At the European Spallation Source (ESS) ERIC, the liquid hydrogen moderator development is undertaken for its predominantly high parahydrogen fraction, which helps to attain a higher neutron intensity at a very high brightness. The Cryogenic Moderator System (CMS) is equipped with a catalyst to convert hydrogen from the ortho to the parastate to keep desirably high parahydrogen fractions of more than 99.5% in the cold moderators, which is required to deliver high brightness cold neutron beams to the neutron instruments. An in-situ measurement system for the ortho and para fractions of liquid hydrogen (OPMS) has been developed using a Raman spectroscopy to detect any undesirable shift towards a high orthohydrogen fraction caused by neutron scattering driven para-to-ortho back conversion. A Raman optics system was installed into a mock-up OPMS vacuum chamber and its performance evaluation tests have been conducted by flowing liquid hydrogen. It was verified that the developed Raman optics system succeeded in measuring the parahydrogen fraction with an accuracy of 0.1%, which met the requirement.