Co-doped Zinc Research Articles

Mg and Cr doped ZnO nanoparticles for oxygen evaluation reaction

This study introduces an innovative approach to developing low-cost materials for renewable energy technologies by synthesizing a novel series of zinc oxide (ZnO)-based nanoparticles, including chromium-doped zinc oxide (ZnOCr) and magnesium-chromium co-doped zinc oxide (ZnOCr-Mg), via the solution combustion method. The novelty of this work lies in the strategic co-doping of ZnO with both Cr and Mg, a combination not extensively explored in the field of electrocatalysis for Oxygen Evolution Reactions (OER). By leveraging this co-doping strategy, the structural, morphological, and electrocatalytic properties of the nanoparticles were systematically analyzed using techniques such as linear sweep voltammetry (LSV), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA). Among the tested variants, ZnOCr-Mg:5 exhibited a significantly lower overpotential and superior stability, maintaining its catalytic performance over 18,000 s, thus outperforming traditional ZnO catalysts. These findings highlight the synergistic effects of Cr and Mg doping, showcasing ZnOCr-Mg:5 as a highly efficient and durable catalyst for OER, offering a novel and scalable solution for advancing sustainable energy technologies.

Optoelectronic properties of Mg and Cu co-doped ZnO nanostructure

In this work, both pure and Mg-Cu co-doped zinc oxide thin films are prepared by sol-gel spin coating technique. Microscopic glass substrates are used for the synthesis of thin films. The thin films are examined by X-ray spectroscopy (XRD), photoluminescence spectroscopy (PL), scanning electron microscopy (SEM), ultraviolet-visible spectroscopy (UV-Vis), and energy dispersive X-ray analysis (EDX). The XRD reveals the hexagonal wurtzite phase of the films. The observed grain size is 23.34 nm to 15.94 nm for pure and Mg-Cu co-doped ZnO respectively. The SEM image shows an increase in grain size and a smoothing of the surface with Mg-Cu co-doping. The presence of Mg and Cu in the ZnO nanofilm is confirmed by EDX analysis. UV analysis shows an increase in percent transmittance with doping. The Tauc relation is used to estimate the band gap of the samples, and a significant shift in the band gap is observed. The photoluminescence diagram shows greater emission and surface defects with doping. The visible spectrum is completely covered by the low- level emission.

Influence of transition metal (Cu) and rare earth metal (Dy) co-doping on spinel zinc ferrite (Cu0.1Dy0.08Zn0.9Fe1.92O4) for improved photocatalytic degradation of industrial effluents

In the present era, design and development of novel, highly stable, easily and magnetically separable, cost effective, and visible light driven catalytic material for the removal of harmful industrial effluents is of great importance. In this context, facile co-precipitation route was adopted for the synthesis of ZnFe2O4 (ZFO), Cu0.1Zn0.9Fe2O4 (CZFO), Dy0.08ZnFe1.92O4 (DZFO), and Cu0.1Dy0.08Zn0.9Fe1.92O4 (CDZFO) and their fabrication was confirmed by XRD, FTIR, SEM, and UV-Visible spectroscopy. The phase analysis of all designed materials exhibits that there is an increment in the crystallite size of co-doped zinc ferrite (CDZFO) i.e. 11.51 nm as compared to ZFO (10.74 nm), CZFO (10.92 nm), and DZFO (11.41 nm). The optical study shows a significant decrease in bandgap of CDZFO i.e. 1.82 eV as compared to DZFO (1.89 eV), CZFO (2.0 eV), and ZFO (2.14 eV). This decrease in optical bandgap and increase in crystallite size of the CDZFO is due to the quantum confinement effect. The photocatalytic efficiency of pure, doped, and co-doped samples was investigated against organic dye (Congo red), pharmaceutical drug (ibuprofen), and colorless organic compound (benzoic acid). The photocatalytic results reveal that CDZFO showed about ∼90 % degradation of Congo red while ZFO, CZFO, and DZFO showed only 59 %, 70 %, and 79 % respectively. Moreover, CDZFO also showed highest photocatalytic removal efficiency against ibuprofen (88 %) and benzoic acid (74 %) out of all other synthesized materials. The remarkable photodegradation ability of CDZFO for all targeted pollutants could be attributed to the generation of crystal defects in its lattice, its small bandgap, and higher absorption in visible region. Furthermore, the recyclability experiment confirmed the stability and reusability of the prepared sample.

Stokes and anti-Stokes emission characteristics of Er3+/Yb3+ co-doped zinc tellurite glasses under 377 and 1550 nm excitations for solar energy conversion application

One of the best rare earth combinations for down- and up-converting the solar photons is Er3+/Yb3+. Therefore, at present, by using the traditional melt quench technique, zinc tellurite glasses doped with Er3+ and Er3+/Yb3+ were characterised. Several methods of down-conversion that result in the emission of 1000 nm from the acceptor (Yb3+) under excitation of donor (Er3+) were studied. On the other hand, the impact of acceptor (Yb3+) concentration and excitation pump power on the excited state absorption and its influence on the up-conversion emission (1000 nm) properties were investigated in detail under 1535 nm excitation. The studies on emission and decay results are discovered to be very significant. Suggesting that these glasses when used as conversion layers, can append the conversion efficiency of Si-based solar cells.

Structural and Optical Properties of Cobalt-Doped Zinc Oxide Thin Films Prepared By Spray Pyrolysis Technique

Undoped and Co-doped zinc oxide (CZO) thin films have been prepared by spray pyrolysis technique using solution of zinc acetate and cobalt chloride. The effect of Co dopants on structural and optical properties has been investigated. The films were found to exhibit maximum transmittance (~90%) and low absorbance. The structural properties of the deposited films were examined by x-ray diffraction (XRD). These films, deposited on glass substrates at (400? C), have a polycrystalline texture with a wurtzite hexagonal structure, and the grain size was decreased with increasing Co concentration, and no change was observed in lattice constants while the optical band gap decreased from (3.18-3.02) eV for direct allowed transition. Other parameters such as Texture Coefficient (Tc), dislocation density (?) and number of crystals (M) were also calculated .

Preparation and Application of Co-Doped Zinc Oxide: A Review.

Due to a wide band gap and large exciton binding energy, zinc oxide (ZnO) is currently receiving much attention in various areas, and can be prepared in various forms including nanorods, nanowires, nanoflowers, and so on. The reliability of ZnO produced by a single dopant is unstable, which in turn promotes the development of co-doping techniques. Co-doping is a very promising technique to effectively modulate the optical, electrical, magnetic, and photocatalytic properties of ZnO, as well as the ability to form various structures. In this paper, the important advances in co-doped ZnO nanomaterials are summarized, as well as the preparation of co-doped ZnO nanomaterials by using different methods, including hydrothermal, solvothermal, sol-gel, and acoustic chemistry. In addition, the wide range of applications of co-doped ZnO nanomaterials in photocatalysis, solar cells, gas sensors, and biomedicine are discussed. Finally, the challenges and future prospects in the field of co-doped ZnO nanomaterials are also elucidated.

The structural, optical, electrical and radiation shielding properties of Co-doped ZnO thin films

Co:ZnO thin films are promising due to the similar ionic radii of cobalt and ZnO, and their potential for carrier spin injection, transfer, and detection. This study aims to investigate the structural, optical, electrical, and radiation shielding properties of Co-doped zinc oxide (Co:ZnO) thin films for potential applications in various fields such as semiconductors, solar cells, spintronics, and radiation shielding. The effect of commercially available Cobalt acetate tetrahydrate and Cobalt complex (Co with conjugated NN ligand) as cobalt additives on the synthesis of ZnO thin films is compared, aiming to discern their respective impacts. The dopants are incorporated in 2, 4, and 6 wt%, employing the sol-gel spin coating method.Applying cobalt complex additive as Co precursor resulted in ZnO:Co films with a superior enhancement of the electronic band gap of 2.84–3.00 eV compared to cobalt acetate precursor (2.62–2.84 eV). With the introduction of Cobalt, there is a notable change in the electrical conductivity, showcasing a decrease from 1.5x10−7 to 2.11x10−10 (S/cm). Also, radiation shielding parameters were experimentally measured in the energy range of 186.1–1764.5 keV within the scope of gamma ray spectral analysis. Exposure buildup factors (EBF) in the energy range of 15–15,000 keV were calculated up to 1–40 mean free path (mfp). Mass stopping power (MSP) and projected range values (PR) for nuclear safety applications were calculated for protons and alpha particles using the SRIM code. Thin film thicknesses were determined by using Lambert-Beer law. It was observed that the thin film thicknesses obtained from gamma spectrometry (2.090–2.628 μm) and SEM (2.157–2.725 μm) were compatible with each other.

Transparent Conductive Titanium and Fluorine Co-doped Zinc Oxide Films.

Aerosol-assisted chemical vapor deposition (AACVD) was used to deposit highly transparent and conductive titanium or fluorine-doped and titanium-fluorine co-doped ZnO thin films on glass substrate at 450 °C. All films were characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), UV-Vis spectroscopy, scanning electron spectroscopy (SEM), and four-point probe. The films were 600-680 nm thick, crystalline, and highly transparent (80-87 %). The co-doped film consisted of 0.70 at % titanium and 1 at % fluorine, and displayed a charger carrier mobility, charge carrier concentration, and a minimum resistivity of 8.4 cm2 V-1 s-1, 3.97×1020 cm-3, and 1.69×10-3 Ω cm, respectively. A band gap of 3.6 eV was observed for the co-doped film. Compared to the undoped and singly doped films, the co-doped film displayed a notably higher structure morphology (more homogenous grains with well-defined boundaries) suitable for transparent conducting oxide applications.

Exploring luminescence dynamics in Ce3+/Er3+ co-doped lithium zinc barium borate optical glasses: A study for advancing photonic technologies

Lithium zinc barium borate glasses were synthesized using the melt-quenching method and doped with Ce3+, Er3+, and their combination. The study examines the influence of Ce3+ on the photoluminescence of Er3+ in these glasses. X-ray diffraction confirmed the amorphous nature of both undoped and doped glasses, while Fourier-transform infrared spectroscopy showed the conversion of BO3 to BO4 units, and Raman spectroscopy indicated a phonon energy around 1136 cm−1. The Ce3+-doped glasses exhibited a blue emission at 447 nm due to the 5d→4f1 transition. Co-doping with Ce3+ and Er3+ led to decreased visible upconversion emissions but significantly enhanced near-infrared emissions at 1.53 μm. This enhancement is attributed to reduced non-radiative decay and improved energy transfer between Er3+ and Ce3+ ions, facilitated by the phonon energy of host glass. The 1.53 μm emission intensity in Ce3+/Er3+ co-doped glass was about 60% higher than in singly Er3+-doped samples, highlighting the potential of Ce3+ co-doping for broad amplification at 980 nm excitation.

IGZO thin films deposited by ultrasonic spray pyrolysis: effect of Zn precursor milling and In and Ga concentration

Codoped zinc oxide thin films with indium and gallium (IGZO) were deposited on soda-lime glass substrates by the ultrasonic chemical spray (USP) technique. The influence of the mechanical grinding process of Zn precursor (zinc acetate, AcZn) and the In and Ga concentrations was analyzed. The grinding process was carried out in a planetary ball mill, with a ball:/precursor ratio of 4:1, and a constant rotation speed of 300 RPM. The starting solutions were prepared at a molar concentration of 0.2 and variable In and Ga atomic concentration (1, 1.5, 2, 2.5 and 3 at%). The deposition conditions were kept constant, substrate temperature of 450 °C and deposition time of 7 min. Structural, morphological, optical, and electrical properties were analyzed. From the structural analysis a preferential orientation along the (101) plane for dominant In concentrated IGZO films was observed, whereas for dominant Ga concentrated was the (002) plane. The average optical transmission was in the range of 83–90%, confirming the high transparency of all the deposited films. The bandgap values, Eg, showed slight variations, from 3.43 to 3.53 eV. The best electrical properties were obtained in the IGZO films with an In:Ga ratio of 1.5:1 [IGZO(1.5:1)], evaluated by the figure of merit, 3.50 × 10–3 (Ω/□)−1, calculated for an optical transmission of 86% and a sheet resistance of 63 Ω/□. According to the obtained results, the IGZO thin films deposited by the USP technique, are potentially applicable in the field of optoelectronics, mainly as transparent electrode.

Photocatalytic evaluation of disperse purple dye using Polyvinylpyrrolidone capped bare and Cu+2/Fe+3 codoped ZnO nano catalysts

Polyvinylpyrrolidone capped bare zinc oxide and codoped with cupric and ferric ions, have been fabricated by a facile polyol reduction method with ethylene glycol. The as-fabricated nanoparticles were calcinated to control their size and morphology. The fabricated nanoparticles were characterized using various techniques including X-ray diffraction, scanning electron microscopy, energy dispersion X-rays, UV–Vis spectroscopy, and Fourier transform infrared Spectroscopy. The results showed phase pure nanoparticles with wurtzite zinc oxide structure, and a blue shift in absorbance spectrum when zinc oxide was codoped with cupric and ferric ions.The study examined the degradation rate of disperse purple dye using bare and codoped zinc oxide nanoparticles in the solar region. Codoped nanocatalysts showed superior efficiency compared to bare zinc oxide. The kinetic analysis of the dye was conducted, revealing that the degradation of the dye followed a pseudo-first-order kinetics pattern. Furthermore, about 99 % degradation of the dye solution in 110 min by codoped zinc oxide as compared to bare zinc oxide (84 %) under solar light suggests Cu+2/Fe+3 codoped zinc oxide is an emerging tool for environmental remediation.

Energy transfer-based color tunability, thermal quenching, and quantum yield of Sm3+/Eu3+ codoped lithium zinc borophosphate glasses

Lithium zinc borophosphate (LZBP) glasses, imbedded with Sm3+, Eu3+, & Sm3+/Eu3+ ions in solely and combinedly were synthesized using melt-quenching technique, and their energy-transfer-dependent photoluminescence (PL)-related characteristics were explored. LZBP: 0.5 % Sm3+ and LZBP: 0.5 % Eu3+ glasses exhibited intense orange and red emissions under 404 and 394 nm excitation wavelengths, respectively. When the Sm3+/Eu3+ codoped glass systems were excited with Sm3+ excitation (404 nm), has lead to a noticeable drop in the emission intensity of Sm3+ peaks at 562 nm (4G5/2 → 6H5/2; yellow), 602 nm (4G5/2 → 6H7/2, orange), and 645 nm (4G5/2 → 6H9/2, red) whereas the emission intensity of Eu3+ peaks at 591 nm (5D0→7F1; orange) and 617 nm (5D0→7F2; red) has enhanced. At the same time, the decay lifetime of singly doped Sm3+ decreased from 1.54 to 0.91 ms, with codoping different concentrations of Eu3+ ions. The decrease in both PL intensity and lifetimes of Sm3+ in the presence of Eu3+ suggests an efficient energy transfer (ET) from Sm3+→Eu3+, which is facilitated by dipole-dipole interaction. The ET from Sm3+→Eu3+ achieved through the channels, Sm3+:4G5/2 + Eu3+:7F1 → Sm3+:6H7/2 + Eu3+:5D0 and Sm3+:4G5/2 + Eu3+:7F2 → Sm3+:6H5/2 + Eu3+:5D1. Furthermore, ET from Sm3+ to Eu3+ is supported by the spectral overlay between Sm3+ emission and Eu3+ absorption, ET parameters (η(Sm3+⟶Eu3+) = 40.91 % and P(Sm3+⟶Eu3+) = 1098.9 S-1). The shift in color coordinated from orange to red, with an increase in Eu3+ doping content in the codoped glasses at 404 nm excitation demonstrates the promising application of the Sm3+/Eu3+ codoped glass system in orange-red light-emitting diodes. LZBP: 0.5 Sm3+/1.0 Eu3+ codoped glass exhibited good thermal stability (Ea = 0.19 eV), depending on temperature-dependent PL properties. The quantum yield (η) for the LZBP glass containing 0.5 Sm3+/1.0 Eu3+ codoped ions is evaluated to be 44.6 %.

Enhanced reddish-orange luminescence from Sm3+/Ag co-doped barium zinc borophosphate glasses: Structural and Judd-Ofelt analysis

We report the synthesis and optical response of Sm3+/Ag nanoparticles (NPs) co-doped glasses through melt quenching method. TEM analysis confirmed Ag NP formation, and the diverse functional groups were confirmed through FTIR studies. The Judd-Ofelt (JO) parameters are calculated using JO theory from absorption spectra. The PL spectra were recorded under 402 nm excitation and they show four PL bands in the visible range. The PL spectra are utilized to obtain radiative parameters to claim their utility in visible laser applications. The dominant emission color was obtained by using the CIE color chromaticity diagram. The excited state lifetime values were estimated through decay curve fitting method. All the obtained results are discussed in detail based on Ag NP concentrations.

Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method

Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method

Synthesis and characterization of cobalt-strontium co-doped zinc oxide nanoparticles by chemical precipitation

This study presents a meticulous investigation into the synthesis and characterization of zinc oxide (ZnO) nanoparticles co-doped with cobalt (Co) and strontium (Sr) using the co-precipitation method. Varied doping ratios were employed to create Zn1-(x+y)CoxSryO nanoparticles to synergize the advantageous properties of Co and Sr dopants. Comprehensive characterization was performed, encompassing X-ray diffraction (XRD), UV–VIS spectroscopy, Raman spectroscopy, field emission scanning electron microscopy (FESEM), and energy-dispersive X-ray analysis (EDAX). Contrary to prior assumptions, our XRD analysis revealed that the wurtzite crystal structure of ZnO remained unaltered with Co and Sr doping. FESEM and EDAX characterized the nanoparticle size, morphology, and composition, providing essential insights into the structural changes induced by the doping process. Furthermore, a red shift in the bandgap was observed upon doping, suggesting potential alterations in the optical properties. Our study aims to contribute to the ongoing exploration of ZnO-based nanomaterials by presenting a detailed analysis of the structural and optical modifications by Co-Sr co-doping. The findings offer valuable insights for further understanding nanoscale modifications and their potential applications in optoelectronics, photovoltaics, and photocatalytic systems. Our comprehensive analysis enriches the understanding of the synthesized nanoparticles and their potential applications.

Nonlinear optical and luminescence studies on Zinc Alumino-Boro-Silicate glasses co-doped with Dy3+ and Sm3+ ions for optical limiting and W-LEDs applications

In the present work, Dy3+ and Sm3+ co-doped Zinc Alumino-Boro-Silicate (ZABS) glasses doped with an optimized Dy3+ concentration (0.5 mol%) and varying Sm3+ concentrations are prepared using a conventional melt-quenching method. Optical absorption spectra showed the signature of Dy3+ and Sm3+ peaks through possible transitions in the range of 300–1800 nm. The optical bandgap of the glasses is obtained in the range of 4.2 to 3.9 eV. The emission curves aswellas decay lifetimes of Dy3+ and Sm3+ ions under 350 nm and 402 nm excitation were investigated using photoluminescence studies. Through the Inokuti-Hirayama (I-H) energy fitting model, the nature of energy transfer between Dy3+ and Sm3+ is found to be a ‘dipole–dipole’ type. Neutral to near warm white light emissions from the co-doped glasses were evaluated through colour chromaticity and correlated colour temperature calculations. The nonlinear optical measurements showed the reverse saturable absorption behaviour of the glasses whose nonlinear absorption coefficients (β) decreased with higher concentrations of Sm3+. Among the prepared glasses, ZABSDS1 (Sm3+ 0.1 mol%) glass showed the highest nonlinear coefficient (3.56 × 10−12 W cm−2) and lowest optical limiting (37.5 × 1011 W cm−2) threshold. From the overall studies, the suitability of the prepared glasses for White LEDs and optical limiting laser device applications were realized.

Structural, Optical, and Electrical Properties of Hafnium-Aluminum-Zinc-Oxide Films Grown by Atomic Layer Deposition for TCO Applications.

ZnO is a widely studied material that exhibits versatile doping possibilities. Most research presents singly doped ZnO, leaving the potential of codoping unexplored. Within this study, hafnium-aluminum codoped zinc oxide (HAZO) thin films were grown on a glass substrate using the atomic layer deposition technique at 200 °C. A comprehensive analysis of the surface morphology and electrical and optical properties of the samples was conducted for varying the Al/Hf doping ratio. X-ray diffraction studies showed that the obtained films are polycrystalline, exhibiting a preferential growth direction along the (1 0 0) plane without any detectable precipitates. Moreover, the electrical measurements of HAZO films revealed that they exhibit lower resistivity (∼9.5 × 10-4 Ωcm) than the commonly used aluminum zinc oxide films (AZO). This improvement can be primarily attributed to the promotion of the n-type carrier concentration to 4.45 × 1020 cm-3 while maintaining a mobility value equal to 14.7 cm2/Vs. The doping also influences the optical properties of the material by widening the band gap and changing the refractive index, as observed by spectroscopy and ellipsometry studies. These findings highlight the potential of proposed HAZO thin films for future applications in electronic devices utilizing transparent conducting oxides.

Aluminum and Molybdenum Co-Doped Zinc Oxide Films as Dual-Functional Carrier-Selective Contact for Silicon Solar Cells.

Aluminum-doped zinc oxide (AZO) is considered as a promising candidate as transparent conductive oxide (TCO) for silicon heterojunction solar cells due to its high carrier density, nontoxic nature, and low cost. Herein, it is presented that the transparency of the AZO film can be optimized through co-sputtering of AZO and molybdenum oxide (MoOx). Furthermore, aluminum and molybdenum co-doped zinc oxide (MAZO) can be used as both the TCO layer and electron-selective contact (ESC) for silicon heterojunction solar cells. The surface morphology, cation oxidation state, and optical and electrical properties of all MAZO films are characterized. It is found that the transmittance of all MAZO films is significantly increased at a wavelength of 450-800 nm due to MAZO with a stronger Zn-O bond and a wider band gap. The conductivity of MAZO films is approximate to AZO films at a low MoOx target deposit power (50 W), and the sheet resistance of MAZO films increases significantly by increasing the deposition power up to 100 W. Finally, the optimized MAZO films are used as TCO and ESC for silicon heterojunction solar cells, showing a power conversion efficiency of 19.58%. The results show an effective stage to improve the optical properties of AZO through co-doping and the possibility of applying MAZO as a dual-functional layer for silicon solar cells.

Charge transfer and X-ray absorption investigations in aluminium and copper co-doped zinc oxide nanostructure for perovskite solar cell electrodes

This study explores influence of charge transfer and X-ray absorption characteristics in aluminum (Al) and copper (Cu) co-doped zinc oxide (ZnO) nanostructures for perovskite solar cell electrodes. Sol-gel technique was employed to synthesize the nanostructures, and their optical and morphological properties were investigated. X-ray diffraction (XRD) analysis confirmed high crystallinity and also single-phase composition of all the samples, particularly up to 5% Al co-doping. Field emission scanning electron microscopy (FESEM) exhibited the formation of pseudo-hexagonal wurtzite nanostructure and the transition to nanorods at 5% Al co-doping. Diffuse reflectance spectroscopy indicated a reduction in the optical band gap of co-doped zinc oxide from 3.11 to 2.9 eV with increasing Al doping. Photoluminescence spectra (PL) exhibited a decrease in peak intensity, suggesting enhanced conductivity in ZnO, also confirmed from I-V measurements. Near-edge X-ray absorption fine structure (NEXAFS) analysis depicts that charge transfer from Al to oxygen (O) species enhanced the photosensing properties of the nanostructure, which was supported by FESEM micrographs and PL spectra. Furthermore, the study discovered that 5% Al co-doping significantly reduced the density of emission defects (deep-level) in Cu–ZnO nanostructure. These findings highlight the potential of Cu and Al co-doped ZnO materials for perovskite solar cell electrodes, as their improved optical and morphological properties resulting from charge transfer could enhance device performance. The investigation of charge transfer and X-ray absorption characteristics provides valuable insights into the underlying mechanisms and behaviors of the co-doped ZnO nanostructures. However, further research is required to delve into the intricate hybridization resulting from charge transfer and explore the broader impact of co-doping on other properties of the nanostructures, enabling a comprehensive understanding of their potential applications in perovskite solar cells.

Sensitizing effect of Sm3+ ions on Eu3+ incorporated boro-tellurite glasses for tunable red emission

Sm3+, Eu3+ singly doped and Sm3+/Eu3+ co-doped tungsten sodium zinc boro-tellurite glasses were prepared by melt quenching technique and the optical properties of these glasses have been investigated thoroughly. Under the excitation at 394 nm the Eu3+ doped prepared glass shows global red emission at x = 0.648, y = 0.341 in CIE1931 chromaticity diagram which is close to commercially developed phosphor Y2O2S: Eu3+ (0.647, 0.343) under near-UV excitation. Upon excitation at 404 nm, the Sm3+/Eu3+ co-doped glasses exhibit all the emission peaks for Sm3+ as well as Eu3+ ions, while exciting at 464 nm does not show the same result. Emission quenching occurs beyond 0.5 mol% of Sm3+ ions concentration in the present co-doped glasses. The possibility of non-radiative energy transfer from Sm3+ ions to Eu3+ ions has been verified by Forster-Dexter theory. The analysis of the decay profile for the 4G5/2 energy level of Sm3+ ions in the co-doped glass using Inokuti-Hirayama model suggests that the interaction between Sm3+-Eu3+ ions may be dipole-dipole in nature. The efficiency (ηT(Sm→Eu)) and probability rate (PT(Sm→Eu)) of energy transfer from Sm3+ → Eu3+ have been evaluated as 0.08 and 167 s−1, respectively. The results obtained from the radiative analysis suggest that the prepared glasses could be potentially used as red and orange-red or tuning red emitting materials.