Cold-bonded Pellets Research Articles

Assessment of the properties of concrete containing artificial green geopolymer aggregates by cold bonding pelletization process

Recently, the usage of a cold-bonded method in the production of artificial green geopolymer coarse aggregates (GCA) has been crucial from an economic and environmental perspective because the sintering method consumes an enormous quantity of energy and generates a significant quantity of pollutants. This research investigated the manufacture of GCA via cold-bonded pelletization using two distinct industrial byproducts (GGBFS and FA) via a new and simpler pelletization technology. Three different binders were used to produce three distinct types of GCAs as partial replacements for natural coarse aggregate (NCA) at varying replacement rates (0%, 25%, 50%, and 75%). The first group used ground-granulated blast furnace slag, while the second used GGBFS with perlite, and the third used FA with perlite. An alkaline activator was commonly used with all three groups. The physical and mechanical properties of three distinct varieties of GCA were recorded. The results indicated that the mechanical and chemical properties of three different types of GCAs were nearly identical to those of natural aggregate, with the exception of their increased water absorption. According to the findings, the recommended mixtures were suitable for usage in the construction industry. The results indicated that the ratio of all investigated attributes declined as the number of GCAs increased. In contrast, lightweight concrete can be obtained at a ratio of GCA (FA with perlite) equal to 75%, where unit weight, compressive, splitting tensile, flexural, and water absorption strengths were 1.87 gm/cm3, 20.2 MPa, 1.8 MPa, 8 MPa, and 6.0%, respectively (FA with perlite).

Reduction characteristics of cold-agglomerated pellets in blast furnace conditions

There is a significant and necessary drive towards reducing CO2 emissions produced by iron and steelmaking industries. Binding Solutions Ltd has developed a technology to contribute to the reduction of CO2 in the short and long term, by introducing a cold-bonded iron ore pellet to the furnace burden. Binding Solutions’ cold-agglomerated pellets, manufactured from magnetite and hematite iron ore, were tested in accordance with ISO standard tests alongside a standard market pellet. ISO standards were developed to assess the quality of lump ore, sinter and hot-bonded or alternatively known as indurated pellets, and there can be anomalies when testing cold-agglomerated pellets by the same methods. Additional test methodology, outside the scope of international standards may be utilised to give a fuller picture of pellet characteristics. The HOSIM test method was used to assess the properties of cold-bonded pellets of different minerologies. Results found that the time needed to reach a set point of reduction for a cold-agglomerated pellet is shorter than for an indurated control pellet. The data also showed that for the same iron ore source, alternate cold agglomeration methods can have a significant impact on the balance of pellet properties.

Innovative B-PA binder for enhanced cold pelletization: a sustainable strategy for utilizing iron-containing dust and sludge

A large amount of iron dust and sludge is produced in the process of iron and steel metallurgy, and its efficient utilization has important economic value and environmental significance. In this study, a method of cold-bonded aggregate is used to co-process stainless steel pickling sludge (SSPS) and gravity dust (GD). The preparation process parameters of cold-bonded pellet are optimized. The role mechanism of the binder on cold-bonded aggregates is studied, and a new type of composite binder, bentonite-plant asphalt (B-PA), is invented. The optimal ratio of bentonite to plant asphalt is determined to be 3:1. The metallurgical performance of B-PA agglomerates is tested, with results showing an RDI+3.15 at 93.6%, a RI at 79.3%, an RSI at 14.2%, a DI at 4.01%, and a thermal cracking temperature reaching 721 °C. The microstructure of the agglomerates after performance testing is characterized using XRD and SEM. This cold-bonding pelletization technology is expected to be widely used in the efficient comprehensive utilization of metallurgical dust in the future, which is of great significance for reducing costs, increasing efficiency, and promoting green environmental protection in the steel industry.

Production, properties and life cycle assessment of artificial lightweight aggregates produced with corn straw ash (CSA) and concrete slurry waste (CSW)

Open burning of corn straw has been a long-standing environmental problem in developing agricultural countries. The development of the concrete material industry supplies a feasible consumption outlet for the bulk solid wastes from agriculture and construction fields. In this study, therefore, corn straw and concrete waste were turned into available cementitious materials: corn straw ash (CSA) and concrete slurry waste (CSW) powder. Then CSA and CSW were reused to be artificial lightweight aggregates (ALAs) by cold-bonding pelletization and carbonation curing. A multi-criteria decision-making model for ALAs was finally proposed to comprehensively evaluate the technical, environmental, and economic factors and select the most valuable candidate. The findings indicate that it is technically feasible to produce ALAs by using CSA and CSW. The optimal mechanical parameters of the disc granulator are 35 rpm and 45° inclination in the cold-bonding pelletization process of ALA production. From a technical point of view, with the increase of CSA content in ALAs, the strength of ALAs increased first and then decreased, reaching the optimum value of 14.2 MPa with the addition of 5% CSA. According to the sustainability score, the descending order of ALAs is C1, C4, C3, C2 and C0. Sustainability results show that the ALAs of the mixture of 5 wt% CSA and 95 wt% CSW is the optimal solution. The ALAs with dual-function in terms of reducing CO2 emissions and capturing CO2 is a promising candidate for low-carbon concrete production. The decision model could be suitable for the sustainable selection of artificial aggregates or recycling construction materials.

Producing of alkali-activated artificial aggregates by pelletization of fly ash, slag, and seashell powder

In the construction sector, the material supply chain of aggregates is frequently disturbed due to seasonal unavailability, quarrying issues, and environmental norms. The production of artificial aggregates has gained prominence to conserve natural resources and promote green construction practices. The current study encompasses the production of alkali-activated artificial aggregates through cold-bonding pelletization technique using three different raw materials, including fly ash, ground granulated blast furnace slag, and seashell powder in binary and ternary blending combinations. The cold bonding was achieved by alkali activation of binders with the aid of a sodium-based alkaline solution, which acts as an activator and hydrating liquid. The fresh artificial aggregates were subjected to surface treatment using the same alkaline solution to enhance their characteristics. The mechanical properties of artificial aggregates confirmed their potential as a substitute for conventional aggregates by exhibiting crushing and impact values of 18.19–27.53% and 12.06–18.85%, respectively. The microstructural and mineralogical characteristics depicted dense microstructure and compact matrix. The study concludes that artificial aggregates can effectively replace natural coarse aggregate in making structural concrete with many economic, environmental, and technical advantages.

Developing Iron Ore Pellets Using Novel Binders for H2-Based Direct Reduction

The transformation from traditional iron- and steelmaking technologies to green H2-based new technologies will require an improvement in the quality and purity of iron ore burden materials. Iron ore pellets are essential inputs for producing direct reduced iron (DRI), but the conventional binders, used in iron ore pelletizing, introduce gangue oxides to the DRI and consequently increase the slag generation and energy consumption in the steelmaking unit. Partial and/or full replacement of the traditional binders with novel organic binders would significantly contribute to improving the process efficiency, particularly in the next-generation H2-based direct reduction technology. This study illustrates the feasibility of pelletizing magnetite iron ore concentrate using four organic binders: KemPel, Alcotac CS, Alcotac FE16, and CMC, in comparison to bentonite as a reference. The study explores the influence of binder type, binder dosage, and moisture content on the characteristics and properties of the pellets. The efficiency of binders was characterized by the moisture content, drop number test, cold compression strength, and H2 reduction of pellets. For dry pellets, CMS was superior among other binders including bentonite in developing dry strength. After firing, the pellets produced by the partial replacement of bentonite with 0.1 wt.% KemPel demonstrate a performance nearly identical to the reference pellets. While the complete replacement of bentonite with organic binder shows a lower performance of fired pellets compared to the reference, it may still be suitable for use in DR shaft furnaces. The cold-bonded pellets demonstrate a superior reduction rate compared to fired pellets.

Green Building Materials: Mechanical Performance and Environmental Sustainability

In recent years, in the field of waste management, waste-to-energy plants have been attained great attention as a valid method for mitigating landfill disposal in addition to valorizing waste from the energy point of view. Moreover, there are several technological proposals aimed at valorizing and reusing the residues produced by incinerators. Nonetheless, pre-treatment and treatment techniques, including washing and the solidification/stabilization process, may be necessary for the recovery and recycling of this type of by-product. In this regard, the objective of this research is the production of lightweight artificial aggregates with acceptable quality, capable of guaranteeing specific requirements and technical performance, through the recycling of fly ash derived from municipal solid waste incineration (MSWI). The properties of the three types of aggregates, produced through the cold-bonding pelletization, were evaluated through the mechanical and leaching tests.

Mechanical Properties of Concrete Produced by Light Cement-Based Aggregates

There is great growing concern regarding the environmental impact of the building and construction industry. Aggregate, one of the most crucial ingredients of concrete, is among the concerns in this regard. There will be a steady increase in demand for aggregates in the near future, but limited natural reserves will not be able to respond to this demand due to the risk of depletion. This current situation is forcing researchers to conduct new and artificial material production techniques that keep the resources within the allowed boundaries. Artificial aggregate production is one of the new methods for sustainable, environmentally friendly material production. The mechanical and environmental properties of lightweight concrete produced via artificial aggregates in different ratios were investigated in this study. Fly ash (FA), ground granulated blast-furnace slag (GGBFS), and quartz powder (QP) were utilized in the production of artificial lightweight aggregate (LWA) by using a special technique known as cold-bonding pelletization. The prepared concrete samples with the artificial aggregates were subjected to compressive, tensile, flexural, and bonding tests. The test results demonstrated that the bonding, tensile, and compressive strength values of lightweight concrete with a 20% GGBFS coarse aggregate replacement ratio of lightweight aggregates increased by 11%, 12%, and 30%, respectively. Moreover, it has been observed that a 41% increase in compressive strength is possible with a 40% QP coarse aggregate replacement ratio of lightweight aggregates. Finally, in addition to significantly impacting the mechanical properties of the lightweight concrete produced via artificial lightweight aggregates, we demonstrated that it is possible to control and reduce the harmful environmental effects of waste materials, such as FA, GGBFS, and QP in the present study.

Production and characterization of lightweight aggregates from municipal solid waste incineration fly-ash through single- and double-step pelletization process

The performance of a cold-bonding pelletization process was investigated for lightweight aggregates (LWAs) production from municipal solid waste incineration (MSWI) fly-ash (FA), by including multiple waste materials in the aggregate mixture. Before pelletization, FA was pre-treated by washing with water, which led to a reduction of chloride (66.79%) and sulphate (25.30%) content. This was further confirmed by XRF and XRD analyses, which showed a reduction of chloride elements and the content of chlorine crystalline phases. The pelletization process was carried out using both single- and double-step methods. For single-step pelletization, all the mixtures contained 80% FA, combined with various compositions of cement (5, 10, and 15%) and granulated blast furnace slag (GBFS) (5, 10, and 15%). For the double-step pelletization 30% of cement and 70% of marble sludge (MS) were added to each of the previous mixtures. The apparent density of all the aggregates varied between 1.60 and 1.87 g cm−3, suggesting their suitability to be classified as LWAs. Aggregates produced from double-step pelletization showed improved characteristics, with water absorption capacity and open porosity generally lower compared to the corresponding aggregates from the single-step pelletization. The best values of compressive (crushing) strength (almost 11 MPa) were observed for double-step pelletization aggregates with initial cement: GBFS mixture of 15%:5%. Results from leaching tests showed an overall significant release of chloride and sulphate. Nevertheless, leaching from double-step pelletization aggregates was reduced by 1.73-4.02 times for chloride and 1.58-5.67 times for sulphate, further suggesting that better performances are achievable through the addition of an aggregate second layer.

Cold Bonded and Low Temperature Sintered Artificial Aggregate Production by Using Waste Materials

The paper presented the possibility of manufacturing aggregates from industrial waste materials and their ecological benefits. The cold bonding process to create aggregates uses substantially less energy than the sintering technique. This study deals with the outcomes of an experimental assessment of the physical and strength properties of environment-friendly cold-bonded and sintered fly ash (FA), ground granulated blast furnace slag (GGBFS), and quartz (Q) lightweight aggregates. The waste materials were mixed with Portland cement at 20–50 percent by weight to make artificial lightweight aggregates. To investigate the impacts of temperature on the physical properties, such as crushing strength, density, and water absorption, the pellets were sintered at 300, 600, and 900 °C for an hour. The results show that all the produced aggregates might be categorized as lightweight aggregates due to the combinations' average densities being less than 2,000 kg/m3. The fly ash lightweight aggregates had higher density and crushing strength, as well as decreased water absorption. The density and crushing strength improved somewhat by raising the temperature, while the water absorption decreased with increased temperature. In this research, the most efficient mineral admixture concentration has been evaluated as 50 percent for both fly ash and ground granulated blast furnace slag and 30 percent for quartz for cold-bonded pellets. Furthermore, superior physical qualities have been reported at the 900 °C sintering temperature.

Impact of manufactured fiber aggregate in the production of lightweight concrete

The present investigation experimentally tested the impact of alkali-resistant glass fibres (AR-GF) on manufactured aggregate properties through cold-bonding pelletization and the impact of manufactured aggregates in the production of lightweight concrete. The aggregates manufactured in this study were produced with a combination of 80% fly ash, 10% cement and 10% hydrated lime at 0%, 0.10%, 0.12%, 0.14%, 0.16%, 0.18%, 0.20% addition of AR-GF. Seven mixture combinations of aggregates were tested with various properties like production efficiency, bulk density, specific gravity, water absorption, and impact strength. Selected the optimum mixture combination of manufactured aggregate to study lightweight concrete's slump, density, and compressive strength and compared with natural aggregate concrete. Test results on manufactured aggregates indicate that, as the percentage addition exceeds 0.18% of AR-GF, aggregate properties do not show adequate results. Also, the lightweight concrete result shows that slump value increases with manufactured aggregate. Similarly, the compressive strength result satisfies the structural grade for concrete. The utilization of manufactured aggregates in the production of lightweight concrete results in both economic and ecological benefits.

Preparation process of cold bonded pellets with iron-bearing dust and sludge from steel production process

Blast furnace dust (BFD) and converter sludge (CS) were used as raw materials for preparing of cold bonded pellets (CBPs). The results showed that BFD contained high content of C, Fe and harmful element of Zn. Conversely, the CS had more Fe and Ca content and less Zn. BFD particles are mostly large and irregular in shape with poor hydrophilicity, whereas CS particles are generally smaller spherical and could bond together easily. Additionally, the main factors influencing the performance of CBPs are the binder, moisture, and pressing pressure. By controlling the mixing ratio of BFD and CS, selecting the appropriate binder and binder amount, and controlling the moisture and pressure, CBPs with a compressive strength and a falling strength of up to 142.7 N and 8.34 times, respectively, can be prepared, thus meeting the requirements of the rotary hearth furnace and the OxyCup production process.

Experimental & computational study on fly ash and kaolin based synthetic lightweight aggregate

The objective of this study is to manufacture environmentally-friendly synthetic lightweight aggregates that may be used in the structural lightweight concrete production. The cold-bonding pelletization process has been used in the agglomeration of the pozzolanic materials to achieve these synthetic lightweight aggregates. In this context, it was aimed to recycle the waste fly ash by employing it in the manufacturing process as the major cementitious component. According to the well-known facts reported in the literature, it is stated that the main disadvantage of the synthetic lightweight aggregate produced by applying the cold-bonding pelletization technique to the pozzolanic materials is that it has a lower strength in comparison with the natural aggregate. Therefore, in this study, the metakaolin made of high purity kaolin and calcined kaolin obtained from impure kaolin have been employed at particular contents in the synthetic lightweight aggregate manufacturing as a cementitious material to enhance the particle crushing strength. Additionally, to propose a curing condition for practical attempts, different curing conditions were designated and their influences on the characteristics of the synthetic lightweight aggregates were investigated. Three substantial features of the aggregates, specific gravity, water absorption capacity, and particle crushing strength, were measured at the end of 28-day adopted curing conditions. Observed that the incorporation of thermally treated kaolin significantly influenced the crushing strength and water absorption of the aggregates. The statistical evaluation indicated that the investigated properties of the synthetic lightweight aggregate were affected by the thermally treated kaolin content more than the kaoline type and curing regime. Utilizing the thermally treated kaolin in the synthetic aggregate manufacturing lead to a more than 40% increase in the crushing strength of the pellets in all curing regimes. Moreover, two numerical formulations having high estimation capacity have been developed to predict the crushing strength of such types of aggregates by using softcomputing techniques: gene expression programming and artificial neural networks. The R-squared values, indicating the estimation performance of the models, of approximately 0.97 and 0.98 were achieved for the numerical formulations generated by using gene expression programming and artificial neural networks techniques, respectively.

Study on Binder of Cold-Bonded Pellets Containing Basic Oxygen Furnace Dust Based on Hydration Mechanism of Magnesium Potassium Phosphate Cementitious Material

Basic Oxygen Furnace (BOF) dust can be mixed with binders to prepare cold-bonded pellets and return to BOF for recycling, because of its high total iron and alkaline oxide content. Nevertheless, the lengthy digestion reaction of dead-burned MgO and CaO contained in BOF dust causes expansion and cracking of the pellets, which seriously affect the pellet strength. In this study, it was first proposed to use a hydration reaction between dead-burned MgO and KH2PO4 to form bonding phases based on the hydration mechanism of magnesium potassium phosphate (MKP) cementitious material, to solidify MgO contained in BOF dust and improve the pellet strength. The key issue of using MKP cementitious material as a binder to improve the pellet strength is to choose appropriate magnesium-to-phosphate molar ratio M/P and water-to-binder mass ratio w/b. Based on this, cold-bonded pellets were prepared by using different ratios of MKP binder. The compressive strength, hydration products, microstructure and thermal properties of the pellets were analyzed, and the bonding mechanism of MKP binder in the pellets was proposed. The results show that the pellets have the highest mechanical strength and the most K-Struvite crystals under M/P molar ratio of 4 and w/b mass ratio of 0.5. At high temperatures, K-Struvite crystals will not evaporate harmful phosphorus-containing substances due to the decomposition of the binder components. MKP binder is unevenly distributed in the pellets: in the binder concentrated areas, the massive and dense K-Struvite crystals wrap BOF dust particles; in the binder decentralized areas, the fine K-Struvite crystals are filled between the dust particles or adhere to the surface of dust matrix, connecting the dust particles into a whole.

The Impact of Artificial Lightweight Aggregate on the Engineering Features of Geopolymer Mortar

In this study, a research on the effectiveness of artificial lightweight aggregate (A-LWA) on the fresh and hardened properties of geopolymer mortars is presented. The main aim of this study is to propose a relatively newer means of recycling of FA through geopolymer mortar production. Therefore, firstly, artificial lightweight aggregate (A-LWA) was produced through the cold-bonding pelletization process of FA. Then, FA based geopolymer mortars were produced with this aggregate. The geopolymer mortars manufactured in this study had constant source material and alkaline activator quantities of 600 and 300 kg m-3, respectively. The proportion of Na2SiO3-to-NaOH was 2.5 and the molarity of NaOH was 12 M. The A-LWA sand was replaced partially with river sand up to 100%. The compressive strength, ultrasonic pulse velocity, fresh and dry densities of the geopolymer composites were measured at the age of 7 days and the flow table test was conducted to indicate the consistency of the geopolymer mixtures. The results indicated the A-LWA utilization enhanced the workability of the geopolymer mixtures and the highest increase of flow diameter of %20 was obtained using 100% A-LWA. Compressive strength values of geopolymer mortars varied between 4.28 and 32.3 MPa. A systematical decrease in the compressive strength and revealed with respect to the increasing level of A-LWA due to the softness and weakness of the A-LWA particles. Ultrasonic pulse velocity results of geopolymer mortars ranged from 1479 to 2596 m s-1 with related the replacement level of A-LWA.

Cold-bonding process for treatment and reuse of waste materials: Technical designs and applications of pelletized products

This work provides a comprehensive review of research on the cold-bonding pelletization process used to produce lightweight aggregates (LWAs) using waste materials, to valorize the waste and, at the same time, minimize risks related to disposal. Research investigating various aspects of the cold-bonding process highlight: i) feasible mix-designs for pellet production; ii) the most relevant operating parameters affecting the process; and iii) the potential applications of the LWAs produced. The analysis gives a wide overview of the fundamental key-points that control the cold-bonding process. Data comparison provides a useful way to identify the optimal process conditions to allow development of optimum products. This involves the selection of the correct mix-design, including suitable binders and potential additives, and the selection of appropriate operating conditions, which are a function of the waste investigated, and/or waste mix characteristics. The review proposes an optimized approach to experimental studies on cold-bonding processes that has potential to enhance future process performance. Moreover, the present work provides a complete framework useful for decision-making for both manufacturers and researchers working to use this promising technique.

Hydration and Crystallization Behavior of MgO in Cold-Bonded Pellets Containing Basic Oxygen Furnace Dust

Basic oxygen furnace (BOF) dust is a kind of solid waste in the metallurgical steelmaking process, which contains more than 50 pct total iron and a certain amount of overburned MgO and CaO. Based on the nonhydraulic cementitious property of MgO in BOF dust, MgCl2 is added together as a binder to prepare cold-bonded pellets returning to BOF, which is the most economical route to recycle secondary resources. In this study, we investigated the hydration and crystallization behavior of MgO-based binder prepared by MgO superheated at 1500 °C and MgCl2 in cold-bonded BOF dust pellets, to solve the problem of whether the overburned MgO can be hydrated with MgCl2 to form crystalline phases, and generated nonhydraulic cementitious structure with high strength to consolidate the pellets. The results show that the overburned MgO prepared at 1500 °C and MgCl2 can form adhesive gels to absorb BOF dust particles by hydration reaction. The gels develop to 5Mg(OH)2·MgCl2·8H2O crystalline phase with a reticular structure after solidification, and the crystalline phase produces pellet mechanical strength by wrapping and connecting bridge. The hydration reaction produced by overburned MgO is incomplete, and the hydration reaction degree is 50 to 65 pct.

Strength enhancement of artificial aggregate prepared with waste concrete powder and its impact on concrete properties

Waste concrete powder (WCP), a byproduct generated in the production of recycled concrete aggregates, is proposed as the main material for manufacturing artificial aggregate (WCPA) through cold-bonding pelletization. The addition of cement, ground granulated blast furnace slag and calcium hydroxide as well as the application of CO2 curing are integrated with the purpose of strength enhancement. Experimental results indicate that aggregate strength increases in proportion with cement and slag dosages while calcium hydroxide content reaches the optimum at 3%. By optimizing mix proportion, the aggregate obtains the highest strength of 3.0 MPa and the lowest water absorption of 6.3%. In addition, when it is incorporated in concrete, WCPA shows stronger interactions with cement matrix as compared with natural aggregate and ceramsite since the width of interfacial transition zone is only 30 μm as compared to 60 μm in the reference groups. The compressive strength of WCPA concrete reaches over 30 MPa, suggesting the viability of WCPA in many civil engineering applications; however, it is found that the drying shrinkage tends to increase by up to 47%. Overall, this study contributes to the establishment of waste to resources chain with regards to the concrete industry through the green production of artificial aggregate with WCP.

Sodium Silicate Cold-Bonded Chromite Pellets for the Ferrochromium Industry – Identifying a Suitable Process

Abstract Chromite fines (defined as particles smaller than 6 mm) account for a significant fraction of mined South African chromite ore. These fines are pelletized to allow safe furnace smelting conditions. However, pelletization is an energy- and cost-intensive process that requires significant capital investment and has high operational costs as continuous curing temperatures of 1300 – 1500 °C are required. In this study, various cold-bonded pelletization processes were investigated to identify a process to prepare cold-bonded chromite pellets. A feasible process was identified and developed to produce mechanically strong chromite pellets using 3wt% sodium silicate-3 wt% SiO2 as the binder and KOH as an alkaline activator. The binding mechanism is based on the combined effects of sodium silicate and geopolymerization. It was determined that pellets cured at 75 °C had compressive strengths of 2.41 – 3.12 kN. The mechanical strength of these cold-bonded pellets where similar to, or exceed that of pellets currently used in the FeCr industry.

Thermal Properties of Carbon-Containing Iron Ore Composite Prepared by Vapor Deposition of Tar for Limonite

The optimal conditions for preparing composites, in which tar-derived carbonaceous materials completely fill the pores in Indonesian limonite(IL), were investigated using the vapor deposition (VD) method of tar. Characterization of the composites and their reactivity (reduction/combustion/gasification) during heat treatment was examined. The specific surface area and pore volume of the as-received-IL and dehydrated-IL decreased after the VD treatment for different combinations of tar pyrolysis temperature (TPT) and VD temperature (VDT). It was also noted that the carbon content and crushing strength of the samples increased after the VD treatment, and the optimal values for the TPT-VDT are 700 °C and 350 °C. The C content and the crushing strengths of the composites prepared at TPT-VDT = 700 °C to 350 °C increased with an increase of the VD time to 50 pct carbon content and 10 daN at 240 minutes, respectively. The strength was similar to that of commercial metallurgical coke used in blast furnaces. The reduction of the composite prepared at TPT-VDT = 700 °C to 350 °C for 240 minutes started above 400 °C and was almost completed at 1000 °C. This reduction rate was higher than that of commercial cold-bonded pellets or a coke/IL mixture. The combustion and gasification rates of the composites prepared under different conditions depended on the preparation condition of composites, and the rates were higher than those of commercial metallurgical coke used in blast furnaces.