High-performance ferroelectric materials have garnered increased attention due to their exceptional dielectric, piezoelectric, and electrostrictive properties. A solid-state reaction method was used to prepare the perovskite Pb(1-x)Smx[(Zr0.52Ti0.48)0.9(Mo1/3In2/3)0.05(Zn1/3Sb2/3)0.05]O3 (where x = 0, 0.02, 0.04, 0.06, and 0.08) ceramics, abbreviated PSZT-PSMI-PSZS. Energy-dispersive X-ray spectroscopy (EDX) and Fourier-transform infrared (FT-IR) spectroscopy were employed to verify the elemental composition and molecular structure, respectively. The results showed good agreement between nominal and measured compositions, and indicated structural changes post-calcination, suggesting successful formation of the perovskite phase. Piezoelectric properties were evaluated, revealing the highest piezoelectric coefficient (d33 = 310 pC/N) at x = 0.02, attributed to optimal morphological features and the morphotropic phase boundary effect. This sample also demonstrated the highest electromechanical coupling factors (kp = 60 %, k31 = 35 %) and the largest impedance resonance frequency difference (Δf = 15.05 kHz). Ferroelectric testing indicated excellent ferroelectric characteristics, with the maximum remanent polarization (Pr = 17.71 μC/cm2) and saturation polarization (Ps = 22.75 μC/cm2) observed at x = 0.02, along with the lowest coercive field (Ec = 10.16 kV/cm). Additionally, this composition exhibited the highest unipolar strain (Smax = 0.17 %) and the inverse piezoelectric coefficient (d∗33 = 427.57 p.m./V). This comprehensive analysis emphasizes the potential of Sm-doped PZT-PMI-PZS ceramics for advanced piezoelectric and ferroelectric applications, particularly at a doping concentration of x = 0.02, where the materials exhibited excellent electrical and mechanical properties.
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