We give a complete description of Green's D relation for the multiplicative semigroup of all n-by-n tropical matrices. Our main tool is a new variant on the duality between the row and column space of a tropical matrix (studied by Cohen, Gaubert and Quadrat and separately by Develin and Sturmfels). Unlike the existing duality theorems, our version admits a converse, and hence gives a necessary and sufficient condition for two tropical convex sets to be the row and column space of a matrix. We also show that the matrix duality map induces an isometry (with respect to the Hilbert projective metric) between the projective row space and projective column space of any tropical matrix, and establish some foundational results about Green's other relations.
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