CO2 Absorption Research Articles

Predictive modeling of CO2 capture efficiency using piperazine solutions: a comparative study of white-box algorithms

The urgency to mitigate carbon dioxide (CO2) emissions and combat climate change has spurred the development of effective CO2 capture technologies. One of the industry’s most well-known CO2 collection processes is CO2 absorption utilizing amine solvents. However, designing a successful amine scrubbing system in power plants requires precise prediction of CO2 absorption in aqueous amine solutions under various operating circumstances. Using aqueous piperazine (PZ) solutions for chemical absorption is promising due to the favorable reactivity of PZ with CO2. In this study, a comprehensive evaluation of PZ solution performance in CO2 capturing, employing the white-box algorithms, namely, Genetic Programming (GP), Gene Expression Programming (GEP), and Group Method of Data Handling (GMDH), was performed. Through extensive experimentation and data analysis, several correlations were developed with high and acceptable R2 values, such as 0.933 for GP, 0.949 for GEP, and 0.889 for GMDH, which shows high accuracy and reliability in predicting the CO2 capture efficiency of PZ solutions under varying operating conditions. The results of sensitivity analysis revealed that CO2 partial pressure increased CO2 absorption, while PZ concentration and temperature had negative and decreasing effects. These insights provide essential guidance for optimizing process conditions to enhance the CO2 capture efficiency. Finally, the leverage method was used to assess the reliability of both experimental and predicted data from white-box algorithms. This analysis identified potential outliers and validated the accuracy of the model’s predictions, enhancing the credibility of developed correlations and demonstrating the robustness of the approach.

Sustainable Solutions in Gas Separation: Exploring the Potential of Deep Eutectic Solvents

In the face of escalating environmental concerns, particularly related to greenhouse gas emissions, this study delves into the potential of Deep Eutectic Solvents (DESs) as a sustainable alternative in gas separation technologies. Focusing on the significant emissions of CO2, SO2, and H2S from industrial processes, this work reviews the application of DESs for their capture and separation. We investigate the physical properties of DESs, such as solubility and viscosity, which are crucial for their efficacy as sorbents. This review includes a comprehensive analysis of various DES formulations, exploring their roles in CO2 absorption, SO2 removal, and the separation of other gases like H2S. Additionally, we extend our examination to the applicability of DESs in the oil and gas industry, highlighting their effectiveness in removing sulfur and nitrogen impurities, and their potential in the extraction of organic constituents. The study reveals that DESs, characterized by their biodegradability and environmental sustainability, offer promising performance in gas separation, aligning with the principles of green chemistry. However, challenges such as high viscosity and the need for further understanding of their solubility dynamics under different conditions are addressed. This work underscores the importance of DESs as novel sorbents for gas purification and sets a foundation for future research aimed at enhancing their application on a broader industrial scale.

Characteristics of Carbon Fluxes and Their Environmental Control in Chenhu Wetland, China

Carbon dioxide (CO2) flux measurements were conducted throughout the year 2022 utilizing the eddy covariance technique in this study to investigate the characteristics of carbon fluxes and their influencing factors in the Chenhu wetland, a representative subtropical lake-marsh wetland located in the middle reaches of the Yangtze River in China. The results revealed that the mean daily variation of CO2 flux during the growing season exhibited a U-shaped pattern, with measurements ranging from −12.42 to 4.28 μmolCO2·m−2·s−1. The Chenhu wetland ecosystem functions as a carbon sink throughout the growing season, subsequently transitioning to a carbon source during the non-growing season, as evidenced by observations made in 2022. The annual CO2 absorption was quantified at 21.20 molCO2·m−2, a figure that is lower than those documented for specific subtropical lake wetlands, such as Dongting Lake and Poyang Lake. However, this measurement aligns closely with the average net ecosystem exchange (NEE) reported for wetlands across Asia. The correlation between daytime CO2 flux and photosynthetically active radiation (PAR) can be accurately represented through rectangular hyperbola equations throughout the growing season. Vapor pressure deficit (VPD) acts as a constraining factor for daytime NEE, with an optimal range established between 0.5 and 1.5 kPa. Furthermore, air temperature (Ta), relative humidity (RH), and vapor pressure difference (VPD) are recognized as the principal determinants affecting NEE during the nocturnal period. The association between Ta and NEE during the non-growing season conforms to the van’t Hoff model, suggesting that NEE increases in response to elevated Ta during this timeframe.

The Recycling of Lithium from LiFePO4 Batteries into Li2CO3 and Its Use as a CO2 Absorber in Hydrogen Purification

The growing adoption of lithium iron phosphate (LiFePO4) batteries in electric vehicles (EVs) and renewable energy systems has intensified the need for sustainable management at the end of their life cycle. This study introduces an innovative method for recycling lithium from spent LiFePO4 batteries and repurposing the recovered lithium carbonate (Li2CO3) as a carbon dioxide (CO2) absorber. The recycling process involves dismantling battery packs, separating active materials, and chemically treating the cathode to extract lithium ions, which produces Li2CO3. The efficiency of lithium recovery is influenced by factors such as leaching temperature, acid concentration, and reaction time. Once recovered, Li2CO3 can be utilized for CO2 capture in hydrogen purification processes, reacting with CO2 to form lithium bicarbonate (LiHCO3). This reaction, which is highly effective in aqueous solutions, can be applied in industrial settings to mitigate greenhouse gas emissions. The LiHCO3 can then be thermally decomposed to regenerate Li2CO3, creating a cyclic and sustainable use of the material. This dual-purpose process not only addresses the environmental impact of LiFePO4 battery disposal but also contributes to CO2 reduction, aligning with global climate goals. Utilizing recycled Li2CO3 decreases the demand for virgin lithium extraction, supporting a circular economy. Furthermore, integrating Li2CO3-based CO2 capture systems into existing industrial infrastructure provides a scalable and cost-effective solution for lowering carbon footprints while securing a continuous supply of lithium for future battery production. Future research should focus on optimizing lithium recovery methods, improving the efficiency of CO2 capture, and exploring synergies with other waste management and carbon capture technologies. This comprehensive strategy underscores the potential of lithium recycling to address both resource conservation and environmental protection challenges.

Estimating the Greenhouse Gas Emission Potential Due to Construction Work on the 225 kV Segou - Bamako High Voltage BI-Ternal Electric Line in Mali in The Context of Climate Change

The aim of this study is to assess the carbon emissions resulting from the construction of the power line linking Bamako to Ségou. It focuses on direct emissions, more specifically those linked to the degradation and desctruction of the vegetation cover in the project right-of-way. To collect the data, surveys were set up on the project right-of-way, through which 3302 trees were inventoried in situ at the three sites. Circumference was measured at 1.30 m from the ground surface. Allometric equations for direct biomass estimation were used as a predictor o f tree diameter. Emission factors were then used to estimate the potential greenhouse gas emissions resulting from tree felling during power line construction. The standard error associated with the carbon fraction in dry biomass was calculated. In the Ségou, Koulikoro and Dioïla project areas, there are a number of plant species that provide local populations with various ecosystem services, including micro-climate regulation through carbon sequestration or absorption of atmospheric CO2. The implementation of the project will undoubtedly result in the felling of these trees. This felling will generate emissions of 22.11 t.eqCO2/ha in Ségou, 16.56 t.eqCO2/ha in Koulikoro and 15.43 t.eqCO2/ha in Dioïla. Across Ségou, Koulikoro and Dioïla, the trees in the project right-of-way represent a reservoir of 34.04 t/ha of above-ground woody biomass. This biomass represents a carbon stock of around 16.58 t.C/ha. This carbon stock will be transformed into a carbon source with emissions of 60.78 t.eqCO2/ha if the trees in the power line right-of-way are systematically felled. Mitigation measures are therefore urgently needed, with compensatory reforestation areas planted with species with high carbon sequestration potential.

The effects of counter ion on CO2 capture performance of amino acid salt solutions for direct air capture applications

Direct CO2 capture from the atmosphere has received growing attention driven by the imperative of achieving global net-zero emission targets. Amino acid salt solutions are promising candidates for liquid-based direct air capture processes. Utilised as a neutralized salt by reacting initially with hydroxides, it has been speculated that their performance may vary with the type of counter ion present in the solution. This work investigates the influence of counter ions, potassium, sodium, and lithium, of amino acid salt solutions on the physical properties, the CO2 absorption capacities, and the CO2 absorption kinetics under atmospheric CO2 concentration levels. The potassium-containing amino acid solutions exhibited significantly lower viscosities and mildly elevated densities compared to sodium- and lithium-containing ones. At 25 °C, the potassium-prolinate solution demonstrated the highest viscosity (8.5 mPa⋅s), whereas K-glycinate exhibited the lowest viscosity (2.5 mPa⋅s). Additionally, potassium-based solutions consistently displayed the highest CO2 mass transfer coefficients, followed by sodium- and lithium-containing ones. The CO2 mass transfer coefficient was highest for potassium-prolinate (2.99 mmol m−2⋅s−1⋅kPa−1) with the lowest rate observed for potassium-β-alaninate (1.68 mmol m−2⋅s−1⋅kPa−1). Interestingly, the type of counter ion had minimal impact on the CO2 absorption capacity, with potassium-based solutions exhibiting only a slightly elevated capacity compared to sodium- and lithium-based solutions. Specifically, potassium-lysinate displayed the highest CO2 absorption capacity (0.7 mol CO2 /mol amine), while potassium-β-alaninate showed the lowest (0.65 mol CO2/mol amine). It should be noted that all lithium-based solutions of all amino acids formed precipitates during CO2 absorption. From a practical and operational perspective, these findings suggest that the potassium salt solution of amino acids would be the optimal choice for direct air capture applications due to their enhanced solubility and CO2 mass transfer rates compared to the corresponding sodium and lithium counter ion salt solutions.

Performance of a novel waste heat-powered ionic liquid-based CO2 capture and liquefaction system for large-scale shipping

In this work, we proposed a novel CO2 capture and liquefaction system for large-scale shipping using ionic liquid as capture solvent. By utilizing the waste heat of the exhaust gas and jacket cooling water from the ship’s engine as well as the residual pressure energy of the N2-O2 mixture from the CO2 absorption and desorption process, the system’s net energy consumption has been significantly reduced. We established the thermodynamic model of the system and investigated the effect of 10 primary system operational parameters on system performance with 3 different ionic liquids as CO2 capture solvent. The results demonstrated that the system with [DEME][TF2N] as the CO2 capture solvent had the best system performance. In addition, we performed a multi-parameter optimization of the system using simulated annealing algorithm with net energy consumption as the optimization objective and the minimal net energy consumption is 0.467 GJ/tCO2. Compared to the CO2 capture system that do not utilize waste heat and residual pressure energy, the net energy consumption was reduced by 57.29 % under optimal operational conditions which proves that the novel system significantly reduces the energy consumption of the CO2 capture and liquefaction process.

Screening and evaluation of phase change absorbents by molecular polarity index: Experimental and quantum chemical calculation studies

Phase change absorbents have recently received increasing attention due to their potential to reduce the energy penalty of CO2 capture. However, its complex composition makes the prediction of phase separation performance difficult. Phase separation behavior and phase separation rate have been investigated for the amine-aqueous 5.0 M amine blends by experimental and quantum chemical calculations (including MPI, hydrogen bonds and Gibbs free energy). The different phase behaviors upon CO2 absorption were discussed and well explained by the polarity change of components and the reaction products. A defined MPI value of tertiary amines was recommended to predict the immiscible type (MPI > 10.55 Kcal/mol), phase separation type (9.00 Kcal/mol < MPI < 10.08 Kcal/mol), and miscible type (MPI < 6.74 Kcal/mol). The electron density at the critical point of hydrogen bonds and interaction region indicators were employed to visually evaluate the influence of intramolecular and intermolecular hydrogen bonds on phase separation behaviors. The results show that the presence of excessive hydrogen bonds decreased the phase separation capacity. Furthermore, the relationship between the MPI, the Gibbs free energy of the proton transfer process and the phase separation time were explored. The increase of MPI caused by the tertiary amines can enhance the stability of the final product, delay the appearance of the phase separation peak and reach a maximum phase separation time of 230 min. Therefore, this study is significant for the screening and evaluation of efficient phase change absorbents with good potential for industrial applications in CO2 capture.

A study of nano-micro-bubble process for CO2 absorption in water for biogas upgrading application

The work proposed a novel micro-bubble system using swirling jet flow method for improving the physical absorption of CO2 in water. The effects of operating conditions; e.g. gas flow rate (from 500 to 2000 mL/min), inlet pressure (2 and 3.5 bar) and inlet CO2 concentration (from 5 to 60% v/v in CO2/N2 gas mixture) on the physical absorption of CO2 were studied. It was found that the CO2 absorption system reached to steady state after 30 minutes with the outlet CO2 concentrations of 2.9% and 8.8% at 40% and 60% of inlet CO2 concentrations, respectively. These outlet CO2 concentrations demonstrated the standard of bio-methane for replacing natural gas in vehicle use, from which less than 10% CO2 is required. Moreover, the increase of gas flow rate resulted in increase of outlet CO2 concentration. The rising of inlet pressure from 2 to 3.5 bars let to reduction of the outlet CO2 concentration together with enhancing the dissolved CO2 concentration in water from 49.1 to 51.7 mg/L at gas flow rate of 2000 mL/min and 60% of inlet CO2 concentration. The highest efficiency of CO2 removal was 98.41% under gas flow rate at 500 mL/min with 60% of inlet CO2 concentration. Under the optimized conditions, this system was tested with real biogas as raw material containing mainly 57.7% of CH4 and 40.3% of CO2 which achieved to remove the 95.1% of CO2 removal and no significant loss of CH4. This highlight demonstrated the potential application of this technology for biogas upgrading or purification further.

Out of the Darkness: High-resolution Detection of CO Absorption on the Nightside of WASP-33b

We observed the ultrahot Jupiter WASP-33b with the SpectroPolarimètre InfraRouge on the Canada–France–Hawaii Telescope. Previous observations of the dayside of WASP-33b show evidence of CO and Fe emission indicative of a thermal inversion. We observed its nightside over five Earth nights to search for spectral signatures of CO in the planet’s thermal emission. Our three pretransit observations and two posttransit observations are sensitive to regions near the morning or evening terminators, respectively. From spectral retrievals, we detect CO molecular absorption in the planet’s emission spectrum after transit at ∼6.6σ. This is the strongest ground-based detection of nightside thermal emission from an exoplanet and only the third ever. CO appearing in absorption suggests that the nightside near the evening terminator does not have a temperature inversion; this makes sense if the dayside inversion is driven by absorption of stellar radiation. On the contrary, we do not detect CO from the morning terminator. This may be consistent with heat advection by an eastward jet. Phase-resolved high-resolution spectroscopy offers an economical alternative to space-based full-orbit spectroscopic phase curves for studying the vertical and horizontal atmospheric temperature profiles of short-period exoplanets.

Highly efficient CO2 capture by a non-aqueous amine-based absorbent of 3 aminopropanol/polyethylene glycol 200: Experimental and computational simulation

In the present work, a novel non-aqueous 3-aminopropanol/polyethylene glycol 200 (3AP/PEG200) absorbent for efficient carbon dioxide (CO2) capture was designed using environment-benign and non-toxic polyethylene glycol 200 (PEG200) as an alternative to water. The mechanism, physical, thermodynamic, and kinetic properties of absorption process was investigated through a combination of experimental and multi-scale computational simulation approaches including molecular dynamics (MD) simulation and quantum chemical (QC) calculations. It was found that the addition of PEG200 not only enhanced the thermal stability of the absorbent, but also did not significantly increase the viscosity. In addition, kinetic studies revealed that the absorption process conforms to a pseudo-first-order equation, with the activation energy (Ea) value of 20.40 kJ/mol, significantly lower than that of the benchmark 30 % monoethanolamine (MEA) aqueous solution used in industrial CO2 capture. Furthermore, the enthalpy change (ΔH) and entropy change (ΔS) values were found to be more negative than those of other liquid absorption systems, indicating that the 3AP/PEG200 absorbent is favorable for CO2 absorption even at low partial pressures. Most importantly, the absorption system exhibited good regeneration capability, as demonstrated by five absorption–desorption cycle experiments. In conclusion, the non-aqueous 3AP/PEG200 absorbent exhibits low viscosity, high thermal stability, enhanced absorption capacity, and excellent cyclic performance, positioning it as a promising candidate for CO2 absorption in industrial applications.

New insights into the functional group influence on CO2 absorption heat and CO2 equilibrium solubility by piperazine derivatives

New insights into the functional group influence on CO2 absorption heat and CO2 equilibrium solubility by piperazine derivatives

Preparation activated tailings by pH swing process: Towards yielding cemented tailings backfill and in-situ CO2 mineralization

In-situ CO2 mineralization of tailings has shown great potential for large-scale CO2 sequestration, but its development is seriously limited by the low CO2 conversion rate. This study proposed an innovative pH swing process to produce activated tailings through magnesium extraction from raw tailings and subsequent leachate precipitation. By the combination of activated tailings and high-belite calcium sulfoaluminate cement, a new type of cemented activated tailings backfill (CATB) was developed. The results demonstrate that 82.33% of magnesium is extracted from raw tailings and precipitates in the form of Mg(OH)2 serving as the dominating carbonation active phase during the pH swing process. Besides the aragonite forms in the carbonated cemented raw tailings backfill (CRTB), carbonated CATB also contains calcite, nesquehonite, and hydromagnesite. Substituting activated tailings for raw tailings led to the higher CO2 absorption capability (ranging from 8.88% to 14.17% with various binder-to-tailings ratios). These indicate that the activated tailings have a promising application scenario in large scale in-situ CO2 mineralization.

Dual-channel infrared OPO lidar optical system for remote sensing of greenhouse gases in the atmosphere: design and characteristics

Current global warming and climate change under the greenhouse effect call for a thorough understanding of the spatial distribution of greenhouse gases in different atmospheric layers. Lidar systems are the most effective for remote greenhouse gas monitoring. We design a two-channel infrared OPO lidar optical system for remote DIAL/DOAS sensing of carbon dioxide and water vapor in the atmosphere. In this work, optimal geometric parameters of the transceiving channel of the lidar optical system are chosen, a need to focus laser radiation at a distance of 1 km from an observation point is demonstrated, and numerical simulations confirm the possibility of detecting lidar signals ranging from 10–7 to 10–10 W in the informative spectral range 4800–5100 cm–1 (1960–2083 nm). Laboratory experiments with the main components of the lidar system with experimentally confirmed parameters, which simulate atmospheric measurements of CO2 absorption at a calibrated sensing wavelength of 2005 nm (4987 cm–1) (pressure of 1 atm; CO2 concentration corresponding to the midlatitude summer background atmosphere) in the informative spectral range of the lidar system, enable selecting a pair of wavelengths with resonant absorption of the target gas near 2005 nm to study the background state of the atmosphere in the surface layer. Efficiency of the lidar optical system is confirmed by in situ test experiments, where backscattering signals from a topographic target with an albedo of ∼0.15 spaced 168 m apart from an observer are recorded at 60 mV when operating along a horizontal atmospheric path. The lidar system we design can be used in measuring complexes at carbon test sites. It can also be used for atmospheric monitoring in industrial centers, at background measuring stations, and in swamp areas.

Computational evaluation of phosphonium ILs as CO2 absorbents for electrochemistry

Since phosphonium-based ionic liquids (ILs) are suitable electrolytes for electrochemical reduction, a computationally informed analysis of these ILs was conducted to assess their ability to absorb CO2. In this work, theoretical and experimental approaches were mixed with a focus on gas solubility, transport properties, and structural characterization. The calculations included free energy of solvation (ΔG), the Henry constant (Kh), and short-range energies (Coulomb plus Lennard–Jones). Two ILs, [P1444][TFSI] and [P1444][FSI], were selected for further evaluation because of their lower Kh values. The enthalpy and entropy of the solvation process for these selected ILs were computationally determined; both ILs were found to have a favourable enthalpy of solvation for gas dissolution, and [P1444][TFSI] had a lower penalty for solvation (less negative entropy). Moreover, the analysis revealed competition among the ions interacting with the gas. The structural characterization of the [P1444][TFSI] and [P1444][FSI] with the CO2 systems involved radial and spatial distribution functions. The gas was likely enveloped by an anion cage, and oxygen and fluorine exhibited greater interactions with the carbon atom of CO2 than nitrogen. The viscosity and density were also calculated for the two systems, and the addition of CO2 only caused a slight change on these values. Experiments on viscosity and density confirmed the computational results; here, compared with those of neat ionic liquids, an approximate 4 % decrease in the viscosity of CO2-saturated systems was observed. Finally, the actual CO2 solubility in [P1444][TFSI] was experimentally determined to be 120 mM; this value was nearly four times greater than those of typical aqueous bicarbonate solutions.

Experimental research on the bubble dynamic characteristics during carbon capture in the novel prepared functionalized porous ionic liquids

Porous ionic liquids have received widespread attention as one of the novel CO2 absorbers to reduce CO2 produced by the combustion of fossil fuels. Based on this, the CO2 capture experiments are conducted in ionic liquids ([TEP][MIm] and [TEP][FA]), and the porous ionic liquid (ZIF-8/[TEP][MIm]). The dynamic characteristics of CO2 bubbles in different concentrations of ZIF-8/[TEP][MIm] liquid are researched. The results show that the CO2 capture capacity of the aqueous solution with a concentration of [TEP][MIm] of 20 wt% reaching 2.06 mol/mol ILs. The optimal addition amount of ZIF-8 in the porous ionic liquid using the ethylene glycol as a cosolvent is 1.0 g/100 g, and the maximum CO2 capture amount is about 2.22 mol/mol. Furthermore, the aspect ratio and cross-sectional ratio of CO2 bubbles generated by the four nozzles decrease with the increase of ZIF-8 and [TEP][MIm] concentrations, and the difference between the extreme values of CO2 equivalent diameter under experimental conditions is about 0.513 cm. In addition, the Eo number decreases with the rise of CO2 bubble, and the maximum different value is about 2.94. This work explores the dynamic characteristics of CO2 bubbles in ZIF-8/[TEP][MIm] within a bubbling tower, aiming to optimize the CO2 capture process and provide a valuable reference for advancements in the carbon capture, utilization, and storage technology.

Transcutaneous CO2 application combined with low-intensity pulsed ultrasound accelerates bone fracture healing in rats

BackgroundLow-intensity pulsed ultrasound (LIPUS) is a non-invasive therapy that accelerates fracture healing. As a new treatment method for fracture, we recently reported that the transcutaneous application of CO2 accelerated fracture healing in association with promoting angiogenesis, blood flow, and endochondral ossification. We hypothesized that transcutaneous CO2 application, combined with LIPUS, would promote bone fracture healing more than the single treatment with either of them.MethodsFemoral shaft fractures were produced in 12-week-old rats. Animals were randomly divided into four groups: the combination of CO2 and LIPUS, CO2, LIPUS, and control groups. As the transcutaneous CO2 application, the limb was sealed in a CO2-filled bag after applying hydrogel that promotes CO2 absorption. Transcutaneous CO2 application and LIPUS irradiation were performed for 20 min/day, 5 days/week. At weeks 1, 2, 3, and 4 after the fractures, we assessed the fracture healing process using radiography, histology, immunohistochemistry, real-time PCR, and biomechanical assessment.ResultsThe fracture healing score using radiographs in the combination group was significantly higher than that in the control group at all time points and those in both the LIPUS and CO2 groups at weeks 1, 2, and 4. The degree of bone fracture healing in the histological assessment was significantly higher in the combination group than that in the control group at weeks 2, 3, and 4. In the immunohistochemical assessment, the vascular densities of CD31- and endomucin-positive microvessels in the combination group were significantly higher than those in the control and LIPUS groups at week 2. In the gene expression assessment, significant upregulation of runt-related transcription factor 2 (Runx2) and vascular endothelial growth factor (VEGF) was detected in the combination group compared to the LIPUS and CO2 monotherapy groups. In the biomechanical assessment, the ultimate stress was significantly higher in the combination group than in the LIPUS and CO2 groups.ConclusionThe combination therapy of transcutaneous CO2 application and LIPUS had a superior effect in promoting fracture healing through the promotion of angiogenesis and osteoblast differentiation compared to monotherapy.

Investigation of the formation and variability of dissolved inorganic carbon and dissolved organic carbon in the water of a small river (on the example of the Styr River, Ukraine).

This paper presents the results of a study on the dynamics in the concentrations of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) in water samples collected from the Styr River between 2019 and 2022. The concentrations of DIC and DOC were measured using an Elementar liqui TOC II analyzer. The study methodology involved analyzing the changes in DIC and DOC concentrations and their relationship with flow rates, temperature, seasonality, and other indicators such as hydrogen pH levels, total alkalinity (TA), and total dissolved solids (TDS). The purpose of this article is to identify patterns in the formation and changes of DIC and DOC concentrations in the Styr River. The concentrations of DIC and DOC in the samples ranged from 1.55 to 4.93mM and 0.49 to 1.43mM, respectively, with DOC accounting for an average of 22% of the total dissolved carbon content. The highest DOC concentrations were observed in summer, while the highest DIC concentrations were observed in winter. Based on the results, it can be concluded that water flow and temperature have an impact on DOC concentration, while flow, temperature, and pH affect DIC concentration. There was no correlation between DIC and DOC concentrations, but a strong positive relationship (r = 0.9056, p < 0.001) was found between DIC and TA concentrations. Therefore, the main factors influencing DIC in the Styr River are those that affect the carbonate equilibrium, such as leaching of carbonate and silicate rocks, CO2 absorption from the atmosphere, and changes in pH. Additionally, the concentration of DOC is influenced by biological activity and is higher during the warm season. These findings can be used to develop a strategy for managing water resources in the Styr River basin and to assess and predict the ecological state of the river.

Experimental investigation of CO2 absorption enhancement with functionalized MWCNT

Experimental investigation of CO2 absorption enhancement with functionalized MWCNT

A molecular study of CO2 adsorption performance of functionalized Mg-MOF-74 at different water vapor concentrations and pressures

This study numerically evaluates the CO2 adsorption capability of functionalized Mg-MOF-74 at different water vapor concentrations and pressures. The −O-Li- and –NO2 display the most advantageous adsorption locations for CO2 and enhance the adsorption energy for H2O within the secondary building unit region. The enhancement of CO2 adsorption at 1 bar is achieved through the incorporation of Li-O and –NO2, whereas introducing –CH3 improves the selectivity of Mg-MOF-74 towards CO2/H2O. The absorption of CO2 at 10 bar is influenced by the available void space within the pores and altering the functional groups leads to a reduced porosity, thereby hindering the CO2 adsorption. However, –CH3 can effectively improve the CO2/H2O selectivity. The increased CO2 adsorption sites by the functionalization is more advantageous for enhancing CO2 adsorption capacity in gas/vapor mixtures at low pressures. Furthermore, enhancing absorbent hydrophobicity results in an enhanced selectivity for CO2/H2O, thereby facilitating CO2 adsorption at elevated pressures.