Cold Trap Research Articles

Effect of freezing and freezing-thawing pretreatment on wood properties and drying characteristics of Eucalyptus urophylla × E. grandis

ABSTRACT Eucalyptus wood has uneven density and poor permeability, which can lead to defects such as wrinkling and cracking during the drying process, limiting applications. Freezing and freeze–thaw treatments can improve wood permeability by disrupting its microstructure, thus enhancing drying quality. In this experiment, Eucalyptus urophylla × E. grandis was subjected to cold trap freezing (CF), refrigerator freezing (RF), cold trap freeze–thaw (CFT), and refrigerator freeze–thaw (RFT) pretreatments. The pretreated materials were then dried and tested to investigate properties such as permeability, moisture absorption, shrinkage, and drying characteristics. The results indicated that the moisture content (MC) during pre-freezing, with lower freezing temperatures leading to greater reductions in MC. The water absorption rates for the CF, RF, CFT, and RFT pretreated wood increased by 16%, 7%, 16%, and 14%, respectively, showing significant improvement in permeability, which in turn resulted in increased drying rates of 24%, 11%, 26%, and 13%, respectively, when the MC exceeded the fiber saturation point (FSP). The shrinkage ratios were reduced by 8%, 2%, 4%, and 8%, respectively, but increased the equilibrium moisture content (EMC) by 5% for all groups. Overall, the improvement in drying rate from freeze–thaw treatment was greater than that from freezing treatment.

Effects of the internal temperature on vertical mixing and on cloud structures in ultra-hot Jupiters

Context. The vertical mixing in hot-Jupiter atmospheres plays a critical role in the formation and spacial distribution of cloud particles in their atmospheres. This affects the observed spectra of a planet through cloud opacity, which can be influenced by the degree of cold trapping of refractory species in the deep atmosphere. Aims. We aim to isolate the effects of the internal temperature on the mixing efficiency in the atmospheres of ultra-hot Jupiters (UHJs) and the spacial distribution of cloud particles across the planet. Methods. We combined a simplified tracer-based cloud model, a picket fence radiative-transfer scheme, and a mixing length theory to the Exo-FMS general circulation model. We ran the model for five different internal temperatures at typical UHJ atmosphere system parameters. Results. Our results show the convective eddy diffusion coefficient remains low throughout the vast majority of the atmosphere, with mixing dominated by advective flows. However, some regions can show convective mixing in the upper atmosphere for colder interior temperatures. The vertical extent of the clouds is reduced as the internal temperature is increased. Additionally, a global cloud layer gets formed below the radiative-convective boundary (RCB) in the cooler cases. Conclusions. Convection is generally strongly inhibited in UHJ atmospheres above the RCB due to their strong irradiation. Convective mixing plays a minor role compared to advective mixing in keeping cloud particles aloft in UHJs with warm interiors. Higher vertical turbulent heat fluxes and the advection of potential temperature inhibit convection in warmer interiors. Our results suggest that isolated upper atmosphere regions above cold interiors may exhibit strong convective mixing in isolated regions around Rossby gyres, allowing aerosols to be better retained in these areas.

Ice-mining lunar rover using Americium-241 radioisotope power systems

Permanently Shadowed Regions (PSRs) of the Moon contain rich deposits of water ice. They are very valuable to the space community as in-situ extracted water can be used for many purposes, such as propellant production and human habitat support. PSR craters never see sunlight, therefore solar power is not available there. They also present a cryogenic environment with regolith as cold as 40 K. These challenges can be overcome by employing a Radioisotope Power System (RPS) to provide both thermal and electrical power to resource extraction systems in the PSRs. The work presented here aims at characterizing an ice-mining lunar rover. The rover will be equipped with an Americium-241 (or 241Am) based RPS. 241Am has a 432-year long half-life and can provide decades of stable power output for the rover operations. The innovation lies in the fact that the RPS will not only provide electrical power to the rover, but that its waste heat will be employed to thermally mine ice from its deposits. The rover is equipped with a sublimation plate irradiating the underlying regolith to sublimate ice contained within, and with a cold trap where extracted volatiles will be deposited. This work studied the rover concept feasibility and developed a model of its Thermal Management System (TMS) to meet sublimation plate and cold trap temperature requirements. The results have been validated by a 3D finite element method thermal simulation for icy regolith conditions of 0–10 vol% water-ice content. The findings of this work suggest that it is possible to perform thermal ice-mining in the lunar PSR environment with an RPS-powered rover, with different degrees of efficiencies depending on the amount of ice in the deposits.

Climate Regimes across the Habitable Zone: A Comparison of Synchronous Rocky M and K Dwarf Planets

M and K dwarf stars make up 86% of the stellar population and host many promising astronomical targets for detecting habitable climates in the near future. Of the two, M dwarfs currently offer greater observational advantages and are home to many of the most exciting observational discoveries in the last decade. But K dwarfs could offer even better prospects for detecting habitability by combining the advantages of a relatively dim stellar flux with a more stable stellar environment. Here we explore the climate regimes that are possible on Earth-like synchronous planets in M and K dwarf systems, and how they vary across the habitable zone. We focus on surface temperature patterns, water availability, and implications for habitability. We find that the risk of nightside cold trapping decreases with increased orbital radius and is overall lower for K dwarf planets. With reduced atmospheric shortwave absorption, K dwarf planets have higher dayside precipitation rates and less day-to-night moisture transport, resulting in lower nightside snow rates. These results imply a higher likelihood of detecting a planet with a moist dayside climate in a habitable “eyeball” climate regime orbiting a K dwarf star. We also show that “terminator habitability” can occur for both M and K dwarf land planets, but would likely be more prevalent in M dwarf systems. Planets in a terminator habitability regime tend to have slightly lower fractional habitability, but offer alternative advantages including instellation rates more comparable to Earth in regions that have temperatures amenable to life.

Full-Dimensional Analysis of Gaseous Products to Unlocking In Depth Thermal Runaway Mechanism of Li-Ion Batteries.

In this study, state-of-the-art on-line pyrolysis MS (OP-MS) equipped with temperature-controlled cold trap and on-line pyrolysis GC/MS (OP-GC/MS) injected through high-vacuum negative-pressure gas sampling (HVNPGS) programming are originally designed/constructed to identify/quantify the dynamic change of common permanent gases and micromolecule organics from the anode/cathode-electrolyte reactions during thermal runaway (TR) process, and corresponding TR mechanisms are further perfected/complemented. On LiCx anode side, solid electrolyte interphase (SEI) would undergo continuous decomposition and regeneration, and the R-H+ (e.g., HF, ROH, etc.) species derived from electrolyte decomposition would continue to react with Li/LiCx to generate H2. Up to above 200°C, the O2 would release from the charged NCM cathode and organic radicals would be consumed/oxidized by evolved O2 to form COx, H2O, and more corrosive HF. On the contrary, charged LFP cathode does not present obvious O2 evolution during heating process and the unreacted flammable/toxic organic species would exit in the form of high temperature/high-pressure (HT/HP) vapors within batteries, indicating higher potential safety risks. Additionally, the in depth understanding of the TR mechanism outlined above provides a clear direction for the design/modification of thermostable electrodes and non-flammable electrolytes for safer batteries.

Temporal Variations of 222Rn Density Distributions in the Lunar Exosphere

Because of radiogenic processes, the lunar interior is a source of rare gases like helium (4He), argon (40Ar), and radon (222Rn) that might be released continuously, or impulsively during moonquakes. The detection of radon is therefore important in the sense that it can help trace the crustal dynamics on the Moon. In this study, we will introduce a Monte Carlo–based model designed to investigate the time-dependent transient dynamics of the lunar 222Rn exosphere. Our model accounts for the background emission and transient ejection of gas molecules from the lunar surface, encompassing loss processes such as radioactive decay, photoionization, and the cold trapping in permanently shadowed regions near the poles. Additionally, it incorporates the diurnal temperature fluctuations of the lunar surface, which significantly influence the condensation duration of the radon atoms and their subsequent release near the sunrise. This model also can support future observations in missions such as Chang’E 6 or other lunar explorations.

Investigation on the influences of CaO on tar of biomass model compounds by Boltzmann-Monte Carlo-Percolation (BMCP) model

CaO have been widely used in biomass thermal conversion processes to deal with tar of biomass. The influences of the CaO on the function groups or intermediates of the bio tars are crucial because strategies on refining bio tars can be determined. The pyrolysis experiments of three typical model compounds, lignin, cellulose, hemicellulose, are carried out in a multi-stage tube followed by a cold trap. The influence of CaO can be analyzing the products distribution and components obtained from Nuclear Magnetic Resonance and Gas Chromatography-Mass Spectrometry technologies with and without CaO-loaded honeycombs. As the adsorbed matters on CaO-loaded honeycombs are hardly to be analyzed, the Boltzmann-Monte Carlo-Percolation model is introduced to make further investigations on the possible influence of CaO. The experimental results suggest that generations of unsaturated structures are inhibited by CaO, and the comparison of simulation and experimental results suggest that aliphatic carbon-centered radicals rather than oxygen-centered radicals are adsorbed and stabilized by CaO.

Quantifying bimolecular reaction kinetics of isoprene hydroxy peroxy radical: From dry to highly humid atmospheric environment

Isoprene hydroxy peroxy radicals (ISOPOO), derived from isoprene oxidation by hydroxy radicals (OH), are key intermediates for ozone and secondary organic aerosol (SOA) formation in the atmosphere. Although ISOPOO-water complexes are ubiquitous, their impacts on ISOPOO chemistry remain obscure. Here the previously overlooked water effect on the bimolecular reaction kinetics of ISOPOO was investigated in an oxidative flow reactor. The major first-generation products of ISOPOO, isoprene hydroxy hydroperoxides (ISOPOOH), methacrolein (MACR), and methyl vinyl ketone (MVK), were measured simultaneously at various relative humidity (RH) with the help of a cold trap to avoid potential losses in direct gas sampling. We found that ISOPOO reactions were accelerated significantly under wet conditions, with a greater enhancement on 1,2-ISOPOO than 4,3-ISOPOO. 1,2-ISOPOOH yield appeared faster growth with RH than 4,3-ISOPOOH. MVK yield showed an upward-downward trend with RH, while MACR yield plateaued from 30% RH. To explain the enhancement in the ISOPOOH yield from 3% to 80% RH, the overall rate constants of 1,2-ISOPOO + HO2 and 4,3-ISOPOO + HO2 reactions at 80% RH should be 13 times and twice those at 3% RH, respectively. The empirical formulas were proposed for the first time to parameterize the water effect on ISOPOO + HO2 reactions. The updated kinetics of ISOPOO reactions were incorporated in a box model to simulate the RH-dependent ISOPOOH and C4 carbonyl yields under typical atmospheric conditions. High RH can enhance the ISOPOOH yield in urban, rural, and forest areas, and promote SOA formation correspondingly. Our findings shed light on the critical role of humidity in the reactions of ISOPOO and benefit evaluating the fate of isoprene and its impacts on air quality more accurately in the ambient atmosphere.

Effects of operating parameters on single-stage ultrasonic separation of ethanol from its aqueous solutions

The effects of operating parameters on separation of ethanol from its aqueous solutions using ultrasonic atomization were investigated in a single-stage process. With an experimental setup similar to those used in previous work, we measured the degree of enrichment and the combined molar collection rate of ethanol and water for a single combination of the ultrasound power and frequency at 126 combinations of bulk liquid depth, composition, and temperature; carrier-gas inlet/outlet elevation and flow rate; and collection temperature. Enrichment depends strongly on bulk liquid composition, reaching a maximum at an ethanol mole fraction below 0.1, with the maximum enrichment depending on bulk liquid depth and inlet/outlet elevation. The collection rate depends strongly on inlet/outlet elevation and bulk liquid pool depth, and for high ethanol mole fractions is nearly independent of bulk liquid composition. Enrichment and collection rate increase with increasing bulk liquid temperature and decreasing collection temperature. The fact that increasing the carrier-gas flow rate increases the collection rate and decreases enrichment is interpreted in terms of size-selective transport of drops from the ultrasonically-generated fountain where they are atomized, to the cold trap where they are collected. The results are discussed in terms of operating parameters, transport phenomena (including evaporation and gravitational settling of atomized drops), the ultrasonically-induced fountain, and previously reported drop-size distributions. The duration of the experiments, conducted in batch, was such that the results should be relevant to both batch and continuous-flow operation. The work provides guidance and critical data for process scale-up.

Lunar regolith water ice simulation method and characterization

The exploration of lunar water resources has always been a cutting-edge topic in human space exploration. This paper presents a method for gas deposition and ice formation to simulate the mixture of ice and regolith in lunar polar shadowed regions. Following the principles of “physical structure equivalence and environmental parameter approximation,” based on the principle of water molecule deposition and adsorption in a cold trap environment, water ice is converted into water vapor by raising the temperature in a vacuum environment. Then, water molecules deposit and adsorb on the surface of dry, low-temperature mineral particles, forming an ice film under the action of the cold trap capture principle. The morphology and occurrence status of the particle surface ice film has been obtained through microscopic characterization of the samples in a cold environment. Vacuum pressure monitoring equipment is used to verify the pressure changes of water during the sublimation and deposition, and the phase diagram of water is analyzed to understand its state changes within the simulated setup. Samples are retrieved from a high-purity nitrogen glove box, and their water content is verified using thermogravimetric analysis (TGA). The effectiveness of the proposed lunar regolith simulation method is validated through macroscopic and microscopic approaches. This method provides high-fidelity samples for lunar water resource utilization, scientific exploration, and payload development on the Moon.

Potential surface ice distribution on close-in terrestrial exoplanets around M dwarfs

Abstract Previous studies suggested that surface ice could be distributed on close-in terrestrial exoplanets around M-dwarfs if heat redistribution on the planets is very inefficient. In general, orbital and atmospheric parameters play an important role in the climate on terrestrial planets, including the cold-trap region where the permanent surface water reservoir can potentially be distributed. Here, we develop a simple coupled land-atmosphere model to explore the potential surface ice distribution on close-in terrestrial planets with various orbital and atmospheric parameters, assuming that the planets are airless or have a thin N2 atmosphere. We find that the most significant factors in deciding the surface cold trap region are the spin-orbit ratio and obliquity. The incident stellar flux and the surface pressure play a limited role in the thin N2 simulations for incident flux smaller than Mercury’s and surface pressure lower than 104 Pa. Our result illustrates the possible distribution of surface ice on arid terrestrial planets and can help to understand the climate of these exoplanets.

Lunar North Polar Cold Traps Based on Diurnally and Seasonally Varying Temperatures

Lunar cold traps are defined by extremely low sublimation rates, such that water ice could have accumulated in them. Here time-averaged sublimation rates are calculated for the north polar region of the Moon based on over 14 years of Diviner surface temperature measurements. Data for each spatial pixel are binned according to subsolar (diurnal) and ecliptic (seasonal) longitude. The cold trap area poleward of 80°N is about 32% larger when defined by a time-average sublimation rate instead of by peak temperature. Apparently sunlit cold traps are identified, e.g., in Lenard Crater, where modeling of direct illumination reveals that the Sun briefly rises above the horizon each Draconic year. The true cold trap area is smaller than what can be determined from Diviner data. Also presented are north polar maps for the potential sublimation rate of relic buried ice and for subsurface cold trapping.

Properties of Cirrus Cloud Observed over Koror, Palau (7.3°N, 134.5°E), in Tropical Western Pacific Region

This study presented an analysis of the geometric and optical properties of cirrus clouds with data produced by Compact Cloud-Aerosol Lidar (ComCAL) over Koror, Palau (7.3°N, 134.5°E), in the Tropical Western Pacific region. The lidar measurement dataset covers April 2018 to May 2019 and includes data collected during March, July and August 2022. The results show that cirrus clouds occur approximately 47.9% of the lidar sampling time, predominantly between altitudes of 15 and 18 km. Seasonal variations in cirrus top height closely align with those of the cold point tropopause. Most cirrus clouds exhibit low cloud optical depth (COD < 0.1), with an annual mean depolarization ratio of 31 ± 19%. Convective-forming cirrus clouds during the summer monsoon season exhibit a larger size by notably lower values in terms of color ratio. Extremely thin cirrus clouds (COD < 0.005) constituting 1.6% of total cirrus occurrences are frequently observed at 1–2 km above the cold point, particularly during winter and summer, suggesting significant stratosphere–troposphere exchange. The coldest and highest tropopause over Palau is persistent during winter, and related to the pathway of tropospheric air entering the stratosphere through the cold trap. In summer, the extremely thin cirrus above the cold point is likely correlated with equatorial Kelvin waves induced by western Pacific monsoon convection.

Production of [211At]NaAt solution under GMP compliance for investigator-initiated clinical trial.

The alpha emitter astatine-211 (211At) is garnering attention as a novel targeted alpha therapy for patients with refractory thyroid cancer resistant to conventional therapy using beta emitter radioiodine (131I). Herein, we aimed to establish a robust method for the manufacturing and quality control of [211At]NaAt solution for intravenous administration under the good manufacturing practice guidelines for investigational products to conduct an investigator-initiated clinical trial. 211At was separated and purified via dry distillation using irradiated Bi plates containing 211At obtained by the nuclear reaction of 209Bi(4He, 2n)211At. After purification, the 211At trapped in the cold trap was collected in a reaction vessel using 15 mL recovery solution (1% ascorbic acid and 2.3% sodium hydrogen carbonate). After stirring the 211At solution for 1h inside a closed system, the reaction solution was passed through a sterile 0.22μm filter placed in a Grade A controlled area and collected in a product vial to prepare the [211At]NaAt solution. According to the 3-lot tests, decay collected radioactivity and radiochemical yield of [211At]NaAt were 78.8 ± 6.0 MBq and 40 ± 3%, respectively. The radiochemical purity of [211At]At- obtained via ion-pair chromatography at the end of synthesis (EOS) was 97 ± 1%, and remained > 96% 6h after EOS; it was detected at a retention time (RT) 3.2-3.3min + RT of I-. LC-MS analysis indicated that this principal peak corresponded with an astatide ion (m/z = 210.988046). In gamma-ray spectrometry, the 211At-related peaks were identified (X-ray: 76.9, 79.3, 89.3, 89.8, and 92.3keV; γ-ray: 569.7 and 687.0keV), whereas the peak at 245.31keV derived from 210At was not detected during the 22h continuous measurement. The target material, Bi, was below the 9 ng/mL detection limit in all lots of the finished product. The pH of the [211At]NaAt solution was 7.9-8.6; the concentration of ascorbic acid was 9-10mg/mL. Other quality control tests, including endotoxin and sterility tests, confirmed that the [211At]NaAt solution met all quality standards. We successfully established a stable method of [211At]NaAt solution that can be administered to humans intravenously as an investigational product.

Production and recovery system for furan compounds from rice straw using an ionic liquid (1-methylimidazolium hydrogen sulfate) and vacuum steam distillation

Furan compounds, including 5-hydroxymethylfurfural and furfural, can be synthesized from biomass and have garnered attention for their potential applications in biofuels and resin precursors. In this study, the synthesis of the furan compounds from rice straw was explored using a combined approach of ionic liquid treatment, specifically 1-methylimidazolium hydrogen sulfate ([MIM]HSO4), and vacuum steam distillation. Through the optimization of various processing parameters, we established that the best conditions for the furan compound production include: a cold trap cooling temperature of – 196 ℃, a system pressure of 10 hPa, a treatment temperature of 180 ℃, a reaction duration of 30 min, a sample loading of 1wt%, and a particle size range of 45–90 µm. Under these conditions, the resultant yield of the furan compounds was quantified at 27.9wt%. Additionally, the recyclability of the utilized ionic liquid was evaluated. Notably, even after four recycling cycles (encompassing a total of five reactions), the yield of the furan compounds remained consistent, underscoring the viability of ionic liquid reuse.

History of Ceres’s Cold Traps Based on Refined Shape Models

Permanently shadowed regions (PSRs) in the north polar region of Ceres have been previously mapped by the Dawn spacecraft. Putative ice deposits are found in some of these PSRs, whereas most PSRs host no bright deposits, which is thought to be due to oscillations of the axis tilt with a ∼25 ka period. We use stereophotoclinometry to construct refined topographic models of PSR-hosting craters. Ray-tracing calculations reveal that no PSRs remain at the maximum axis tilt, which implies that the ice deposits are remarkably young. The bright ice deposits do not extend beyond PSRs at an axis tilt of 10°, which last occurred about 6 ka ago. This suggests that water is delivered to the polar regions or exposed within the craters by frequent and short-lived events. Surface temperatures are calculated with a terrain irradiance model to delineate cold traps. Based on maximum equilibrium temperatures, Cerean PSRs are too warm to trap supervolatiles.

Soluble Organic Compounds and Cyanide in Apollo 17 Lunar Samples: Origins and Curation Effects

AbstractWe analyzed 12 Apollo 17 samples through the Apollo Next Generation Sample Analysis (ANGSA) program to determine the abundances of a variety of compound classes, including amino acids, aldehydes, ketones, amines, carboxylic acids, and cyanide‐releasing species. Analyzed samples included portions of double drive tube 73001/73002, the bottom half of which (73001) was hermetically sealed under lunar vacuum, as well as lunar regolith samples from three different illumination environments that had been curated frozen for ∼50 years. Consistent with previous results, we detected low levels of amino acids in the hot‐water extracts of most samples (0.55–12.03 nmol/g in unhydrolyzed samples; 0.53–72.38 nmol/g after acid hydrolysis of the extracts). We also detected one‐carbon and two‐carbon species of amines, aldehydes, and carboxylic acids (i.e., methylamine, ethylamine, formaldehyde, acetaldehyde, formic acid, acetic acid) not previously reported in lunar samples, as well as insoluble cyanide‐forming species. Although these compounds are potential precursor molecules for amino acids, no specific precursor relationships could be determined. Nylon contamination was the likely source of some amino acids. Abundances of some species (e.g., cyanide) decreased with increasing depth in the drive tube, suggesting that exogenous delivery and concentration mechanisms near the surface outweighed surface degradation processes. In addition, we observed the potential cold trapping of volatile amines in the persistently shadowed samples analyzed. Finally, we noted the effects of different curation conditions; hermetic sealing appeared to preserve higher amounts of volatile compounds, while frozen curation did not have a noticeable preservation effect on the organic volatiles analyzed here.

Development of the high temperature PbLi experimental facility for CFETR

Chinese Fusion Engineering and Test Reactor (CFETR) aims to demonstrate the fusion energy production up to 200MW, and finally reach commercial electricity power level 1GW. As one key component, the blanket is in charge of tritium breeding, neutron shielding and energy conversion. The liquid breeder blanket has many important advantages of simpler structure, tritium extraction and fuel replenishment online, as well as the high thermoelectric conversion efficiency. Moreover, the supercritical carbon dioxide (S-CO2) cOoled Lithium-Lead (COOL) blanket has been proposed for CFETR. However, the key issue of MagnetoHydroDynamics (MHD) needs further investigation, especially for the experiments. Therefore, the high temperature PbLi experimental loop is under development, which mainly includes three systems of PbLi, oil and water. The main components include the mechanical pump, main heater, cold trap as well as the superconducting magnet. At the test section, the mass flow rate, temperature and magnetic intensity will be up to 32 kg/s, 700 °C and 3T, respectively. In addition, the ultrasonic doppler velocimeter and potential probe instruments will be adopted to obtain the flow field. The main goal is to establish flow and heat transfer models, which are the critical input for the liquid breeder blanket design and optimization.

Determination of organic acids and anions in exhaled breath by condensation collection-ion chromatography

A non-invasive condensation collection-ion chromatography method was established for the determination of organic acids and anions including lactic acid, formic acid, acetic acid, pyruvic acid, chloride, nitrate, nitrite, and sulfate in the exhaled breath of humans. The breath exhaled was condensed and collected using a home-made exhaled breath condensation equipment. This equipment included a disposable mouthpiece as a blow-off port, one-way valve and flow meter, cold trap, disposable condensate collection tube placed in the cold trap, and gas outlet. A standard sampling procedure was used. Before collection, the collection temperature and sampling volume were set on the instrument control panel, and sampling was started when the cold-trap temperature dropped to the set value, while maintaining the balance. Subjects were required to gargle with pure water before sampling. During the sampling process, the subjects were required to inhale deeply until the lungs were full of gas and then exhale evenly through the air outlet. When the set volume was collected, the instrument made a prompt sound; then, the collection was immediately ended, the expiration time was recorded, and the average collection flow was calculated according to the expiration time and sampling volume. After collection, the disposable condensation collection tube was immediately taken out, sealed, and stored in the refrigerator at -20 ℃ away from light, and immediately used for further testing. The organic acids and anions in exhaled breath condensation (EBC) were filtered through a 0.22 μm membrane filter before injection and detected by ion chromatography with conductivity detection. Factors such as collection temperature and collection flow rate during condensation collection were optimized. The optimal cooling temperature was set at -15 ℃, and the optimal exhaled breath flow rate was set at 15 L/min. The mobile phase consisted of a mixture of sodium carbonate (1.5 mmol/L) and sodium bicarbonate (3 mmol/L). The flow rate was 0.8 mL/min, and the injection volume was 100 μL. An IC-SA3 column (250 mm×4.0 mm) was used, and the temperature was set at 45 ℃. An ICDS-40A electrodialysis suppressor was used, and the current was set at 150 mA. The linear ranges of the eight organic acids and anions were 0.1-10.0 mg/L; their correlation coefficients (r) were ≥0.9993. The limits of detection (LODs) for the eight organic acids and anions were 0.0017-0.0150 mg/L based on a signal-to-noise ratio of 3, and the limits of quantification (LOQs) were 0.0057-0.0500 mg/L based on a signal-to-noise ratio of 10. The intra-day precisions were 5.06%-6.33% (n=5), and the inter-day precisions were 5.37%-7.50% (n=5). This method was used to detect organic acids and anions in the exhaled breath of five healthy subjects. The contents of organic acids and anions in the exhaled breath were calculated. The content of lactic acid was relatively high, at 1.13-42.3 ng/L, and the contents of other seven organic acids and anions were 0.18-11.0 ng/L. During a 10 km-long run, the majority of organic acids and anions in the exhaled breath of five subjects first increased and then decreased. However, due to abnormal metabolism, the content changes of lactic acid, acetic acid, pyruvic acid and chloride in one subject were obviously different from others during exercise, showing a continuous rise. This method has the advantages of involving a simple sampling process and exhibiting good precision, few side effects, and no obvious discomfort or risk to the subjects. This study provides experimental ideas and a theoretical basis for future research on human metabolites.

Tuning selectivity in low-temperature Fischer-Tropsch synthesis by applying gas recycle mode

While hydrocarbons production by Fischer-Tropsch synthesis (FTS) is widely recognized, commercial interest in FTS products is mainly constrained by oil prices. The FTS-derived fuels, although higher quality and greener, cannot currently compete with cheaper fossil fuels, motivating to shift the FTS products distribution to higher value-added chemicals, such as olefins-C5+. The high olefin selectivity in FTS over Co-based catalysts is usually ascribed to Co2C on the catalyst surface with its inherent deficiencies. This study demonstrates a novel approach to alter low-temperature FTS selectivity by applying off-gas recycling. At slow gas recycling rates, C19+ selectivity increases due to re-adsorption and re-incorporation into the growing chain of gaseous olefins from the off-gas. High-intensity gas recycling facilitates C5+ olefin vapors removal from the reactor by enhanced gas flow with their subsequent cut-off in the cold trap, thus reducing residence time of condensed olefins and probability of their secondary reactions.