Coal Structure Research Articles

Comparative Study of Raw and Water Rinsed Loa Janan’s Bituminous Coal Structure

East Kalimantan’s Coal has total humidity level at 18.21%, inherent humidity of 12.39%, fly ash content of 5.18%, volatile compounds of 38.22% and heat content of 6084 kcal/kg. However, chemical composition, functional group and crystallinity of raw and water rinsed Loa Janan bituminous coal have not been reported elsewhere. This research aims to investigate whether water rinsed treatment affects the structure of the coal or not. Coal size at 100 mesh-200 mesh is divided into 2, labeled as bituminous (a) stands for raw bituminous and bituminous (b) is for water rinsed-one. The bituminous (a) was analyzed using scanning electron miscroscopy (SEM)-energy dispersive xray (EDX), x-ray fluorescence (XRF), fourier transform infrared (FTIR) and powder x-ray diffraction (p-XRD) spectrophotometer. Meanwhile, bituminous (b) was heated at 40°C for 10 hours, cooled, rinsed using aquademin (1:5), stirred for 3 hours at 1500 rpm, and filtered. The bituminous (b) was heated at 40°C for another 10 hours and was characterized using the same technique as conducted to bituminous (a). Images revealed by SEM-EDX confirms the morphology ang topology of bituminous coal and the carbon content of them are 70.24% ± 0.87 (coal a) and 70.73% ± 0.08 (coal b). X-ray fluorescence analysis revealed that the bituminous (a) consisted of: Fe (46%), Si (21.5%), Al (5.4%) and bituminous (b): Fe (45%), Si (18.4%), Al (4.5%). There is a significant difference of their infrared spectra, both showed the peak at 1620 cm-1 (C=C) for carbon aromatic vibration. The wide area of peak at 3423 cm-1 is responsible for OH stretching vibration. Peaks intensity at 1620 cm-1 and 3420 cm-1 of bituminous (b) increased about 43.11% and 43.34%, respectively. The crystallinity degree of bituminous (b) (47.56%) is lower than that of bituminous (a) (69.72%). A sharp peak of XRD spectrum located at 2θ of 26.6o (hkl = 002) was responsible for both quartz and graphite.

Study on the Failure and Instability Mechanism of Coal–Rock Parting–Coal Structures under Unloading

Study on the Failure and Instability Mechanism of Coal–Rock Parting–Coal Structures under Unloading

Theoretical and numerical investigations of the floor failure characteristics affected by coal mining near complex fault structures

Water inrush from underlying aquifers under the synergistic action of complex faults and mining activities seriously threatens the mining of coal seams in North China. The failure characteristics of the coal seam floor under complex fault conditions are the keys to understanding the water inrush mechanism during mining. To investigate floor failure characteristics and water inrush mechanisms influenced by complex fault structures, theoretical analysis and numerical simulation were carried out. An improved theoretical model is first proposed, including complex fault structures such as horst, graben, and step fault structures. The calculation formula for waterproof coal pillars under complex fault conditions is established based on the improved theoretical model. The failure and displacement characteristics of the coal floor under complex faults are analyzed via numerical simulation. Compared with those under normal mining conditions, the theoretical and numerical simulation results reveal the following: (1) Under the horst structure, the floor failure characteristics show an increase in the compression failure area on both sides, and shear failure occurs on the large-dip fault side. The simulation results reveal that the failure width on the large-dip fault side increases by 25%, indicating a failure trend toward the large-dip fault side. The width of waterproof coal pillars needs to be increased by 20% to ensure mining safety. (2) Under the graben structure, the floor failure characteristics show an increase in the compression failure area on both sides, and shear failure occurs on the small-dip fault side. The simulation results reveal that the failure width on the small-dip fault side increases by 25%, indicating a failure trend toward the small-dip fault side. The width of waterproof coal pillars needs to be increased by 40% to ensure mining safety. (3) Under the step fault structure, the floor failure characteristics show compression failure on both sides, increasing the floor compression failure area on the large-dip fault side. The simulation results show that the failure width on the small-dip fault side increases by 15%, the large-dip fault side increases by 50%, and the floor failure depth increases by 20%. The width of waterproof coal pillars needs to be increased by 50% to ensure mining safety.

Effects of indigenous microorganisms on the CO2 adsorption capacity of coal

The adsorption capacity of coal is a crucial criterion for CO2 sequestration in deep unminable coal seams. Previous studies have documented how indigenous microorganisms interact with supercritical carbon dioxide (ScCO2) in coal. But how these interactions affect the adsorption capacity were rarely investigated. In this study, we treated bituminous coal samples with ScCO2-H2O and ScCO2-H2O-microorganism interactions in high-pressure reactors for 120 days at 35 °C and 10 MPa, respectively. After the treatments, we characterized both coal pore types and structures. The comparisons between two different post-treatments indicate that no significant change in coal pore types but notable alterations in pore structures are observed. Specifically, the treated coal with microorganisms exhibits a significant increase in micropore specific surface area (SSA) and surface roughness than the one without them. However, changes in meso/macropore structures and overall pore complexity of the coal sample treated with microorganisms were less pronounced than in coal sample treated with ScCO2-H2O alone. FTIR spectra analysis indicated that the absorption peak intensity of oxygen-containing groups and aliphatic functional groups in the sample treated with microorganisms decreased much more significantly than the sample treated without microorganisms. The CO2 adsorption capacity slightly increased in all treated samples at equilibrium pressures below 2.5 MPa. Above this pressure, the coal sample treated with microorganisms maintained a higher CO2 adsorption capacity, while the sample treated without microorganisms exhibited lower CO2 adsorption capacity compared to untreated coal sample. The increased SSA and the reduced oxygen-containing functional groups of coal after the treatment exerted antagonistic effects on CO2 adsorption. These findings suggest that indigenous microorganisms in coal seams affect CO2 adsorption through antagonistic effects, necessitating site-specific microbial assessments.

Methane Desorption-Diffusion Behaviors in Micropores of Coal under Different Water Displacement Pressures.

Hydraulic fracturing not only enhances the flow conductivity of coal seams but also transforms the CH4 adsorbed in coal seams into free CH4 and then outputs it via the desorption-diffusion process, thus improving the output quantity and efficiency of CH4. In this paper, taking the coal from Changping mine in Shanxi as the research object, the 3D macromolecule model of coal was established by using analytical test experiments, and the molecular dynamics simulation method of desorption and diffusion was applied to study the characteristics of methane desorption rate and diffusion behaviors under different driving water pressures through the parameters of gas-water concentration distribution, desorption and diffusion rates, and the interaction energies between the coal and the gas-liquid. The results show that the water drive can increase the desorption rate of methane. With the increase of methane adsorption pressure, the desorption effect of water drive becomes stronger and then weaker. The desorption effect of water drive was best when the methane adsorption pressure was 5 MPa and the pressure difference was 2 MPa. Generally, the water drive promoted the methane diffusion, but if the water drive time was too long, it formed a water plug, and the water drive methane inhibited the diffusion. In shallow reservoirs, water drive can obviously promote the desorption-diffusion of methane. The binding energy between CH4 molecules is mainly composed of the repulsive force, while that between water molecules is mainly the adsorption force. In the binding energy between CH4 molecules and coal structures, the van der Waals (VDW) force accounts for 99% of the effect; in the binding energy between water molecules and coal structures, the electrostatic force contributes 84% to ∼88% thereto. The VDW force is significantly influenced by the pressure, while the electrostatic force is slightly affected. As the water displacement differential pressure is increased, the binding energy between CH4 molecules and coal structures decreases.

Research on the Characteristics of Seepage Failure in the Surrounding Rock (Coal) of the Goafs

During mining, the brittle fracture structure of coal makes it highly susceptible to disturbance, leading to changes in the permeability of the coal seam from non-conductive to water-conductive, which poses a significant threat to the stability and safety of coal pillars in goafs. Therefore, understanding the damage mechanisms of coal during water–rock interactions is crucial for ensuring mine safety. In this paper, based on laboratory seepage tests, the impact of hydrodynamic forces on the microstructure of fissured coal and its subsequent effect on permeability is examined. The study found that increasing confining pressure causes the “closure” of coal fissures, leading to a reduction in permeability. Additionally, during the initial stage of seepage, fine particles within the coal samples are mobilized due to seepage damage, leading to channel blockages and further reductions in permeability. However, as seepage continues, the hydraulic channels eventually open fully, resulting in a sharp increase in permeability. Furthermore, using a two-dimensional fracture seepage model, the study investigated how the scale of fractures in the water-conducting channels influences seepage behavior. A critical fracture width method was proposed to predict permeability surges, offering a new approach for analyzing the stability of coal pillars in mining areas.

Study on I/III mixed fracture characteristics of coal in different regions of China

The fracture mechanical property of coal rock constitutes an important mechanical constraint for hydraulic fracturing of coal reservoir, and its three-dimensional fracture characteristics hold great significance for coal-bed methane mining. In this study, non-invasive methods were employed to investigate the pore structure and permeability of coal, aiming to understand the gas storage, distribution, and mobility of coal from various regions. To assess the influence of geological stress on coal during coal-bed methane mining, a three-point bending test was conducted to determine the characteristics of coal I/III mixed fractures. The experimental results indicate that with the decrease of the modal mixing parameter Me, the fracture area expends, the fracture load Pf and fracture energy Ef increase, while the fracture toughness declines. The 3D fracture criterion is utilized to predict the toughness ratio of coal rock I/III mixed fracture. The 3D-MTS and 3D-MMTSN criteria offer the upper and lower limits of prediction respectively. The 3D-MTSED criterion proves to be a more appropriate fracture criterion for analyzing the 3D fracture.

Effects of surface tension and contact angle on pore structure development of coal samples under chemical solution erosion

To explore the influence of surfactant concentration on the pore structure and permeability of coal samples during the chemical enhancement of coalbed methane production, different kinds and different concentrations of surfactants were added to the chemical solution, and the coal samples were soaked. Methods such as low-field nuclear magnetic resonance testing (NMR), fractal theory, permeability testing, surface tension testing, and contact angle testing were employed to analyze the variation patterns of coal sample pore structure, fractal characteristics, and permeability, and to explore the correlation between surface tension, contact angle, and the degree of pore structure development. The results show that the increase in total porosity of coal samples, the increase in the seepage pore porosity, the decrease in Dt, and the growth rate of permeability increase with the increase in surfactant concentration, and are negatively correlated with the surface tension of the solution and the contact angle of the coal-solution interface, while the decrease in Ds is not significantly correlated with surfactant concentration, surface tension, or contact angle. In terms of the erosion effect of a chemical solution on coal samples, the influence of contact angle is greater than that of surface tension, while surface tension has the greatest impact on the development of adsorption pores. By adding different surfactants, the surface tension of the chemical solution and the contact angle of the coal-solution interface can be controlled, further promoting the erosion of coal samples, which is of positive significance for the chemical enhancement of coalbed methane production.

Microwave-induced alterations in the structure of coals at different metamorphic stages

Despite the global trend toward decarbonization, coal continues to play a significant role in energy production, as current renewable energy sources cannot fully meet the increasing global energy demand. The main objective of decarbonization is to reduce greenhouse gas emissions, especially carbon dioxide. Enhancing coal usage efficiency can help decrease these emissions. Electromagnetic activation of bituminous coal is already employed for dehydration, ash removal, desulfurization, and improving the grinding process of raw coal. This research aims to study the specifics of coal electromagnetic activation using microwave radiation and its effects on the physical and chemical processes occurring in coals at different metamorphic stages. The results suggest that this electromagnetic treatment leads to the destruction of hydroxyl groups and the formation of free hydrogen. Coals at higher metamorphic stages heat up faster due to their higher structural density. Coals at lower metamorphic stages take longer to heat up and require more processing time to be effective, while lower power levels are necessary to avoid mechanical breakdown. Activation time and coal particle size are significant factors; their optimal combination provides the maximum effect. These findings contribute to optimizing microwave treatment parameters for different coal types, potentially enhancing coal utilization efficiency and reducing environmental impact.

Microscopic adsorption study from coal rank comparison on the feasibility of CO2-rich industrial waste gas injection enhanced coal bed methane recovery

A new method of injecting CO2-rich industrial waste gas (CO2-rich IWG) to displace coal bed methane (CBM) is proposed for energy conservation and green growth. In this study, theadsorption mechanisms of this method were studied by the Giant canonical Monte Carlo and molecular dynamics methods in macromolecular coal models with three ranks (brown, bituminous, and anthracite coal). It is found that the proportion of gas molecules in the adsorbed state is higher in the anthracite coal slit than in the brown and bituminous slits, indicating that anthracite coal seams are more appropriate for waste gas sequestration. The adsorption selectivity of NO and CO2 is consistent among the three coal ranks, with the order of brown > bituminous > anthracite > 1.0, and that of N2 orders as 1.0 > bituminous > anthracite > brown.This is due to the different dominant factors affecting the competitive adsorption between different waste gas components and CBM, namely competition for adsorption sites in the NO and CO2 systems and thefilling effect in the N2 system. There is a positive correlation between the number of major competitive adsorption sites and the adsorption selectivity of theCO2(NO) system. CO2 and CH4 compete for COC structures in brown and bituminous coal and OH structures in anthracite coal, and OH structures in the three coals are the major adsorption sites for NO systems. Our work advances the understanding of the microscopic adsorption mechanisms of CO2-rich IWG in the CBM reservoirs, which provides a theoretical basis for CO2-rich injection-enhanced CBM recovery technology.

Supercritical Methane Adsorption Characteristics and Pore Structure Characteristics of Deep Middle Rank Coal

Abstract In order to accurately analyze the adsorption characteristics, pore structure, and fractal law of deep middle rank coal, high-pressure isothermal adsorption tests based on magnetic levitation high-pressure thermobalance and pore structure tests based on mercury intrusion method were carried out on coal samples collected from typical kilometer level deep wells. The fractal law of sponge model was studied. The results showed that: a. The weight method adsorption test showed “excess adsorption” phenomenon with the increase of equilibrium pressure, and the modified Gibbs surface excess adsorption theory was in line with the Langmuir adsorption model; b. The distribution of macropore volume in deep middle rank coal accounts for a dominant proportion of 57.44% to 62.47%, and the proportion of microporous specific surface area reaches 72.96% to 74.27%, indicating that microporous adsorption capacity is the strongest; c. The pore structure parameters and adsorption constants exhibit strong nonlinear characteristics.

Analysis of dominant flow in tectonic coal during coalbed methane transport

Diffusion and seepage are the main flow forms of coal seam gas transport, and are one of the key factors in the selection of gas extraction improvement methods. Changes in the physical structure of tectonic coal make gas transport more complex during coalbed methane extraction. In this paper, we develop a multi-field coupled model of methane transport in coal seams, taking into account the effects of tectonics, and theoretically analyze the dominant flow patterns for methane extraction. Then, the evolution of gas dominated flow is analyzed for different initial pressures, initial permeabilities, and initial diffusion coefficients of tectonic and intact coal seams. The results show that the amount of daily methane seepage in tectonic coal increases with the initial pressure of the coal reservoir, but decreases with the initial diffusion coefficient of the coal reservoir. Methane seepage in tectonic coal has a longer control time than in intact coal at different initial pressures, initial permeabilities, and initial diffusion coefficients of the coal reservoir. For different coal reservoir initial pressures, coal reservoir initial permeabilities, and coal reservoir initial diffusion coefficients, the maximum seepage control time for tectonic coal is 20, 17, and 15 times longer than for intact coal, respectively. Finally, the discrepancies of methane dominant flow in tectonic coal and intact coal during methane extraction were analyzed by using the double bottleneck flow model, and methods for methane enhanced extraction in tectonic coal and intact coal were discussed. The results presented in this paper may provide a theoretical reference for the extraction of differentiated gas in coal seams.

Study on influencing factors of controllable mechanical behavior of rock-like porous materials.

Due to the discrete and non-homogeneous of similar materials and the inability to realize large-size and original scale modeling, it is difficult to restore the structure and stress state of underground coal and rock mass in similar simulation tests. To solve this problem, a lightweight and suitable for large-scale modeling similar material, rock-like porous material has been developed. The quasi-static uniaxial compression experiment was carried out by using the large tonnage multi-module electronic control test system. And the influencing factors of controllable mechanical behavior of rock-like porous materials were studied. The results showed that, under uniaxial compression conditions, the material stress-strain curve exhibits three phases: elastic stage, failure stage, and platform stage. The uniaxial compressive strength, elasticity modulus, stress drop, and softening modulus of rock-like porous materials basically increase with the increase of density. The stress after peak strength changes from a slow decrease to a "stepped" or even "cliff like" downward trend. Polypropylene fibers have the effect of enhancing the uniaxial compressive strength, elasticity modulus, stress drop, softening modulus, shear deformation, and residual strength stability of rock-like porous materials. The rock-like porous material has a critical loading velocity, and it increases with density. At the critical loading velocity, the material shows obvious shear failure, and the shear inclination angle is the largest, and so is the uniaxial compressive strength. Through the experimental research, the influence laws of density, polypropylene fiber, and loading velocity on the failure mode, mechanical parameters, and mechanical behavior of the material are clarified, and the quantitative relationship between density and each mechanical parameter is obtained. The research is helpful to realize the accurate control of mechanical behavior of rock-like porous materials and further inverts the deformation and failure mechanism of underground coal and rock structures through indoor similar simulation tests.

Kinetic analysis of coal oxidative pyrolysis before and after immersion effect

The oxidative pyrolysis kinetics of coal before and after immersion effect was studied by thermogravimetric experiments. Non-isothermal thermogravimetric analysis data were analyzed at four heating rates of 5, 10, 20 and 30 K/min. Furthermore, temperature-programmed experiments and Fourier-transform infrared (FTIR) spectroscopy were employed to understand the oxidation activity and chemical structure of raw coal and soaked coal. After coal immersion effect, the increase in the content of active functional groups, the increase in the concentration of gaseous products, and the decrease in crossing point temperature during oxidation process all indicate that soaked coal is easier to oxidize and spontaneously combust. Lastly, four model-free methods such as Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS), Friedman and Kissinger methods are employed to calculate the activation energy (Eα). Kinetic analysis reveals that Eα value obtained by the former three methods significantly depends on the conversion of coal oxidative pyrolysis process, and the average Eα value of soaked coal obtained by four methods is lower than that of raw coal. For the kinetic analysis of coal oxygen adsorption and combustion stages, it is more reliable to adopt the FWO and KAS methods in turn. This research helps to better understand the mechanism of enhanced oxidation activity of soaked coal and optimizes the calculation method of kinetic parameters in different oxidation stages of coal.

Direct liquefaction behavior of Shenhua Shangwan coal under CO containing atmosphere

Direct coal liquefaction (DCL) under CO or syngas atmosphere is beneficial to reduce the cost of hydrogen production. Effects of CO on liquefaction process of Shangwan coal were investigated by comparing the liquefaction behavior in three atmospheres of CO, H2, and N2. Then, effects of different CO/H2 ratios and catalysts on the liquefaction process in syngas were investigated. The results indicated that the oil yield under CO atmosphere reached 43.1%, which was 4.2% lower than that under H2, but 10.2% higher than that under N2. The liquefaction performance was further improved by adding the Shenhua 863 catalyst. It is analyzed that CO promoted liquefaction in two ways: water-gas shift reaction and the reaction between CO and organic structures of coal. Through characterization of the products by GC-MS and FT-IR, it was found that CO makes benzenes, aliphatics, and oxygen-containing compounds in liquefied oil simultaneously increased. The effect on functional groups and free radicals concentration in the solid products was not obvious. The experimental results under syngas showed that the highest oil yield, 57.4%, can be obtained in DCL with 20% CO syngas, and further improved by increasing moisture content of coal appropriately. In addition, the Shenhua 863 catalyst had a good catalytic effect on the liquefaction process and also water-gas shift reaction.

Characterization of coal permeability considering fracture shape—Using the MP-Otsu threshold segmentation algorithm

Coal seepage simulation based on digital images is capable of visualizing the three-dimensional seepage process and providing permeability data. However, Otsu's conventional thresholding algorithm is prone to image mis-segmentation for extracting pores and fractures, which makes the reconstructed model unable to reestablish the coal structure truly. The present work first explains the failure mechanism of the conventional Otsu algorithm for image segmentation based on computed tomography (CT) images of coal. Three weighting factors, including the slope of the mineral content fitting curve against the Otsu threshold and the approximate proportion of the target in the image, are introduced to enhance the accuracy of the threshold relation. In continuing, the MP-Otsu thresholding algorithm is proposed. Finally, the 3D fracture model of the coal is reconstructed from the CT image via the MP-Otsu thresholding algorithm. Focusing on the shape of the model, the permeability is then calculated on the basis of the pipe flow model and the parallel plate model. The contribution of fractures with various radii in the pipe model and different apertures in the parallel plate model is appropriately incorporated into the permeability evaluation. The obtained results reveal that the presence of mineral components and the low porosity of coal are the chief reasons for the failure of the conventional Otsu algorithm in the digital image segmentation of coal. The porosities calculated by the improved MP-Otsu algorithm are predicted to be 7.13 %-72.03 % lower than those of the Otsu’s method, which effectively improves the over-segmentation of fractures by Otsu and could accurately extract fractures in images. The permeability model, considering the fracture shape, gives results similar to the simulation results, and parallel plate fractures remarkably affect the permeability of the coal body. In particular, fractures with radius R > 7 μm and apertures b > 50 μm account for more than 90 % of the permeability and thus play a key role in the seepage process.

Scale-span feature of surface analysis, macromolecular and pore structure in coal: Implications for inherent evolutionary mechanism of morphological microstructure

Morphological microstructural evolution of tectonic coal determines CBM storage and transportation mechanism as well as the occurrence of coal and gas outburst. Scale-span morphological feature of original and tectonic coals was characterized by AFM, Raman spectrum and physisorption method. The results demonstrate that metamorphism could remold the surface property of coal from rugged band to flat porous structure with pore form factor from 0.572 to 0.831, promoting the formation of regular and round pores. Tectonism facilitates ability of gas sorption in coal, breaking the basic structural integrity. Metamorphism could facilitate the ordered macromolecular structural evolution on recombination and aromatization as well as condensation; besides, tectonism may promote the evolution and development of microcrystalline structure in advance. The aforementioned results have revealed essential differences in morphological microstructure between original and tectonic coals, which are of great guiding significance to safe mining of CBM and prediction of coal and gas outburst.

Evolution characteristics and molecular constraints of microbial communities during coal biogasification.

This study investigates the production of biomethane, and variation in microbial community and coal molecular structures using gas chromatography, 16S rRNA high-throughput sequencing and Fourier transform infrared spectroscopy. Additionally, the factors influencing microbial community structure at a molecular level are discussed. The results demonstrate that bituminous coal exhibits a higher biomethane yield than anthracite coal. In bituminous coal samples, Escherichia and Proteiniphilum are the predominant bacteria at day 0, while Macellibacteroides dominates from days 5 to 35. Methanofollis is the dominated archaea during days 0 to 15, followed by Methanosarcina on day 35. In anthracite coal samples, Soehngenia is the dominant bacterial genus at day 0; however, it transitions to mainly Soehngenia and Aminobacterium within days 5-15 before evolving into Acetomicrobium on day 35. Methanocorpusculum is predominantly found in archaeal communities during days 0-15 but shifts to Methanosarcina on day 35. Alpha diversity analysis reveals that bacterial communities have higher species abundance and diversity compared to archaeal communities. Redundancy analysis indicates a significant correlation between coal molecular structure and bacterial community composition (P value < 0.05), whereas no correlation exists with archaeal community composition (P value > 0.05). The research findings provide theoretical support for revealing the biological gasification mechanisms of coal.

Microscopic mechanism of oxygen consumption inhibitor delaying the oxidation of coal

In order to inhibit the coal-oxygen complex that triggers spontaneous coal combustion, a retardant consisting of sodium alginate solution, sodium bicarbonate, inorganic salt MgCl2 and deoxidiser that can achieve multiple effects of hysteresis and oxygen depletion was developed. Taking the sulfur-containing side-chain reactive group of coal molecule -CH2-SH as the object of study, the Gaussian 16W procedure and density-functional-transfer theory (DFT) were applied to investigate the electrostatic potential and reaction tendency, oxygen adsorption capacity, front-line orbitals, natural bonding capacity, and oxygen adsorption capacity of the reactive group before and after the formation of the complexes with Na+ and Mg2+, using the solvation effect at the level of B3LYP/6-31G(d, p), respectively. The changes of electrostatic potential and reaction tendency, oxygen adsorption, front orbitals, natural bonding orbitals and charge transfer before and after the formation of complexes between -CH2-SH reactive groups and Na+, Mg2+, respectively. Comparative analysis of the interaction with oxygen before and after the formation of coordination blocking structure of coal and inorganic salts in gaseous environment, aqueous environment and retarded oxygen-depleting sodium alginate blocking solution environment, respectively. The calculated results show that the side chain of the aromatic ring of the raw coal is the active site for easy adsorption of oxygen, and the stability of the coordination blocking structure is significantly enhanced under the environment of hysteretic oxygen-depleting sodium alginate gel blocking agent, and the adsorption of oxygen before and after the coal molecule combines with Na+ and Mg2+ is the weakest under the environment of hysteretic oxygen-depleting sodium alginate gel blocking agent; The absolute value of the HOMO orbital energy increases the most, and the energy level difference (ELUMO - EHOMO) of the complexes increases the most; the natural bonding orbital analysis reveals that the lone pair of electrons of S atoms in -CH2-SH under the environment of hysteresis oxygen depletion sodium alginate gel blocker has a strong coordination effect with Na+ and Mg2+. In the hysteresis oxygen depletion sodium alginate gel resist environment, the stability of the coordination blocking structure is strengthened due to the moderateness of the dielectric constant, and its oxygen depletion also reduces the number of O2 molecules, which further reduces the adsorption and collision chances between the two, and a more desirable blocking effect can be obtained. The results reveal the micro-mechanism of the hysteresis oxygen depletion inhibitor in preventing spontaneous combustion of coal, which can provide a reference for further improving the inhibition effect of the inhibitor.

The mechanism and prevention of rockburst induced by the instability of the composite hard-roof coal structure and roof fractures

Despite the implementation of prevention and control measures, rockburst still occur. The characteristics of composite coal were analyzed by combining monitoring and early warning means. Two types of composite coal in the hard roof were distinguished based on their distinct initiation and destruction processes despite experiencing the same rockburst event. Rockburst caused by structural instability was studied in different mining stages, and the following conclusions were considered. 1) The mechanical model of the instability of composite coal in hard roof was established for different mining stages to reveal rockburst mechanisms. The high-speed advance of working faces changed the fractured structure of upper hard rocks in the pressure-relief protection range. The sudden fracture of long cantilever structures caused dynamic load disturbance to high-stress coal, which resulted in rockburst in the insufficient mining stage. The failure and deformation of coal under high-stress static loads created conditions for the instability and fractures of roof. The disturbance of low hard rock strata aggravated the deformations of damaged coal. Therefore, rockburst appeared in the full mining stage. 2) Structural instability and roof fracture caused by different factors were the main causes of rockburst for composite coal in hard roof in different mining stages. Relevant prevention and control measures were formulated to ensure the safety of working faces, which provided references for the prevention and control of rockburst in working faces under similar conditions.