Cobalt In Soils Research Articles

Accumulation of heavy metals (Cr, Cu, As, Cd, Pb, Zn, Fe, Ni, Co) in the water, soil, and plants collected from Edayar Region, Ernakulam, Kerala, India

The accumulation of heavy metals in the environment is a significant concern due to their potential toxicity and persistence. This study investigates the levels of heavy metal contamination in the water, soil, and plants of the Edayar region in Ernakulam, Kerala, India. The region has experienced industrialization and urbanization, leading to concerns about heavy metal pollution. The study aims to assess the concentrations of chromium (Cr), copper (Cu), arsenic (As), cadmium (Cd), lead (Pb), zinc (Zn), iron (Fe), nickel (Ni), and cobalt (Co) in water, soil, aquatic and terrestrial plants. Samples were collected from various locations within the Edayar region, and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) was conducted to quantify heavy metal concentrations. The findings of this study will contribute to the assessment of heavy metal pollution in the Edayar region. Plants with a high diversity index were taken for analysis from both aquatic and terrestrial habitats. Scoparia dulcis L. seems to specialize in metal accumulation, possibly for protective purposes. Synedrella nodiflora Gaertn demonstrates adaptability to metal-rich environments through robust metal uptake and tolerance mechanisms. Alternanthera philoxeroides (Mart.) Griseb, on the other hand, appears to have developed mechanisms to manage heavy metal exposure. The results indicate significant levels of heavy metal contamination across all samples, with the highest concentrations detected in soil, followed by water and plants. Chromium and lead levels in soil exceeded the permissible limits set by international standards, posing potential risks to human health and the ecosystem. The accumulation patterns in plants varied, with higher bioaccumulation factors observed for zinc and copper, suggesting their preferential uptake. This study highlights the urgent need for remediation strategies and continuous monitoring to mitigate the impact of heavy metal pollution in the Edayar region. The results will help in understanding the environmental impact of human activities.

New insights into assembly processes and driving factors of urban soil microbial community under environmental stress in Beijing

Rapid urbanization leads to drastic environmental changes, directly or indirectly affecting the structure and function of soil microbial communities. However, the ecological response of soil microbes to environmental stresses has not yet been fully explored. In this study, we used high-throughput sequencing to analyze the assembly mechanism and driving factors of soil microbial community under environmental stresses. The results indicated that environmental stresses significantly affected soil properties and the levels of beryllium, cobalt, antimony, and vanadium contamination in soil generally increased from the suburban areas toward the city core. The composition and distribution of soil microbial communities demonstrated clear differences under different levels of environmental stress, but there was no significant difference in microbial diversity. Random forest and partial least squares structural equation modeling results suggested that multiple factors influenced microbial diversity, but antimony was the key driver. The influence of environmental stress led to deterministic processes dominating microbial community assembly processes, which promoted the regional homogenization of soil microbes. Therefore, this study provides new insights into urban soil microbial management under environmental stresses.

Nickel, chromium, and cobalt in soils developed on nickel laterites near an abandoned mining area in southern Czech Republic

Geochemical anomalies are gaining importance due to the Europe's renewed prospecting activities for technologically critical metals, such as nickel (Ni) and cobalt (Co). In this context, soils developed on Ni laterites near old open pit mining and exploration works near Křemže in southern Czech Republic were investigated using multi-method approach to assess the distribution, solid speciation, and (bio)availability of the trace metals, with a particular focus on Ni, chromium (Cr), and Co. The total concentrations of metals in the studied soils (Ni: 170–4950 mg/kg, Cr: 56–1190 mg/kg, Co: 14–424 mg/kg) exceeded the median world regulatory guideline values (Ni: 112 mg/kg; Cr: 250 mg/kg; Co: 50 mg/kg) as well as the Czech concentration limits for agricultural soils for most of the samples. The concentration of metals in the soil profiles generally increased as a function of depth with surface horizons in agricultural plots homogenized by ploughing. The effect of a former open pit mine (already closed for ca 80 years) on the vertical distribution of metallic elements has not been demonstrated. The extractable metals were relatively low (extraction efficiency order: water < DTPA < EDTA). The mean EDTA-extractable values corresponded to 4.2 % Nitot, 8.6 % Cotot, and only 0.14 % Crtot. This contrasting metal availability is strictly related to the metal speciation in the solid phase. The primary minerals (olivine, clinopyroxene) are highly weathered to secondary phyllosilicates (lizardite, talc) and Fe oxyhydroxides and Mn oxides, all representing important carriers for Ni. Cobalt was exclusively hosted by Mn oxides, and the less mobile Cr was mainly bound in insoluble phases, likely spinel-family oxides. Despite the relatively low metal availability, elevated concentrations of Ni in the crop biomass (86 mg/kg) collected in the agricultural area suggest a metal uptake from the soil, which should be further investigated in detail.

Heavy metal toxicological analysis of vegetables cultivated in sewage-irrigated soil in the Indian metropolis of Ahmedabad City, Gujarat

Using wastewater for irrigation poses a significant health risk. We measured the concentration of (cobalt, chromium, copper, manganese, nickel, lead, and zinc) in wastewater, soil, and vegetation at 8 sites along a 60 km stretch of the Sabarmati River in Ahmedabad city. An evaluation of the potential danger from consuming contaminated vegetables was conducted using Estimated Daily Intake (EDI), Target Hazard Quotient (THQ), and Target Cancer danger (TCR). The average concentration of the metals Co, Cr, Cu, Mn, Ni, Pb, and Zn exceeds the maximum permitted limits for irrigation purposes as established by regulatory bodies. The heavy metals in the collected soil sample are ranked in descending order of concentration as follows: Zn &gt; Mn &gt; Cu &gt; Cr &gt; Ni &gt; Pb &gt; Co. The average metal concentrations in vegetables range from 0.10-11.3 µg g-1 for Co, 5.2-11.8 µg g-1 for Cr, 0.04-9.9 µg g-1 for Cu, 12.3-110 µg g-1 for Mn, 0.7-4.2 µg g-1 for Ni, 0.4-8.4 µg g-1 for Pb, and 4.4-44 µg g-1 for Zn. The mean content of heavy metals (µg g-1) in the collected vegetable samples is highest in spinach, followed by brinjal, cabbage, tomato, and cauliflower. The Hazardous Quotient (THQ) shows a high health risk for Pb (6.1) and Mn (1.02), and a medium health risk for Cr (0.9). The Target Cancer Risk (TCR) emphasized the cancer risk posed by Chromium (Cr) and Nickel (Ni), following with Lead (Pb). The study indicates a link between health risks and consuming vegetables grown in the study area. It recommends improving wastewater treatment facilities and monitoring heavy metal levels in vegetables grown in soil irrigated with wastewater at regular intervals.

Assessment of heavy metals pollution status of surface soil dusts at the Katima Mulilo urban motor park, Namibia

The aim of the study was to examine the pollution status of environmentally concerned heavy metals: lead, cadmium, chromium, arsenic, cobalt, nickel, copper, zinc, vanadium, and manganese in surface soil dusts at the Katima Mulilo urban motor park (KMUMP), Namibia. Composite surface soil dusts samples were randomly collected from three points at 10 m apart within the motor park, and a control site on a weekly basis over 8 weeks. Pooled sampled were homogenized and 20 sub-samples (<75 μm soil fraction) were taken from the large sieved sample and digested according to EPA method 3050B. The digestates were analyzed for concentrations of the heavy metals using ICP-OES (Perkin Elmer Optima 7000 DV). The results showed a wide range of heavy metals concentrations from 0.33 mg/kg Cd to 13.7 mg/kg Zn, and differed statistically between study locations (p < 0.05). The results were generally lower than their WHO’s maximum permissible concentrations in soils for the protection of ecosystem’s health. The ecological risk indexes of the heavy metals suggest that the surface soil dusts at KMUMP were not contaminated by the heavy metals at this point. However, this does not preclude exposure risks to travelers, especially vulnerable children due to heavy metals’ toxicity and bioaccumulation.

Ecological risk assessment of trace elements (TEs) pollution and human health risk exposure in agricultural soils used for saffron cultivation

Contamination of farmland soils by trace elements (TEs) has become an international issue concerning food safety and human health risks. In the present research, the concentrations of TEs including cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), zinc (Zn) and iron (Fe) in soils of 16 farmlands were determined in Gonabad, Iran. In addition, the human health risks due to exposure to the TEs from the soils were assessed. Moreover, the soil contamination likelihood was evaluated based on various contamination indices including contamination factor (mathrm{CF}), enrichment factor (EF), geo-accumulation index (Igeo), and pollution load index (PLI) calculations. The soil mean concentrations for Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and Fe ranges as 0.102, 6.968, 22.550, 29.263, 475.281, 34.234, 13.617, 54.482 and 19,683.6 mg/kg in farmland soils. The mean concentrations of the TEs decreased in the order of Fe > Mn > Zn > Ni > Cu > Cr > Pb > Co > As > Cd. Levels of all metals in this study were within the FAO/WHO and Iranian soil standards. The HQ values from investigated elements for adults and children in the studied farms were less than the limit of 1, indicating no health risks for the studied subpopulations. The results of the present research indicated no significant carcinogenic health hazards for both adults and children through ingestion, skin contact and inhalation exposure routes. mathrm{CF} values of Ni and Zn in 100% and 6.25% of farmlands were above 1, showing moderate contamination conditions. EF values of metals in farmlands were recorded as “no enrichment”, “minimal enrichment” and “moderate enrichment” classes. Furthermore, it can be concluded that the all farms were uncontaminated except Ni (moderately contaminated) based on Igeo. This is an indication that the selected TEs in the agricultural soils have no appreciable threat to human health.

Effect of non-engineered municipal solid waste landfills located in the Zagros forest on heavy metals pollution in forest soils and leaf of Brant’s oak (Quercus brantii)

In recent years, many factors such as climate change and drought have changed the Zagros forests in western Iran. Also, unsuitable use of the forest is now threatening the long-term survival of Zagros forests by local natives. The municipal solid waste (MSW) disposal of Ilam city (in the west of Ilam province) is located in the Zagros forests. In this study, the effects of the Ilam landfill on soil and Oak tree (leaf) contamination with heavy metals (HMs) were investigated. 31 points around the landfill (at different distances from the landfill) were considered for sampling, and also 6 points were selected in forest areas that are far away from pollution sources as control areas. The forest soils and oak leaves were randomly collected from the control area and landfill. The soil and tree leaf samples were analyzed for cadmium, chromium, cobalt, copper, iron, lead, nickel, magnesium, and zinc using atomic absorption spectrophotometry. Several pollution indices, the Kriging method, and principal component analyses were applied for evaluating the contamination level spatial distribution, and possible sources of heavy metals. The concentrations of chromium, cobalt, and nickel in landfill soils were 531.6, 43.87, and 408.8, respectively, which were 5–10 times higher than the United States Environmental Protection Agency (USEPA) standards. The concentrations of chromium and nickel in oak leaves were 2.83 and 5.91, respectively, which are higher than the permissible limit. The results showed that there were statistically significant differences (p < 0.05) in metal soil concentrations between (lead, cobalt, zinc, and copper) the control area and landfill (with was 2 times higher than in the control). Higher values of soil pollution indices were obtained for the landfill sites than for the control sites. The findings of the spatial distribution confirmed that the heavy metals from the landfill significantly affected the soils of the Zagros forest. The presence of heavy metals in soil and leaf samples shows that contamination is due to leachate migration from an open dumping site. Regular monitoring around this non-engineered landfill is required.Graphical abstract

Sources, Microbial Interaction and Available Strategies for Remediation of Heavy Metals

High concentrations of heavy metals (Cadmium, Arsenic, Chromium, Lead, Mercury, Copper, Cobalt, Zinc, Nickel, and Selenium) in soil are threat to the ecosystem, human health, food safety, animal health. Heavy metal contaminants are increasing rapidly due to industrialization especially automobile industry. Previously, various techniques were developed and improved over time like encapsulation, surface capping, landfilling, soil washing, soil flushing, electro kinetic extraction, solidification, stabilization, phytoremediation, and bioremediation. These techniques minimize the contaminants by utilizing immobilization, containment and removal mechanisms. Bioremediation is a promising technique that utilizes the capability of plants and microbial resources for decontamination of ecosystem from heavy metal contaminants. Microbes have shown capability to utilize heavy metal remediation and assist plant tolerance for heavy metal accumulation. Earlier published studies have not yet completely evaluated proficiencies to large scale however, in the present review, critical analysis of reported techniques focusing on the bioremediation have been discussed. In depth analysis for the heavy metal remediation is of paramount importance of heavy metal contaminant emerging issue of soil pollution.

Evaluation of heavy metal contamination in copper mine tailing soils of Kitwe and Mufulira, Zambia, for reclamation prospects

Understanding the level of heavy metal contamination coupled with the assessment of environmental and human risks associated with mine waste dumpsites is an important step to initiating efficient measures for mine wasteland restoration, stabilization, and bioremediation. In the present study, concentration of the heavy metals; Copper (Cu), Cobalt (Co), Iron (Fe), Lead (Pb), Manganese (Mn), and Zinc (Zn) in soil from mine waste dumpsites around Kitwe (Sites: BM and TD26) and Mufulira (Site: TD10), Zambia, was assessed to determine the level of contamination, ecological risks, and progress made in reclamation. The mine waste dumpsites in the two towns are located in the vicinity of residential areas. Therefore, there is need to provide information for optimization of protocols for post-mining landscape in Zambia and elsewhere to limit soil, river, and groundwater contamination and to accelerate the restoration process . Mean values for soil pH, electrical conductivity, and organic matter varied between 5.9–8.4, 2534.8–538.6 μS/cm, and 0.90–2.75%, respectively. The mean concentrations of heavy metals of BM, TD26, and TD10 decreased in order of Fe > Cu > Co > Mn > Pb > Zn across all sites. However, the order of overall degree of heavy metal contamination computed using control soil as a baseline in BM, TD26, and TD10 was Cu > Co > Fe > Pb > Mn > Zn. The pollution load index was 0.355 at BM, 0.329 at TD26, and 0.189 at TD10, indicating high soil pollution at BM and TD26. The Potential Ecological Risk Index for all heavy metals tested at BM, TD26, and TD10 showed low ecological risk in the vicinity of the studied dumpsites. Furthermore, the present study also showed that the polluted soils around smelter sites and mine waste dumpsites are susceptible to dispersion by wind and water. Additionally, results from TD10 revealed that the initiated remediation of the tailings dam was somewhat successful. Finally, this study provided an updated status regarding the accumulation of heavy metals in mine waste dumpsites of Kitwe and Mufulira, Zambia and baseline information necessary to enhance post-mining landscape reclamation.

Potential of visible and near infrared spectroscopy coupled with machine learning for predicting soil metal concentrations at the regional scale

Chemical analytical methods for metal analysis in soils are laborious, time-consuming and costly. This paper aims to evaluate the potential of short-range (SR) and full-range (FR) visible and infrared spectroscopy (vis-NIR) combined with linear and nonlinear calibration methods to estimate concentrations of nickel (Ni), cobalt (Co), cadmium (Cd), lead (Pb) and copper (Cu) in soils. A total of 435 soil samples were collected over agricultural sites, forest (7 %), pasture (5 %) and fallow land across a region in the northern part of Belgium. Generally, better predictions were obtained when using partial least squares regression (PLSR) and nonlinear calibration method [i.e., random forest (RF)] for processing of the spectral data, than when using support vector machine (SVM). FR generally outperformed SR and provided the best prediction results for Ni (R2p = 0.76), Co (R2p = 0.77), Cd (R2p = 0.64) and Pb (R2p = 0.65), when using PLSR and RF. SVM produced the best prediction result only for Pb (R2p = 0.57) using the SR spectra. The metals Ni, Co, Cd and Pb can be predicted successfully (good accuracy) from the FR vis-NIR spectra using PLSR for Co, and RF for Ni, Cd, Pb and Cu. Compared to the FR spectrophotometer, improvement in accuracy was obtained for Cd and Co, using the SR spectra when combined with PLSR and RF, respectively. It is concluded that the SR spectrometer can be used successfully for the prediction of Co with RF (R2p = 0.70), while it best predicted Cd with PLSR with an R2p value of 0.67, which is of value for regional survey.

Investigation of Heavy Metal Accumulation in Vegetables and Health Risk to Humans From Their Consumption

Heavy metals contamination of soil and edible parts of vegetables is presently a challenging environmental issue worldwide. The present study determined the accumulated amount of cadmium (Cd), lead (Pb), nickel (Ni), cobalt (Co), zinc (Zn), copper (Cu), and manganese (Mn) in soil, coriander, onion, and tomato collected from agricultural fields of Jhansi city, India. The bio-concentration factor and non-carcinogenic health risks were also assessed to know the vegetables’ accumulation potential of heavy metals from soil and possibility to have non-carcinogenic health risks via an intake of these vegetables. The samples were digested using di-acid solution prior to heavy metals analysis by atomic absorption spectrometric method. The average content of Cd, Pb, Ni, Co, Zn, Cu, and Mn were 2.02, 19.09, 21.56, 9.31, 35.34, 14.96, and 15.21 mg/kg dry weight (dw) in soil, 0.23, 2.12, 0.77, 0.47, 36.65, 5.92, and 21.65 mg/kg dw in coriander, 0.13, 0.66, 0.54, 0.32, 23.94, 6.25, and 20.15 mg/kg dw in onion, 0.14, 0.46, 0.89, 0.22, 16.77, 4.77, and 14.46 mg/kg dw in tomato, respectively. The bio-concentration factor revealed significant accumulation of Zn (1.04) and Mn in coriander (1.42), and in onion (1.32). The target hazard quotient and health risk index signaled that the population consuming these vegetables is risk-free. However, it is recommended that the concentration of heavy metals in the soil and crops of the study area and its related health risks be regularly monitored to avoid significant health risks in the future.

Soil applied cobalt alters the growth parameters and dry matters production of Bhendi (Abelmoschus esculentus L.)

In this study, an economically important crop plant Bhendi (Abelmoschus esculentus L.) were treated with various concentrations of cobalt to test its effect on the growth of the plants. For the growth of many plants, cobalt is necessary. Conversely, higher amounts of cobalt are poisonous to plants. Seeds were cultivated in pots with soil that had not been treated (the control) and soil that had cobalt added to it in doses of 50, 100, 150, 200, and 250 mg kg-1. For each sample, the several morphological characteristics including root length, shoot length, number of nodules, total leaf area, dry weight of root and shoot per plant, and leaf area were measured. Soil cobalt level of 50 mg kg-1 was found beneficial to the plants.

Antimony, beryllium, cobalt, and vanadium in urban park soils in Beijing: Machine learning-based source identification and health risk-based soil environmental criteria

The pollution situation of antimony (Sb), beryllium (Be), cobalt (Co), and vanadium (V) is poorly understood, although they are widely used in daily life and production processes. Moreover, threshold levels (“soil environmental criteria”, SEC) for these pollutants are lacking in China, which impedes effective soil quality management. This study explored pollution characteristics for park soils in urban area of Beijing, China at first. Then multivariate statistical analysis and machine learning model were used to identify the main sources of pollutants. Additionally, probabilistic health risk and SEC were studied to assess the risks of pollutants and manage soil pollutants. The results revealed that the overall pollution levels of Be, Co, Sb, and V were low, but Be and Sb were enriched to varying degrees. Source apportionment showed that Sb (85.5%) was mainly derived from fuel combustion and industrial legacy, Co (66.7%) and V (82.5%) from natural processes, and Be from the natural background (39.3%) and anthropogenic sources (53.8%). Risk assessment indicated that the pollutants' carcinogenic and noncarcinogenic risks were negligible. Exposure frequency and soil ingestion rate were the most important parameters affecting health risks. The SEC of Be, Co, Sb, and V were 31, 39.7, 41.3, and 348 mg/kg, respectively, all of which are higher than the corresponding soil quality standards in China, indicating that current soil quality standards may be too conservative for urban park land. This study provides a reference for the management of soil pollutants in Beijing's urban parks, and the formulation of soil environmental quality standards.

Determination of cobalt and copper in water, plant, and soil samples by magnetite nanoparticle-based solid-phase microextraction (SPME) coupled with microsample injection system-flame atomic absorption spectrometry (MIS-FAAS)

A magnetic solid-phase microextraction (SPME) procedure was optimized using Fe3O4 nanoparticles (NPs) to preconcentrate and determine cobalt and copper in real samples using microsample injection system-flame atomic absorption spectrometry (MIS-FAAS). Recoveries over 95% for Co(II) and 80% for Cu(II) from 90 mL of sample buffered to pH 4.0 were obtained using 50 mg Fe3O4 NPs as the adsorbent and 0.5 mL of 0.5 mol L−1 HNO3 as the eluent. The extraction time was 10 min. The preconcentration factors for Co(II) and Cu(II) were 180. The detection limits for Co(II) and Cu(II) were 1.2 and 0.9 µg L−1, respectively. The relative uncertainties and relative standard deviations were lower than 5.3% and 2.4%, respectively. The developed method was verified by analyzing TMDW-500 drinking water, NIST 1573a Tomato leaves, and NCS DC 78302 Tibet soil as standard reference materials. The spiking experiments provided recoveries exceeding 95%. The method was applied to determine cobalt and copper in water, soil, tea infusion, and vegetable samples.

High-sensitivity determination of available cobalt in soil using laser-induced breakdown spectroscopy assisted with laser-induced fluorescence.

Conventional laser-induced breakdown spectroscopy could not conduct high-sensitivity determination of available cobalt due to spectral interference and weak spectral intensity. To improve the poor detection sensitivity of available cobalt in soil, available cobalt was extracted from soil and prepared. Laser-induced breakdown spectroscopy assisted with laser-induced fluorescence was introduced to excite and detect the cobalt element. The results showed that coefficients of the calibration curve for the available cobalt element could reach 0.9991, and the limits of detection could reach 0.005 mg/kg in soil under optimized conditions, which were all much better than conventional LIBS and reach the international minimum detection standards. This work provides a possible approach for detecting available trace elements in soil.

Аккумуляция кобальта и никеля в почве, подстилке и в органах сосны обыкновенной в условиях Елецкого промышленного центра

Information was obtained on the content of cobalt and nickel in soil, litter, and organs of Scots pine in the conditions of the Yelets industrial center. It was found that, under pollution conditions, the content of cobalt and nickel in vegetative organs, soil, litter is higher than the control values. Moreover, their content increases both during the growing season and with an increase in the age of the pine (needles and shoots). There is an uneven accumulation of metal in various organs of Scots pine. A high level of correlation was noted: between the content of cobalt in the soil and needles of the 1st year, shoots of the 1st year - PP No. 1 (r = 0.86; r = 0.78); between the content of cobalt in the soil and bark, litter - PP No. 2 (r = 0.99; r = 0.96); between the nickel content in the soil and needles of the 1st year, needles of the 2nd year, shoots of the 1st year - PP # 1 (r = 0.84; r = 0.78; r = 0.80); between the nickel content in soil and needles of the 1st year, shoots of the 1st year, bark, litter - PP No. 2 (r = 0.92; r = 0.89; r = 0.78; r = 0.87). Keywords: COBALT, NICKEL, SCOTS PINE, NEEDLES, SHOOTS, SOIL LITTER

Occurrence and enrichment sources of cobalt, chromium, and nickel in soils of Mitrovica Region, Republic of Kosovo

The main purpose of this study is to determine the differences between anthropogenic sources and lithogenic sources of the content of certain potentially toxic elements in the region of Mitrovica, Republic of Kosovo. For that purpose, the results of a study on the spatial distribution and enrichment of cobalt, chromium and nickel in surface soil from Mitrovica and its environ, are reported. The average content of Co, Cr and Ni in soil amounts to 22 mg kg−1, 60 mg kg−1 and 96 mg kg−1, respectively. Spatial distribution maps of Co, Cr and Ni shows their predominance in the area of Triassic serpentinites on the North-eastern and Western parts of study area. The lowest contents are found on the outcropping of Miocene latites, quartz-latites and pyroclastites. It has been established that the increased content of Co, Cr and Ni in soils from this area is of lithogenic origin. It is shown that content of Co, Cr and Ni exceeds the target Dutch value in 173 km2, 82 km2 and 256 km2 (from 302 km2 of the study area), respectively, while the content of Cr and Ni exceeds the action Dutch value in 17 km2 and 63 km2, respectively.

Interaction of Salicylamide and Salicylic Acid with Iron and Cobalt and their Comparative Study by IR and NMR

The complexes formed by salicylic acid and several substituted derivatives of salicylic acid (Salicylamide) with essential metal ions of the soil (iron and cobalt) have been investigated at 25° and in a medium of variable ionic strength using pH. The equilibrium constants of complex formation of the 1 : 1 , 1 : 2 and1 : 3 mole ratio metal–acid complexes formed are discussed with reference to the activity degradation of substituents. Salicylic acid and Salicylamide after disposal can also react with the various metal ions present in the soil to form complexes. The rate at which these complexes are formed is done with the help of UV-vis. Spectroscopy. The complexes formed are characterized by various Spectroscopic technique viz. FTIR and NMR.

Evaluation and speciation of cobalt, copper, and zinc in saline soil bymicrowave‐assistedsingle extraction

AbstractThe present research assessed the chemical fractionation of Cobalt (Co), Copper (Cu), and Zinc (Zn), detected in saline soil samples of Hyderabad Pakistan. The partitioning of Co, Cu, and Zn in soil samples was carried by single‐step extraction using microwave irradiation energy. The validity of the methods was confirmed using the same operating conditions applied and checked as in BCR sequential extraction fractionation using certified reference material BCR‐701 and the standard method of addition (recoveries 96%–102%). Atomic absorption spectrometry was used to test extractable Co, Cu, and Zn contents obtained by the comparative method. Using compromised microwave conditions steps 1–3 of the sequential extraction (excluding hydrogen peroxide digestion in step 3) could be accomplished with an ultrasonic bath between 15 and 30 min, whereas 60–120 s were needed for microwave single‐extraction (MSE). The total concentrations of Co, Cu, and Zn extractable metals produced by three separate extractions ranged from 1.02–3.30, 5.02–9.95, and 3.97–8.01 μg/g respectively. Consequently, the use of single‐step extraction with the aid of microwave and ultrasound energy to reduce the time required for single‐step extraction based on the BCR sequential extraction method. However, with the aid of developed single‐step extraction methods, the obtained results were comparable to those values obtained from BCR sequential extraction method. For further study, the MSE can be frequently used to know the metal‐bound intensity with a different chemical fraction on environmental solid samples.

Contamination Level of Chromium, Iron, Nickel, Lead and Cobalt in Soil from an Agricultural area of Urmar Bala, Peshawar Pakistan

Contamination Level of Chromium, Iron, Nickel, Lead and Cobalt in Soil from an Agricultural area of Urmar Bala, Peshawar Pakistan