: 2.18 for coating USG with sulfer and acacia oil. The research would provide guidelines to researchers and policymakers to select the appropriate tool for precise prediction of nitrate leaching, which would optimise the yield and the benefit–cost ratio.

Manure derived hydrochar reduced phosphorus loss risk via an alteration of phosphorus fractions and diversified microbial community in rice paddy soil

Phosphorus (P) loss caused by the irrational use of manure organic fertilizer has become a worldwide environmental problem, which has caused a potential threat to water safety and intensified agricultural non-point source pollution. Hydrothermal carbonization is method with a low-energy consumption and high efficiency to deal with environmental problems. Application of pig manure-derived hydrochar (PMH) to soil exhibited potential of sustainable development compared with the pristine pig manure (PM). However, the effects of PMH on the distribution of P among the fractions/forms and the interaction between microorganisms and P forms and its relevance to the potential loss of P in paddy fields has not been clarified. Therefore, in this study, a soil column experiment was conducted using the untreated soil (control), and the PM, PMH1 (PMH derived at 180 °C), and PMH2 (PMH derived at 260 °C) treated soils (at the dose of 0.05 %) and rice was cultivated to investigate the effects of PM and PMH on the P fractions, mobilization, ad potential loss via the induced changes on soil microbial community after a complete growing season of rice. The trend of P utilization was evaluated by P speciation via continuous extraction and 31P NMR. The addition of PMH reduced the proportion of residual P in soil by 23.8–26.3 %, and increased the proportion of HCl-P and orthophosphate by 116.2–158.6 % and 6.1–6.8 % compared to PM. The abundance of gcd gene developed after the application of PMH2, which enhanced the mobile forms of soil P utilization via secreting gluconic acid. The network diagram analysis concluded that the changes in various P forms were mainly related to Proteobacteria, Bacteroides, Firmicutes and Acidobacteria. The results illustrated that PMH mitigate the potential risk of P loss more than PM by altering P fractions and affecting soil microbial community.

Co-application of straw incorporation and biochar addition stimulated soil N2O and NH3 productions.

Nitrous oxide (N2O) and ammonia (NH3) volatilization (AV) are the major pathways of nitrogen (N) loss in soil, and recently, N2O and NH3 mitigation has become urgently needed in agricultural systems worldwide. However, the influence of straw incorporation (SI) and biochar addition (BC) on N2O and NH3 emissions are still unclear. To fill this knowledge gap, a soil column experiment was conducted with two management strategies using straw - straw incorporation (S1) and straw removal (S0) - and four biochar application rates (0 (C0), 15 (C1), 30 (C2), and 45 t ha-1 (C3)) to evaluate the impacts of their interactions on N2O and NH3 emissions. The results showed that NO3--N concentration and pH was the major contributors to affect the N2O and NH3 losses. Without biochar addition, N2O emissions was decreased by 59.6% (P<0.05) but AV was increased by 97.3% (P<0.05) under SI when compared to SR. Biochar was beneficial for N2O mitigation when straw was removed, but increased N2O emission by 39.4%-83.8% when straw was incorporated. Additionally, biochar stimulated AV by 27.9%-60.4% under S0 and 78.6%-170.3% under S1. Consequently, SI was found to significantly interact with BC in terms of affecting N2O (P<0.001) and NH3 (P<0.001) emissions; co-application of SI and BC promoted N2O emissions and offset the mitigation potential by SI or BC alone. The indirect N2O emissions caused by AV, however, might offset the reduction of direct N2O caused by SI or BC, thus leading to an increase in overall N2O emission. This paper recommended that SI combined BC at the amount of 8.2 t ha-1 for maintaining a lower overall N2O emission for future agriculture practices, but the long-term impacts of straw incorporation and biochar addition on the trade-off between N2O and NH3 emissions and reactive N losses should be further examined and assessed.