Coal Combustion Residues Research Articles

Pioneering study of radioactivity in soil near the Payra 1320 MW Thermal Power Plant, the largest coal-fired thermal power plant in Bangladesh

ABSTRACT Coal combustion increases atmospheric radioactivity, harming those live in the periphery of coal-fired thermal power plants (CFTPPs). A pioneering study has been performed using a high-purity germanium detector by analysing 30 soil samples collected from distances of 50, 600, 1200, and 3000 metres in the periphery of the largest 1320 MW CFTPP, Payra, Bangladesh. The activity concentrations of 226Ra, 232Th and 40K ranged from 19–32, 31–90, and 420–870 Bq/kg, respectively, with most of the samples show 232Th and 40K levels above global averages. Elevated levels of 232Th and 40K in soil around Payra thermal power plant stem from natural minerals, granitic rocks, ash disposal, coal combustion residues, and environmental factors. Radiological hazard indices, including dose rates and cancer risk, exceed global averages, indicating unsafe radiation exposure for coal miners and locals. These findings are crucial for planning coal-fired power plants and stress the need for municipal regulation of fly ash and health monitoring to mitigate risks for workers and residents.

The Application of Atomic Spectroscopy Techniques in the Recovery of Critical Raw Materials from Industrial Waste Streams, Part II

This month’s column is Part 2 of a contribution from my daughter Glenna, who recently completed her PhD studies in Environmental Science from the University of Copenhagen in Denmark. Her article explores the current landscape of global critical raw materials (CRM) trends in research and the applications of atomic spectroscopy (AS), including inductively coupled plasma–mass spectrometry (ICP-MS), inductively coupled plasma–optical emission spectrometry (ICP-OES), and X-ray analytical techniques in their identification of diverse industrial and environmental media, which have been essential in method validation and quantification of CRMs in complex matrices presenting high risks of interference. Some important examples to be presented include rare earth elements (REEs) in water leaching purification (WLP) residues that co-occur with radioactive materials; REEs and other metals in acid mine drainage (AMD) environments; REEs in coal combustion (fly ash) residues; arsenic (As) from groundwater treatment sediment; and platinum-group elements (PGEs) from sewage sludge. The article also classifies the different techniques in use at each stage of the CRM recovery train, investigates present challenges to each analytical method, and discusses the problem-solving tools used.

Coal combustion residue for crop productivity in the semiarid US High Plains

AbstractCarbon (C) amendments can enhance crop productivity, particularly in semiarid regions. Understanding the potential interference of C amendment with herbicide efficacies is essential to informing the practice. An experiment was conducted in western Nebraska in 2016–2018 to evaluate the effects of coal combustion residue (CCR) and herbicides on crop yields and weed density in the dry bean (Phaseolus vulgaris L.)–maizedb (maize [Zea mays L.] following dry bean)–sugarbeet (Beta vulgaris L.)–maizesb (maize following sugarbeet) rotation. All crop phases of the rotation were present each year and received CCR at varying rates (0, 3.3, 6.6, 13.1, and 19.7 Mg C ha−1) in spring 2016. Overall, CCR did not have consistent beneficial effects on crop yields. There were trends for yield benefits with CCR application compared to no‐CCR plots in dry bean (p = 0.066) and sugar beet (p = 0.155) in 2017 and maizedb in 2018 (p = 0.222). In 2016, among no‐herbicide treatments, the treatment with the highest CCR rate had a greater maizesb yield (16.2 ± 0.1 Mg ha−1) than the rest of the CCR treatments, including the control. The CCR application did not adversely affect herbicide efficacy in weed control. However, in 2016, among plots where herbicide (saflufenacil + dimethenamid‐p) was applied, the CCR treatment (6.6 Mg C ha−1) had lower maizesb yield than the control. Future research should consider factors such as application rates, methods, and timing to assess the potential adverse effects of C amendments on herbicide efficacies.

The Application of Atomic Spectroscopy Techniques in the Recovery of Critical Raw Materials from Industrial Waste Streams, Part I

This month’s column is a contribution from my daughter Glenna, who recently completed her PhD studies in environmental science from the University of Copenhagen in Denmark. Her article explores the current landscape of global critical raw materials (CRM) trends in research and the applications of atomic spectroscopy (AS), including inductively coupled plasma–mass spectrometry (ICP–MS), inductively coupled plasma–optical emission spectrometry (ICP–OES), and X-ray analytical techniques in their identification of diverse industrial and environmental media, which have been essential in method validation and quantification of CRMs in complex matrices presenting high risks of interference. Some important examples that are presented include rare earth elements (REE) in water leaching purification (WLP) residues that co-occur with radio- active materials, REEs and other metals in acid mine drainage (AMD) environments, REEs in coal combustion (fly ash) residues, arsenic (As) from groundwater treatment sediment, and platinum-group elements (PGE) from sewage sludge. In addition, the article classifies the different techniques in use at each stage of the CRM recovery train, investigate present challenges to each analytical method, and discuss the problem-solving tools used.

Synthesis and characterization of bentonite-based lightweight ceramic aggregates using coal combustion residue and kerosene bloating agent

Coal combustion residue (CCR) is an industrial by-product that has been widely adopted in civil engineering applications. However, a significant portion of CCR is still left unused around the world. This study investigates the feasibility of incorporating CCR into ceramic aggregates to enhance their engineering properties. Through a combination of kerosene as a bloating agent and CCR addition, the study demonstrates significant improvements in ceramic aggregate properties. Particle strength ranged from 0.33 to 8.53 MPa, with density variations between 0.39 and 0.95 g/cm³. Additionally, the additives also promoted the crystallization process, as shown by the increase in crystallinity from 40.67% to 61.87%. This was confirmed by the X-ray diffraction analysis, which revealed the changes in the mineral composition and crystallinity due to the additives. Furthermore, the micro and macro pores of bentonite profoundly influence the bloating process of aggregate, contributing to the formation of a well-distributed porous structure in ceramic pellets. The resulting ceramic aggregate exhibited favorable strength-to-density ratios suitable for both structural and non-structural concrete applications. This research highlights the potential of CCR utilization in ceramic aggregates, offering sustainable solutions for the construction industry while mitigating waste disposal concerns.

Environmental sustainability and life cycle assessment of pilot scale application of coal combustion residue as structural fill in mechanically stabilized earth walls

In this study, three types of coal combustion residue (CCR) have been used, and the life cycle impact of CCR as structural fill behind mechanically stabilized earth (MSE) walls of three different heights has been conducted. The analysis has been done using OpenLCA software. Results have been compared with MSE walls using natural sand as a structural fill. It is observed that the environmental impacts of using CCR reduce by more than 50 % compared to those of using natural sand. Amongst CCR, the maximum impact is shown by fly ash and the least by bottom ash. Relative to natural sand, the impacts of using CCR decrease with an increase in wall height. The cost analysis of the walls indicates that if structural fills are transported from the same distance, the cost of construction with natural sand is 18–46 % higher than that by CCR as fill. Results reveal that utilizing CCR as structural fill in MSE walls proves to be a more economic and eco-conscious choice compared to the conventional natural soil. These findings could hold considerable implications for the construction sector and its efforts to minimize ecological footprint.

An original set of nanometer-scale mineralogical analyses of cookeite and the implications for Li enrichment: No. 21 coal, Mengjin Mine, western Henan

Critical elements in coal deposits, such as lithium (Li), have attracted attention recently due to their economic value. Many studies have suggested that the high enrichment of Li in coals is predominantly associated with cookeite, a Li–bearing chlorite mineral of hydrothermal origin. However, the identification of cookeite in coal has primarily relied on indirect methods, owing to the low atomic number of Li, which presents significant challenges for precise observation. The Shanxi Formation No. 21 coal in North China is enriched in Li. This study established a nanometer–scale mineralogical analytical technique (including high–resolution transmission electron microscopy (HR–TEM), fast Fourier transformation (FFT), and standard mineral simulation single-crystal diffraction (SSCD)) for the identification of the cookeite and evaluated the Li enrichment mechanism and recovery in this coal (low–volatile bituminous to semi–anthracite) based on a model for the Li mineralization. The Li content of the No. 21 coal ranges from 25.2 to 203 ppm. The Li content shows a strong correlation with the ash yield, Al2O3, SiO2, and detrital elements, indicating a dominant aluminosilicate affinity and detrital origin. The major aluminosilicate minerals in coal are kaolinite, chlorite, and illite. The geochemical indicators (the Al2O3/TiO2 ratio and its relationships with the Zr/TiO2, Nb/Y, and Nb/Yb ratios) indicate that the sediment sources are determined to be intermediate–felsic igneous rocks, probably the Mesoproterozoic moyite (a type of K– feldspar granite) in the Yinshan Oldland. Additionally, the coal can be divided vertically into three sections (Sections I, II, and III), corresponding to three stages of peat formation. Overall, from Section I to Section III, the degree of detrital input increased, and the groundwater and marine influences strengthened and weakened, respectively. Section II exhibits anomalous Li enrichment mainly associated with reducing environments and the geochemical barrier caused by the interaction between infiltrating seawater and groundwater. The detrital kaolinite assemblage with authigenic minerals such as secondary REE–rich minerals (bastnasite), chamosite, and quartz, as well as the REY enrichment patterns, suggests that the No. 21 coals, mainly Section II, may have existed the hydrothermal alteration. Cookeite is identified primarily in Section II and coexists with kaolinite based on TEM observations, suggesting that the cookeite is of hydrothermal origin and formed from pre–existing Li–rich kaolinite. Most samples from Section II meet the mining grade of Be–Li–Nb–Ta ore deposits (Li2O > 0.2%). Thus, this study offers valuable insights into the extraction and recovery of Li from coal combustion residues, particularly when cookeite is the primary Li–bearing mineral.

Separation of coal combustion residue for critical element extraction and other bulk uses

Critical rare earth elements are enriched in the >250 μm size fraction of ash with an outlook coefficient > 2.0. Co-extraction with alumina is advantageous. Ash disposal policies should explore size fractions to preserve enriched ash fractions.

Comparison of the Analytical Performance of Inductively Coupled Plasma Mass Spectrometry and Instrumental Neutron Activation Analysis Techniques in the Elemental Analysis of Coal Fly Ash

Inductively coupled plasma mass spectrometry (ICP-MS) and instrumental neutron activation analysis (INAA) were applied to study the elemental content of coal combustion residues. Both methods’ analytical applicability and suitability for this type of material were described in detail. A certified reference material, fine fly ash (CTA-FFA-1), was used to examine the capabilities and validation of both methods. A comparison study allowed for the modification of the procedures for these materials (previously elaborated in the Institute of Nuclear Chemistry and Technology), resulting in more accurate data with lower uncertainty. We highlighted that INAA and ICPs complemented each other in the analysis of coal and coal combustion residues. The digestion procedure was an integral part of the measurement and affected the environmental analysis results. Both methods were applied to the chemical characteristics of coal ashes from household furnaces. The hard coal was from Polish, Columbian, and Kazakh mines. The majority of elements had similar concentrations, independently of coal origin. Because ash from domestic coal combustion is used as a fertilizer or an anti-icing agent, we assessed the potential environmental impact via leaching experiments (according to PN-EN 12457-2). The potential risk of soil contamination due to ash dumping around the house and its surroundings was determined as insignificant (for the elements investigated).

Incorporation of Bottom Ash as Aggregates in High-Volume Fly Ash (HVFA) Concrete

Research has been conducted on the utilization of coal combustion residues, specifically fly ash and bottom ash, in order to produce concrete products that meet national standards. Fly ash is employed as a high-volume replacement for cement in what is known as high-volume fly ash (HVFA) concrete. On the other hand, bottom ash is used as both fine and coarse aggregates, serving as a substitute for sand in the concrete mixture. Various characterizations were performed, encompassing the examination of the constituent minerals, crystallinity levels of bottom ash, water absorption, porosity, abrasion resistance, compressive strength, and morphological properties of the concrete specimens. Both fly ash and bottom ash exhibit significant proportions of SiO2, Al2O3, Fe2O3, and CaO, which possess pozzolanic properties and contribute to the compressive strength of the concrete. Concrete samples were produced with varying amounts of bottom ash and other ingredients according to the mix design. The highest compressive strength achieved after 28 days of curing was 27.57 MPa (designated as code B5), accompanied by the lowest porosity of 6.25%. Specimens with code B5 also displayed the lowest abrasion rate of 0.02 mm/minute and water absorption of 1.1%. These results suggest that the formulated mixture has the potential for developing concrete products suitable for walls and paving, adhering to the requirements specified in standard SNI 03-0349-1989 and SNI 03-0691-1996.

Batı Anadolu Kıyısındaki Deniz Suyunda Eser Element Konsantrasyonlarının Belirlenmesi

In this study, we examined seawater from Izmir Bay, Turkey for its trace element content. Three stations were chosen to carry out our mission. The sample collection process took place between November 2019 and May 2020. We focused on pH levels, dissolved oxygen, total dissolved solids, salinity, conductivity values, and trace elements (Ag, Al, Ba, Cd, Co, Cr, Cu, Fe, Li, Mn, Ni, Pb, Sr, and Zn) concentrations. Trace element analysis was done using an ICP-OES. Trace element concentrations were as follows: Ag (0.4 mg/l), Al (0.47 mg/l), Cu (0.82 mg/l), Li (0.81 mg/l), Pb (0.065 mg/l), and Sr (8.06 mg/l). Meanwhile, Ba, Cd, Co, Cr, Fe, Mn, and Ni levels were below the measurable limits. Our results are generally high when compared with the literature. Industrial pollution sources (cement, metallurgy, iron and steel industries, electric arc furnaces (EAF-Steel), coal combustion residuals (CCRs), and petrol refineries) all cause marine pollution because they leak trace elements into the sea, which consequently accumulate over time.

Natural radioactivity assessment of coal combustion residues produced in Indian thermal power plants using high-purity germanium detector

Abstract Huge amount of coal combustion residue (CCR) is being generated in India every year. Since coal contains some natural radionuclides, the CCR may contribute to the enhanced natural radiation background. Hence, it is important to monitor the natural radioactivity levels in Indian CCR samples. The present study aims to estimate the natural radioactivity levels in CCRs produced in Indian thermal power plants. Accordingly, six CCR samples from different thermal power plants were collected and packed to achieve secular equilibrium among daughter products of 226Ra. The samples were counted for activity of gamma radionuclides using high purity germanium detector based high resolution gamma spectrometer. Results show that 40K is the most abundant among analyzed radionuclides, and the lowest was observed for 226Ra. Secular equilibrium was observed between 228Ra and 228Th, whereas no equilibrium was observed between 226Ra and 238U. The activity concentration for 226Ra and its daughter products (214Pb and 214Bi) was found to be similar in CCR sample before and after equilibrium, indicating that progenies are in secular equilibrium in CCR. The X ray diffraction analysis of CCR indicates the presence of aluminosilicate as major fraction, which has potential of trapping of 226Ra and daughter products. The values observed are very low and similar to those observed in naturally occurring radioactive materials such as coal, soil, and sediment, hence are not of radiological concern with respect to human/environment.

Bioaccumulation of contaminants in Scarabaeidae and Silphidae beetles at sites polluted by coal combustion residuals and radiocesium

Anthropogenic contamination from coal-fired power plants and nuclear reactors is a pervasive issue impacting ecosystems across the globe. As a result, it is critical that studies continue to assess the accumulation and effects of trace elements and radionuclides in a diversity of biota. In particular, bioindicator species are a powerful tool for risk assessment of chemically contaminated habitats. Using inductively coupled plasma mass spectrometry (ICP-MS) and auto-gamma counting, we analyzed trace element and radiocesium contaminant concentrations in Scarabaeidae and Silphidae beetles (Order: Coleoptera), important taxa in decomposition and nutrient cycling, at contaminated and reference sites on the Savannah River Site, South Carolina, U.S. Our results revealed variability in trace element concentrations between Scarabaeidae and Silphidae beetles at uncontaminated and contaminated sites. Compared to Scarabaeidae, Silphidae had higher levels of chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), and zinc (Zn). Unexpectedly, concentrations of Cr, Cu, and Ni were higher in both taxa at the uncontaminated sites. Scarabaeidae and Silphidae beetles at the coal combustion waste site consistently had high concentrations of arsenic (As), and Scarabaeidae had high concentrations of selenium (Se). Of the 50 beetles analyzed for radiocesium levels, two had elevated radioactivity concentrations, both of which were from a site contaminated with radionuclides. Our results suggest carrion beetles may be particularly sensitive to bioaccumulation of contaminants due to their trophic position and role in decomposition, and thus are useful sentinels of trace element and radionuclide contamination.

Physicochemical and mineral characteristics of soil materials developed naturally on two ∼ 50 years old coal combustion residue disposal sites in Croatia

Coal combustion has been one of the most dominant sources of energy for the last two centuries, generating tonnes of coal combustion residue (CCR). Rapid soil formation has been observed at old CCR disposal sites, altering the physiochemical and mineral properties of CCR, affecting contaminant release mechanisms and nutrient availability. Although ubiquitous, pedological properties of weathered CCR have been studied at only a small number of disposal sites. This study characterized two CCR landfills of similar age (∼50 years) using a range of parameters, including pH, total nitrogen and organic carbon content, major oxides (Al2O3, CaO, and SiO2), and macronutrients (Ca, K, Mg, P, and S), as well as textural and mineralogical data. In addition, specific surface area and cation exchange capacity were determined to assess particle properties, and 13C and 29Si NMR spectra were examined to characterize the organic matter and degree of polymerization of the coal ash glassy phase. Such comprehensive approach aimed to determine indicators of soil formation and to characterize the capacity of such landfills to retain water, nutrients, and contaminants. Both landfills displayed evidence of pedogenesis reflected in the pH decrease, formation of secondary minerals (such as ettringite, hydrotalcite, gypsum, and calcite), and changes in the C:N ratio. The Plaški landfill seems to have a better capacity to hold water, nutrients, and contaminants evident by higher clay content, CEC, and SSA values, possibly explaining why it developed more rapidly than Štrmac despite their similar age. The presence of montmorillonite in Plaški could be one of the main factors accelerating pedogenesis. 13C NMR spectra point to the unburned coal particles as the main origin of organic matter and 29Si NMR spectra showed higher depolymerization of a non-crystalline fraction in bare ash samples than in vegetated ash samples.

Coal Combustion Residuals Regulation

Coal Combustion Residuals Regulation

Landfill Codisposal of On-Site Vegetation and Coal Combustion Residuals: Implications for Gas Management

Historically, ash from coal combustion has been disposed of in ponds that were not designed with engineered containment systems. As a result of regulatory changes, it is estimated that coal combustion residuals (CCRs) from hundreds of unlined ponds will have to be excavated and disposed of in new lined landfills or the existing CCR ponds will have to been closed in-place with an engineered final cover system. The excavated or in-place CCR may contain vegetative matter that has the potential to decompose to CH4 and CO2. The objective of this study was to demonstrate a framework to assess the need for a gas collection system to accommodate the disposal of a mixture of CCR and vegetation in a lined landfill. Methane generation rates and yields for vegetative matter mixed with CCR were measured in biochemical methane potential and specific methane activity tests at 15, 20, and 37 °C. The data were then used to parameterize a methane generation model to estimate the gas flux at the landfill surface for a series of hypothetical disposal scenarios. Results showed that the specific decay rate constant (k) ranged from 0.00037 to 0.00872 yr–1, while the methane yield (L0) ranged from 84 to 120 mL CH4/dry g. Temperature was the most important determinant of the decomposition behavior. Simulations of gas flux for several disposal scenarios showed that the modeled flux from the decomposition of vegetation was below the CH4 and CO2 transmission rates reported for a geomembrane liner final cover system, suggesting that an active gas collection will not be necessary under the modeled disposal conditions.

Pile covering of waste disposal using technosols made of municipal solid waste incineration bottom ash and coal combustion residues: A column leaching experiment

Technosols are characterized by a substantial quantity of artifacts or industrial wastes in the upper 100 cm. They can be used as cover caps in mining rehabilitation, in which vegetation cover is subsequently established. However, prolific vegetation growth can be limited by the chemical and physical properties of technogenic substrates. As further studies need to be conducted to evaluate the suitability of municipal solid waste incineration bottom ash and coal combustion residues as cover caps, the pH, electrical conductivity, total porosity, and bulk density of these substrates were measured. Furthermore, the seepage pH and electrical conductivity of the covered and uncovered technosols after saturation were determined. The municipal solid waste incineration bottom ash, 4–10 mm in diameter, showed the highest bulk density (1.16 g cm-3) and lowest total porosity by saturation (24.7%). In contrast, the coal combustion residues registered the highest total porosity (57.2%). The coal combustion residues also revealed a higher pH of 12.5 and electrical conductivity values of 7.8 mS cm-1. Furthermore, no differences were observed between the treatments for pH seepage (8.2–8.3) and its electrical conductivity (14.3–16.0 mS cm-1) in the covered and uncovered columns, when using a technosol. This study provides information on the use of municipal solid waste incineration bottom ash and coal combustion residues as evapotranspiration covers during mining rehabilitation. The management of municipal solid waste residues is a global challenge and the use of this resource is valuable not only for the mining industry but potentially also in other fields, such as construction. The heavy metal content of the bottom ash from municipal solid waste incineration and coal combustion residues should be studied before implementing these waste residues on a large scale.

Investigation of mineral commodity residues based on alkalinity, solubility and other physicochemical aspects aiming the management of amazonian acidic soils

The large amounts of mineral residues generated by the bauxite-alumina industries in the Amazon — with a production scale in the same order of magnitude as their source commodities — have been seen as new sources of raw materials (secondary mines) and/or an inseparable part of a sustainable production system, i.e., a source for the generation of co-products within a circular economy system. In the present study, two alkaline residues from this mining-metallurgical industry were assessed for their potential to amend productive acidic Amazonian soils, namely, (1) insoluble solid residue from the Bayer process (bauxite residue, BR) and (2) ash from energy production from coal (coal combustion residues, CCRs: fly ash, FA, and bottom ash, BA). A physicochemical investigation was performed to evaluate the possible benefits that these residues can offer to the soil‒plant system. The alkalinity of the residues was adjusted “to a value of pH 8–10” by leaching with H3PO4 using a central composite experimental design. The chemical analyses indicated high levels (total and soluble) of essential elements such as Ca and S in the CCRs. All residues showed a high cation exchange capacity (CEC). Regarding the water holding capacity (WHC), FA showed a higher value than the other residues (68.6%). After pH adjustment, available P increased significantly for all residues, and the Ca and S contents remained high for the CCRs, while in BR, there was a decrease in available Na, and aluminum (Al3+) was not available because the potential acidity (H + Al) < 0.6. Finally, complementary analyses showed that with respect to mineralogy, BR is composed mainly of iron oxyhydroxides and aluminosilicate phases, while carbonate, sulfide and silicate phases dominate the CCRs. The neutralizing character, the presence of nutrients in the CCRs and the unavailability of Al3+ in BR are positive physicochemical characteristics for the management of Amazonian acid soils; the use of this residues would add to the circular economy and sustainability of the Amazon.

Characterization of Coal Combustion Residues Using Transmission Electron Microscopy Technique

Indian coal-based thermal power stations produces huge amount of coal combustion residues. Proper disposal, management and utilization of these ashes have always been a challenge before the thermal power plant management people. In order to find out the potential use of coal combustion residues one need to explore and look deeply into its various characteristic properties. In the present study the coal combustion residue samples from thermal power station of eastern India were used for characterizing ashes on the basis of Transmission Electron Microscopy technique. The study of the micrographs of Transmission Electron Microscopy showed that the coal combustion residue samples consisted of all the three viz. crystalline, polycrystalline and amorphous phases. The coal combustion residue samples were found to consist of single crystal, single crystal with hexagonal structure, polycrystalline substances and closed packed hexagonal structure. Concentric circles as seen in the diffraction pattern show the presence of polycrystalline substances in the samples. Presence of plerosphere in the coal combustion residue samples can also be seen from some SEM micrographs as well as one of TEM images. XRD studies show the presence of various crystalline substances present in the coal combustion residues. The study shows that the CCR samples are typically formed of Si-Al-Fe system with traces of sodium, potassium, calcium, magnesium, sulphur and titanium.

Environmental Impacts of Coal Combustion Residuals: Current Understanding and Future Perspectives.

On-site solid-waste impoundments, landfills, and receiving water bodies have served as long-term disposal sites for coal combustion residuals (CCRs) across the United States for decades and collectively contain billions of tons of CCR material. CCR components include fine particulate material, minerals, and trace elements such as mercury, arsenic, selenium, lead, etc., which can have deleterious effects on ecosystem functioning and public health. Effects on communities can occur through consumption of drinking water, fish, and other aquatic organisms. The structural failure of impoundments, water infiltration, leakage from impoundments due to poor construction and monitoring, and CCR effluent discharges to water bodies have in the past resulted in harmful environmental impacts. Moreover, the risks posed by CCRs are present to this day, as coal continues to account for 11% of the energy production in the United States. In this Critical Review, the legacy of CCR disposal and the concomitant risks posed to public health and ecosystems are assessed. The resiliency of CCR disposal sites in the context of increased frequency and intensity of storm events and other hazards, such as floods and earthquakes, is also evaluated. We discuss the current state of knowledge on the environmental fate of CCR-derived elements, as well as advances in and limitations of analytical tools, which can improve the current understanding of CCR environmental impacts in order to mitigate the associated risks. An assessment of the 2015 Coal Ash Final Rule is also presented, along with needs to improve monitoring of CCR disposal sites and regulatory enforcement.