OH Column Densities Research Articles

JWST-MIRI Spectroscopy of Warm Molecular Emission and Variability in the AS 209 Disk

We present MIRI Medium-resolution Spectrograph observations of the large, multi-gapped protoplanetary disk around the T Tauri star AS 209. The observations reveal hundreds of water vapor lines from 4.9–25.5 μm toward the inner ∼1 au in the disk, including the first detection of rovibrational water emission in this disk. The spectrum is dominated by hot (∼800 K) water vapor and OH gas, with only marginal detections of CO2, HCN, and a possible colder water vapor component. Using slab models with a detailed treatment of opacities and line overlap, we retrieve the column density, emitting area, and excitation temperature of water vapor and OH, and provide upper limits for the observable mass of other molecules. Compared to MIRI spectra of other T Tauri disks, the inner disk of AS 209 does not appear to be atypically depleted in CO2 nor HCN. Based on Spitzer Infrared Spectrograph observations, we further find evidence for molecular emission variability over a 10 yr baseline. Water, OH, and CO2 line luminosities have decreased by factors of 2–4 in the new MIRI epoch, yet there are minimal continuum emission variations. The origin of this variability is yet to be understood.

Investigating the OH-H2 relation in diffuse Galactic clouds

Abstract We investigate the correlation between OH and H2 column densities in diffuse Galactic clouds, in order to identify potential molecular tracers of interstellar H2. For this, we analyse near-UV spectra extracted from the ESO/VLT archives towards seventeen sightlines (five of them new) with known N(H2), along with nine sightlines with no H2 information. N(OH) shows only marginal correlation with N(H2) (1020 to 2 × 1021 cm−2), at the 95 per cent confidence level. We use orthogonal distance regression analysis to obtain N(OH) /N(H2) = (1.32±0.15) × 10−7, which is ∼ 33 per cent higher than the previous estimates based on near-UV data. We also obtain N(CH) /N(H2) = (3.83±0.23) × 10−8 and a significant correlation between N(OH) and N(CH), with N(OH) = (2.61±0.19) × N(CH), both of which are consistent with previous results. Comparison with predictions of numerical models indicate that OH absorption arises from diffuse gas (nH ∼ 50 cm−3) illuminated by radiation fields ∼ 0.5–5 G0, while CH is associated with higher density of 500 cm−3. We posit that the apparent dichotomy in the properties of the diffuse clouds giving rise to OH and CH absorption could be due to either (a) the presence of multiple spectroscopically unresolved clouds along the line-of-sight, or, (b) density gradients along the line-of-sight within a single cloud.

ATOMIUM: Probing the inner wind of evolved O-rich stars with new, highly excited H2O and OH lines

Context. Water (H2O) and the hydroxyl radical (OH) are major constituents of the envelope of O-rich late-type stars. Transitions involving energy levels that are rotationally or vibrationally highly excited (energies ≳4000 K) have been observed in both H2O and OH. These and more recently discovered transitions can now be observed at a high sensitivity and angular resolution in the inner wind close to the stellar photosphere with the Atacama Large Millimeter/submillimeter Array (ALMA). Aims. Our goals are: (1) to identify and map the emission and absorption of H2O in several vibrational states, and of OH in Λ-doubling transitions with similar excitation energies; and (2) to determine the physical conditions and kinematics in gas layers close to the extended atmosphere in a sample of asymptotic giant branch stars (AGBs) and red supergiants (RSGs). Methods. Spectra and maps of H2O and OH lines observed in a 27 GHz aggregated bandwidth and with an angular resolution of ~0."02−1."0 were obtained at two epochs with the main ALMA array. Additional observations with the Atacama Compact Array (ACA) were used to check for time variability of water transitions. Radiative transfer models of H2O were revisited to characterize masing conditions. Up-to-date chemical models were used for comparison with the observed OH/H2O abundance ratio. Results. Ten rotational transitions of H2O with excitation energies ~4000–9000 K were observed in vibrational states up to (υ1,υ2,υ3) = (0,1,1). All but one are new detections in space, and from these we have derived accurate rest frequencies. Hyperfine split Λ-doubling transitions in υ = 0, J = 27/2 and 29/2 levels of the 2Π3/2 state, as well as J = 33/2 and 35/2 of the 2Π1/2 state of OH with excitation energies of ~4780–8900 K were also observed. Four of these transitions are new detections in space. Combining our measurements with earlier observations of OH, the υ = 0 and υ = 1 Λ-doubling frequencies have been improved. Our H2O maps show compact emission toward the central star and extensions up to twelve stellar radii or more. The 268.149 GHz emission line of water in the υ2 = 2 state is time variable, tends to be masing with dominant radiative pumping, and is widely excited in AGBs and RSGs. The widespread but weaker 262.898 GHz water line in the υ2 = 1 state also shows signs of maser emission. The OH emission is weak and quasithermally excited. Emission and absorption features of H2O and OH reveal an infall of matter and complex kinematics influenced by binarity. From the OH and H2O column densities derived with nonmasing transitions in a few sources, we obtain OH/H2O abundance ratios of ~(0.7–2.8) × 10−2.

A major asymmetric ice trap in a planet-forming disk

Context. Most well-resolved disks observed with the Atacama Large Millimeter/submillimeter Array (ALMA) show signs of dust traps. These dust traps set the chemical composition of the planet-forming material in these disks, as the dust grains with their icy mantles are trapped at specific radii and could deplete the gas and dust at smaller radii of volatiles. Aims. In this work, we analyse the first detection of nitric oxide (NO) in a protoplanetary disk. We aim to constrain the nitrogen chemistry and the gas-phase C/O ratio in the highly asymmetric dust trap in the Oph-IRS 48 disk. Methods. We used ALMA observations of NO, CN, C2H, and related molecules in the Oph-IRS 48 disk. We modeled the effect of the increased dust-to-gas ratio in the dust trap on the physical and chemical structure using a dedicated nitrogen chemistry network in the thermochemical code DALI. Furthermore, we explored how ice sublimation contributes to the observed emission lines. Finally, we used the model to put constraints on the nitrogen-bearing ices. Results. Nitric oxide (NO) is only observed at the location of the dust trap, but CN and C2H are not detected in the Oph-IRS 48 disk. This results in an CN/NO column density ratio of <0.05 and thus a low C/O ratio at the location of the dust trap. Models show that the dust trap cools the disk midplane down to ~30 K, just above the NO sublimation temperature of ~25 K. The main gas-phase formation pathways to NO though OH and NH in the fiducial model predict NO emission that is an order of magnitude lower than what has been observed. The gaseous NO column density can be increased by factors ranging from 2.8 to 10 when the H2O and NH3 gas abundances are significantly boosted by ice sublimation. However, these models are inconsistent with the upper limits on the H2O and OH column densities derived from Herschel PACS observations and the upper limit on CN derived from ALMA observations. As the models require an additional source of NO to explain its detection, the NO seen in the observations is likely the photodissociation product of a larger molecule sublimating from the ices. The non-detection of CN provides a tighter constraint on the disk C/O ratio than the C2H upper limit. Conclusions. We propose that the NO emission in the Oph-IRS 48 disk is closely related to the nitrogen-bearing ices sublimating in the dust trap. The non-detection of CN constrains the C/O ratio both inside and outside the dust trap to be <1 if all nitrogen initially starts as N2 and ≤ 0.6, consistent with the Solar value, if (at least part of) the nitrogen initially starts as N or NH3.

A Search for OH 18 cm Emission from Intermediate-velocity Gas at High Galactic Latitudes

We present search results of 22 high-latitude (∣b∣ > 25°) sightlines for OH 18 cm emission using the 305 m radio telescope at the Arecibo Observatory. These sightlines appear in neutral hydrogen emission at intermediate velocities −90 ≤ V LSR ≤ −20 km s−1 and are predicted to have a sufficient molecular composition so as to be detectable in molecular emission. Such objects, known as intermediate-velocity molecular clouds (IVMCs), have historically been detected through 12CO emission. Recent studies indicate that IVMCs may be widespread in the galaxy and have important implications for models of the interstellar medium and star formation. However, we report nondetections of OH emission toward the 22 sightlines and provide stringent upper limits on the OH column density. Using available H i and A v data in combination with existing state-of-the-art PDR models, we estimate H2 column densities and find that they are more than an order of magnitude lower than the predicted values. We also find that the hydrogen volume density of these clouds is ≲25 cm−3. In addition, we discuss the known IVMCs with previous 12CO detections in the context of the PDR models. Our analysis of these clouds indicates that the structure of molecular material in IVMCs is morphologically clumpy. These results motivate the need for future sensitive, on-the-fly searches (rather than targeted searches) for CO emission from IVMCs with resolutions on the order of ∼1′. High angular resolution (∼1′) H i and A v data will also be helpful to better constrain the structure and composition of IVMCs.

Precise Measurements of CH Maser Emission and Its Abundance in Translucent Clouds

Abstract We present high-sensitivity CH 9 cm ON/OFF observations toward 18 extragalactic continuum sources that have been detected with OH 18 cm absorption in the Millennium survey with the Arecibo telescope. CH emission was detected toward 6 of the 18 sources. The excitation temperature of CH has been derived directly through analyzing all detected ON and OFF velocity components. The excitation temperature of CH 3335 MHz transition ranges from −54.5 to −0.4 K and roughly follows a log-normal distribution peaking within [−5, 0] K, which implies overestimation by 20% to more than 10 times during calculating CH column density by assuming the conventional value of −60 or −10 K. Furthermore, the column density of CH would be underestimated by a factor of 1.32 ± 0.03 when adopting local thermal equilibrium assumption instead of using the CH three hyperfine transitions. We found a correlation between the column density of CH and OH following log N(CH) = (1.80 ± 0.49) log N(OH) −11.59 ± 6.87. The linear correlation between the column density of CH and H2 is consistent with that derived from visible wavelengths studies, confirming that CH is one of the best tracers of H2 components in diffuse molecular gas.

Detection of OH 18 cm Emission from Comet C/2020 F3 NEOWISE Using the Arecibo Telescope

Abstract We report the detection of emission from the OH 18 cm Λ-doublet transitions toward Comet C/2020 F3 NEOWISE using the Arecibo Telescope. The antenna temperatures are 113 ± 3 mK for the 1667 MHz line and 57 ± 3 mK for the 1665 MHz line. The beam-averaged OH column density (centered on the comet nucleus) derived from the 1667 transition is N OH = (1.11 ± 0.06) × 1013 cm−2. We implemented the Haser model to derive an OH production rate. The estimated OH production rate using the 1667 transition is Q OH = (3.6 ± 0.6) × 1028 s−1, a factor of 2.4 lower than optically derived values for the same observing day, the difference of which is likely explained by quenching.

Quantum study of reaction O(3 P) + H2 (v, j) → OH + H: OH formation in strongly UV-irradiated gas.

The reaction between atomic oxygen and molecular hydrogen is an important one in astrochemistry as it regulates the abundance of the hydroxyl radical and serves to open the chemistry of oxygen in diverse astronomical environments. However, the existence of a high activation barrier in the reaction with ground state oxygen atoms limits its efficiency in cold gas. In this study we calculate the dependence of the reaction rate coefficient on the rotational and vibrational state of H2 and evaluate the impact on the abundance of OH in interstellar regions strongly irradiated by far-UV photons, where H2 can be efficiently pumped to excited vibrational states. We use a recently calculated potential energy surface and carry out time-independent quantum mechanical scattering calculations to compute rate coefficients for the reaction O(3 P) + H2 (v, j) → OH + H, with H2 in vibrational states v = 0-7 and rotational states j = 0-10. We find that the reaction becomes significantly faster with increasing vibrational quantum number of H2, although even for high vibrational states of H2 (v = 4-5) for which the reaction is barrierless, the rate coefficient does not strictly attain the collision limit and still maintains a positive dependence with temperature. We implemented the calculated state-specific rate coefficients in the Meudon PDR code to model the Orion Bar PDR and evaluate the impact on the abundance of the OH radical. We find the fractional abundance of OH is enhanced by up to one order of magnitude in regions of the cloud corresponding to A V = 1.3-2.3, compared to the use of a thermal rate coefficient for O + H2, although the impact on the column density of OH is modest, of about 60%. The calculated rate coefficients will be useful to model and interpret JWST observations of OH in strongly UV-illuminated environments.

The magnetic field in the dense photodissociation region of DR 21

ABSTRACT Measuring interstellar magnetic fields is extremely important for understanding their role in different evolutionary stages of interstellar clouds and star formation. However, detecting the weak field is observationally challenging. We present measurements of the Zeeman effect in the 1665 and 1667 MHz (18 cm) lines of the hydroxyl radical (OH) lines towards the dense photodissociation region (PDR) associated with the compact H ii region DR 21 (Main). From the OH 18 cm absorption, observed with the Karl G. Jansky Very Large Array, we find that the line-of-sight magnetic field in this region is ∼0.13 mG. The same transitions in maser emission towards the neighbouring DR 21(OH) and W 75S-FR1 regions also exhibit the Zeeman splitting. Along with the OH data, we use [C ii] 158 μm line and hydrogen radio recombination line data to constrain the physical conditions and the kinematics of the region. We find the OH column density to be ∼3.6 × 1016(Tex/25 K) cm−2, and that the 1665 and 1667 MHz absorption lines are originating from the gas where OH and C+ are co-existing in the PDR. Under reasonable assumptions, we find the measured magnetic field strength for the PDR to be lower than the value expected from the commonly discussed density–magnetic field relation while the field strength values estimated from the maser emission are roughly consistent with the same. Finally, we compare the magnetic field energy density with the overall energetics of DR 21’s PDR and find that, in its current evolutionary stage, the magnetic field is not dynamically important.

OH Evolution in Molecular Clouds

We have conducted a OH 18 cm survey toward 141 molecular clouds in various environments, including 33 optical dark clouds, 98 Planck Galactic cold clumps (PGCCs), and 10 Spitzer dark clouds with the Arecibo telescope. The deviations from local thermal equilibrium are common for intensity ratios of both OH main lines and satellite lines. Line intensity of OH 1667 MHz is found to correlate linearly with visual extinction when is less than 3 mag. It was converted into OH column density by adopting the excitation temperature derived from Monte Carlo simulations with 1σ uncertainty. The relationship between OH abundance X(OH) relative to H2 and is found to follow an empirical formula, Linear correlation is found between OH and 13CO intensity. Besides, nonthermal velocity dispersions of OH and 13CO are closely correlated. These results imply tight chemical evolution and spatial occupation between OH and 13CO. No obvious correlation is found between column density and nonthermal velocity dispersion of OH and H i narrow self-absorption (HINSA), indicating different chemical evolution and spatial volume occupation between OH and HINSA. Using the age information of HINSA analysis, OH abundance X(OH) is found to increase linearly with cloud age, which is consistent with previous simulations. Fourteen OH components without corresponding CO emission were detected, implying the effectiveness of OH in tracing the "CO-dark" molecular gas.

A pilot search for extragalactic OH absorption with FAST

ABSTRACT OH absorption is currently the only viable way to detect OH molecules in non-masing galaxies at cosmological distances. There have been only six such detections at z > 0.05 to date and so it is hard to put a statistically robust constraint on OH column densities in distant galaxies. We carried out a pilot OH absorption survey towards eight associated and one intervening H i 21-cm absorbers using the Five-hundred-meter Aperture Spherical radio Telescope (FAST). We were able to constrain the OH abundance relative to H i ([OH]/[H i]) to be lower than 10−6 ∼ 10−8 for redshifts z∈ [0.1919, 0.2241]. Although no individual detection was made, stacking three associated absorbers free of RFI provides a sensitive OH column density 3σ upper-limit $\sim 1.57 \times 10^{14} (T_x^{\rm OH}/10\,\mathrm{ K})(1/f_\mathrm{ c}^{\rm OH})\mathrm{ cm}^{-2}$, which corresponds to a [OH]/[H i] < 5.45 × 10−8. Combining with archival data, we show that associated absorbers have a slightly lower OH abundance than intervening absorbers. Our results are consistent with a trend of decreasing OH abundance with decreasing redshift.

The Effect of Far-infrared Radiation on the Hyperfine Anomaly of the OH 18 cm Transition

Abstract We present observations of the four hyperfine structure components of the OH 18 cm transition (1612, 1665, 1667 and 1720 MHz) toward Heiles Cloud 2 (HCL2) in Taurus and the dense cores L183 and L169. Toward the peculiar straight structure in the northern part of HCL2, the 1720 MHz line shows absorption against the cosmic microwave background at a velocity of ∼5.5 km s−1, whereas the 1612 MHz line shows brighter emission than expected in local thermodynamic equilibrium (LTE). Such an intensity anomaly is also observed toward TMC-1 (CP), L183, and L169, where the 1612 MHz line is stronger and the 1720 MHz line is weaker than those expected under LTE. We conduct statistical equilibrium calculations considering the effect of far-infrared (FIR) radiation from surrounding clouds and find that the absorption feature of the 1720 MHz line can be reproduced by the following conditions: gas kinetic temperature lower than about 30 K, OH column density higher than 1015 cm−2, H2 density lower than 103 cm−3, and an ortho-to-para ratio of H2 lower than 1. Therefore, the absorption feature of the 1720 MHz line is considered to trace relatively cold and dense gas that is surrounded by a warm envelope consisting of CO-dark molecular gas.

Time-of-day-dependent behavior of surficial lunar hydroxyl/water: Observations and modeling

In this study we determine the depth of the absorption band around 3 µm wavelength, which indicates the presence of OH/H2O in a thin surficial layer of the lunar regolith, for 18 lunar highland regions observed by the Moon Mineralogy Mapper (M3) instrument at 4–8 different local times of day. For removing the thermal emission component, a physically motivated thermal equilibrium based method is used, which also takes into account the roughness of the regolith surface. We propose a continuity equation based model of the time-of-day-dependent column densities of surficial atomic hydrogen (H) and hydroxyl (OH). The considered source processes for H are implantation of solar wind protons and photolysis of OH, and for OH the reaction H+O→OH. Sink processes are diffusive loss for H and OH, and photolysis for OH. Sputtering of H and OH is found to be negligible in comparison to the other sink processes. Additionally, we suggest a similar differential equation based model to describe the time-of-day-dependent behavior of micrometeoroid-delivered OH and H2O. The observed 3 µm band depth values indicate that the surficial OH/H2O does not vanish even at local midday at low latitudes, while the model predicts nearly complete removal of surficial OH/H2O at midday. This apparent contradiction between model and observations is reconciled by adding to the model a region-specific “offset” OH component which is assumed to be stable against diffusive loss and photolysis and is therefore interpreted as a strongly bounded OH component. Meteoroid bombardment is found to be negligible in comparison with the solar wind source of OH. Fitting the model to the observed 3 µm band depth values allows for estimating the H activation energy, the OH photolysis time, region-specific values of the offset OH component, and the proportionality factor between OH column density and 3 µm band depth. The observed time-of-day-dependent behavior of the 3 µm band depth at low and high latitudes can be explained convincingly by the modeled source and sink processes. The best-fit OH photolysis time is much shorter than the lunar day and corresponds to 1–3 times the gas-phase value, which indicates that photolysis is a mechanism of high relevance for the behavior of solar wind induced surficial OH. The surface roughness assumed in the M3 data analysis does not have a major influence on the modeling results. The strongly bounded OH component is nearly latitude-independent for low latitudes but decreases sharply for high latitudes. As a possible mode of origin, we suggest slow diffusion of solar wind induced OH to depths inaccessible for ultraviolet photons and into binding states of higher energy, counteracted by sputtering.

Discovery of OH Absorption from a Galaxy at z ∼ 0.05: Implications for Large Surveys with SKA Pathfinders

Abstract We present the first detection of OH absorption in diffuse gas at z > 0, along with another eight stringent limits on OH column densities for cold atomic gas in galaxies at 0 < z < 0.4. The absorbing gas detected toward Q0248+430 (z q = 1.313) originates from a tidal tail emanating from a highly star-forming galaxy G0248+430 (z g = 0.0519) at an impact parameter of 15 kpc. The measured column density is N(OH) = (6.3 ± 0.8) × 1013 cm−2, where and T ex are the covering factor and the excitation temperature of the absorbing gas, respectively. In our Galaxy, the column densities of OH in diffuse clouds are of the order of N(OH) ∼ 1013–14 cm−2. From the incidence (number per unit redshift; n 21) of H i 21 cm absorbers at 0.5 < z < 1 and assuming no redshift evolution, we estimate the incidence of OH absorbers (with log N(OH) > 13.6) to be n OH = at z ∼ 0.1. Based on this we expect to detect such OH absorbers from the MeerKAT Absorption Line Survey (MALS). Using H i 21 cm and OH 1667 MHz absorption lines detected toward Q0248+430, we estimate (ΔF/F) = (5.2 ± 4.5) × 10−6, where , α is the fine structure constant, μ is the electron–proton mass ratio, and g p is the proton gyromagnetic ratio. This corresponds to Δα/α(z = 0.0519) = (1.7 ± 1.4) × 10−6, which is among the stringent constraints on the fractional variation of α.

Constraints on the OH-to-H Abundance Ratio in Infrared-bright Galaxies Derived from the Strength of the OH 35 μm Absorption Feature

Abstract We analyze Spitzer/InfraRed Spectrograph (IRS) observations of the OH 35 μm feature in 15 nearby ( ) (ultra-)luminous infrared galaxies (U/LIRGs). All objects exhibit OH 35 μm purely in absorption, as expected. The small optical depth of this transition makes the strength of this feature a good indicator of the true OH column density. The measured OH 35 μm equivalent widths imply an average OH column density and a 1-σ standard deviation to the mean of cm−2. This number is then compared with the hydrogen column density for a typical optical depth at 35 μm of ∼0.5 and gas-to-dust ratio of 125 to derive an OH-to-H abundance ratio of . This abundance ratio is formally a lower limit. It is consistent with the values generally assumed in the literature. The OH 35 μm line profiles predicted from published radiative transfer models constrained by observations of OH 65, 79, 84, and 119 μm in 5 objects (Mrk 231, Mrk 273, IRAS F05189-2524, IRAS F08572+3915, and IRAS F20551-4250) are also found to be consistent with the IRS OH 35 μm spectra.

Near-UV OH Prompt Emission in the Innermost Coma of 103P/Hartley 2

Abstract The Deep Impact spacecraft flyby of comet 103P/Hartley 2 occurred on 2010 November 4, 1 week after perihelion with a closest approach (CA) distance of about 700 km. We used narrowband images obtained by the Medium Resolution Imager on board the spacecraft to study the gas and dust in the innermost coma. We derived an overall dust reddening of 15%/100 nm between 345 and 749 nm and identified a blue enhancement in the dust coma in the sunward direction within 5 km from the nucleus, which we interpret as a localized enrichment in water ice. OH column density maps show an anti-sunward enhancement throughout the encounter, except for the highest-resolution images, acquired at CA, where a radial jet becomes visible in the innermost coma, extending up to 12 km from the nucleus. The OH distribution in the inner coma is very different from that expected for a fragment species. Instead, it correlates well with the water vapor map derived by the HRI-IR instrument on board Deep Impact. Radial profiles of the OH column density and derived water production rates show an excess of OH emission during CA that cannot be explained with pure fluorescence. We attribute this excess to a prompt emission process where photodissociation of H2O directly produces excited OH*(A 2Σ+) radicals. Our observations provide the first direct imaging of near-UV prompt emission of OH. We therefore suggest the use of a dedicated filter centered at 318.8 nm to directly trace the water in the coma of comets.

Towards a three-dimensional distribution of the molecular clouds in the Galactic Centre

We present a study of the three-dimensional structure of the molecular clouds in the Galactic Centre (GC) using CO emission and OH absorption lines. Two CO isotopologue lines, $^{12}$CO ($J$=1$\rightarrow$0) and $^{13}$CO ($J$=1$\rightarrow$0), and four OH ground-state transitions, surveyed by the Southern Parkes Large-Area Survey in Hydroxyl (SPLASH), contribute to this study. We develop a novel method to calculate the OH column density, excitation temperature, and optical depth precisely using all four OH lines, and we employ it to derive a three-dimensional model for the distribution of molecular clouds in the GC for six slices in Galactic latitude. The angular resolution of the data is 15.5 arcmin, which at the distance of the GC (8.34 kpc) is equivalent to 38 pc. We find that the total mass of OH in the GC is in the range 2400-5100 Solar mass . The face-on view at a Galactic latitude of b = 0{\deg} displays a bar-like structure with an inclination angle of 67.5 $\pm$ 2.1{\deg} with respect to the line of sight. No ring-like structure in the GC is evident in our data, likely due to the low spatial resolution of the CO and OH maps.

OH Survey along Sightlines of Galactic Observations of Terahertz C+

Abstract We have obtained OH spectra of four transitions in the ground state, at 1612, 1665, 1667, and 1720 MHz, toward 51 sightlines that were observed in the Herschel project Galactic Observations of Terahertz C+. The observations cover the longitude range of (32°, 64°) and (189°, 207°) in the northern Galactic plane. All of the diffuse OH emissions conform to the so-called “Sum Rule” of the four brightness temperatures, indicating optically thin emission conditions for OH from diffuse clouds in the Galactic plane. The column densities of the H i “halos” N(H i) surrounding molecular clouds increase monotonically with OH column density, N(OH), until saturating when cm−2 and cm−2, indicating the presence of molecular gas that cannot be traced by H i. Such a linear correlation, albeit weak, is suggestive of halos’ contribution to the UV shielding required for molecular formation. About 18% of OH clouds have no associated CO emission (CO-dark) at a sensitivity of 0.07 K, but are associated with C+ emission. A weak correlation exists between C+ intensity and OH column density for CO-dark molecular clouds. These results imply that OH seems to be a better tracer of molecular gas than CO in diffuse molecular regions.

Revisiting the OH–CH correlation in diffuse clouds

Based on the analysis of available published data and archival data along 24 sightlines (5 of which are new) we derive more accurate estimates of the column densities of OH and CH towards diffuse/translucent clouds and revisit the typically observed correlation between the abundances of these species. The increase in the sample size was possible because of the equivalence of the column densities of CH derived from a combination of the transitions at 3137 & 3143 Angstrom, and a combination of transitions at 3886 & 3890 Angstrom, which we have demonstrated here. We find that with the exception of four diffuse clouds, the entire source sample shows a clear correlation between the column densities of OH and CH similar to previous observations. The analysis presented also verifies the theoretically predicted oscillator strengths of the OH A--X (3078 & 3082 Angstrom), CH B--X (3886 & 3890 Angstrom) and C--X (3137 & 3143 Angstrom) transitions. We estimate N(H) and N(H2) from the observed E(B-V) and N(CH) respectively. The N(OH)/N(CH) ratio is not correlated with the molecular fraction of hydrogen in the diffuse/translucent clouds. We show that with the exception of HD 34078 for all the clouds the observed column density ratios of CH and OH can be reproduced by simple chemical models which include gas-grain interaction and gas-phase chemistry. The enhanced N(OH)/N(CH) ratio seen towards the 3 new sightlines can be reproduced primarily by considering different cosmic ray ionization rates.

Molecular formation along the atmospheric mass loss of HD 209458b and similar Hot Jupiters

The chemistry along the mass loss of Hot Jupiters is generally considered to be simple, consisting mainly of atoms, prevented from forming more complex species by the intense radiation field from their host stars. In order to probe the region where the temperature is low (T<2000K), we developed a 1D chemical and photochemical reaction model of the atmospheric mass loss of HD 209458b, involving 56 species, including carbon chain and oxygen-bearing ones, interacting through 566 reactions. The simulation results indicate that simple molecules like OH+, H2O+ and H3O+ are formed inside the region, considering that residual H2 survives in the exosphere, a possibility indicated by recent observational work. The molecules are formed and destroyed within a radial distance of less than 107km, but the estimated integrated column density of OH+, a potential tracer of H2, is high enough to allow detection, which, once achieved, would indicate a revision of chemical models of the upper atmosphere of Hot Jupiters. For low density Hot Jupiters receiving less intense XUV radiation from their host stars than HD 209458b, molecular species could conceivably be formed with a higher total column density.